CN106635282A - High-wearing-resistance sewing-machine oil composition and purposes thereof - Google Patents

High-wearing-resistance sewing-machine oil composition and purposes thereof Download PDF

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Publication number
CN106635282A
CN106635282A CN201610833619.XA CN201610833619A CN106635282A CN 106635282 A CN106635282 A CN 106635282A CN 201610833619 A CN201610833619 A CN 201610833619A CN 106635282 A CN106635282 A CN 106635282A
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Prior art keywords
sewing machine
wear
resistant
fluid composition
weight
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CN201610833619.XA
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Chinese (zh)
Inventor
熊星
朱明�
王靖宇
李谨
严丽珍
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China Petroleum and Chemical Corp
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China Petroleum and Chemical Corp
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Priority to CN201610833619.XA priority Critical patent/CN106635282A/en
Publication of CN106635282A publication Critical patent/CN106635282A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/045Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/287Partial esters
    • C10M2207/289Partial esters containing free hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/047Thioderivatives not containing metallic elements
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention relates to a high-wearing-resistance sewing-machine oil composition and purposes thereof. The high-wearing-resistance sewing-machine oil composition mainly solves the problem of wearing of parts of high-speed sewing-machines such as bearings, cams, worms and gears under high-speed movement. The high-wearing-resistance sewing-machine oil composition is composed of, by weight part, a) 0.2-1.5 parts of extreme-pressure anti-wear reagent, b) 0.1-1 part of antioxygen, c) 0.05-1 part of antirust agent, d) 0-0.1 part of defoamer and e) 96.4-99.65 parts of base oil. The high-wearing-resistance sewing-machine oil composition can well solve the problem and is applicable to lubrication of the high-speed sewing-machines.

Description

High wear-resistant held sewing machine fluid composition and application thereof
Technical field
The present invention relates to a kind of high wear-resistant held sewing machine fluid composition and application thereof.
Background technology
The manufacturing development of sewing machine has had the history of more than 150 years, in the evolution of sewing machine, sewing Constantly the mark of upgrading is exactly to stitch speed constantly accelerating to be lifted to technology.In the early days of foundation, China can only produce seam speed and be not more than The Purely mechanical domestic sewing machine of 1500r/min;It is 3000r/min that the 60 to 70's of eighties of last century develops into and can produce seam speed Middling speed industrial sewing machine;Nowadays, the seam speed of domestic sewing machine has reached the level of 8000r/min, and realizes substantially Electromechanical integration, occur in that part ultrahigh speed industrial sewing machine.Sewing machine makes each fitness machine as a mechanical system, high speed The fretting wear aggravation of structure, common sewing machine oil met should not sewing machine high speed at present lubricating requirement.Therefore, improve The Extreme-pressure antiwear of sewing machine oil is the inevitable requirement of sewing machine high speed.
Document《Wear-resisting sewing machine oil》(Qingdao City south petrochemical plant) discloses a kind of sewing machine oil, and the country there is no Wear-resisting sewing machine oil, to the moving component of various sewing machines, particularly industrial sewing machines preferable protective effect can be played.Text Offer the specification of quality for describing sewing machine oil, including kinematic viscosity, acid number, ash content, flash-point (remaining silent), water-soluble acid and alkali, machine Tool impurity, moisture and corrosion, but the concrete data of concrete anti-wear performance are not provided, formula is also not disclosed.Document《Special 18 is high The development of fast industrial sewing machine oil》(Hu Wenlong, Jiang Lianming, Zhejiang chemical industry the 1st phase of volume 23) discloses a kind of sewing machine oil, main The component is wanted to be:Base oil, viscosity index improver, pour-point depressant, extreme pressure anti-wear additives, defoamer of certain cut etc., can be used for The lubrication of 7000 revs/min of overedgers, wherein in the experiment of four balls, maximum nonseizure load PB values are up to 627N, and wear scar diameter is most It is low for 0.31mm.
In sum, the wear scar diameter of sewing machine oil is reduced, its abrasion resistance is improved and will further be expanded sewing machine oil and exist Application on high speed sewing machine.
The content of the invention
The technical problem to be solved is bearing, cam and the worm gear that prior art has high speed sewing machine equipment A kind of wear problem of the worm screw part under high-speed motion, there is provided new high wear-resistant held sewing machine fluid composition.
To solve above-mentioned technical problem, the technical solution used in the present invention is as follows:A kind of high wear-resistant held sewing machine oil combination Thing, is made up of in terms of parts by weight following component:
A) 0.2~1.5 part of extreme pressure anti-wear additives;
B) 0.1~1 part of antioxidant;
C) 0.05~1 part of antirust agent;
D) 0~0.1 part of defoamer;
E) 96.4~99.65 parts of base oils;
The extreme pressure anti-wear additives selected from fatty alcohol ether phosphate, trithiophenyl phosphate, dialkyl thiocarbamic acid zinc, In phosphite ester, dialkyl dithiophosphate, amine neutralising phosphoric acid ester, D2EHDTPA multiple ester ammonium salt and phosphoric acid butoxyethyl It is at least one;
The antioxidant selected from 2- (2'- hydroxyl -5'- t-octyl phenyl) BTA, DBPC 2,6 ditertiary butyl p cresol, Right, in p- dioctyl diphenylamine and dialkyl diphenylamine at least one;
The antirust agent selected from alkaline dinonyl naphthalene sulfonate barium, dodecenylsuccinic acid, high base number alkyl benzene calcium sulfonate or One kind in sorbitan fatty acid ester;
At least one of the base oil in II class hydrogenation mineral oil or III class hydrogenation mineral oil.
In above-mentioned technical proposal, it is preferable that in terms of parts by weight, it is characterised in that in terms of parts by weight, extreme pressure anti-wear additives Consumption be 0.2~1 part, the consumption of antioxidant is 0.2~0.8 part, and the consumption of antirust agent is 0.1~0.5 part, the use of defoamer Measure as 0~0.05 part, the consumption of base oil is 97.65~99.5 parts.
In above-mentioned technical proposal, the extreme pressure anti-wear additives are in trithiophenyl phosphate, dialkyl dithiophosphate, amine At least one in the multiple ester ammonium salt of the phosphate and D2EHDTPA of sum.
In above-mentioned technical proposal, the base oil is selected from II -2, II -4, II -6, III -2, III -4 and III -6 hydrogenation mineral oil In at least one.
In above-mentioned technical proposal, phosphorus content is 3~6 weight % in the amine neutralising phosphoric acid ester, and nitrogen content is 1.5~3.5 Weight %;Phosphorus content is 5~10 weight % in the multiple ester ammonium salt of the D2EHDTPA, and nitrogen content is 1~2 weight %, and sulfur content is 8 ~12 weight %.
Component of the present invention is colourless or light color, and the composition outward appearance is colourless transparent liquid.
The present invention also provides a kind of purposes of the composition, and the high wear-resistant held sewing machine fluid composition is used to stitch at a high speed Thread the lubrication of machine equipment.
The preparation method of the high wear-resistant held sewing machine fluid composition of the present invention is as follows:Reactor, unlatching is added to stir base oil Mix, then extreme pressure anti-wear additives, antirust agent and antioxidant are added into reactor, be warming up to 50~60 DEG C and continue to stir 1~2 hour directly To composition clear, defoamer is added to continue to stir 0.3-0.5 hours until composition clear, obtains final product the sewing machine Fluid composition.
The present invention is matched somebody with somebody in the case that in the phase, addition is less by preferred extreme pressure anti-wear additives with antioxidant, antirust agent 5, and the hydrogenated base oil of colourless high viscosity index (HVI) is selected, high wear-resistant held sewing machine fluid composition is obtained, wear scar diameter reaches 0.25mm, PB value reaches 1167N, meets the lubricating requirement of high speed sewing machine equipment, while sewing machine oil composition has preferably Rustless property and antioxygenic property, usage cycles are long, achieve preferable technique effect.
Below by embodiment, the invention will be further elaborated.
Specific embodiment
【Embodiment 1~7】
High wear-resistant held sewing machine fluid composition each component and its content are shown in Table 1.
Table 1
【Comparative example 1】
According to document《The development of special 18 high-speed industrial sewing machines oil》Comparative example 1 (base oil of certain cut, viscosity index (VI) Modifier, pour-point depressant, extreme pressure anti-wear additives, defoamer etc., because document does not announce Ju Ti Pei Fang, therefore data in citation), go forward side by side Row wear scar diameter and maximum nonseizure load are detected, as a result such as table 2:
Will【Embodiment 1~6】Wear resistence and maximum nonseizure load, such as table 2 are carried out with existing sewing machine oil.
Table 2
Project Outward appearance Wear scar diameter, mm (196N, 30min) PB, N
Test method Range estimation SH/T 0189 GB/T 3142
Embodiment 1 Colourless transparent liquid 0.33 461
Embodiment 2 Colourless transparent liquid 0.27 834
Embodiment 3 Colourless transparent liquid 0.29 834
Embodiment 4 Colourless transparent liquid 0.25 1167
Embodiment 5 Colourless transparent liquid 0.28 981
Embodiment 6 Colourless transparent liquid 0.26 1118
Comparative example 1 Colourless transparent liquid 0.31 637
As shown in Table 2, the high wear-resistant sewing machine oil composition appearance colorless of the present invention is transparent, wear scar diameter very little, PB values compared with Height, with excellent extreme pressure and antiwear behavior.

Claims (5)

1. a kind of high wear-resistant held sewing machine fluid composition, is made up of in terms of parts by weight following component:
A) 0.2~1.5 part of extreme pressure anti-wear additives;
B) 0.1~1 part of antioxidant;
C) 0.05~1 part of antirust agent;
D) 0~0.1 part of defoamer;
E) 96.4~99.65 parts of base oils;
The extreme pressure anti-wear additives are selected from fatty alcohol ether phosphate, trithiophenyl phosphate, dialkyl thiocarbamic acid zinc, phosphorous In the multiple ester ammonium salt of acid esters, dialkyl dithiophosphate, amine neutralising phosphoric acid ester, D2EHDTPA and phosphoric acid butoxyethyl at least It is a kind of;
The antioxidant is p- selected from 2- (2'- hydroxyl -5'- t-octyl phenyl) BTA, BHT, right At least one in dioctyl diphenylamine and dialkyl diphenylamine;
The antirust agent is selected from alkaline dinonyl naphthalene sulfonate barium, dodecenylsuccinic acid, high base number alkyl benzene calcium sulfonate or dehydration One kind in Span;
At least one of the base oil in II class hydrogenation mineral oil or III class hydrogenation mineral oil.
2. high wear-resistant held sewing machine fluid composition according to claim 1, it is characterised in that the extreme pressure anti-wear additives are thio At least one in triphenyl phosphate, dialkyl dithiophosphate, the phosphate of amine neutralization and the multiple ester ammonium salt of D2EHDTPA.
3. high wear-resistant held sewing machine fluid composition according to claim 1, it is characterised in that the base oil selected from II -2, At least one in II -4, II -6, III -2, III -4 and III -6 hydrogenation mineral oil.
4. high wear-resistant held sewing machine fluid composition according to claim 1, it is characterised in that phosphorus in the amine neutralising phosphoric acid ester Content is 3~6 weight %, and nitrogen content is 1.5~3.5 weight %;Phosphorus content is 5~10 weights in the multiple ester ammonium salt of the D2EHDTPA Amount %, nitrogen content is 1~2 weight %, and sulfur content is 8~12 weight %.
5. arbitrary high wear-resistant held sewing machine fluid composition is used for the lubrication of high speed sewing machine equipment in Claims 1 to 4.
CN201610833619.XA 2016-09-20 2016-09-20 High-wearing-resistance sewing-machine oil composition and purposes thereof Pending CN106635282A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108587739A (en) * 2017-12-18 2018-09-28 上海摩克润滑油技术有限公司 A kind of synthesis worm and gear lubricating oil
CN114479994A (en) * 2020-11-13 2022-05-13 中国石油天然气股份有限公司 Sewing machine oil composition

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676342A (en) * 1969-12-01 1972-07-11 Exxon Research Engineering Co Lubricant for textile machinery
CN104263478A (en) * 2014-09-24 2015-01-07 中国石油化工股份有限公司 Easy-to-clean antirust knitting machine oil composition and use thereof
CN104342254A (en) * 2014-09-24 2015-02-11 中国石油化工股份有限公司 Highly wear-resistant type knitting oil composition and applications thereof
CN105238526A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Knitting machine oil composite and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676342A (en) * 1969-12-01 1972-07-11 Exxon Research Engineering Co Lubricant for textile machinery
CN104263478A (en) * 2014-09-24 2015-01-07 中国石油化工股份有限公司 Easy-to-clean antirust knitting machine oil composition and use thereof
CN104342254A (en) * 2014-09-24 2015-02-11 中国石油化工股份有限公司 Highly wear-resistant type knitting oil composition and applications thereof
CN105238526A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Knitting machine oil composite and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108587739A (en) * 2017-12-18 2018-09-28 上海摩克润滑油技术有限公司 A kind of synthesis worm and gear lubricating oil
CN114479994A (en) * 2020-11-13 2022-05-13 中国石油天然气股份有限公司 Sewing machine oil composition
CN114479994B (en) * 2020-11-13 2022-11-04 中国石油天然气股份有限公司 Sewing machine oil composition

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