CN106634174A - Biodegradable color printing ink auxiliary - Google Patents
Biodegradable color printing ink auxiliary Download PDFInfo
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- CN106634174A CN106634174A CN201611214763.1A CN201611214763A CN106634174A CN 106634174 A CN106634174 A CN 106634174A CN 201611214763 A CN201611214763 A CN 201611214763A CN 106634174 A CN106634174 A CN 106634174A
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- biodegradable
- auxiliary agent
- scopolin
- menthol
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention discloses a biodegradable color printing ink auxiliary which comprises the following main raw materials in parts by weight: 5-10 parts of menthol, 2-6 parts of glaucocalyxin, 17-22 parts of hasmanine, 20-30 parts of 13-dehydroxyindaconintine, 8-17 parts of gomisin G, 15-25 parts of rhoifolin, 11-14 parts of scopolin, 5-9 parts of 2-chlorin-6-fluorophenol, 7-12 parts of chloromethyl methyl ether, 0.5-0.8 part of boron trifluoride methyl alcohol, 2-4 parts of pentobarbital sodium salt, 2-4 parts of 2-aminophenol-4-(2-carboxyl) sulphonanilid and 2-4 parts of cis-dichloride (diethyl sulfide) platinum. The biodegradable color printing ink auxiliary has the advantages of environmental protection, harmless effect, high safety, stable property and good printing effect. When the wastes are recycled, under the effect of a decolorizing agent, the ink can be quickly decolorized, the problem of volatilization of the organic solvent in the oil-based ink can be eliminated and the problems of high deinking difficulty of wastepaper and serious sewage discharge can be solved.
Description
Technical field
The present invention relates to a kind of ink addition agent preparation field, specifically a kind of biodegradable litho ink auxiliary agent.
Background technology
With Social Culture, science and technology, expanding economy, printing industry develops at a speed unheard of before, and ink
It is the greatest contamination source of printing industry.Traditional oil-based ink has with organic solvents such as aromatic hydrocarbon, ester, ketone as solvent in ink
Machine solvent is generally 50%-70%, and these solvent major parts can volatilize in printing link, seriously pollute environment,
Directly compromise the health of the mankind.The solvent that water color ink is used is mainly deionized water, can greatly reduce organic solvent
Volatilization (VOC) discharge, mitigate pollution to air, therefore, the research and development of water color ink are becoming the main flow of printing industry.
But, in the research and development of current water color ink, people have only focused on the printing link of ink, emphasize that attachment fastness is strong, do not take off
Color, ignores completely deinking link when waste paper is recycled, and greatly, technique is multiple to cause the deinking difficulty when waste paper is recycled
It is miscellaneous.The exhaust emission environment of sewage is not only due to, and because the difficulty of deinking has influence on greatly the recovery utilization rate of waste paper, greatly
Big wastes resource.Under current environmental protection, the development topic of energy-saving and emission-reduction, solving the above problems will become ink row
The task of top priority of industry.
The content of the invention
It is an object of the invention to provide a kind of biodegradable litho ink auxiliary agent, to solve above-mentioned background technology in carry
The problem for going out.
For achieving the above object, the present invention provides following technical scheme：
A kind of biodegradable litho ink auxiliary agent, be according to the primary raw material of weight portion：Menthol 5-10 parts, blue calyx first
Plain 2-6 parts, Cha Simanlin 17-22 parts, 13- remove hydroxyl Indaconitone 20-30 parts, Gomisin G 8-17 parts, Rhoifolin 15-25
Part, scopolin 11-14 parts, the chloro- 6- fluorophenols 5-9 parts of 2-, chloromethyl methyl ether 7-12 parts, boron trifluoride methanol 0.5-0.8 parts,
Sodium pentobarbital 2-4 parts, Ortho-Aminophenol -4- (2- carboxyls) sulfonanilide 2-4 parts, cis- dichloro two (diethyl thioether) platinum
2-4 parts.
As further scheme of the invention：The biodegradable litho ink auxiliary agent, according to the main original of weight portion
Expect be：Menthol 6-8 parts, glaucocalyxin A 2-6 parts, Cha Simanlin 18-21 parts, 13- remove hydroxyl Indaconitone 22-26 parts, Gomisin G
10-15 parts, Rhoifolin 18-23 parts, scopolin 11-14 parts, the chloro- 6- fluorophenols 5-9 parts of 2-, chloromethyl methyl ether 8-11 parts,
Boron trifluoride methanol 0.5-0.8 parts, sodium pentobarbital 2-4 parts, Ortho-Aminophenol -4- (2- carboxyls) sulfonanilide 2-4 parts,
Cis- dichloro two (diethyl thioether) platinum 2-4 parts.
As further scheme of the invention：The biodegradable litho ink auxiliary agent, according to the main original of weight portion
Expect be：7 parts of menthol, 4 parts of glaucocalyxin A, 20 parts of Cha Simanlin, 13- remove 24 parts of hydroxyl Indaconitone, 13 parts of Gomisin G, wild paint
20 parts of glycosides of tree, 13 parts of scopolin, 7 parts of the chloro- 6- fluorophenols of 2-, 10 parts of chloromethyl methyl ether, 0.7 part of boron trifluoride methanol, penta bar
Than 3 parts of appropriate sodium salt, 3 parts of Ortho-Aminophenol -4- (2- carboxyls) sulfonanilide, 3 parts of cis- dichloro two (diethyl thioether) platinum.
A kind of preparation method of biodegradable litho ink auxiliary agent, concretely comprises the following steps：
First, menthol, glaucocalyxin A, Cha Simanlin, 13- are weighed by above-mentioned metering ratio and removes hydroxyl Indaconitone, Ge meter Xin
The chloro- 6- fluorophenols of G, Rhoifolin, scopolin, 2-, chloromethyl methyl ether, boron trifluoride methanol, sodium pentobarbital, 2- amino
Phenol -4- (2- carboxyls) sulfonanilide, cis- dichloro two (diethyl thioether) platinum, sieve, and machinery adds ultra-pure water after mixing, and puts
In putting mixer, mix 4-8min, control RSD≤5%, be spray-dried after mixing, packaging obtains final product biodegradable color printing
Ink addition agent.
As further scheme of the invention：Mix 6min in concrete steps.
Compared with prior art, the invention has the beneficial effects as follows：
The ink addition agent has that environmentally friendly, harmless, security is good, stable in properties, printing effect is good；Recycle in useless product
When, in the presence of decolorising agent, ink can decolourize quickly, both eliminate the problem of organic solvent volatilization in oil-based ink, and
Solve deinking difficulty big, the serious problem of sewage discharge.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of biodegradable litho ink auxiliary agent, be according to the primary raw material of weight portion：5 parts of menthol, glaucocalyxin A 2
Part, 17 parts of Cha Simanlin, 13- remove 20 parts of hydroxyl Indaconitone, 8 parts of Gomisin G, 15 parts of Rhoifolin, 11 parts of scopolin, 2-
5 parts of chloro- 6- fluorophenols, 7 parts of chloromethyl methyl ether, 0.5 part of boron trifluoride methanol, 2 parts of sodium pentobarbital, Ortho-Aminophenol -4-
2 parts of (2- carboxyls) sulfonanilide, 2 parts of cis- dichloro two (diethyl thioether) platinum.
A kind of preparation method of biodegradable litho ink auxiliary agent, concretely comprises the following steps：
First, menthol, glaucocalyxin A, Cha Simanlin, 13- are weighed by above-mentioned metering ratio and removes hydroxyl Indaconitone, Ge meter Xin
The chloro- 6- fluorophenols of G, Rhoifolin, scopolin, 2-, chloromethyl methyl ether, boron trifluoride methanol, sodium pentobarbital, 2- amino
Phenol -4- (2- carboxyls) sulfonanilide, cis- dichloro two (diethyl thioether) platinum, sieve, and machinery adds ultra-pure water after mixing, and puts
In putting mixer, mix 4min, control RSD≤5%, be spray-dried after mixing, packaging obtains final product biodegradable color printing oil
Black auxiliary agent.
Embodiment 2
A kind of biodegradable litho ink auxiliary agent, be according to the primary raw material of weight portion：6 parts of menthol, glaucocalyxin A 2
Part, 18 parts of Cha Simanlin, 13- remove 22 parts of hydroxyl Indaconitone, 10 parts of Gomisin G, 18 parts of Rhoifolin, 11 parts of scopolin, 2-
5 parts of chloro- 6- fluorophenols, 8 parts of chloromethyl methyl ether, 0.5 part of boron trifluoride methanol, 2 parts of sodium pentobarbital, Ortho-Aminophenol -4-
2 parts of (2- carboxyls) sulfonanilide, 2 parts of cis- dichloro two (diethyl thioether) platinum.
A kind of preparation method of biodegradable litho ink auxiliary agent, concretely comprises the following steps：
First, menthol, glaucocalyxin A, Cha Simanlin, 13- are weighed by above-mentioned metering ratio and removes hydroxyl Indaconitone, Ge meter Xin
The chloro- 6- fluorophenols of G, Rhoifolin, scopolin, 2-, chloromethyl methyl ether, boron trifluoride methanol, sodium pentobarbital, 2- amino
Phenol -4- (2- carboxyls) sulfonanilide, cis- dichloro two (diethyl thioether) platinum, sieve, and machinery adds ultra-pure water after mixing, and puts
In putting mixer, mix 4min, control RSD≤5%, be spray-dried after mixing, packaging obtains final product biodegradable color printing oil
Black auxiliary agent.
Embodiment 3
A kind of biodegradable litho ink auxiliary agent, be according to the primary raw material of weight portion：7 parts of menthol, glaucocalyxin A 4
Part, 20 parts of Cha Simanlin, 13- remove 24 parts of hydroxyl Indaconitone, 13 parts of Gomisin G, 20 parts of Rhoifolin, 13 parts of scopolin, 2-
7 parts of chloro- 6- fluorophenols, 10 parts of chloromethyl methyl ether, 0.7 part of boron trifluoride methanol, 3 parts of sodium pentobarbital, Ortho-Aminophenol -4-
3 parts of (2- carboxyls) sulfonanilide, 3 parts of cis- dichloro two (diethyl thioether) platinum.
A kind of preparation method of biodegradable litho ink auxiliary agent, concretely comprises the following steps：
First, menthol, glaucocalyxin A, Cha Simanlin, 13- are weighed by above-mentioned metering ratio and removes hydroxyl Indaconitone, Ge meter Xin
The chloro- 6- fluorophenols of G, Rhoifolin, scopolin, 2-, chloromethyl methyl ether, boron trifluoride methanol, sodium pentobarbital, 2- amino
Phenol -4- (2- carboxyls) sulfonanilide, cis- dichloro two (diethyl thioether) platinum, sieve, and machinery adds ultra-pure water after mixing, and puts
In putting mixer, mix 6min, control RSD≤5%, be spray-dried after mixing, packaging obtains final product biodegradable color printing oil
Black auxiliary agent.
Embodiment 4
A kind of biodegradable litho ink auxiliary agent, be according to the primary raw material of weight portion：8 parts of menthol, glaucocalyxin A 6
Part, 21 parts of Cha Simanlin, 13- remove 26 parts of hydroxyl Indaconitone, 15 parts of Gomisin G, 23 parts of Rhoifolin, 14 parts of scopolin, 2-
9 parts of chloro- 6- fluorophenols, 11 parts of chloromethyl methyl ether, 0.8 part of boron trifluoride methanol, 4 parts of sodium pentobarbital, Ortho-Aminophenol -4-
4 parts of (2- carboxyls) sulfonanilide, 4 parts of cis- dichloro two (diethyl thioether) platinum.
A kind of preparation method of biodegradable litho ink auxiliary agent, concretely comprises the following steps：
First, menthol, glaucocalyxin A, Cha Simanlin, 13- are weighed by above-mentioned metering ratio and removes hydroxyl Indaconitone, Ge meter Xin
The chloro- 6- fluorophenols of G, Rhoifolin, scopolin, 2-, chloromethyl methyl ether, boron trifluoride methanol, sodium pentobarbital, 2- amino
Phenol -4- (2- carboxyls) sulfonanilide, cis- dichloro two (diethyl thioether) platinum, sieve, and machinery adds ultra-pure water after mixing, and puts
In putting mixer, mix 8min, control RSD≤5%, be spray-dried after mixing, packaging obtains final product biodegradable color printing oil
Black auxiliary agent.
Embodiment 5
A kind of biodegradable litho ink auxiliary agent, be according to the primary raw material of weight portion：10 parts of menthol, glaucocalyxin A
6 parts, 22 parts of Cha Simanlin, 13- go 30 parts of hydroxyl Indaconitone, 17 parts of Gomisin G, 25 parts of Rhoifolin, 14 parts of scopolin,
9 parts of the chloro- 6- fluorophenols of 2-, 12 parts of chloromethyl methyl ether, 0.8 part of boron trifluoride methanol, 4 parts of sodium pentobarbital, Ortho-Aminophenol-
4 parts of 4- (2- carboxyls) sulfonanilide, 4 parts of cis- dichloro two (diethyl thioether) platinum.
A kind of preparation method of biodegradable litho ink auxiliary agent, concretely comprises the following steps：
First, menthol, glaucocalyxin A, Cha Simanlin, 13- are weighed by above-mentioned metering ratio and removes hydroxyl Indaconitone, Ge meter Xin
The chloro- 6- fluorophenols of G, Rhoifolin, scopolin, 2-, chloromethyl methyl ether, boron trifluoride methanol, sodium pentobarbital, 2- amino
Phenol -4- (2- carboxyls) sulfonanilide, cis- dichloro two (diethyl thioether) platinum, sieve, and machinery adds ultra-pure water after mixing, and puts
In putting mixer, mix 8min, control RSD≤5%, be spray-dried after mixing, packaging obtains final product biodegradable color printing oil
Black auxiliary agent.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be in other specific forms realized.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of biodegradable litho ink auxiliary agent, it is characterised in that the primary raw material according to weight portion is：Menthol 5-10
Part, glaucocalyxin A 2-6 parts, Cha Simanlin 17-22 parts, 13- remove hydroxyl Indaconitone 20-30 parts, Gomisin G 8-17 parts, Rhus succedanea
Glycosides 15-25 parts, scopolin 11-14 parts, the chloro- 6- fluorophenols 5-9 parts of 2-, chloromethyl methyl ether 7-12 parts, boron trifluoride methanol
0.5-0.8 parts, sodium pentobarbital 2-4 parts, Ortho-Aminophenol -4- (2- carboxyls) sulfonanilide 2-4 parts, (diethyl of cis- dichloro two
Base thioether) platinum 2-4 parts.
2. biodegradable litho ink auxiliary agent according to claim 1, it is characterised in that the biodegradable color printing
Ink addition agent, be according to the primary raw material of weight portion：Menthol 6-8 parts, glaucocalyxin A 2-6 parts, Cha Simanlin 18-21 parts, 13-
Remove hydroxyl Indaconitone 22-26 parts, Gomisin G 10-15 parts, Rhoifolin 18-23 parts, scopolin 11-14 parts, the chloro- 6- fluorine of 2-
Phenol 5-9 parts, chloromethyl methyl ether 8-11 parts, boron trifluoride methanol 0.5-0.8 parts, sodium pentobarbital 2-4 parts, 2- aminobenzenes
Phenol -4- (2- carboxyls) sulfonanilide 2-4 parts, cis- dichloro two (diethyl thioether) platinum 2-4 parts.
3. biodegradable litho ink auxiliary agent according to claim 1, it is characterised in that the biodegradable color printing
Ink addition agent, be according to the primary raw material of weight portion：7 parts of menthol, 4 parts of glaucocalyxin A, 20 parts of Cha Simanlin, 13- remove hydroxyl
24 parts of Indaconitone, 13 parts of Gomisin G, 20 parts of Rhoifolin, 13 parts of scopolin, 7 parts of the chloro- 6- fluorophenols of 2-, chloromethyl methyl ether
10 parts, 0.7 part of boron trifluoride methanol, 3 parts of sodium pentobarbital, 3 parts of Ortho-Aminophenol -4- (2- carboxyls) sulfonanilide, cis- two
3 parts of chlorine two (diethyl thioether) platinum.
4. a kind of preparation method of the biodegradable litho ink auxiliary agent as described in claim 1-3 is arbitrary, it is characterised in that
Concretely comprise the following steps：
First, menthol, glaucocalyxin A, Cha Simanlin, 13- are weighed by above-mentioned metering ratio and goes to hydroxyl Indaconitone, Gomisin G, open country
The chloro- 6- fluorophenols of lacquer tree glycosides, scopolin, 2-, chloromethyl methyl ether, boron trifluoride methanol, sodium pentobarbital, 2- aminobenzenes
Phenol -4- (2- carboxyls) sulfonanilide, cis- dichloro two (diethyl thioether) platinum, sieve, and machinery adds ultra-pure water after mixing, and place
In mixer, mix 4-8min, control RSD≤5%, be spray-dried after mixing, packaging obtains final product biodegradable color printing oil
Black auxiliary agent.
5. the preparation method of biodegradable litho ink auxiliary agent according to claim 4, it is characterised in that concrete steps
Middle mixing 6min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611214763.1A CN106634174A (en) | 2016-12-26 | 2016-12-26 | Biodegradable color printing ink auxiliary |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611214763.1A CN106634174A (en) | 2016-12-26 | 2016-12-26 | Biodegradable color printing ink auxiliary |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634174A true CN106634174A (en) | 2017-05-10 |
Family
ID=58827111
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611214763.1A Pending CN106634174A (en) | 2016-12-26 | 2016-12-26 | Biodegradable color printing ink auxiliary |
Country Status (1)
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| CN (1) | CN106634174A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1244555A (en) * | 1998-08-06 | 2000-02-16 | 研能科技股份有限公司 | Aromatic alcohol ink for jet printer |
| CN1477099A (en) * | 2002-08-23 | 2004-02-25 | 百瑞全球有限公司 | Ortho-pyridinequinone derivative, composite containing said derivative, its preparation method and application |
| CN1543334A (en) * | 2001-08-25 | 2004-11-03 | P&G | Oxidation hair dyes containing 3-aminophenol derivatives, and novel 3-aminophenol derivatives |
| CN1551875A (en) * | 2001-08-25 | 2004-12-01 | P&G | M-aminophenol derivatives and coloring agents containing them |
-
2016
- 2016-12-26 CN CN201611214763.1A patent/CN106634174A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1244555A (en) * | 1998-08-06 | 2000-02-16 | 研能科技股份有限公司 | Aromatic alcohol ink for jet printer |
| CN1543334A (en) * | 2001-08-25 | 2004-11-03 | P&G | Oxidation hair dyes containing 3-aminophenol derivatives, and novel 3-aminophenol derivatives |
| CN1551875A (en) * | 2001-08-25 | 2004-12-01 | P&G | M-aminophenol derivatives and coloring agents containing them |
| CN1477099A (en) * | 2002-08-23 | 2004-02-25 | 百瑞全球有限公司 | Ortho-pyridinequinone derivative, composite containing said derivative, its preparation method and application |
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Application publication date: 20170510 |
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