CN106631167A - Rose gold color preparation for ceramic decoration - Google Patents
Rose gold color preparation for ceramic decoration Download PDFInfo
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- CN106631167A CN106631167A CN201611145200.1A CN201611145200A CN106631167A CN 106631167 A CN106631167 A CN 106631167A CN 201611145200 A CN201611145200 A CN 201611145200A CN 106631167 A CN106631167 A CN 106631167A
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- bismuth
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/88—Metals
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
- C03C17/10—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the liquid phase
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/5183—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal inorganic
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/251—Al, Cu, Mg or noble metals
- C03C2217/254—Noble metals
- C03C2217/255—Au
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/27—Mixtures of metals, alloys
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/114—Deposition methods from solutions or suspensions by brushing, pouring or doctorblading
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/119—Deposition methods from solutions or suspensions by printing
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/32—After-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a rose gold color preparation for ceramic decoration. The rose gold color preparation is prepared from a metal organic compound of gold dissolved into a solvent, a metal organic compound of bismuth dissolved into the solvent, a metal organic compound of rhodium dissolved into the solvent, a metal organic compound of silicon dissolved into the solvent, a basic metal fluxing agent dissolved into the solvent and an existing sufficient number of molten metal substrate, wherein the weight percent of the gold is 3-7%; the content of the basic metal fluxing agent meets the condition of dissolving all gold, bismuth, rhodium and silicon; and the basic metal of the basic metal fluxing agent is the bismuth, the rhodium or a mixture thereof. By adopting the rose gold color preparation, ceramic, ceramic whiteware or glass material is decorated by the rose gold color preparation and then roasted, and a rose gold color film is generated on the ceramic surface; and a deep rose gold color or a hollow rose gold color can be achieved through adjusting the metal content of the compound.
Description
Technical field
The invention belongs to decoration technique field, is related to a kind of rose gold color and luster preparation for ceramic decoration, refer in particular to
Ornamental synthetic after baking outward appearance present rose gold color and luster preparation.
Background technology
Glossy for ceramics and the ornamental gold of ceramic whiteware, general using the preparation containing special gold lustre, it is by expensive
Metal mixes the preparation of composition with other organic metal.These preparations typically contain organic metal mixture, such as resinate, carboxylic
Hydrochlorate and the element containing alkoxide, metallic element is such as：Rhodium, bismuth, chromium, vanadium, nickel, cobalt, iron, tin, zirconium, copper, silicon, aluminium；These metals
Noble metal color can be affected.
At present, ceramic decorative synthetic produces gold color, and true yellow gold content scope is generally in 10-15% and flux
With medium phase balance.
Patent DE-PS 24 35 859 is disclosed, and sintering temperature can manifest polishing gold synthesis at 1100 DEG C to 1400 DEG C
Thing, noble metal of the metal preparation employed in it comprising one or multiple high-melting-point powders, its flux weight ratio reaches
To 10%.The gold content of this coating composition is apparently higher than traditional bright-gold preparations, but the ornament of this high brightness cannot be obtained
Obtain rose color and luster.Patent DE-PS36 16547 is containing the weight ratio of highest 30% on the basis of having brightness noble metal preparation
Resin, resinous type can be selected from asphaltic resin, polyamide, maleic acid resin, phenol resin, ketone resin and epoxy resin.
The only a kind of use of resinous type lecture from quality causes result unsatisfactory.Maleic acid resin often causes dress
Jewelry brightness not enough, therefore is unable to reach rose gold effect.Patent DE-PS 22 08 915 discloses polishing bronze and contains titanium dioxide
Improving baking resistance, bismuth borate is used as flux for the preparation of tin, ferrous oxide and aluminium.This preparation, can be only achieved sub- light dress
Decorations effect.Patent DE-PS 14 21 865 discloses the non-noble metal noble metal preparation of substantial amounts of dilution, comprising aluminium, boron, and bismuth, chromium,
Cobalt, indium, silicon, titanium and zirconium.It is mentioned to gold sulfate and titanium can not produce the gold film of high brightness, but produces Dark grey
Film.Containing gold sulfate, the preparation of rhodium resinate, bismuth resinate and chromium resinate generally produces sub- light or color
Very deep film, this dark-coloured film is not matched that with deep rose color and luster.Patent DE-PS 38 09 541 describes sintering temperature perhaps
In a kind of 1250 DEG C of light noble metals, it is used in the generation of the noble metal decoration of anti-dish-washing machine light.Organosilicon noble metal
Compound, during roasting, forms transparent glass layer on noble metal film, and this glassy layer has good wearability, but fills
Jewelry generally shows inclined red change color, still can not manifest rose gold color and luster.
Up to now, noble metal only has lemon yellow, and yellow is red, partially green and white.Rose golden is because outward appearance is beautiful
It is welcomed by the general public, and adopts which type of metal preparation causes ceramic surface that rose gold is presented after the roasting together with ceramics
Color, in particular how depression rose gold color and luster of light color and saturate, becomes the difficult point of ceramic industry, at present in ceramic industry
Also report is had no.
The content of the invention
For above technical problem, the invention discloses a kind of rose gold color and luster preparation for ceramic decoration, brushes
On ceramics or glass baseplate, the decorative appearance composition of rose gold color and luster is produced after baking, it is used for the decoration of ceramics, ceramic whiteware
On.
In this regard, the technical solution used in the present invention is：
A kind of rose gold color and luster preparation for ceramic decoration, closes including the Organometallic of the gold being dissolved in solvent
Thing, the metallo-organic compound of the bismuth being dissolved in solvent, the metallo-organic compound of the titanium being dissolved in solvent, it is dissolved in solvent
The metallo-organic compound of silicon, the underlying metal flux being dissolved in solvent and the enough fusing metal base materials of on-hand quantity；Institute
State gold and account for 3%～7%；The content of underlying metal flux meet can melt whole gold,
Bismuth, rhodium, silicon；The underlying metal of the underlying metal flux is bismuth, rhodium or their mixture；Described fills for ceramics
The rose gold color and luster preparation brushing of decorations or after being transferred on ceramics, ceramic whiteware or glass baseplate, in 500～800 DEG C of roastings.Using this
Technical scheme, produces after baking the decorative appearance composition of rose gold color and luster.
Wherein, the underlying metal flux is the typical soluble organic metal of base metal, for melting ceramic base material
Metal level.Flux has the performance for softening or melting under the conditions of sintering temperature.They and ceramic base material react and can produce
The metallic film of a raw glue glassy layer, improves adhesive force and wearability, and equally the metal film color after roasting is produced in addition
Effect, the metallo-organic compound of the preferred base metal rhodium of other fluxs, chromium and zirconium.
Preferably, the metallo-organic compound of the gold is preferably the sulphonic resin hydrochlorate of gold.
As a further improvement on the present invention, the total content of the titanium and bismuth is accounted for before roasting
3%～10%.
As a further improvement on the present invention, as metal titanium and the weight ratio of bismuth is 5:1～10:1.
As a further improvement on the present invention, as metal bismuth and the weight ratio of silicon is 1:1.
As a further improvement on the present invention, as metal titanium and the weight ratio of silicon is 1:1.
The total content of bismuth, silicon and titanium as a further improvement on the present invention, as metal is accounted for
3%～5%.
Using above technical scheme, the preparation brushing on ceramics, ceramic whiteware or glass baseplate, after baking on ceramics
Produce the ornamental composition of deep rose color and luster.
As a further improvement on the present invention, also including the metallo-organic compound of the barium being dissolved in solvent.
As a further improvement on the present invention, as metal bismuth and the weight ratio of barium is less than 2:1, as the barium of metal
It is 3 with the weight ratio of silicon:1～4:1.
As a further improvement on the present invention, the bismuth, silicon and barium tenor percentage by weight altogether be 1%～
3%.Using this technical scheme, the preparation brushing produces dress on ceramics, ceramic whiteware or glass baseplate, after baking on ceramics
The shallow rose gold color and luster of decorations figure.
As a further improvement on the present invention, the underlying metal of the underlying metal flux is closed for the Organometallic of rhodium
Thing.
As a further improvement on the present invention, the organo-metallic compound of bismuth is the carboxylate of bismuth, the organometallic of titanium
Compound is the carboxylate of titanium, and the organo-metallic compound of barium is the carboxylate of barium.
As a further improvement on the present invention, the organic chemical combination of fluxing of the metal of the metallo-organic compound and underlying metal
Thing is to come from metal sulfonate, metal sulfate, metal thioether or metal carboxylate.
As a further improvement on the present invention, the metallo-organic compound of the barium preferably adopts barium carboxylate.
As a further improvement on the present invention, the solvent is benzyl alcohol, cyclohexanone, turpentine oil, pine tar, diformazan
In the dilute resin of benzene, terpene, dipentene, lavender spike oil, lemon thin oil, Lavender, Rosemary Oil or camphor essential oil at least one
Kind.Using this technical scheme, the sulphonic resin hydrochlorate of the gold, the metallo-organic compound of bismuth, the Organometallic of titanium is closed
Thing, the metallo-organic compound of silicon are dissolved in organic solvent, are easy to mixing to be uniformly dispersed, easy to use.
As a further improvement on the present invention, also including auxiliary agent, the auxiliary agent includes rosin and flexible resin, the flexibility
Resin such as polyamide.
Using this technical scheme, the flexible resin dissolves as carrier in organo-metallic compound, beneficial to carrying out silk
Wire mark brush.
As a further improvement on the present invention, the auxiliary agent also includes defoamer and thixotropic agent.Using this technical scheme, have
Beneficial to preferably carrying out serigraphy or brushing.
The invention also discloses a kind of metal film of rose gold color and luster, using the rose for being used for ceramic decoration as above
Golden pool preparation brushing or after being transferred on ceramics, ceramic whiteware or glass baseplate, obtains in 500～800 DEG C of roastings.
Wherein, the problem of roasting depend on base material, using coating roasting after, burn organic matter such as resin, auxiliary agent and melt
Base material, for other ceramic materials, temperature is generally at 500 DEG C to 850 DEG C.The sintering temperature of glass baseplate is 480-600 DEG C；
780-850 DEG C of the sintering temperature of ceramic whiteware, china, stone material and pottery.
The rose gold color and luster preparation can be used on base material using different methods, for example, brushed or protector printing,
Or adopt indirect screen printing.It is the significant process for producing marble paper that the indirect screen printing process is screen printing.Spending
In paper application, the decorative coveringn containing metal preparation is directly applied to the paper that solvable water paint is contained at tray paper, the particularly back side
.Additionally, decorative coveringn is separated from tray paper after soaking in water.
The invention provides the method for producing the deep dark or shallow rose gold color and luster of decoration figure after roasting on ceramics.The method
It is to decorate synthetic containing organic solvent by preparation, flexible resin dissolves as carrier step group in organo-metallic compound
Into feature is substantially to be made up of compound metal content：
(1) for dark rose gold color and luster：Titanium, silicon and bismuth organo-metallic compound are dissolved in solvent.
(2) for shallow rose gold color and luster：Barium, silicon and bismuth organo-metallic compound are dissolved in solvent.
(3) the organic flux compound of base metal is dissolved in solvent as rhodium, and the enough fusing metal bases of on-hand quantity
Material.
(4) flexible resin such as polyamide, as the slurry of patch serigraphy.
(5) necessary additive such as defoamer and thixotropic agent.
Application is brushed using serigraphy or on ceramics, ceramic whiteware or glass material surface, is roasted after decorative porcelain material
Burn, the film of rose gold color and luster is produced on ceramic surface.
Using technical scheme, using carrying out roasting after the rose gold color and luster preparation decorative porcelain material,
The film of rose gold color and luster is produced on ceramic surface；And can by modulating compound tenor, realize deep rose gold color and luster or
The shallow rose gold color and luster of person.
Specific embodiment
The preferably embodiment of the present invention is described in further detail below.
Precious metal chemical complex can include any suitable organic solvent, or have two kinds and two or more mixing
Thing, such as benzyl alcohol, cyclohexanone, turpentine oil, terpinol, dimethylbenzene, various terpenes dilute such as sobrerone and/or contains dipentene
There are Lavender, Rosemary Oil, camphor essential oil.Mixture is equally containing adhesive such as rosin and any number of flexibility
Resin such as polyamide.Usual metal ingredient such as bismuth, titanium, chromium and silicon are the mixed compounds of solvable organic metal, and carboxylic acids is preferential.Its
He perhaps equally can be used solvable organo-metallic compound.Bismuth, titanium, chromium and silicon compound are with the organic gold of solvent in solution
The compound form of category is described, and general carboxylate is preferential.
Synthetic another important composition is flux, and flux is the typical soluble organic metal of base metal, is used for
Metal level on molten ceramic base material.Flux has the performance for softening or melting under the conditions of sintering temperature.They and base material are anti-
Ying Bingneng produces the metallic film of a glue glassy layer, adhesive force and wearability is improved, in addition equally to the metal film after roasting
Color generation is acted on, it is well known that particularly base metal such as bismuth, titanium and rhodium.
Following examples are the representative components provided in preferred plan of the present invention.
Embodiment 1
Deep roseate gold paste is presented after roasting, the percentage by weight shared by concrete composition is as shown in table 1：
The formula table of the embodiment 1 of table 1
The paste sample that the ratio be given according to embodiment 1 is provided, is highly suitable for manufacturing the serigraphy of ceramic marble paper.
As a result it is deep rose color and luster after 500～850 degree of roastings.
Embodiment 2
The gold paste of misty rose is presented after roasting, concrete composition proportion is as shown in table 2：
The formula table of the embodiment 2 of table 2
The paste sample that the ratio be given according to embodiment 2 is provided, by the serigraphy at the paper substrate back side, there is light
The coating of paint, is subsequently dried, and through 500-850 DEG C of roasting on ceramics, produces a kind of misty rose pool.
Embodiment 3
Deep roseate liquid noble metal preparation is presented after roasting, concrete composition proportion is as shown in table 3：
The formula table of the embodiment 3 of table 3
Aforesaid liquid noble metal preparation viscosity is 110MPAS, is squeegeed onto on ceramics, 800 DEG C of sintering temperature, in ceramics
Surface presents deep rose-colored.
Embodiment 4
The liquid noble metal preparation of misty rose is presented after roasting, concrete composition proportion is as shown in table 4：
The formula table of the embodiment 4 of table 4
Aforesaid liquid noble metal preparation is printed on ceramics, 800 DEG C of sintering temperature, and shallow rose is presented in ceramic surface after roasting
Rare color.
Generally, as solvent, lavender, rosemary, lavender spike oil and turpentine oil prioritizing selection.
Solvent and resin contribute to forming cream, for specific utilization, are added to the viscosity for requiring to be adjusted to need.It is logical
Often, it is well known that in 500-2000mPas, this range of viscosities is adapted to screen printing to the range of viscosities of chemical composition in technique
Brush, however, range of viscosities for liquid noble metal preparation is optimal in 80-120mPas.
After ceramic base material is employed, the synthetic roasting within specified temperatures of invention at present, for porcelain, temperature
Between 650 DEG C to 820 DEG C.During baking, organic material is fully burned off, and leaves the noble metal film of light.
Above content is to combine specific preferred embodiment further description made for the present invention, it is impossible to assert
The present invention be embodied as be confined to these explanations.For general technical staff of the technical field of the invention,
On the premise of without departing from present inventive concept, some simple deduction or replace can also be made, should all be considered as belonging to the present invention's
Protection domain.
Claims (10)
1. a kind of rose gold color and luster preparation for ceramic decoration, it is characterised in that：Including the metal of the gold being dissolved in solvent
Organic compound, the metallo-organic compound of the bismuth being dissolved in solvent, the metallo-organic compound of the rhodium being dissolved in solvent, it is dissolved in
The metallo-organic compound of the silicon in solvent, the underlying metal flux being dissolved in solvent and the enough fusing metals of on-hand quantity
Base material；The gold accounts for 3% ~ 7%；The content of underlying metal flux meets can melt whole
Gold, bismuth, rhodium, silicon；The underlying metal of the underlying metal flux is bismuth, rhodium or their mixture；It is described for making pottery
The rose gold color and luster preparation brushing of porcelain decoration or after being transferred on ceramics, ceramic whiteware or glass baseplate, obtains in 500 ~ 800 DEG C of roastings
Arrive.
2. the rose gold color and luster preparation for ceramic decoration according to claim 1, it is characterised in that：It is described for ceramics
The rose gold color and luster preparation of decoration also includes the metallo-organic compound of the titanium being dissolved in solvent.
3. the rose gold color and luster preparation for ceramic decoration according to claim 2, it is characterised in that：The titanium before roasting
Account for 3% ~ 10% with the total content of bismuth, the weight ratio of the titanium and bismuth as metal is 5:1 ~10:1.
4. the rose gold color and luster preparation for ceramic decoration according to claim 2, it is characterised in that：As the bismuth of metal
It is 1 with the weight ratio of silicon:1.
5. the rose gold color and luster preparation for ceramic decoration according to claim 2, it is characterised in that：As the titanium of metal
It is 1 with the weight ratio of silicon:1.
6. the rose gold color and luster preparation for ceramic decoration according to claim 2, it is characterised in that：As metal
The total content of bismuth, silicon and titanium accounts for 3% ~ 5%.
7. the rose gold color and luster preparation for ceramic decoration according to claim 1, it is characterised in that：It is also molten including being dissolved in
The metallo-organic compound of the barium in agent.
8. the rose gold color and luster preparation for ceramic decoration according to claim 7, it is characterised in that：As the bismuth of metal
Weight ratio with barium is less than 2:1, the weight ratio of the barium and silicon as metal is 3:1~4:1.
9. the rose gold color and luster preparation for ceramic decoration according to claim 8, it is characterised in that：The bismuth, silicon and
Barium tenor percentage by weight altogether is 1% ~ 3%.
10. the rose gold color and luster preparation for ceramic decoration according to claim 1 ~ 9 any one, it is characterised in that：
The organo-metallic compound of the bismuth is the carboxylate of bismuth, and the organo-metallic compound of the titanium is the carboxylate of titanium, the barium
Organo-metallic compound be barium carboxylate；The solvent be benzyl alcohol, cyclohexanone, turpentine oil, pine tar, dimethylbenzene,
At least one in the dilute resin of terpene, dipentene, lavender spike oil, lemon thin oil, Lavender, Rosemary Oil or camphor essential oil；
The described deep rose gold color and luster preparation for ceramic decoration also includes auxiliary agent, and the auxiliary agent includes rosin and flexible resin, institute
Flexible resin is stated for polyamide；The auxiliary agent also includes defoamer and thixotropic agent.
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| CN201611145200.1A CN106631167A (en) | 2016-12-13 | 2016-12-13 | Rose gold color preparation for ceramic decoration |
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| CN201611145200.1A CN106631167A (en) | 2016-12-13 | 2016-12-13 | Rose gold color preparation for ceramic decoration |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113524964A (en) * | 2020-04-17 | 2021-10-22 | Oppo广东移动通信有限公司 | Electronic equipment shell, decoration method thereof and electronic equipment |
| CN113543538A (en) * | 2020-04-20 | 2021-10-22 | Oppo广东移动通信有限公司 | Shell of electronic terminal, shell preparation method and electronic terminal |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113524964A (en) * | 2020-04-17 | 2021-10-22 | Oppo广东移动通信有限公司 | Electronic equipment shell, decoration method thereof and electronic equipment |
| CN113543538A (en) * | 2020-04-20 | 2021-10-22 | Oppo广东移动通信有限公司 | Shell of electronic terminal, shell preparation method and electronic terminal |
| CN113543538B (en) * | 2020-04-20 | 2023-06-06 | Oppo广东移动通信有限公司 | Shell of electronic terminal, shell preparation method and electronic terminal |
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