CN104342254B - High wear-resistant type knitting machine oil composition and application thereof - Google Patents

High wear-resistant type knitting machine oil composition and application thereof Download PDF

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Publication number
CN104342254B
CN104342254B CN201410494831.9A CN201410494831A CN104342254B CN 104342254 B CN104342254 B CN 104342254B CN 201410494831 A CN201410494831 A CN 201410494831A CN 104342254 B CN104342254 B CN 104342254B
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knitting machine
wear
machine oil
ester
resistant type
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CN104342254A (en
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熊星
王靖宇
朱明�
李谨
严丽珍
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China Petroleum and Chemical Corp
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China Petroleum and Chemical Corp
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Abstract

The present invention relates to a kind of high wear-resistant type knitting machine oil composition and application thereof, mainly solves the problem of knitting needle, syringe and three corner wears that prior art has knitting equipment, knitting machine oil wear resistence difference.The present invention is made up of following component by using being counted with parts by weight:A) 0.2~1 part of extreme pressure anti-wear additives;B) 0.2~3 part of emulsifying agent;C) 0.1~1 part of antioxidant;D) 0.05~0.3 part of antirust agent;E) technical scheme of 95~99 parts of base oil preferably solves the problem, the lubrication available for high speed circular cyiinder knitting machine seamless knitting equipment.

Description

High wear-resistant type knitting machine oil composition and application thereof
Technical field
The present invention relates to a kind of high wear-resistant type knitting machine oil composition and application thereof.
Background technology
With electronics, the continuous progress of industrial technology such as automatically control, knitting is also to automatic, high-speed and high-efficiency direction Development, but the thing followed is the increased wear of knitting needle and syringe, temperature rise, therefore modern knitting equipment is especially without suture needle Lubricity and cooling requirement of the loom to knitting machine oil proposes higher requirement.The quality of knitting machine oil quality directly affects To the service life of knitting needle and the quality of product.But existing market upper inlet knitting machine oil price, and domestic knitting machine oil resists Poor-performing is ground, corrodes machine parts, easy the shortcomings of polluting fabric.
Therefore, must possess excellent wearability first suitable for the knitting machine oil of high speed knitting equipment now, reduction is knitted The abrasion of pin and syringe, extend its service life;In addition, knitting machine oil outward appearance is wanted water white transparency and easily washed away from fabric, Prevent from polluting fabric;Possess certain rust-preventing characteristic, prevent equipment from getting rusty and corroding;With higher cost performance.Patent CN101235336A《High abrasion-resisting easy-cleaning knitting machine oil composition》Disclose it is a kind of be applied to circular disc knitting machine, footwear machine with The knitting machine oil of the equipment lubrications such as inner wear machine, including following component and weight percentage:Base oil 70~95%, activating agent 1 ~10%, emulsifying agent 1~10%, cleaning agent 1~10%.The knitting machine oil possesses good lubricity, wear resistence, rust-preventing characteristic with And the features such as cleaning, wear scar diameter minimum 0.43mm.Patent CN1995302A《Emulsifiable oil for knitting》Disclose a kind of for spinning Knit, weave process as lubrication, the fluid composition of antistatic, antirust and cooling, including 85~92% by a variety of viscous Degree base oil compounding the mineral type base oil and 8~15% additive that form, the additive include emulsifying agent, antirust agent, Anti-friction composition, antioxidant, metal deactivator and distilled water, wear scar diameter 0.44mm.Therefore, the wear scar diameter of knitting machine oil is reduced Its application will further be expanded.
The content of the invention
One of technical problems to be solved by the invention are knitting needle, syringe and the triangle mill that prior art has knitting equipment A kind of damage, the problem of knitting machine oil wear resistence difference, there is provided new high wear-resistant knitting machine oil composition.Said composition can be used at a high speed The lubrication of circular cyiinder knitting machine and seamless knitting equipment, has the characteristics of wear resistence is good, while provides cooling down, prevent well for equipment Rust acts on, and ensures that knitting process is smoothed out.The two of the technical problems to be solved by the invention are to provide a kind of and solution technology The purposes of the corresponding high wear-resistant type knitting machine oil composition of one of problem.
To solve one of above-mentioned technical problem, the technical solution adopted by the present invention is as follows:A kind of high wear-resistant type knitting machine oil Composition, counted with parts by weight and be made up of following component:
A) 0.2~1 part of extreme pressure anti-wear additives;
B) 0.2~3 part of emulsifying agent;
C) 0.1~1 part of antioxidant;
D) 0.05~0.3 part of antirust agent;
E) 95~99 parts of base oil;
The extreme pressure anti-wear additives are selected from phosphorous acid two (2- ethylhexyls) ester, phosphorous acid two (octadecylene base) ester, castor oil Phosphate, fatty alcohol ether phosphate, different tridecyl alcohol phosphate ester, Tryfac 5573, phosphoric acid butoxyethyl, amine neutralising phosphoric acid ester At least one of;
The emulsifying agent is in AEO, polyoxyethylene carboxylate or APES At least one;
The antioxidant is selected from 2- (2'- hydroxyl -5'- aminomethyl phenyls) BTA, 2- (2'- hydroxyl -5'- t-octyl benzene Base) BTA, Irganox L135 phenol, at least one of Vanlube BHC phenol;
The antirust agent is selected from alkaline dinonyl naphthalene sulfonate barium, middle base number calcium mahogany sulfonate or sorbitan fatty acid ester In one kind;
The base oil is selected from least one of II class hydrogenation mineral oil or III class hydrogenation mineral oil.
In above-mentioned technical proposal, the amine neutralising phosphoric acid ester, its phosphorus content is 3~10 weight %, and nitrogen content is 1.5~4 Weight %.
To solve the two of above-mentioned technical problem, the technical solution adopted by the present invention is as follows:The wear-resistant type knitting machine oil of height Composition is used for the lubrication of high speed circular cyiinder knitting machine and seamless knitting equipment.
The preparation method of high wear-resistant type knitting machine oil composition of the invention is as follows:Base oil is added into reactor, unlatching is stirred Mix, then by extreme pressure anti-wear additives, emulsifying agent and antioxidant add reactor, be warming up to 55~65 DEG C continue stir 1-2 hours it is straight To composition clear, the knitting machine oil composition is produced.
The present invention by preferred extreme pressure anti-wear additives, in the case where extreme pressure anti-wear additives addition is few with emulsifying agent, antioxygen Agent carries out compatibility, and selects the hydrogenated base oil of colourless high viscosity index (HVI), obtains high wear-resistant type knitting machine oil composition, and mill spot is straight Footpath reaches 0.28mm, meets high speed circular knitting machine, the lubricating requirement of seamless knitting equipment, while provide well cold for equipment But, anti-rust action, preferable technique effect is achieved.
Below by embodiment, the invention will be further elaborated.
Embodiment
【Embodiment 1~7】
High wear-resistant type knitting machine oil composition each component and its content are shown in Table 1.
Table 1
Will【Embodiment 1~7】Wear resistence detection is carried out with existing knitting machine oil, such as table 2.
【Comparative example 1】
Wear resistence detection is carried out from domestic knitting machine oil (Bamda cylinder knitting machine oil), as a result such as table 2.
【Comparative example 2】
According to document CN101235336《High abrasion-resisting easy-cleaning knitting machine oil composition》Embodiment 2 (5cst60 parts, 5# 21 parts of white oil, 10 parts of butyl phthalate, RL-33 parts, 4 parts of oleic acid, TX-101 parts, Span801 parts) disclosure preparation Composition, and wear resistence detection is carried out, as a result such as table 2.
Table 2
Project Outward appearance Wear scar diameter (mm) Corrosion (steel disc, 100 DEG C, 3h)
Test method Range estimation SH/T 0189 SH/T0195
Embodiment 1 Colourless transparent liquid 0.32 It is qualified
Embodiment 2 Colourless transparent liquid 0.37 It is qualified
Embodiment 3 Colourless transparent liquid 0.34 It is qualified
Embodiment 4 Colourless transparent liquid 0.33 It is qualified
Embodiment 5 Colourless transparent liquid 0.28 It is qualified
Embodiment 6 Colourless transparent liquid 0.35 It is qualified
Comparative example 1 Colourless transparent liquid 0.42 It is qualified
Comparative example 2 Colourless transparent liquid 0.43 It is qualified
As shown in Table 2, the abrasion resistance of the high wear-resistant knitting machine oil composition of the present invention is better than common domestic knitting machine oil.
The wear-resistant type knitting machine oil composition of height is applied on certain factory's seamless underwear machine, and production practices show, the present invention The lubricity of knitting machine oil is good, wear-resistant sexual satisfaction technological requirement, and product water white transparency easy cleaning, will not pollute fabric, obtain Producer is approved.

Claims (2)

1. a kind of high wear-resistant type knitting machine oil composition is used for the purposes of the lubrication of high speed circular cyiinder knitting machine and seamless knitting equipment, The wear-resistant type knitting machine oil composition of height, is counted with parts by weight and is made up of following component:
A) 0.2~1 part of extreme pressure anti-wear additives;
B) 0.2~3 part of emulsifying agent;
C) 0.1~1 part of antioxidant;
D) 0.05~0.3 part of antirust agent;
E) 95~99 parts of base oil;
The extreme pressure anti-wear additives are selected from phosphorous acid two (2- ethylhexyls) ester, phosphorous acid two (octadecylene base) ester, castor-oil plant oleophosphoric acid In ester, fatty alcohol ether phosphate, different tridecyl alcohol phosphate ester, Tryfac 5573, phosphoric acid butoxyethyl, amine neutralising phosphoric acid ester It is at least one;
The emulsifying agent in AEO, polyoxyethylene carboxylate or APES extremely Few one kind;
The antioxidant is selected from 2- (2'- hydroxyl -5'- aminomethyl phenyls) BTA, 2- (2'- hydroxyl -5'- t-octyls phenyl) benzene And at least one of triazole, Irganox L135 phenol, Vanlube BHC phenol;
The antirust agent is in alkaline dinonyl naphthalene sulfonate barium, middle base number calcium mahogany sulfonate or sorbitan fatty acid ester It is a kind of;
The base oil is selected from least one of II class hydrogenation mineral oil or III class hydrogenation mineral oil.
2. high wear-resistant type knitting machine oil composition is used for high speed circular cyiinder knitting machine and seamless knitting equipment according to claim 1 Lubrication purposes, it is characterised in that the amine neutralising phosphoric acid ester, its phosphorus content are 3~10 weight %, and nitrogen content is 1.5~4 Weight %.
CN201410494831.9A 2014-09-24 2014-09-24 High wear-resistant type knitting machine oil composition and application thereof Active CN104342254B (en)

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Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105238526A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Knitting machine oil composite and application thereof
CN105623814B (en) * 2016-02-04 2019-10-18 江苏龙蟠科技股份有限公司 Advanced knitting machine oil of a kind of degradable type of environmental protection and preparation method thereof
CN106520258B (en) * 2016-08-31 2019-04-02 江苏龙蟠科技股份有限公司 A kind of emulsifier and the preparation method and application thereof
CN106635282A (en) * 2016-09-20 2017-05-10 中国石油化工股份有限公司 High-wearing-resistance sewing-machine oil composition and purposes thereof
CN106479646A (en) * 2016-10-09 2017-03-08 纷响新材料科技(上海)有限公司 A kind of Knitting Machinery lubricating oil
CN111471509A (en) * 2020-03-18 2020-07-31 江苏悦孚油品有限公司 Knitting auxiliary agent with good extreme pressure wear resistance and preparation process thereof
CN111635806A (en) * 2020-05-27 2020-09-08 中国石油化工股份有限公司 Naturally degradable knitting machine oil composition, preparation method and application thereof
CN111635807B (en) * 2020-05-27 2022-06-24 中国石油化工股份有限公司 Warp knitting machine lubricating oil composition, preparation method and application thereof
CN114574269A (en) * 2020-12-02 2022-06-03 中国石油化工股份有限公司 Oxidation-resistant long-life knitting machine oil composition
CN112522014A (en) * 2020-12-14 2021-03-19 滨州市坤厚工贸有限责任公司 Knitting machine oil composition and preparation method thereof

Citations (4)

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US5213700A (en) * 1991-05-20 1993-05-25 Texaco Inc. Method of lubricating a textile machine
CN1807565A (en) * 2006-02-14 2006-07-26 中国石油化工股份有限公司 Lubricant composition for computer flat-knitting machine
CN1865417A (en) * 2006-04-29 2006-11-22 甘一凡 Shuttle-free lubricant and its preparation method
CN103865620A (en) * 2014-04-09 2014-06-18 刘佩仓 Special lubricating oil for dobby

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5213700A (en) * 1991-05-20 1993-05-25 Texaco Inc. Method of lubricating a textile machine
CN1807565A (en) * 2006-02-14 2006-07-26 中国石油化工股份有限公司 Lubricant composition for computer flat-knitting machine
CN1865417A (en) * 2006-04-29 2006-11-22 甘一凡 Shuttle-free lubricant and its preparation method
CN103865620A (en) * 2014-04-09 2014-06-18 刘佩仓 Special lubricating oil for dobby

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