CN1995302A - Emulsifiable oil for knitting - Google Patents
Emulsifiable oil for knitting Download PDFInfo
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- CN1995302A CN1995302A CN 200610124379 CN200610124379A CN1995302A CN 1995302 A CN1995302 A CN 1995302A CN 200610124379 CN200610124379 CN 200610124379 CN 200610124379 A CN200610124379 A CN 200610124379A CN 1995302 A CN1995302 A CN 1995302A
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- knitting
- oil
- emulsifiable oil
- emulsifiable
- composite
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Abstract
The invention discloses a lubricating, anti-electrostatic, anti-rust and cooling liquid composition in the weaving manufacturing course, which consists of 85-92% mineral typed basic oil with multiple viscous basic oils and 8-15% additive, wherein the additive is composed of emulsifier, antirust agent, abrasion-proof agent, anti-oxidant, metal deactivator and distill water.
Description
Technical field:
The present invention relates to a kind of weaving, braiding course of processing of being used for as lubricated, antistatic, antirust and refrigerative fluid composition.
Background technology:
In weaving, the braiding course of processing, lubricate, cool off, cut down the consumption of energy, reduce the dyeing and finishing process cleaning pressure, the anti-contamination is principal element.But traditional fatty acid ester emulsifier, antistatic, the thermotolerance of anti-friction composition, anti-scroop and anti stick etc., and not in full conformity with the requirement of modern textile, braiding, and color and luster is difficult to reach pure white, anti-level of staiing.These weak points are degraded by fatty acid ester with some synthon, plastifying susceptibility, thereby cause using alkoxylate emulsifying agent and lubricant, but the latter also has the defective of oneself---and frictional coefficient is big (stiction), therefore need be used.
Summary of the invention:
The objective of the invention is to overcome the weak point of existing knitting lubricating oil, the emulsifiable oil for knitting of a kind of suitable modern textile, weaving requirement is provided.
The present invention comprises 85～92% mineral type base oil and 8～15% additive, and it is characterized by: mineral type base oil is by composite the forming of multiple viscosity base oil, and the ratio of its composition is respectively by 40 ℃ of viscosity: 10mm
2/ s: 15mm
2/ s: 30mm
2/ s=0.5～1.5: 2～3: 0.3～0.6, additive comprise the following weight ratio component:
7.0～10.0％；
B, rust-preventive agent 0.1～0.4%;
C, anti-friction composition 0.25～2.5%;
D, oxidation inhibitor 0.2～1.0%;
E, metal passivator 0.05～0.1%;
F, water 0.4～1.0%.
The present invention, described emulsifying agent can constitute by the material of following ratio is composite:
S-80: MOA-3: T-80: NP-5=0.5～1: 5～8: 0.2～0.8: 1～1.5, wherein: S-80 is a sorbitan monooleate; MOA-3 is C
12Aliphatic alcohol polyethenoxy (3) ether; T-80 is polyoxyethylene (a 20) sorbitan monooleate; NP-5 is Nonyl pheno (a 5) ether.
The present invention, described rust-preventive agent can be fatty amide, and molecular formula is: R-CONH
2, wherein R is C
16～C
22Alkyl.
The present invention, described anti-friction composition can constitute by the material of following weight ratio is composite:
1) organically-modified phosphoric acid fat 0.05～1.0;
2) fatty acid ester (different cetaceum base stearate) 0.1～1.0;
3) macrogol ester 0.1～0.5,
The structure of macrogol ester is: R-[CH
2CH
2-O]
n-R, wherein:
N=300～400.
The present invention, described oxidation inhibitor can be T501 or/and T531, and wherein, T501 is 2,6 ditertbutylparacresols; T531 is N-phenyl-a-naphthylamines.Described metal passivator can be T551, i.e. the 124 Triazole derivative.
The present invention, because adopting the high viscosity index (HVI) base oil is matrix, viscosity with temperature rising rangeability is little, and utilize the combination of fatty acid ester and polyoxyethylene-type emulsifying agent, can prevent that frictional force sharply changes in the operational process, make and operate steadily, this just reduces the noise that causes because of static and dynamic friction coefficient difference.The adding of an amount of moisture content helps improving the static resistance and the cooling performance of processing fiber, anti-plastification.And organically-modified phosphoric acid ester also has the function of stable emulsion except excellent antistatic, and processed fiber in the clean-out operation is taken away greasy dirt afterwards, reaches good comprehensive process performance.
Excellent light stability, lubricity (frictional coefficient (four-ball tester) 0.08651d=0.44mm is less than commercially available 0.09137d=0.56mm) nontoxic free from extraneous odour and good clear Xian's property are most important characteristic of the present invention.
The present invention adopts highly purified (two hydrogenation) mineral type base oil and multiple additives, forms through the scientific approach allotment.It is pure white, stable to have oil colours; Oilness is good, the cold-starting sensitivity, and hot operation is steady; The smoke point height, rust-preventing characteristic, cleaning and stain resistance that volatility is little and splendid; Anti-plastification; Antistatic, anti-scroop, noise are low, characteristics such as energy-conserving and environment-protective.Be particularly suitable at a high speed braiding, weaving loom (when after spin oil) use.
Embodiment:
The preparation of emulsifiable oil for knitting can be 10mm by 40 ℃ of viscosity
2The mineral type base oil of/s: 24.0%, 40 ℃ of viscosity are 15mm
2The mineral type base oil of/s: 54.0%, 40 ℃ of viscosity are 30mm
2The mineral type base oil of/s: 10.0%, S-80:0.8%, MOA-3:6.2%, T-80:0.5%, NP-5:1.2%, high fatty acid amide: organically-modified phosphoric acid fat 0.1%: fatty acid ester (different cetaceum base stearate) 0.6%: macrogol ester 0.5%: 0.4%, T501:0.4%, T531:0.2%, T551:0.1% and distilled water 1.0% allotment constitute.
This composition is adjusted in high-quality stainless steel blending kettle, and blending kettle should have chuck heating temperature controllable.
Blending is in proper order: in slowly heating up and stirring, drop into base oil, rust-preventive agent, T501, T531, emulsifying agent, anti-friction composition successively by formula rate, be warming up to 60 ℃ of insulated and stirred 20～30 minutes, treat that solid additive fully dissolves, be cooled to 45 ℃～50 ℃ then and add T551 and distilled water, continue to relax and stir till the composition clear, inspection by sampling is qualified can pack.
The technical requirements of emulsifiable oil for knitting is as shown in the table:
Technical requirements
| Project | Quality index | Test method |
| Outward appearance | Colourless to little yellow transparent liquid | Range estimation |
| 40 ℃ of mm of kinematic viscosity 2/s | 10～18 | GB/T265 |
| Flash-point ℃ (opening) is not less than | 160 | GB/T267 |
| The cooling cloud point ℃ is not higher than | -5 | SH/T0179 |
| Acid number mgKOH/g is not more than | 0.15 | GB/T264 |
| Active principle % is not less than | 99 | (1) |
| Corrosion (distilled water) | Rustless | GB/T11143 |
| Water dispersible | Emulsus is even | Range estimation (2) |
| The washability test | Qualified | Appendix |
| Fiber/metal kinetic friction coefficient (3) is not more than | 0.16 | Y151 frictional coefficient of fiber determinator |
| 1) active principle %=100%-moisture % moisture determination is by G13/T260 2) with finish: water=1: 3 is put into 16mm diameter test tube and is shaken 100 times, estimates 3 after placing 24h) the assurance project | ||
Claims (6)
1, a kind of emulsifiable oil for knitting comprises 85～92% mineral type base oil and 8～15% additive, and it is characterized by: mineral type base oil is by composite the forming of multiple viscosity base oil, and the ratio of its composition is respectively by 40 ℃ of viscosity: 10mm
2/ s: 15mm
2/ s: 30mm
2/ s=0.5～1.5: 2～3: 0.3～0.6, additive comprise the following weight ratio component:
A, emulsifying agent 7.0～10.0%;
B, rust-preventive agent 0.1～0.4%;
C, anti-friction composition 0.2 5～2.5%;
D, oxidation inhibitor 0.2～1.0%;
E, metal passivator 0.05～0.1%;
F, water 0.4～1.0%.
2, emulsifiable oil for knitting according to claim 1 is characterized by: described emulsifying agent constitutes by the material of following ratio is composite:
S-80: MOA-3: T-80: NP-5=0.5～1: 5～8: 0.2～0.8: 1～1.5, wherein: S-80 is a sorbitan monooleate; MOA-3 is C
12Aliphatic alcohol polyethenoxy (3) ether; T-80 is polyoxyethylene (a 20) sorbitan monooleate; NP-5 is Nonyl pheno (a 5) ether.
3, emulsifiable oil for knitting according to claim 1 and 2 is characterized by: described rust-preventive agent is fatty amide, and molecular formula is: R-CONH
2, wherein R is C
16～C
22Alkyl.
4, according to the arbitrary described emulsifiable oil for knitting of claim 1-3, it is characterized by: described anti-friction composition constitutes by the material of following weight ratio is composite:
1) organically-modified phosphoric acid fat 0.05～1.0;
2) fatty acid ester 0.1～1.0;
3) macrogol ester 0.1～0.5,
Wherein, the structure of macrogol ester is: R-[CH
2CH
2-O]
n-R, wherein
5, according to the arbitrary described emulsifiable oil for knitting of claim 1-4, it is characterized by: described oxidation inhibitor is T501 or/and T531, and wherein, T501 is 2,6 ditertbutylparacresols; T531 is N-phenyl-a-naphthylamines.
6, according to the arbitrary described emulsifiable oil for knitting of claim 1-5, it is characterized by: described metal passivator is T551, i.e. the 124 Triazole derivative.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101243792A CN100491509C (en) | 2006-12-25 | 2006-12-25 | Emulsifiable oil for knitting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2006101243792A CN100491509C (en) | 2006-12-25 | 2006-12-25 | Emulsifiable oil for knitting |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1995302A true CN1995302A (en) | 2007-07-11 |
| CN100491509C CN100491509C (en) | 2009-05-27 |
Family
ID=38250505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2006101243792A Expired - Fee Related CN100491509C (en) | 2006-12-25 | 2006-12-25 | Emulsifiable oil for knitting |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100491509C (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263478A (en) * | 2014-09-24 | 2015-01-07 | 中国石油化工股份有限公司 | Easy-to-clean antirust knitting machine oil composition and use thereof |
| CN104962349A (en) * | 2015-06-05 | 2015-10-07 | 广西大学 | Totally-synthetic emulsible oil composition for seamless knitting machine |
| CN105368544A (en) * | 2014-07-25 | 2016-03-02 | 克鲁勃润滑产品（上海）有限公司 | Lubricating oil and preparation method thereof |
| CN109401822A (en) * | 2018-11-02 | 2019-03-01 | 浙江师范大学 | The environmentally friendly degradable emulsification knitting oil of one kind and its production method |
| CN111471509A (en) * | 2020-03-18 | 2020-07-31 | 江苏悦孚油品有限公司 | Knitting auxiliary agent with good extreme pressure wear resistance and preparation process thereof |
| CN111635807A (en) * | 2020-05-27 | 2020-09-08 | 中国石油化工股份有限公司 | Lubricating oil composition for warp knitting machine, preparation method and application thereof |
-
2006
- 2006-12-25 CN CNB2006101243792A patent/CN100491509C/en not_active Expired - Fee Related
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105368544A (en) * | 2014-07-25 | 2016-03-02 | 克鲁勃润滑产品（上海）有限公司 | Lubricating oil and preparation method thereof |
| CN104263478A (en) * | 2014-09-24 | 2015-01-07 | 中国石油化工股份有限公司 | Easy-to-clean antirust knitting machine oil composition and use thereof |
| CN104263478B (en) * | 2014-09-24 | 2018-01-12 | 中国石油化工股份有限公司 | Easy cleaning rust-proof type knitting machine oil composition and application thereof |
| CN104962349A (en) * | 2015-06-05 | 2015-10-07 | 广西大学 | Totally-synthetic emulsible oil composition for seamless knitting machine |
| CN109401822A (en) * | 2018-11-02 | 2019-03-01 | 浙江师范大学 | The environmentally friendly degradable emulsification knitting oil of one kind and its production method |
| CN111471509A (en) * | 2020-03-18 | 2020-07-31 | 江苏悦孚油品有限公司 | Knitting auxiliary agent with good extreme pressure wear resistance and preparation process thereof |
| CN111635807A (en) * | 2020-05-27 | 2020-09-08 | 中国石油化工股份有限公司 | Lubricating oil composition for warp knitting machine, preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100491509C (en) | 2009-05-27 |
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Legal Events
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: GUANGDONG OITA LUBRICATING OIL CO., LTD. Free format text: FORMER OWNER: PENG MEIDONG Effective date: 20091204 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20091204 Address after: Dongshan Road, Jieyang, Guangdong, Dongyang, Lantian Patentee after: Guangdong Oita Lubricating Oil Co. Ltd. Address before: Guangdong Province, Jieyang Dongshan District of Lantian City, Dongyang road Guangdong Oita Lubricating Oil Co.,. Patentee before: Peng Meidong |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090527 Termination date: 20141225 |
|
| EXPY | Termination of patent right or utility model |