CN106830999A - A kind of noble metal preparation of resistance to dish-washing machine - Google Patents
A kind of noble metal preparation of resistance to dish-washing machine Download PDFInfo
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- CN106830999A CN106830999A CN201710015896.4A CN201710015896A CN106830999A CN 106830999 A CN106830999 A CN 106830999A CN 201710015896 A CN201710015896 A CN 201710015896A CN 106830999 A CN106830999 A CN 106830999A
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- Prior art keywords
- dish
- washing machine
- resistance
- noble metal
- metallo
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/88—Metals
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/515—Other specific metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/515—Other specific metals
- C04B41/5161—Tin
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Chemically Coating (AREA)
Abstract
The invention provides a kind of noble metal preparation of resistance to dish-washing machine, the noble metal preparation of the resistance to dish-washing machine includes：The metallo-organic compound of the metallo-organic compound of the gold, platinum or the palladium that are dissolved in solvent, the metallo-organic compound of the vanadium being dissolved in solvent, the metallo-organic compound of the zirconium being dissolved in solvent, the metallo-organic compound of the bismuth being dissolved in solvent, the chromium being dissolved in solvent.Using technical scheme, the noble metal preparation of the resistance to dish-washing machine keeps the color of light using the product after fired on the silicate base material, and with mechanical resistant abrasion and chemical resistance corrosion higher, anti- dish-washing machine excellent performance, still keeps the light of the noble metal decorative layer on silicate base material after being tested through resistance to dish-washing machine.
Description
Technical field
The invention belongs to Inorganic Non-metallic Materials decoration technique field, more particularly to a kind of noble metal system of resistance to dish-washing machine
Agent.
Background technology
The noble metal preparation of light is with organic basic compound shape by soluble organic precious metal compounds and one kind
Soluble fluxes and a kind of organic vehicle composition that formula is presented.As a kind of flux, the number of organo-metallic compound
Amount is 0.25-1mol, and every mole of noble metal can use underlying metal.These preparations are employed for the noble metal film on ceramics
Production, sintering temperature is 1140 DEG C.Although but these external coatings can battle line light noble metal speciality, be not resistant to wash
Bowl machine.
Made referrals in patent DE-AS 22 08 915, the polished bright-gold preparations containing Solid non-metallic oxide, higher than Huang
1063 DEG C of the fusing point of gold, it is adaptable to silicate material.Although the golden thin film that it is fired into has relatively highly dense coating, can also show
Show the characteristic of bright golden color, but their mechanical resistant abrasion and chemical resistance corrode poor, it is impossible to anti-dish-washing machine.
The content of the invention
For above technical problem, the invention discloses a kind of noble metal preparation of resistance to dish-washing machine, it is using in silicate
On base material it is fired after product keep the color of light, and with mechanical resistant abrasion higher and chemical resistance corrosion.
In this regard, the technical scheme is that：
A kind of noble metal preparation of resistance to dish-washing machine, the noble metal preparation of the resistance to dish-washing machine includes：
The metallo-organic compound of the gold, platinum or the palladium that are dissolved in solvent, the Organometallic of the vanadium being dissolved in solvent are closed
Thing, the metallo-organic compound of the zirconium being dissolved in solvent, the metallo-organic compound of the bismuth being dissolved in solvent, it is dissolved in solvent
In chromium metallo-organic compound.
Preferably, the noble metal preparation includes the underlying metal flux being dissolved in solvent.
Preferably, the metallo-organic compound of the gold, platinum or palladium is the resinate of gold, platinum or palladium.
Wherein, the selection of the constituent of the solvent of bearing metal organic compound can come from various suitable organic molten
Agent, wherein essential oil can be selected.For example, the composition of solvent can be any suitable simple organic solvent or two kinds or two kinds
More than organic solvent mixture, such as toluene, nitrobenzene, butanol, phenmethylol, cellosolve, butyl cellosolve, acetone, butanone,
Cyclohexanone, ethyl acetate, butyl acetate, ether, turpentine oil, terpineol, dimethylbenzene, various note alkenes such as firpene, cinene etc..
Essential oil can include lavender oil, rosemary oil, lavender spike oil and/or camphorated oil.The noble metal preparation can also include viscous
Mixture, described adhesive is synthetic resin, preferably phenolic resin.
Using this technical scheme, it is fired on the silicate base material after product keep the color of light, with very strong
Mechanical resistant is worn and torn, anti-dish-washing machine performance, through dish-washing machine after, remain to keep the noble metal on silicate base material such as ceramic whiteware, ceramics
The light of decorative layer.
As a further improvement on the present invention, the content of the vanadium accounts for the 0.016~0.1% of component gross weight.
As a further improvement on the present invention, the noble metal preparation of the resistance to dish-washing machine also includes the tin being dissolved in solvent
Metallo-organic compound.
As a further improvement on the present invention, the content of the tin accounts for the 0.08-0.1% of component gross weight.
As a further improvement on the present invention, the metallo-organic compound of the tin is the carboxylate of tin.
As a further improvement on the present invention, the total content of bismuth, zirconium and chromium accounts for the 0.5-1% of component gross weight.
As a further improvement on the present invention, the content of the bismuth accounts for the 0.4-0.8% of component gross weight, and the chromium contains
Amount accounts for the 0.08-0.2% of component gross weight, and the content of the zirconium accounts for the 0.05-0.1% of component gross weight.
As a further improvement on the present invention, the metallo-organic compound of the bismuth is the carboxylate of bismuth, the gold of the vanadium
Category organic compound is the carboxylate of vanadium, and the metallo-organic compound of the zirconium is the carboxylate of zirconium, and the metal of the chromium is organic
Compound is the carboxylate of chromium.
As a further improvement on the present invention, the carboxylate of the bismuth, the carboxylate of vanadium, the carboxylate of zirconium, the carboxylic acid of chromium
The carboxylate of salt and tin is what is extracted from bismuth, zirconium, vanadium, chromium, tin and its mixture.
As a further improvement on the present invention, the roasting that the noble metal preparation of the resistance to dish-washing machine is used on silicate base material
Temperature is 780~820 DEG C.
As a further improvement on the present invention, the noble metal preparation of the resistance to dish-washing machine also includes auxiliary agent, the auxiliary agent bag
Include rosin and flexible resin, the flexible resin such as polyamide.
Using this technical scheme, the flexible resin dissolves as carrier in organo-metallic compound, beneficial to carrying out silk
Wire mark brush.
As a further improvement on the present invention, the auxiliary agent also includes defoamer and thixotropic agent.Using this technical scheme, have
Beneficial to preferably carrying out silk-screen printing.
It is the noble metal using above-mentioned resistance to dish-washing machine the invention also discloses a kind of noble metal decorating film of resistance to dish-washing machine
Preparation is transferred on silicate base material, is calcined at 780~820 DEG C.
Compared with prior art, beneficial effects of the present invention are：
Using technical scheme, the noble metal preparation of the resistance to dish-washing machine uses fired on silicate base material
Product afterwards keeps the color of light, and with mechanical resistant abrasion and chemical resistance corrosion higher, anti-dish-washing machine performance is excellent
It is different, the light of the noble metal decorative layer on silicate base material is still kept after being tested through dish-washing machine.
Specific embodiment
Preferably embodiment of the invention is described in further detail below.
Embodiment 1
Formula table according to table 1 weighs each component, and be mixed it is uniform after, heated 1.5 hours in 75 DEG C of constant temperature,
It is brushed on the region of hard porcelain 0.5cm*4cm, has after then being fired 90 minutes in 820 DEG C of constant temperature, on hard porcelain surface resistance to
The bright gold external coating of dish-washing machine.
By the bright gold external coating on this hard porcelain surface, tested according to ASTM carbonic ester standard testings, that is, be put into 95 DEG C
In dissolved with the water of 0.5% sodium carbonate, wiped respectively through being used cloth to wipe with after 2,4,6 hours, without abrasion.
Additionally, tested according to the resistance to test b S EN12875-2 that wash the dishes of British Standard, 0.5% detergent specified into
In point, the detergent includes sodium carbonate 1-20%, anhydrous sodium metasilicate 40-80% and sodium dichloro cyanurate 0.25-
2.5%；Temperature is 75 DEG C, is within 16 hours a cycle, and total immersion is steeped 32 hours, wiped with dry cloth afterwards, meets standard requirement.
Washed the dishes program, hard porcelain table in addition, the hard porcelain with bright gold external coating of this example being put into dish-washing machine and carrying out completion
The bright gold external coating in face does not wear and tear.
The formula table of the embodiment 1 of table 1
Embodiment 2
A kind of noble metal silk-screen printing preparation of light, weighs each component, by above-mentioned substance 90 according to the formula table of table 2
DEG C to stirring between 120 DEG C, it is allowed to homogenize and colloidization reaction.Then, matter is printed on as applique
On the very hard porcelain in ground, printing area size is 5 × 5cm, after being calcined through 820 DEG C, forms one layer of golden layer of light, and it is entered
Row dish-washing machine is tested.
The formula table of the embodiment 2 of table 2
% in upper table is weight percentage.
By the bright golden layer on above-mentioned porcelain surface, tested according to ASTM carbonic ester standard testings, that is, be put into 95
In DEG C dissolved with the water of 0.5% sodium carbonate in, wiped respectively through being used cloth to wipe with after 2,4,6 hours, without abrasion.
Additionally, tested according to the resistance to test b S EN12875-2 that wash the dishes of British Standard, 0.5% detergent specified into
In point, the detergent includes sodium carbonate 1-20%, anhydrous sodium metasilicate 40-80% and sodium dichloro cyanurate 0.25-
2.5%；Temperature is 75 DEG C, is within 16 hours a cycle, and total immersion is steeped 32 hours, wiped with dry cloth afterwards, meets standard requirement.
Washed the dishes program, porcelain table in addition, golden layer porcelain of this example with light being put into dish-washing machine and carrying out completion
The bright golden layer in face does not wear and tear.
Embodiment 3
A kind of is the bright white gold preparation (7% gold medal) of silk-screen printing preparation, and formula table is as shown in table 3.According to table 3
Formula table weighs each component, and above-mentioned substance is stirred at 75 DEG C, is allowed to homogenize and thixotropy.Then, as patch
Spend and be equally printed on the very hard porcelain of quality, printing area size is 5x5cm, after being calcined through 820 DEG C, form one layer of light
Bright platinum chromatograph, dish-washing machine test is carried out to it.
The formula table of the embodiment 3 of table 3
% in upper table is weight percentage.
By the bright platinum chromatograph on above-mentioned porcelain surface, tested according to ASTM carbonic ester standard testings, that is, be put into
In 95 DEG C dissolved with the water of 0.5% sodium carbonate in, wiped respectively through being used cloth to wipe with after 2,4,6 hours, without abrasion.
Additionally, tested according to the resistance to test b S EN12875-2 that wash the dishes of British Standard, 0.5% detergent specified into
In point, the detergent includes sodium carbonate 1-20%, anhydrous sodium metasilicate 40-80% and sodium dichloro cyanurate 0.25-
2.5%；Temperature is 75 DEG C, is within 16 hours a cycle, and total immersion is steeped 32 hours, wiped with dry cloth afterwards, meets standard requirement.
Washed the dishes program, porcelain in addition, the porcelain of platinum chromatograph of this example with light being put into dish-washing machine and carrying out completion
The bright platinum chromatograph on device surface does not wear and tear.
Above content is to combine specific preferred embodiment further description made for the present invention, it is impossible to assert
Specific implementation of the invention is confined to these explanations.For general technical staff of the technical field of the invention,
On the premise of not departing from present inventive concept, some simple deduction or replace can also be made, should be all considered as belonging to of the invention
Protection domain.
Claims (10)
1. a kind of noble metal preparation of resistance to dish-washing machine, it is characterised in that：The noble metal preparation of the resistance to dish-washing machine includes：
It is the metallo-organic compound of the gold, platinum or the palladium that are dissolved in solvent, the metallo-organic compound of the vanadium being dissolved in solvent, molten
The metallo-organic compound of the zirconium in solvent, the metallo-organic compound of the bismuth being dissolved in solvent, it is dissolved in solvent
The metallo-organic compound of chromium.
2. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：It is total that the content of the vanadium accounts for component
The 0.016 ~ 0.1% of weight.
3. the noble metal preparation of resistance to dish-washing machine according to claim 1 and 2, it is characterised in that：The resistance to dish-washing machine it is expensive
Metal preparation also includes the metallo-organic compound of the tin being dissolved in solvent.
4. the noble metal preparation of resistance to dish-washing machine according to claim 3, it is characterised in that：It is total that the content of the tin accounts for component
The 0.08-0.1% of weight, the metallo-organic compound of the tin is the carboxylate of tin.
5. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：The total content of bismuth, zirconium and chromium is accounted for
The 0.5-1% of component gross weight.
6. the noble metal preparation of resistance to dish-washing machine according to claim 5, it is characterised in that：It is total that the content of the bismuth accounts for component
The 0.4-0.8% of weight, the content of the chromium accounts for the 0.08-0.2% of component gross weight, and the content of the zirconium accounts for component gross weight
0.05-0.1%。
7. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：The Organometallic of the bismuth is closed
Thing is the carboxylate of bismuth, and the metallo-organic compound of the vanadium is the carboxylate of vanadium, and the metallo-organic compound of the zirconium is zirconium
Carboxylate, the metallo-organic compound of the chromium is the carboxylate of chromium.
8. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：The noble metal of the resistance to dish-washing machine
Preparation also includes auxiliary agent, and the auxiliary agent includes rosin and flexible resin, and the flexible resin is polyamide；The auxiliary agent also includes
Defoamer and thixotropic agent.
9. the noble metal preparation of resistance to dish-washing machine according to claim 1, it is characterised in that：The noble metal of the resistance to dish-washing machine
The sintering temperature that preparation is used on silicate base material is 780 ~ 820 DEG C.
10. a kind of noble metal decorating film of resistance to dish-washing machine, is using the resistance to dish-washing machine as described in claim 1 ~ 9 any one
Noble metal preparation is transferred on silicate base material, is calcined at 780 ~ 820 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710015896.4A CN106830999B (en) | 2017-01-10 | 2017-01-10 | Precious metal preparation resistant to dish washing machine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710015896.4A CN106830999B (en) | 2017-01-10 | 2017-01-10 | Precious metal preparation resistant to dish washing machine |
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| Publication Number | Publication Date |
|---|---|
| CN106830999A true CN106830999A (en) | 2017-06-13 |
| CN106830999B CN106830999B (en) | 2022-09-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201710015896.4A Active CN106830999B (en) | 2017-01-10 | 2017-01-10 | Precious metal preparation resistant to dish washing machine |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4418099A (en) * | 1982-02-05 | 1983-11-29 | Engelhard Corporation | Non-burnished precious metal composition |
| CN1346339A (en) * | 1999-04-09 | 2002-04-24 | W.C.贺利氏股份有限及两合公司 | Bright noble metal preparation |
| CN1637096A (en) * | 2003-12-17 | 2005-07-13 | W.C.贺利氏有限公司 | Noble metal preparations and lustring preparations for direct and indirect screen printing |
| CN101555163A (en) * | 2009-05-13 | 2009-10-14 | 深圳市永丰源实业有限公司 | Noble metal preparation or luster preparation for direct or indirect silk screen printing |
-
2017
- 2017-01-10 CN CN201710015896.4A patent/CN106830999B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4418099A (en) * | 1982-02-05 | 1983-11-29 | Engelhard Corporation | Non-burnished precious metal composition |
| CN1346339A (en) * | 1999-04-09 | 2002-04-24 | W.C.贺利氏股份有限及两合公司 | Bright noble metal preparation |
| CN1637096A (en) * | 2003-12-17 | 2005-07-13 | W.C.贺利氏有限公司 | Noble metal preparations and lustring preparations for direct and indirect screen printing |
| CN101555163A (en) * | 2009-05-13 | 2009-10-14 | 深圳市永丰源实业有限公司 | Noble metal preparation or luster preparation for direct or indirect silk screen printing |
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| Publication number | Publication date |
|---|---|
| CN106830999B (en) | 2022-09-30 |
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