CN102229762B - Water-based ultraviolet (UV) curing silk screening snowflake ink - Google Patents
Water-based ultraviolet (UV) curing silk screening snowflake ink Download PDFInfo
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- CN102229762B CN102229762B CN 201110154193 CN201110154193A CN102229762B CN 102229762 B CN102229762 B CN 102229762B CN 201110154193 CN201110154193 CN 201110154193 CN 201110154193 A CN201110154193 A CN 201110154193A CN 102229762 B CN102229762 B CN 102229762B
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- printing ink
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Abstract
The invention discloses water-based ultraviolet (UV) curing silk screening snowflake ink, which is prepared from the following raw materials in part by weight: 40 to 60 parts of water-based UV resin, 5 to 20 parts of water-soluble aldehyde ketone resin, 8 to 25 parts of water, 1 to 8 parts of water-based UV initiator, 3 to 15 parts of lubricating agent, 0.2 to 1 part of defoaming agent, 0.2 to 1 part of thickening agent and 0.2 to 1 part of dispersant. The invention provides the environment-friendly water-based UV curing silk screening snowflake ink for obviously reducing the peculiar smell of presswork due to ink.
Description
Technical field
Printing technology of the present invention relates to a kind of printing ink, relates in particular to a kind of UV-curable waterborne silk-screen snowflake printing ink.
Background technology
UV-curable waterborne printing ink is called for short water-based UV printing ink, and this printing ink is to make solvent, need carry out a kind of specialty inks that UV curing was just done and then carried out to hot blast earlier in the printing drying process with water.Water-based UV printing ink not only has the characteristics while of water color ink volatilization but also has the advantages that UV printing ink UV solidifies.The silk-screen snowflake printing ink is a kind of printing ink that solidifies, presents the glittering and translucent texture texture as the snowflake in winter through silk screen printing and UV.Because the main component UV aldehyde ketone resin in the present silk-screen snowflake printing ink raw material, UV acrylate resin etc., chemical reaction can take place in by the UV solidification process, produce benzene class material and letones, and give out bigger peculiar smell, contaminate environment, influence HUMAN HEALTH, be a kind of printing ink of non-environmental protection, also do not reach the VOC control requirement of tobacco bale in addition.
Summary of the invention
The technical problem to be solved in the present invention is, at above-mentioned defective of the prior art, provides the peculiar smell that a kind of obvious reduction printed matter produces because of printing ink, the UV-curable waterborne silk-screen snowflake printing ink of environmental protection.
The technical solution adopted for the present invention to solve the technical problems is: a kind of UV-curable waterborne silk-screen snowflake printing ink, made by following parts by weight raw material:
UV-curable waterborne silk-screen snowflake printing ink, preferably made by following parts by weight raw material:
Described water-based UV resin is water soluble acrylic acid UV resin.
Described aquosity ultraviolet light initiator is ciba 1173 aquosity ultraviolet light initiators.
Described lubricant is polyethylene wax or Ke Laien 3620.
Described defoamer is dego 902 defoamers.
Described thickening material is Lu Borun hv30.
Described dispersion agent is the Amp-95 dispersion agent.
Preparation method: with water-based UV resin, water-soluble aldehyde ketone resin, water, aquosity ultraviolet light initiator, lubricant, defoamer, thickening material, dispersant, adopt homogenizer fully to stir, namely make UV-curable waterborne silk-screen snowflake printing ink.
UV-curable waterborne silk-screen snowflake printing ink of the present invention is that a kind of water color ink characteristics that have concurrently have the printing ink that UV-light (UV) is solidified simultaneously.Water is as solvent in the raw material of the present invention, is used for each component of dissolving.Realization environmental protection printing.The common reaction under the effect of ultraviolet initiator of water-based UV resin, water-soluble aldehyde ketone resin forms the special texture effect of snowflake printing ink.The effect of lubricant is the smooth property that increases product, prevents cigarette card machine phenomenon when packing; The effect of defoamer is to reduce printing ink in use because a large amount of bubbles appears in flow circuit, and then it is unreal to have influence on print product surface seal, ignore occurs; The effect of thickening material is to regulate snowflake texture size.The effect of dispersion agent is the dispersing uniformity that improves above component.Said components does not contain other too much chemical assistant substantially, and the content of residual volatile organic compounds is beneficial to production quality control in can reduction printed matter clearly." the mensuration head space-vapor-phase chromatography of volatile organic compounds (VOCs) in YC/T 207 tobacco shreds and the box packaging paper " detects, and meets the requirements fully.And have the power consumption low, efficient height, advantages such as safety and environmental protection.
Embodiment
Embodiment 1, a kind of UV-curable waterborne silk-screen snowflake printing ink are made by following parts by weight raw material: water soluble acrylic acid UV resin 50, water-soluble aldehyde ketone resin 10, water 10, aquosity ultraviolet light initiator (trade(brand)name ciba 1173) 3, polyethylene wax 5, defoamer (trade(brand)name dego 902) 0.5, thickening material (trade(brand)name Lu Borun hv30) 0.5, dispersant A mp-95 0.5.
Preparation method: the raw material of the water soluble acrylic acid UV resin of above-mentioned parts by weight, water-soluble aldehyde ketone resin, aquosity ultraviolet light initiator at first mixed put into homogenizer and stir, 3000 rev/mins of stirring velocitys, stirred 1 hour, after treating its dissolving, add other surplus stock again, stirred again 10 minutes, and made UV-curable waterborne silk-screen snowflake printing ink.
Embodiment 2, a kind of UV-curable waterborne silk-screen snowflake printing ink are made by following parts by weight raw material: water soluble acrylic acid UV resin 55, water-based aldehyde ketone resin 15, water 20, aquosity ultraviolet light initiator (trade(brand)name ciba 1173) 5, polyethylene wax 10, defoamer (trade(brand)name dego 902) 0.5, thickening material (trade(brand)name Lu Borun hv30) 0.5, dispersant A mp-95 0.5.
The preparation method does not repeat them here with embodiment 1.
Embodiment 3, a kind of UV-curable waterborne silk-screen snowflake printing ink are made by following parts by weight raw material: water soluble acrylic acid UV resin 52, water-based aldehyde ketone resin 12, water 15, aquosity ultraviolet light initiator (trade(brand)name ciba 1173) 4, Ke Laien 3,620 8, defoamer (trade(brand)name dego 902) 0.5, thickening material (trade(brand)name Lu Borun hv30) 0.5, dispersant A mp-95 0.5.
The preparation method does not repeat them here with embodiment 1.
Embodiment 4, a kind of UV-curable waterborne silk-screen snowflake printing ink are made by following parts by weight raw material: water soluble acrylic acid UV resin 40, water-based aldehyde ketone resin 20, water 25, aquosity ultraviolet light initiator (trade(brand)name ciba 1173) 8, polyethylene wax 15, defoamer (trade(brand)name dego 902) 0.2, thickening material (trade(brand)name Lu Borun hv30) 0.2, dispersant A mp-95 0.2.
The preparation method does not repeat them here with embodiment 1.
Embodiment 5, a kind of UV-curable waterborne silk-screen snowflake printing ink are made by following parts by weight raw material: water soluble acrylic acid UV resin 60, water-based aldehyde ketone resin 5, water 8, aquosity ultraviolet light initiator (trade(brand)name ciba 1173) 1, Ke Laien 3,620 3, defoamer (trade(brand)name dego 902) 1, thickening material (trade(brand)name Lu Borun hv30) 1, dispersant A mp-95 1.
The preparation method does not repeat them here with embodiment 1.
Test of products: the present invention detects product performance, and concrete the detection thes contents are as follows:
1, detects content: dry solidification, sticking power, snappiness, grain effect
2, detect step:
1. dry solidification detects
With paper clip stratum synoviale surface, nothing comes off.
2. sticking power detects
Peel off adhere firmly rapidly for manual 45 ° with 25mm wide cut 3M scotch tape.
3. snappiness detects
Spend more than 3 times according to indentation line manual folding 180 behind the product die cutting, no oil reservoir comes off.
4. grain effect detects
The range estimation of contrast specimen page
3, detecting instrument:
1. paper clip
2. 3M scotch tape
3. die-cutting machine
4, detected result:
| Embodiment | Dry good | Be cured | Sticking power | Snappiness | Grain effect |
| Embodiment 1 | Dry good | It is qualified to solidify | Good | Good | Fine and smooth |
| Embodiment 2 | Dry good | Be cured | Good | Good | Thick slightly |
| Embodiment 3 | Dry good | Be cured | Very | Very | Fine and smooth |
| Embodiment 4 | Dry qualified | Be cured | Qualified | Qualified | Thicker |
| Embodiment 5 | Dry good | It is qualified to solidify | Qualified | Qualified | Thicker |
Various compositions are to reach certain proportioning among the present invention, could take into account every indexs such as drying property, solidification intensity, sticking power, snappiness, grain effect simultaneously.Because the consumption of light trigger can affect the solidification effect of printing ink.Consumption along with light trigger when just beginning increases, and solidification effect obviously improves; But when consumption is too much, can cause problems such as China ink layer explosion.The consumption of polyethylene wax and thickening material can affect the texture of snowflower effect, and just having begun is that consumption along with them increases, and grain effect obviously improves; But when consumption was too much, grain effect on the contrary can be not obvious.How many consumptions of water affects printing effect and the drying effect of printing ink.The water yield is very few, can cause that printing ink dries up easily on forme, causes printing troubles such as network blocking; Hypervolia can affect the volatile dry of printing ink, and then affects the solidification effect of final printing ink.Embodiment 1～5 detected result shows: the various proportioning raw materials of the present invention are suitable, can reach every indexs such as taking into account drying property, solidification intensity, sticking power, snappiness, grain effect simultaneously fully and all reach print request, also chemical reaction can take place in the corresponding available technology adopting raw material that solved in the UV solidification process, produce benzene class material and letones, and give out the problem that bigger peculiar smell causes environmental pollution and is detrimental to health.
Claims (8)
1. a UV-curable waterborne silk-screen snowflake printing ink is characterized in that, is made by following parts by weight raw material:
2. UV-curable waterborne silk-screen snowflake printing ink according to claim 1 is characterized in that, is made by following parts by weight raw material:
3. UV-curable waterborne silk-screen snowflake printing ink according to claim 1 and 2 is characterized in that, described water-based UV resin is water soluble acrylic acid UV resin.
4. UV-curable waterborne silk-screen snowflake printing ink according to claim 1 and 2 is characterized in that, described aquosity ultraviolet light initiator is ciba 1173 aquosity ultraviolet light initiators.
5. UV-curable waterborne silk-screen snowflake printing ink according to claim 1 and 2 is characterized in that, described lubricant is polyethylene wax or Ke Laien 3620.
6. UV-curable waterborne silk-screen snowflake printing ink according to claim 1 and 2 is characterized in that, described defoamer is dego 902 defoamers.
7. UV-curable waterborne silk-screen snowflake printing ink according to claim 1 and 2 is characterized in that, described thickening material is Lu Borun hv30.
8. UV-curable waterborne silk-screen snowflake printing ink according to claim 1 and 2 is characterized in that, described dispersion agent is the Amp-95 dispersion agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110154193 CN102229762B (en) | 2011-06-09 | 2011-06-09 | Water-based ultraviolet (UV) curing silk screening snowflake ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110154193 CN102229762B (en) | 2011-06-09 | 2011-06-09 | Water-based ultraviolet (UV) curing silk screening snowflake ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102229762A CN102229762A (en) | 2011-11-02 |
| CN102229762B true CN102229762B (en) | 2013-09-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110154193 Expired - Fee Related CN102229762B (en) | 2011-06-09 | 2011-06-09 | Water-based ultraviolet (UV) curing silk screening snowflake ink |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103709826B (en) * | 2013-12-30 | 2014-12-24 | 东莞智源彩印有限公司 | Gravure freezing point snowflake ink and preparation method thereof |
| CN104031230B (en) * | 2014-06-17 | 2016-11-16 | 常熟国和新材料有限公司 | A kind of free from extraneous odour modified acrylic ester resin and preparation method thereof |
| CN104332299B (en) * | 2014-10-25 | 2017-01-18 | 广东风华高新科技股份有限公司 | Preparation method of chip type inductor |
| CN105567006B (en) * | 2016-03-15 | 2018-05-25 | 冠利得商标制品（苏州）有限公司 | A kind of environment-friendly type ink for screen printing |
| CN106118218A (en) * | 2016-08-04 | 2016-11-16 | 福建省华普新材料有限公司 | A kind of environment-friendly digital ink and preparation method thereof |
| CN108165086A (en) * | 2018-02-05 | 2018-06-15 | 浙江美浓材料科技有限公司 | A kind of gravure snowflake printing ink and preparation method thereof |
| CN111253802A (en) * | 2020-03-16 | 2020-06-09 | 珠海奥维数码科技有限公司 | Inorganic pigment UV ink-jet ink suitable for industrial head and preparation method thereof |
| CN112590416A (en) * | 2020-12-03 | 2021-04-02 | 东莞市美盈森环保科技有限公司 | Ultraviolet curing method for water-based snowflake UV ink |
| CN112552740A (en) * | 2020-12-03 | 2021-03-26 | 东莞市美盈森环保科技有限公司 | Water-based snowflake UV ink and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US5296275A (en) * | 1992-07-01 | 1994-03-22 | Xytronyx, Inc. | Phototranschromic ink |
| CN101709182A (en) * | 2009-12-29 | 2010-05-19 | 北京印刷学院 | Water-based ultraviolet dry plastics printing ink |
| CN101974267B (en) * | 2010-11-04 | 2013-07-31 | 中钞油墨有限公司 | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof |
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Inventor after: Chen Huapei Inventor after: Tang Zan Inventor after: Zhu Hongkun Inventor before: Ma Honggang Inventor before: Cao Junzhi |
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