CN109574712A - A kind of composite plating glazed tile and preparation method thereof - Google Patents

A kind of composite plating glazed tile and preparation method thereof Download PDF

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Publication number
CN109574712A
CN109574712A CN201811644743.7A CN201811644743A CN109574712A CN 109574712 A CN109574712 A CN 109574712A CN 201811644743 A CN201811644743 A CN 201811644743A CN 109574712 A CN109574712 A CN 109574712A
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CN
China
Prior art keywords
plating
preparation
semi
finished product
coated metal
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Pending
Application number
CN201811644743.7A
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Chinese (zh)
Inventor
章云党
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FOSHAN ZHANGSHI BROTHERS BUILDING MATERIALS CO LTD
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FOSHAN ZHANGSHI BROTHERS BUILDING MATERIALS CO LTD
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Priority to CN201811644743.7A priority Critical patent/CN109574712A/en
Publication of CN109574712A publication Critical patent/CN109574712A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C04B41/90Coating or impregnation for obtaining at least two superposed coatings having different compositions at least one coating being a metal
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
    • E04F13/142Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of ceramics or clays

Abstract

The invention belongs to Ceramic Tiles technical fields more particularly to a kind of composite plating glazed tile and preparation method thereof.The present invention provides a kind of preparation methods of composite plating glazed tile, comprising the following steps: a) stamps pattern on bottom brick surface, then covers with reeded frit layer, be burnt into, obtains the first semi-finished product;B) the first semi-finished product are subjected to the first plating, obtain the second semi-finished product;C) covering layer, covering layer covering part groove are stamped on the second semi-finished product, then carries out the second plating, obtain third semi-finished product;D) covering layer that third semi-finished product are polished and removed with groove obtains composite plating glazed tile;Wherein, the first plating is different with the coated metal color of the second plating.It is coated with the metal of two or more different colours in the groove for the composite plating glazed tile that the present invention is prepared, enriches the form of expression of glazed tile, can satisfy the different demands of user, there are good market prospects.

Description

A kind of composite plating glazed tile and preparation method thereof
Technical field
The invention belongs to Ceramic Tiles technical fields more particularly to a kind of composite plating glazed tile and preparation method thereof.
Background technique
Glazed tile, also known as Polished crystal tile or glaze polished bricks are to apply one layer of abrasion-resistant clear glaze in billet surface, by complexity Made of firing, polishing.Glazed tile have the characteristics that color glazed brick decoration it is abundant it is low with porcelain water absorption rate, material capability is good, and gram It has taken color glazed brick and has decorated the drawback that not wear-resisting, resist chemical performance is poor and Imitation Rock Porcelain Tiles trailing is simple.Glazed tile uses glaze Lower decoration, high temperature firing, glaze is fine and smooth, noble magnificent, belongs to expensive goods.But current glazed tile only have it is single Metal is gold-plated, and color is single.
Summary of the invention
This is in consideration of it, the present invention provides a kind of composite plating glazed tile and preparation method thereof, for solving existing throwing glaze Brick only has single metal gold-plated, the single problem of color.
The specific technical solution of the present invention is as follows:
A kind of preparation method of composite plating glazed tile, comprising the following steps:
A) pattern is stamped on bottom brick surface, then covered with reeded frit layer, is burnt into, obtain the first semi-finished product;
B) first semi-finished product are subjected to the first plating, obtain the second semi-finished product;
C) covering layer, groove described in the covering layer covering part are stamped on second semi-finished product, then carry out second Plating;
D) the third semi-finished product that step c) is obtained are polished and removed with the covering layer of the groove, obtains composite plating Glazed tile;
Wherein, first plating is different with the coated metal color of second plating.
Preferably, the number of step c) is more than twice;
The covering layer is coated with the recess region of the coated metal of upper primary second plating in rear primary covering part, The coated metal color of second plating is different every time.
Preferably, the decomposition temperature of the step c) covering layer is 880 DEG C~910 DEG C;
The covering layer dissolves in solvent.
Preferably, the ingredient of the covering layer is selected from white glaze, stamp colorant or recycles useless colorant.
Preferably, the coated metal of step b) first plating is selected from electric light, platinum, gold, dark fund, rose gold or unreal Colour TV light.
Preferably, the coated metal of step c) second plating is selected from electric light, platinum, gold, dark fund, rose gold or unreal Colour TV light.
Preferably, the coated metal of first plating is electric light, and the coated metal of second plating is gold;Or
The coated metal of first plating is gold, and the coated metal of second plating is electric light.
Preferably, the temperature of the firing is 910 DEG C~960 DEG C;
The time of the firing is 75min~85min.
Preferably, the depth of the groove is 0.3mm~1.5mm.
The present invention also provides composite plating glazed tiles made from preparation method described in above-mentioned technical proposal.
In conclusion the present invention provides a kind of preparation methods of composite plating glazed tile, comprising the following steps: a) bottom of at Brick surface stamps pattern, then covers with reeded frit layer, is burnt into, and the first semi-finished product are obtained;B) by described the first half Finished product carries out the first plating, obtains the second semi-finished product;C) covering layer is stamped on second semi-finished product, the covering layer covers The part groove, then the second plating is carried out, obtain third semi-finished product;D) the third semi-finished product are polished and is removed recessed The covering layer of slot obtains composite plating glazed tile;Wherein, the coated metal color that first plating is electroplated with described second is not Together.In the present invention, plating includes the first plating and the second plating, stamps screening on the second semi-finished product obtained by the first plating Cap rock, covering layer covering part groove carry out the second plating again, and the first plating is different with the coated metal color of the second plating, makes The metal for being coated with two or more different colours in the groove of composite plating glazed tile is obtained, the form of expression of glazed tile, energy are enriched Enough meet the different demands of user, there are good market prospects.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described.
Fig. 1 is a kind of flow diagram of the preparation method of composite plating glazed tile provided in an embodiment of the present invention;
Fig. 2 is a kind of picture for composite plating glazed tile that the embodiment of the present invention 2 provides;
Fig. 3 is a kind of picture for composite plating glazed tile that the embodiment of the present invention 3 provides.
Specific embodiment
The present invention provides a kind of composite plating glazed tiles and preparation method thereof, only have list for solving existing glazed tile One metal is gold-plated, the single problem of color.
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Referring to Fig. 1, for a kind of process signal of the preparation method of composite plating glazed tile provided in an embodiment of the present invention Figure.
A kind of preparation method of composite plating glazed tile, comprising the following steps:
A) pattern is stamped on bottom brick surface, then covered with reeded frit layer, is burnt into, obtain the first semi-finished product;
B) the first semi-finished product are subjected to the first plating, obtain the second semi-finished product;
C) covering layer, covering layer covering part groove are stamped on the second semi-finished product, then carry out the second plating;
D) the third semi-finished product that step c) is obtained are polished and removed with the covering layer of the groove, obtains composite plating Glazed tile;
Wherein, the first plating is different with the coated metal color of the second plating.
In the embodiment of the present invention, plating includes the first plating and the second plating, in the second half obtained by the first plating Covering layer is stamped on finished product, covering layer covering part groove carries out the second plating, the coating gold of the first plating and the second plating again It is different to belong to color, so that being coated with the metal of two or more different colours in the groove of composite plating glazed tile, enriches glazed tile The form of expression, can satisfy the different demands of user, have good market prospects.
In the embodiment of the present invention, composite plating glazed tile is marble karat gold brick modelled after an antique.
In the embodiment of the present invention, stamp pattern on bottom brick surface, rather than stamp pattern on biscuit surface, bottom brick be by Firing, it is subsequent to stamp covering layer again, subsequent print covering layer set position will not be caused inaccurate because biscuit firing shrinkage rates are inconsistent, Enable to electroplating effect finely accurate, production is stablized, and batch production is able to carry out.
In the embodiment of the present invention, the number of step c) is more than twice;
Covering layer is coated with the recess region of the coated metal of upper primary second plating in rear primary covering part, and every time second The coated metal color of plating is different, so that there are three types of the metals of the above different colours for plating in groove, further enriches glazed tile The form of expression, meet the needs of different user.
In the embodiment of the present invention, step c) stamps covering layer on the second semi-finished product and specifically includes:
Covering layer is stamped on the second semi-finished product using the screen cloth of 40 mesh.
In the embodiment of the present invention, the decomposition temperature of step c) covering layer is 880 DEG C~910 DEG C;
The covering layer dissolves in solvent.
In the embodiment of the present invention, the temperature of the second plating is 330 DEG C~350 DEG C, the decomposition temperature of covering layer is 880 DEG C~ 910 DEG C, it is ensured that covering layer does not decompose when carrying out the second plating, it is ensured that its covering effect.The screening of third semi-finished product plane domain Cap rock is removed by polishing, is not influenced the pattern color below frit layer and is presented.Covering layer of the embodiment of the present invention makes groove can The metal of different colours is plated, and can be removed by being dissolved in solvent, removal is convenient.
In the embodiment of the present invention, the ingredient of covering layer is high temperature resistant inorganic material, be it is powdered, used selected from white glaze, stamp Colorant recycles useless colorant.
The decomposition temperature of white glaze is 880 DEG C~910 DEG C, and white glaze is water-soluble, and white glaze is by by methyl, formaldehyde and basic color Material 4608 is made.
In the embodiment of the present invention, the coated metal that step b) first is electroplated is selected from electric light, platinum, gold, dark fund, rose gold Or illusion-colour electric light.
It should be noted that electric light refers to that coated metal is transparent metal color.
In the embodiment of the present invention, step c) second be electroplated coated metal be selected from electric light, platinum, gold, dark fund, rose Gold or illusion-colour electric light.
The vacuum degree of first plating is 3.0-2~7.0-2Pa, the vacuum degree of the second plating are 3.0-2~7.0-2Pa。
In the embodiment of the present invention, the coated metal of the first plating is electric light, and the coated metal of the second plating is gold;Or
The coated metal of first plating is gold, and the coated metal of the second plating is electric light.
Electric light and gold are combined, can reach the complementation of respective advantage and disadvantage, simple electro-optic effect is avoided to be easy too Low-key, simple gold are easy to make widely known very much, combine the two, can reach the light luxurious stylistic effects of the low-key of market popularity.
In the embodiment of the present invention, the temperature of firing is 910 DEG C~960 DEG C;
The time of firing is 75min~85min.
In the embodiment of the present invention, the depth of groove is 0.3mm~1.5mm, and it is shallower to can be avoided marble groove, polish into Row, which adds lustre to, is easy the problem of metal effect throwing there is not.
The embodiment of the invention also provides composite plating glazed tile made from above-mentioned technical proposal preparation method, the compound electrics Plating glazed tile enriches the form of expression of glazed tile, can satisfy the different demands of user, has good market prospects.
For a further understanding of the present invention, the present invention will be described in detail combined with specific embodiments below.
Embodiment 1
The preparation of the present embodiment progress composite plating glazed tile, comprising the following steps:
1) bottom brick surface is wiped clean, stamps pattern on bottom brick surface with printing machine, then cover with reeded frit layer, 80min, 930 DEG C of firing are carried out in kiln, frit layer fuses into transparent vitreum, and the pattern color below frit layer is in Reveal and, obtains the first semi-finished product;
2) the first semi-finished product are carried out to the first plating in vacuum plating furnace, coated metal is electric light, the first plating it is true Reciprocal of duty cycle is 3.0-2Pa obtains the second semi-finished product;
3) covering layer (ingredient of covering layer is white glaze) is stamped with the screen cloth of 40 mesh on the second semi-finished product, covering layer covers Part recess, the part recess have no need to change coating color, after covering layer drying, then carry out the second plating, coated metal For gold, third semi-finished product are obtained;
4) third semi-finished product are polished using polishing machine, obtains composite plating glazed tile, throw glaze in the composite plating Existing electric light has gold again in the groove of brick, then carries out edging packing.
Embodiment 2
Referring to Fig. 2, a kind of picture of the composite plating glazed tile provided for the embodiment of the present invention 2.The present embodiment carries out The preparation of composite plating glazed tile, the preparation method is the same as that of Example 1, but the coated metal of the first plating is electric light, the second plating Coated metal is platinum.
Embodiment 3
Referring to Fig. 3, a kind of picture of the composite plating glazed tile provided for the embodiment of the present invention 3.The present embodiment carries out The preparation of composite plating glazed tile, the preparation method is the same as that of Example 1, but the coated metal of the first plating is platinum, the second plating Coated metal is gold.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (10)

1. a kind of preparation method of composite plating glazed tile, which comprises the following steps:
A) pattern is stamped on bottom brick surface, then covered with reeded frit layer, is burnt into, obtain the first semi-finished product;
B) first semi-finished product are subjected to the first plating, obtain the second semi-finished product;
C) covering layer, groove described in the covering layer covering part are stamped on second semi-finished product, then carry out the second plating;
D) the third semi-finished product that step c) is obtained are polished and removed with the covering layer of the groove, composite plating is obtained and throws glaze Brick;
Wherein, first plating is different with the coated metal color of second plating.
2. preparation method according to claim 1, which is characterized in that the number of step c) is more than twice;
The covering layer is coated with the recess region of the coated metal of upper primary second plating in rear primary covering part, every time The coated metal color of second plating is different.
3. preparation method according to claim 1, which is characterized in that the decomposition temperature of the step c) covering layer is 880 DEG C~910 DEG C;
The covering layer dissolves in solvent.
4. preparation method according to claim 3, which is characterized in that the ingredient of the covering layer is selected from white glaze, stamp is used Colorant recycles useless colorant.
5. preparation method according to claim 1, which is characterized in that the coated metal of step b) first plating is selected from Electric light, platinum, gold, dark fund, rose gold or illusion-colour electric light.
6. preparation method according to claim 1, which is characterized in that the coated metal of step c) second plating is selected from Electric light, platinum, gold, dark fund, rose gold or illusion-colour electric light.
7. preparation method according to claim 5, which is characterized in that the coated metal of first plating is electric light, institute The coated metal for stating the second plating is gold;Or
The coated metal of first plating is gold, and the coated metal of second plating is electric light.
8. preparation method according to claim 1, which is characterized in that the temperature of the firing is 910 DEG C~960 DEG C;
The time of the firing is 75min~85min.
9. preparation method according to claim 1, which is characterized in that the depth of the groove is 0.3mm~1.5mm.
10. according to claim 1 to composite plating glazed tile made from preparation method described in 9 any one.
CN201811644743.7A 2018-12-30 2018-12-30 A kind of composite plating glazed tile and preparation method thereof Pending CN109574712A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1644559A (en) * 2004-10-13 2005-07-27 陈满坚 Metal plated and polished ceramic products and their manufacture
CN102674899A (en) * 2011-10-21 2012-09-19 佛山市章氏兄弟建材有限公司 Production method of matte underglazed color polished and glazed bricks
KR101369065B1 (en) * 2012-11-13 2014-02-28 이희옥 The manufacturing method of a ceramic cloisonne using conglomerate with quartz powder
CN104130033A (en) * 2014-07-01 2014-11-05 陈伟煊 Gold-plating technology for glazed ceramic tiles
CN107459370A (en) * 2017-08-15 2017-12-12 上海双石钛金有限公司 A kind of colorful coating of ceramic base and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1644559A (en) * 2004-10-13 2005-07-27 陈满坚 Metal plated and polished ceramic products and their manufacture
CN102674899A (en) * 2011-10-21 2012-09-19 佛山市章氏兄弟建材有限公司 Production method of matte underglazed color polished and glazed bricks
KR101369065B1 (en) * 2012-11-13 2014-02-28 이희옥 The manufacturing method of a ceramic cloisonne using conglomerate with quartz powder
CN104130033A (en) * 2014-07-01 2014-11-05 陈伟煊 Gold-plating technology for glazed ceramic tiles
CN107459370A (en) * 2017-08-15 2017-12-12 上海双石钛金有限公司 A kind of colorful coating of ceramic base and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
MANISH ROY: "《抗磨损表面工程技术》", 30 June 2018, 北京:国防工业出版社 *

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