CN105238526A - Knitting machine oil composite and application thereof - Google Patents

Knitting machine oil composite and application thereof Download PDF

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Publication number
CN105238526A
CN105238526A CN201510681132.XA CN201510681132A CN105238526A CN 105238526 A CN105238526 A CN 105238526A CN 201510681132 A CN201510681132 A CN 201510681132A CN 105238526 A CN105238526 A CN 105238526A
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China
Prior art keywords
knitting machine
ester
machine oil
oil composition
parts
Prior art date
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Pending
Application number
CN201510681132.XA
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Chinese (zh)
Inventor
熊星
王靖宇
朱明�
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China Petroleum and Chemical Corp
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China Petroleum and Chemical Corp
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Application filed by China Petroleum and Chemical Corp filed Critical China Petroleum and Chemical Corp
Priority to CN201510681132.XA priority Critical patent/CN105238526A/en
Publication of CN105238526A publication Critical patent/CN105238526A/en
Pending legal-status Critical Current

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Abstract

The invention relates to a knitting machine oil composition and application thereof. The main problems that in the prior art, biological degradability is poor, the environment is polluted, and a knitting needle, a needle cylinder and a cam of knitting equipment are abraded are solved. The knitting machine oil composition is prepared from, by weight, 90-99 parts of base oil, 0.2-2 parts of anti-wear reagent at extreme pressure, 0.5-5 parts of emulsifying agents, 0.2-2 parts of antioxidant and 0-0.5 part of antirust agent. According to the technical scheme, the problems are solved well, and the knitting machine oil composition can be used for lubricating a high-speed cylinder knitting machine or seamless knitting equipment.

Description

Knitting machine oil composition and uses thereof
Technical field
The present invention relates to a kind of knitting machine oil composition and uses thereof.
Background technology
Knitting machine oil is in knitting process, reduce the special lube of knitting equipment as position wearing and tearing such as knitting needle, triangular plate and sinkers.Along with the continuous progress of knitting technology and the reinforcement of environmental protection ideas, knitting machine oil not only will meet the lubricating requirement that in high speed knitting process, the parts such as knitting needle and syringe are higher, reduces wearing and tearing, increases the work-ing life of oil product, and the pollution that will as far as possible reduce environment, accomplish environmental protection.Knitting machine oil base oil is in the past generally be prepared by raw material with oil, and the knitting machine oil biodegradability of mineral oil based is poor, and prolonged stay can pollute water and soil.Biological degradability and the mineral oil of synthesis hydrocarbon are more or less the same.In addition, knitting machine oil color is wanted shallow and is easily washed away from fabric, preventing pollution fabric; Possess certain rust-preventing characteristic, prevent equipment from getting rusty and corrosion.
Document CN102071091A discloses a kind of knitting machine oil, and wherein base oil is three hydrogenated base oils, and content is 40 ~ 60%, but does not investigate the performances such as its lubrication cleaning.Document CN1995302A disclose a kind of for weave, weave the course of processing as lubrication, antistatic, antirust and cooling fluid composition, comprise the mineral type base oil composite by multiple viscosity base oil of 85 ~ 92% and the additive of 8 ~ 15%.Document CN101235336A discloses a kind of knitting machine oil being applicable to the equipment lubrications such as circular disc knitting machine, hosiery machine and inner wear machine, comprise following component and weight percentage: base oil 70 ~ 95%, promoting agent 1 ~ 10%, emulsifying agent 1 ~ 10%, clean-out system 1 ~ 10%.This knitting machine oil possesses good oilness, resistance to abrasion, the feature such as rust-preventing characteristic and cleaning, the minimum 0.43mm of wear scar diameter.
In sum, the knitting machine oil of prior art cannot meet biodegradability and higher lubricity simultaneously.
Summary of the invention
One of technical problem to be solved by this invention is that prior art exists biological degradability difference, produces pollute environment, and the knitting needle of knitting equipment, syringe and three corner wears problem, a kind of new knitting machine oil composition is provided.Said composition has good biological degradability and resistance to abrasion, simultaneously for equipment provides good cooling, rust inhibition, ensures that knitting process carries out smoothly.Two of technical problem to be solved by this invention is to provide a kind of purposes of the knitting machine oil composition corresponding with one of technical solution problem.
For one of solving the problems of the technologies described above, the technical solution used in the present invention is as follows: a kind of knitting machine oil composition, with weight parts, is made up of following component:
A) base oil of 90 ~ 99 parts;
B) 0.2 ~ 2 part of extreme pressure anti-wear additives;
C) 0.5 ~ 5 part of emulsifying agent;
D) 0.2 ~ 2 part of oxidation inhibitor;
E) 0 ~ 0.5 part of rust-preventive agent;
Described base oil is selected from least one in vegetable and animals oils, monoesters, neopentyl alcohol ester, dibasic acid esters, phthalic ester, trihydroxymethylpropanyl ester, pentaerythritol ester or multiple ester;
Described extreme pressure anti-wear additives is selected from least one in tritolyl phosphate, triphenyl-thiophosphate, castor oil phosphate ester, phosphorous acid ester three certain herbaceous plants with big flowers ester, dialkyl dithiophosphate, phosphoric acid butoxyethyl or amine neutralising phosphoric acid ester;
Described emulsifying agent is selected from least one in fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester or alkylphenol polyoxyethylene;
Described oxidation inhibitor is at least one in alkyl diphenylamine, composite 124 Triazole derivative, IrganoxL135 phenol or VanlubeBHC phenol;
Described rust-preventive agent is selected from the one in alkaline dinonyl naphthalene sulfonate barium, dodecenylsuccinic acid, middle base number calcium mahogany sulfonate or sorbitan fatty acid ester.
In technique scheme, preferably, described base oil is at least one in monoesters, trihydroxymethylpropanyl ester or pentaerythritol ester.
In technique scheme, preferably, described extreme pressure anti-wear additives is at least one in triphenyl-thiophosphate or amine neutralising phosphoric acid ester.
In technique scheme, preferably, with weight parts, the consumption of extreme pressure anti-wear additives is 0.3 ~ 1.5 part, and the consumption of emulsifying agent is 2 ~ 4 parts, and the consumption of oxidation inhibitor is 0.2 ~ 1.5 part, and the consumption of rust-preventive agent is 0.1 ~ 0.5 part, and the consumption of base oil is 92 ~ 97 parts.
In technique scheme, preferably, described oxidation inhibitor is the mixture of alkyl diphenylamine and IrganoxL135 phenol, or the mixture of alkyl diphenylamine and VanlubeBHC phenol.
For solve the problems of the technologies described above two, the technical solution used in the present invention is as follows: described knitting machine oil composition is used for the lubrication of high speed circular cyiinder knitting machine or seamless knitting equipment.
The preparation method of knitting machine oil composition of the present invention is as follows: base oil is added reactor, open and stir and heat up, after being warming up to 55 ~ 60 DEG C, extreme pressure anti-wear additives, emulsifying agent, oxidation inhibitor and rust-preventive agent are added reactor, holding temperature continues stirring 1 ~ 2 hour until composition clear at 55 ~ 60 DEG C, obtains described knitting machine oil composition.
The present invention is by oil based on the vegetable and animals oils with fine biodegradability or synthetic ester; and carry out compatibility with extreme pressure anti-wear additives, emulsifying agent, oxidation inhibitor, rust-preventive agent; obtain biodegradation type knitting machine oil composition; high speed circular knitting machine, the lubrication of seamless knitting equipment, antirust requirement can be met; there is higher biological degradation rate simultaneously; be conducive to environment protection, achieve good technique effect.
Below by embodiment, the invention will be further elaborated.
Embodiment
[embodiment 1 ~ 6]
Biodegradation type knitting machine oil composition each component and content thereof are in table 1.
Table 1
[comparative example 1]
According to document CN101235336 " high abrasion-resisting easy-cleaning knitting machine oil composition " comparative example 1 (5cst60 part, 5# white oil 21 parts, butyl phthalate 10 parts, RL-33 part, oleic acid 4 parts, TX-101 part, Span801 part) disclosed content prepares composition, and carry out resistance to abrasion detection, result is as table 2.
[embodiment 1 ~ 6] and existing knitting machine oil are carried out resistance to abrasion detection, as table 2.
Table 2
Note: base oil 21d biological degradability selects from Central South University gold little Rong " the synthesis and property research of green ester class base oil ".
As shown in Table 2, knitting machine oil composition of the present invention and uses thereof biological degradation rate is high, and abrasion resistance is good.
Biodegradation type knitting machine oil composition of the present invention is applied on seamless underwear machine, and production practice show, the oilness of knitting machine oil of the present invention is good, and resistance to abrasion meets processing requirement, and product water white transparency easy cleaning, can not fabric be polluted, obtain producer's accreditation.

Claims (6)

1. a knitting machine oil composition, with weight parts, is made up of following component:
A) base oil of 90 ~ 99 parts;
B) 0.2 ~ 2 part of extreme pressure anti-wear additives;
C) 0.5 ~ 5 part of emulsifying agent;
D) 0.2 ~ 2 part of oxidation inhibitor;
E) 0 ~ 0.5 part of rust-preventive agent;
Described base oil is selected from least one in vegetable and animals oils, monoesters, neopentyl alcohol ester, dibasic acid esters, phthalic ester, trihydroxymethylpropanyl ester, pentaerythritol ester or multiple ester;
Described extreme pressure anti-wear additives is selected from least one in tritolyl phosphate, triphenyl-thiophosphate, castor oil phosphate ester, phosphorous acid ester three certain herbaceous plants with big flowers ester, dialkyl dithiophosphate, phosphoric acid butoxyethyl or amine neutralising phosphoric acid ester;
Described emulsifying agent is selected from least one in fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan fatty acid ester or alkylphenol polyoxyethylene;
Described oxidation inhibitor is at least one in alkyl diphenylamine, composite 124 Triazole derivative, IrganoxL135 phenol or VanlubeBHC phenol;
Described rust-preventive agent is selected from the one in alkaline dinonyl naphthalene sulfonate barium, dodecenylsuccinic acid, middle base number calcium mahogany sulfonate or sorbitan fatty acid ester.
2. knitting machine oil composition according to claim 1, is characterized in that described base oil is at least one in monoesters, trihydroxymethylpropanyl ester or pentaerythritol ester.
3. knitting machine oil composition according to claim 1, is characterized in that described extreme pressure anti-wear additives is at least one in triphenyl-thiophosphate or amine neutralising phosphoric acid ester.
4. knitting machine oil composition according to claim 1, it is characterized in that with weight parts, the consumption of extreme pressure anti-wear additives is 0.3 ~ 1.5 part, the consumption of emulsifying agent is 2 ~ 4 parts, the consumption of oxidation inhibitor is 0.2 ~ 1.5 part, the consumption of rust-preventive agent is 0.1 ~ 0.5 part, and the consumption of base oil is 92 ~ 97 parts.
5. knitting machine oil composition according to claim 1, is characterized in that described oxidation inhibitor is the mixture of alkyl diphenylamine and IrganoxL135 phenol, or the mixture of alkyl diphenylamine and VanlubeBHC phenol.
6. in Claims 1 to 5, arbitrary described knitting machine oil composition is used for the lubrication of high speed circular cyiinder knitting machine or seamless knitting equipment.
CN201510681132.XA 2015-10-19 2015-10-19 Knitting machine oil composite and application thereof Pending CN105238526A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Publications (1)

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CN105238526A true CN105238526A (en) 2016-01-13

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105623814A (en) * 2016-02-04 2016-06-01 江苏龙蟠科技股份有限公司 Environment-friendly easily-degradable high-grade knitting machine oil and preparation method thereof
CN106635282A (en) * 2016-09-20 2017-05-10 中国石油化工股份有限公司 High-wearing-resistance sewing-machine oil composition and purposes thereof
CN109401822A (en) * 2018-11-02 2019-03-01 浙江师范大学 The environmentally friendly degradable emulsification knitting oil of one kind and its production method
CN113717778A (en) * 2021-08-23 2021-11-30 江苏悦孚油品有限公司 Synthetic oil for circular knitting machine and preparation method thereof
CN114574269A (en) * 2020-12-02 2022-06-03 中国石油化工股份有限公司 Oxidation-resistant long-life knitting machine oil composition
CN114686189A (en) * 2022-04-22 2022-07-01 中国石油天然气集团有限公司 Lubricant for water-based drilling fluid, preparation method of lubricant and water-based drilling fluid

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1807565A (en) * 2006-02-14 2006-07-26 中国石油化工股份有限公司 Lubricant composition for computer flat-knitting machine
CN1865417A (en) * 2006-04-29 2006-11-22 甘一凡 Shuttle-free lubricant and its preparation method
CN103865620A (en) * 2014-04-09 2014-06-18 刘佩仓 Special lubricating oil for dobby
CN104342254A (en) * 2014-09-24 2015-02-11 中国石油化工股份有限公司 Highly wear-resistant type knitting oil composition and applications thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1807565A (en) * 2006-02-14 2006-07-26 中国石油化工股份有限公司 Lubricant composition for computer flat-knitting machine
CN1865417A (en) * 2006-04-29 2006-11-22 甘一凡 Shuttle-free lubricant and its preparation method
CN103865620A (en) * 2014-04-09 2014-06-18 刘佩仓 Special lubricating oil for dobby
CN104342254A (en) * 2014-09-24 2015-02-11 中国石油化工股份有限公司 Highly wear-resistant type knitting oil composition and applications thereof

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Title
鲁德尼克等: "《合成润滑剂及其应用》", 31 January 2006, 中国石化出版社 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105623814A (en) * 2016-02-04 2016-06-01 江苏龙蟠科技股份有限公司 Environment-friendly easily-degradable high-grade knitting machine oil and preparation method thereof
CN105623814B (en) * 2016-02-04 2019-10-18 江苏龙蟠科技股份有限公司 Advanced knitting machine oil of a kind of degradable type of environmental protection and preparation method thereof
CN106635282A (en) * 2016-09-20 2017-05-10 中国石油化工股份有限公司 High-wearing-resistance sewing-machine oil composition and purposes thereof
CN109401822A (en) * 2018-11-02 2019-03-01 浙江师范大学 The environmentally friendly degradable emulsification knitting oil of one kind and its production method
CN114574269A (en) * 2020-12-02 2022-06-03 中国石油化工股份有限公司 Oxidation-resistant long-life knitting machine oil composition
CN113717778A (en) * 2021-08-23 2021-11-30 江苏悦孚油品有限公司 Synthetic oil for circular knitting machine and preparation method thereof
CN113717778B (en) * 2021-08-23 2022-12-06 江苏悦孚油品有限公司 Synthetic oil for circular knitting machine and preparation method thereof
CN114686189A (en) * 2022-04-22 2022-07-01 中国石油天然气集团有限公司 Lubricant for water-based drilling fluid, preparation method of lubricant and water-based drilling fluid
CN114686189B (en) * 2022-04-22 2023-10-20 中国石油天然气集团有限公司 Lubricant for water-based drilling fluid, preparation method of lubricant and water-based drilling fluid

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Application publication date: 20160113