CN109401822A - The environmentally friendly degradable emulsification knitting oil of one kind and its production method - Google Patents

The environmentally friendly degradable emulsification knitting oil of one kind and its production method Download PDF

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Publication number
CN109401822A
CN109401822A CN201811302790.3A CN201811302790A CN109401822A CN 109401822 A CN109401822 A CN 109401822A CN 201811302790 A CN201811302790 A CN 201811302790A CN 109401822 A CN109401822 A CN 109401822A
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parts
oil
knitting
emulsification
environmentally friendly
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CN201811302790.3A
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Chinese (zh)
Inventor
王爱军
冯九菊
陈得军
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Zhejiang Normal University CJNU
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Zhejiang Normal University CJNU
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Priority to CN201811302790.3A priority Critical patent/CN109401822A/en
Publication of CN109401822A publication Critical patent/CN109401822A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/24—Epoxidised acids; Ester derivatives thereof
    • C10M2207/243—Epoxidised acids; Ester derivatives thereof used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/401—Fatty vegetable or animal oils used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a kind of environmentally friendly degradable emulsification knitting oil and its production methods, belong to knitting machine oil technical field.Technical solution of the present invention main points are as follows: a kind of environmentally friendly degradable emulsification knitting oil is made of: 30-50 parts of palm oil the raw material of following parts by weight；Rapeseed oil 20-40 parts of oxidation；5-10 parts of methyl oleate；3-10 parts of tricarboxymethyl propane oleate；5-10 parts of Ethylhexyl stearate；2-7 parts of oleic acid；1-2 parts of T746；1-3 parts of triethanolamine；1-2 parts of TX-10；1-2 parts of SP-80.The invention further particularly discloses the production methods of the environmentally friendly degradable emulsification knitting oil.Emulsification knitting oil produced by the invention is conducive to the normal operation and maintenance of knitting equipment, while being also beneficial to the reaction in other products, emulsifying power and biological degradation rate can be improved, and can be effectively reduced production cost.

Description

The environmentally friendly degradable emulsification knitting oil of one kind and its production method
Technical field
The invention belongs to knitting machine oil technical fields, and in particular to a kind of environmentally friendly degradable emulsification knitting it is oily and its Production method.
Background technique
Important people's livelihood industry and conventional column industry of the textile industry as Chinese national economy, with China's conventional industries Adjustment and revitalize planning implementation, obtained further development, be increasingly becoming China with obvious international competition it is excellent One industry of gesture, at the same time, the lubrication of the modern times such as knitting needle, syringe knitting equipment, it is cooling the problems such as also continuously emerge.Tradition Fatty acid ester emulsifier, though anti-friction composition also can play a role, the antistatic of them, heat resistance, anti-scroop Property and anti-caking are poor, can not comply fully with the requirement of modern textile, and color is difficult to reach pure white degree.And it is current Knitting machine oil antirust ability in the market is weak, not easy cleaning, and corrosivity is strong, bigger for the injury of knitting equipment；And it is big Part be all by the product after diethanol amine and fatty acid phase reaction, the product obtained in this way be finally substantially all have it is remaining Diethanol amine, it is not only unhelpful to the health of human body, but also have very big harm to environment.
Be suitable at present modern knitting equipment knitting oil answer first it is harmless and be it is environmentally friendly, to have good Wear resistence, can reduce the degree of wear, prolong the service life；Secondly, the knitting machine speed of service is than very fast, knitting needle and syringe it Between friction it is very big, heating rate quickly, so knitting oil lubricity and cooling performance also must very well, prevent the originals such as broken needle Because making knitting machine can not normal use；Furthermore good anti-rust action and oxidation stability is also indispensable, Ke Yirang Equipment is used for a long time without will lead to corrosion；In addition, fabric can inevitably be infected with upper knitting machine oil during braiding, so needle The cleaning performance of loom oil is also an important index, therefore it is required that knitting machine oil will be easy to emulsify, convenient for the cleaning of fabric And washing.In summary the performance requirement that the emulsification knitting oil should have, this fluid composition should include by a variety of viscous Mineral type base oil and additive made of base oil compounding are spent, additive should include antirust agent, anti-friction composition, emulsifier, metal Passivator, antioxidant etc..
The patent of Publication No. CN101235336A, which discloses one kind, can be used for footwear machine, seamless loom, circular disc knitting machine Etc. equipment knitting machine oil, be readily cleaned, be high wear-resistant, base oil weight percentage is 70%-95%, anti-without extreme pressure in formula Grinding agent wear scar diameter is 0.43-0.63mm, but is not evaluated its rustless property, does not also describe oil product color.Publication No. The patent of CN102071091A discloses a kind of knitting machine oil, is readily cleaned, high lubricating effect, long shelf-life, base oil weight Amount percentage composition is 40%-60%, but the knitting oil can not prevent the corrosion of equipment without antirust agent component.Publication No. The patent of CN1995302A discloses a kind of fluid composition, and lubrication, cooling, antistatic, antirust can be played in fabrication processes Effect, but wear scar diameter also needs to further expand its application.The patent of Publication No. CN1995302A discloses one kind can It is knitted oil for modern textile, the emulsification for being suitble to modern weaving to require, but the antirust agent selected by it is fatty acid ammonium, Human body and natural environment can all be caused greatly to damage.
Summary of the invention
The technical problem to be solved by the present invention is to provide a kind of environmentally friendly degradable emulsification knitting oil and its producers The emulsification knitting oil of method, this method production is conducive to the normal operation and maintenance of knitting equipment, while being also beneficial in other productions Reaction in product can be improved emulsifying power and biological degradation rate, and can be effectively reduced production cost.
The present invention adopts the following technical scheme that the environmentally friendly degradable emulsification of one kind is knitted to solve above-mentioned technical problem Oil, it is characterised in that be made of the raw material of following parts by weight:
30-50 parts of palm oil；
Rapeseed oil 20-40 parts of oxidation；
5-10 parts of methyl oleate；
3-10 parts of tricarboxymethyl propane oleate；
5-10 parts of Ethylhexyl stearate；
2-7 parts of oleic acid；
1-2 parts of T746；
1-3 parts of triethanolamine；
1-2 parts of TX-10；
1-2 parts of SP-80.
Further preferably, the environmentally friendly degradable emulsification knitting oil is made of the raw material of following parts by weight:
40 parts of palm oil；
35 parts of rapeseed oil of oxidation；
6 parts of methyl oleate；
4 parts of tricarboxymethyl propane oleate；
5 parts of Ethylhexyl stearate；
3 parts of oleic acid；
2 parts of T746；
2 parts of triethanolamine；
1 part of TX-10；
2 parts of SP-80.
The production method of environmentally friendly degradable emulsification knitting oil of the present invention, it is characterised in that specific steps Are as follows: first mixed base oil palm oil and oxidation rapeseed oil are added in reaction kettle and is heated to 40 DEG C and is uniformly mixed, then Ester type compound methyl oleate, tricarboxymethyl propane oleate and Ethylhexyl stearate is added, oil is added to being completely dissolved in stirring Acid, triethanolamine and T746 are eventually adding the emulsion stability that emulsifier TX-10 and SP-80 adjust whole system, final to be made Environmentally friendly degradable emulsification knitting oil.
Product cost synthesized by the present invention is high, and used base oil is vegetable oil, the lubricity of vegetable oil Energy is good, volatility is low, viscosity index (VI) is high, nontoxic, recyclable and biological degradation rate is high, can make at technique in this, as base oil Reason energy consumption reduces, resource is renewable, Environmental diffusion is reduced and cheap.Based on vegetable oil oil be not only simple be easy to get, It is renewable, resourceful, it is able to solve oil shortage problem, and due to the biological degradation rate of its product height, it can be effectively Avoid pollution environment, additionally it is possible to push the optimization for the strategical adjustment of the structure of agricultural production, resource distribution etc..
Emulsification knitting oil produced by the invention is conducive to the normal operation and maintenance of knitting equipment, while being also beneficial at it Reaction in its product can be improved emulsifying power and biological degradation rate, and can be effectively reduced production cost.
Specific real-time mode
Above content of the invention is described in further details by the following examples, but this should not be interpreted as to the present invention The range of above-mentioned theme is only limitted to embodiment below, and all technologies realized based on above content of the present invention belong to of the invention Range.
Embodiment
Raw material (kilogram) is weighed respectively according to following weight proportion:
1, palm oil 40, oxidation rapeseed oil 35, methyl oleate 6, tricarboxymethyl propane oleate 4, Ethylhexyl stearate 5, oleic acid 3, T746 2, triethanolamine 2, TX-10 1 and SP-80 2；
2, palm oil 30, oxidation rapeseed oil 40, methyl oleate 5, tricarboxymethyl propane oleate 10, Ethylhexyl stearate 5, oleic acid 7, T746 1, triethanolamine 3, TX-10 1 and SP-80 2；
3, palm oil 50, oxidation rapeseed oil 20, methyl oleate 10, tricarboxymethyl propane oleate 3, Ethylhexyl stearate 10, oil Acid 2, T746 2, triethanolamine 1, TX-10 2 and SP-80 1.
Production method: first mixed base oil palm oil and oxidation rapeseed oil are added in reaction kettle and is heated to 40 DEG C and stirs It mixes uniformly mixed, adds ester type compound methyl oleate, tricarboxymethyl propane oleate and Ethylhexyl stearate, stirring is to complete Oleic acid, triethanolamine and T746 is added in fully dissolved, and the emulsification for being eventually adding emulsifier TX-10 and SP-80 adjusting whole system is steady It is qualitative, environmentally friendly degradable emulsification knitting oil is finally made.
Embodiment above describes basic principles and main features of the invention and advantage, the technical staff of the industry should Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe originals of the invention Reason, under the range for not departing from the principle of the invention, various changes and improvements may be made to the invention, these changes and improvements are each fallen within In the scope of protection of the invention.

Claims (3)

1. a kind of environmentally friendly degradable emulsification knitting oil, it is characterised in that be made of the raw material of following parts by weight:
30-50 parts of palm oil；
Rapeseed oil 20-40 parts of oxidation；
5-10 parts of methyl oleate；
3-10 parts of tricarboxymethyl propane oleate；
5-10 parts of Ethylhexyl stearate；
2-7 parts of oleic acid；
1-2 parts of T746；
1-3 parts of triethanolamine；
1-2 parts of TX-10；
1-2 parts of SP-80.
2. environmentally friendly degradable emulsification knitting oil according to claim 1, it is characterised in that by following parts by weight Raw material composition:
40 parts of palm oil；
35 parts of rapeseed oil of oxidation；
6 parts of methyl oleate；
4 parts of tricarboxymethyl propane oleate；
5 parts of Ethylhexyl stearate；
3 parts of oleic acid；
2 parts of T746；
2 parts of triethanolamine；
1 part of TX-10；
2 parts of SP-80.
3. a kind of production method of environmentally friendly degradable emulsification knitting oil of any of claims 1 or 2, it is characterised in that tool Body step are as follows: first mixed base oil palm oil and oxidation rapeseed oil are added in reaction kettle and is heated to 40 DEG C and is stirred It is even, add ester type compound methyl oleate, tricarboxymethyl propane oleate and Ethylhexyl stearate, stirring to being completely dissolved, Oleic acid, triethanolamine and T746 is added, is eventually adding the emulsion stability that emulsifier TX-10 and SP-80 adjust whole system, most Environmentally friendly degradable emulsification knitting oil is made eventually.
CN201811302790.3A 2018-11-02 2018-11-02 The environmentally friendly degradable emulsification knitting oil of one kind and its production method Pending CN109401822A (en)

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Application Number Priority Date Filing Date Title
CN201811302790.3A CN109401822A (en) 2018-11-02 2018-11-02 The environmentally friendly degradable emulsification knitting oil of one kind and its production method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113717778A (en) * 2021-08-23 2021-11-30 江苏悦孚油品有限公司 Synthetic oil for circular knitting machine and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10298577A (en) * 1997-04-25 1998-11-10 Kao Corp Lubricant composition
CN1807565A (en) * 2006-02-14 2006-07-26 中国石油化工股份有限公司 Lubricant composition for computer flat-knitting machine
CN1995302A (en) * 2006-12-25 2007-07-11 彭美东 Emulsifiable oil for knitting
WO2011131331A1 (en) * 2010-04-21 2011-10-27 KLüBER LUBRICATION MüNCHEN KG Use of water-based lubricants for textile machines
CN102295977A (en) * 2011-07-13 2011-12-28 李胜 Novel lubricant for sewing machine and preparation method thereof
CN105238526A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Knitting machine oil composite and application thereof
CN105623814A (en) * 2016-02-04 2016-06-01 江苏龙蟠科技股份有限公司 Environment-friendly easily-degradable high-grade knitting machine oil and preparation method thereof
CN107474906A (en) * 2017-09-25 2017-12-15 海安纺织机械有限公司 A kind of new textile machinery lubricating oil

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10298577A (en) * 1997-04-25 1998-11-10 Kao Corp Lubricant composition
CN1807565A (en) * 2006-02-14 2006-07-26 中国石油化工股份有限公司 Lubricant composition for computer flat-knitting machine
CN1995302A (en) * 2006-12-25 2007-07-11 彭美东 Emulsifiable oil for knitting
WO2011131331A1 (en) * 2010-04-21 2011-10-27 KLüBER LUBRICATION MüNCHEN KG Use of water-based lubricants for textile machines
CN102295977A (en) * 2011-07-13 2011-12-28 李胜 Novel lubricant for sewing machine and preparation method thereof
CN105238526A (en) * 2015-10-19 2016-01-13 中国石油化工股份有限公司 Knitting machine oil composite and application thereof
CN105623814A (en) * 2016-02-04 2016-06-01 江苏龙蟠科技股份有限公司 Environment-friendly easily-degradable high-grade knitting machine oil and preparation method thereof
CN107474906A (en) * 2017-09-25 2017-12-15 海安纺织机械有限公司 A kind of new textile machinery lubricating oil

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113717778A (en) * 2021-08-23 2021-11-30 江苏悦孚油品有限公司 Synthetic oil for circular knitting machine and preparation method thereof
CN113717778B (en) * 2021-08-23 2022-12-06 江苏悦孚油品有限公司 Synthetic oil for circular knitting machine and preparation method thereof

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