CN1644559A - Metal plated and polished ceramic products and their manufacture - Google Patents

Metal plated and polished ceramic products and their manufacture Download PDF

Info

Publication number
CN1644559A
CN1644559A CN 200410051820 CN200410051820A CN1644559A CN 1644559 A CN1644559 A CN 1644559A CN 200410051820 CN200410051820 CN 200410051820 CN 200410051820 A CN200410051820 A CN 200410051820A CN 1644559 A CN1644559 A CN 1644559A
Authority
CN
China
Prior art keywords
pattern
layer
frit powder
manufacture craft
titanium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 200410051820
Other languages
Chinese (zh)
Other versions
CN1274633C (en
Inventor
陈满坚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Pui Pui culture Ceramics Co., Ltd.
Original Assignee
陈满坚
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34868713&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1644559(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 陈满坚 filed Critical 陈满坚
Priority to CN 200410051820 priority Critical patent/CN1274633C/en
Publication of CN1644559A publication Critical patent/CN1644559A/en
Application granted granted Critical
Publication of CN1274633C publication Critical patent/CN1274633C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

Abstract

A metallized glaze kick-off ceramic product and its production are disclosed. The product consists of bat and bat upper surface producing pattern layer The pattern upper surface of the pattern layer is coated by two block or above smooth-surface transparent block fired frit powder, filling metal cladding material in flute is formed between the transparent blocks, titanium gold, titanium sliver or other metal materials are plated between the patterns. It achieves transparent surface, colorful pattern, and good three-dimension and decorative effect.

Description

A kind of metallizing is thrown glaze ceramic and manufacture craft thereof
Technical field
The present invention relates to a kind of ceramic, relate in particular to and throw glaze metallizing ceramic and preparation method thereof.
Background technology
Golden ceramic is a kind of ornament of top grade, with its noble quality, magnificent and be subjected to the favor in market deeply.Existing golden ceramic is a planar products, and following several manufacture craft is arranged: silk screen print method, and promptly ceramic burns till through after the silk screen printing; The decal paper method promptly earlier is prefabricated into marble paper with Jinsui River, and ceramic burns till behind decal paper; Describe or spraying method, promptly ceramic manually describe or spray gun spraying after burn till.The ceramic that these several technologies are made lacks stereoscopic sensation, shows slightly stiff, visually dislikes flat slightly.
Summary of the invention
The purpose of this invention is to provide the metallizing that a kind of stereoscopic sensation is strong, the surface is glittering and translucent, decorative effect is splendid and throw the glaze ceramic.
Another object of the present invention provides the manufacture craft that this metallizing is thrown the glaze ceramic.
Metallizing of the present invention is thrown the glaze ceramic, comprise adobe, adobe upper surface pattern-making layer, the patterned surfaces of described patterned layer cover the transparent block of two or more than two surface smoothing that is formed by the frit powder sintering, filler metal coating in the groove that forms between the transparent block.
Make above-mentioned metallizing and throw the technology of glaze ceramic, may further comprise the steps successively:
A. at adobe upper surface pattern-making layer;
B. at the patterned surfaces spreading frit powder of patterned layer, the frit powder formation groove of leaving a blank;
C. burn till, make the frit powder sintering form transparent block;
D. the work in-process upper surface at step C plates titanium, titanium silver or other metallic substance, makes metal plating fill up groove;
E. the metal plating that is covered in the transparent block surface is removed in surface finish.
Adopt the throwing glaze ceramic brick surface of manufacture craft made of the present invention glittering and translucent as jewel, appear coloury pattern, then plate between the pattern with titanium, titanium silver or other metallic substance, pattern is carried out sketching the contours of skeletal lines, decorated, interspersed.Titanium-gold-plating or titanium silver layer and transparent block concave-convex surface are inconsistent, and stereoscopic sensation is very strong, have to enrich changeable light diffusion effect, and be bright-colored, shining as color as pearl, the jewel, lively, attractive in appearance far beyond the plane ceramic tile.The ceramic tile that the present invention makes not only has abundant stereoscopic sensation but also has transparent feel and reflecting feel, and its aesthetic property is that existing ceramic tile is incomparable, is a kind of luxurious, high-grade ornamental ceramic tile.
Description of drawings
Fig. 1 a makes raw material adobe synoptic diagram of the present invention.
Fig. 1 b is the side-view of Fig. 1 a.
Fig. 2 a is the adobe of making pattern.
Fig. 2 b is the side-view of Fig. 2 a.
Fig. 3 is the structural representation behind the molten stone flour on the spreading.
Fig. 4 is the structural representation that plates behind the metal level.
Fig. 5 is the finished product structural representation after the polishing.
Fig. 6 is a process principle figure of the present invention.
Embodiment
As shown in Figure 6, the present invention produces according to following processing step successively:
(1) surface treatment is carried out in adobe 1;
Fig. 1 a, 1b are depicted as manufactured adobe 1, with cotton, distilled water its ceramic upper surface stain are removed, and dry then.
(2) at adobe upper surface impressing pattern;
Shown in Fig. 2 a, 2b, at adobe 1 surperficial impressing pattern layer 2, can adopt making of pattern half tone and printing machine to carry out pattern and print, the order number of printing screen is 200～250 orders.Also can adopt other skill and technique such as drafting, massed glaze or applique to carry out design producing.Pattern 21 can be made into coloury pattern, is good with lithotome or jewel line especially.In the present embodiment, pattern 21 is divided into a plurality of Polygonss in irregular shape by skeletal lines 22.
(3) spreading frit powder;
As shown in Figure 3,, then leave a blank, thereby form frit bisque 3 with many grooves 32 corresponding to the position of skeletal lines 22 at the upper surface spreading frit powder 31 of pattern 21.
The thickness of frit powder 31 spreadings is moderate, if spreading must be thin excessively, the finished product stereoscopic sensation that then makes is not strong; Or spreading gets blocked uply, and then the transparency of finished product is undesirable.The coefficient of expansion of frit powder is slightly less than the adobe coefficient of expansion, and is complementary with it.The powder fineness of frit powder is 80～200 orders, its major ingredient following (mass percent):
SiO 2?55～65％ MgO 0.2～0.3％ Al 2O 3?8～9％
K 2O?2～4％ Fe 2O 3 0.1～0.2％ Na 2 O 1～2％
CaO 2～3％ ZnO％ 2.5～4％ BaO 2.5～3.5％
ZrO 2?0.1～0.5％ B 2O 3％?15～20％
The order number of frit paving silk screen is 40～60 orders.
(4) burn till;
The ceramic tile that above-mentioned steps is obtained is carried out three times and is burnt till, and firing temperature is 1000～1030 ℃, and firing period is 40～60 minutes.After burning till, frit powder 31 is formed transparent block 33, appears pattern 21, seems glittering and translucent.
(5) shown in Figure 4, the work in-process upper surface after burning till plates titanium, titanium silver or other metallic substance 4, makes metal plating fill up groove 32 and is covered in monoblock work in-process ceramic tile upper surface;
(6) polishing;
The upper surface that plates behind titanium, titanium silver or other metallic substance is carried out polished finish, grind off the metal plating that is covered in transparent block 33 surfaces, then leave the metal cladding 42 that is covered in from the pattern 22 in the groove 32, metal cladding 42 has different senses of touch and impression with transparent block 33 surfaces, has formed concavo-convex inconsistent top layer.
Through further finally obtaining finished product behind the pick.Finished bricks is level and smooth, glittering and translucent at the master pattern part surface, can see through the pattern that transparent block 33 is seen color class bright-coloured.Metal cladding 42 reaches the strong decorative effect of sketching the contours, interspersing round transparent block 33, and is beautiful as dazzling as jewel, the seven color pearls.
The product that the present invention makes reaches following technical indicator after tested:
Acid resistance: A level
Alkaline resistance properties: A level
Hardness: 6 grades of Mohs
Wear resistance: 2 grades.

Claims (7)

1, a kind of metallizing is thrown the glaze ceramic, comprise adobe (1), adobe (1) upper surface pattern-making layer (2), it is characterized in that: the patterned surfaces of described patterned layer (2) covers the transparent block (33) of two or more than two surface smoothing that is formed by frit powder (31) sintering, the interior filler metal coating of groove (32) (42) that forms between the transparent block (33).
2, metallizing according to claim 1 is thrown the glaze ceramic, and it is characterized in that: described metal plating (42) is titanium-gold-plating, titanium silver layer.
3, a kind of manufacture craft of making the described metallizing throwing of claim 1 glaze ceramic may further comprise the steps successively:
(A) at adobe (1) upper surface pattern-making layer (2);
(B) go up spreading frit powder (31) at the pattern (21) of patterned layer (2), leaving a blank between the frit powder (31) forms groove (32);
(C) burn till, make frit powder (31) sintering form transparent block (33);
(D) surface of semi-finished at step C plates metal level, makes metal plating fill up groove (32);
(E) metal plating that is covered in transparent block (33) surface is removed in surface finish.
4, manufacture craft according to claim 3 is characterized in that: the described making of steps A comprises drafting, impressing pattern, massed glaze or applique skill and technique.
5, manufacture craft according to claim 3 is characterized in that: described frit powder comprises following major ingredient, and its mass percentage content is as follows:
SiO 2 55～65％ MgO 0.2～0.3％ Al 2O 3 8～9％
K 2O 2～4％ Fe 2O 3 0.1～0.2％ Na 2O 1～2％
CaO 2～3％ ZnO％ 2.5～4％ BaO 2.5～4％
ZrO 2 0.1～0.5％ B 2O 3％ 15～20％
6, manufacture craft according to claim 3 is characterized in that: the polishing powder main component that polishing process adopts in the step e is Al 2O 3
7, manufacture craft according to claim 3 is characterized in that: the metal level that plates among the step D is titanium-gold-plating layer or titanizing silver layer.
CN 200410051820 2004-10-13 2004-10-13 Metal plated and polished ceramic products and their manufacture Expired - Fee Related CN1274633C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200410051820 CN1274633C (en) 2004-10-13 2004-10-13 Metal plated and polished ceramic products and their manufacture

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200410051820 CN1274633C (en) 2004-10-13 2004-10-13 Metal plated and polished ceramic products and their manufacture

Publications (2)

Publication Number Publication Date
CN1644559A true CN1644559A (en) 2005-07-27
CN1274633C CN1274633C (en) 2006-09-13

Family

ID=34868713

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200410051820 Expired - Fee Related CN1274633C (en) 2004-10-13 2004-10-13 Metal plated and polished ceramic products and their manufacture

Country Status (1)

Country Link
CN (1) CN1274633C (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100410197C (en) * 2007-02-02 2008-08-13 南安协进建材有限公司 Method for producing metal enamel
CN101654379A (en) * 2008-08-22 2010-02-24 章云树 Porcelain gilded brick and manufacturing method thereof
WO2010148970A1 (en) * 2009-06-22 2010-12-29 Chen Manjian Polished glaze tiles transmutated in furnace and production method thereof
CN101376602B (en) * 2008-09-23 2011-12-21 林敏� Method for forming one layer or multiple layers of metal patterns on surface of ceramic products
CN102503435A (en) * 2011-09-22 2012-06-20 佛山市科捷制釉有限公司 Preparation method for high-temperature once-fired fully-polished glazed porcelain tiles
CN102690131A (en) * 2012-03-02 2012-09-26 佛山市章氏兄弟建材有限公司 Manufacturing method of underglaze flashing K gold glazed brick
CN101571000B (en) * 2008-04-28 2013-02-06 章云树 Foaming mosaic and manufacturing method thereof
CN103373861A (en) * 2012-04-17 2013-10-30 陈满坚 Metallized polished glazed ceramic tile and preparation method thereof
CN103922812A (en) * 2014-04-21 2014-07-16 佛山市金丝玉玛装饰材料有限公司 Matte-underglazed glazed brick and fabrication process thereof
CN104108958A (en) * 2014-08-01 2014-10-22 佛山市东鹏陶瓷有限公司 Microcrystalline glass-ceramic composite panel manufacturing method and product thereof
CN104140296A (en) * 2014-08-01 2014-11-12 佛山市东鹏陶瓷有限公司 Polished crystal tile manufacturing method and polished crystal tile prepared through same
CN107141025A (en) * 2017-07-07 2017-09-08 佛山市章氏兄弟建材有限公司 A kind of marble plating metal modelled after an antique throws the preparation method of glaze Ceramic Tiles
CN107602152A (en) * 2017-09-28 2018-01-19 禹州市正玉钧窑有限公司 A kind of pottery is with bluish white glaze and the technique for preparing pottery with bluish white glaze using pottery
CN109574712A (en) * 2018-12-30 2019-04-05 佛山市章氏兄弟建材有限公司 A kind of composite plating glazed tile and preparation method thereof
CN109605555A (en) * 2018-12-30 2019-04-12 佛山市章氏兄弟建材有限公司 A kind of composite plating underglaze colour glazed tile and preparation method thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104130033B (en) * 2014-07-01 2016-10-05 陈伟煊 A kind of craft of gilding throwing vitreous brick

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100410197C (en) * 2007-02-02 2008-08-13 南安协进建材有限公司 Method for producing metal enamel
CN101571000B (en) * 2008-04-28 2013-02-06 章云树 Foaming mosaic and manufacturing method thereof
CN101654379A (en) * 2008-08-22 2010-02-24 章云树 Porcelain gilded brick and manufacturing method thereof
CN101376602B (en) * 2008-09-23 2011-12-21 林敏� Method for forming one layer or multiple layers of metal patterns on surface of ceramic products
WO2010148970A1 (en) * 2009-06-22 2010-12-29 Chen Manjian Polished glaze tiles transmutated in furnace and production method thereof
CN101747020B (en) * 2009-06-22 2012-07-04 陈满坚 Fambe glaze-polished brick and production method thereof
CN102503435A (en) * 2011-09-22 2012-06-20 佛山市科捷制釉有限公司 Preparation method for high-temperature once-fired fully-polished glazed porcelain tiles
CN102690131A (en) * 2012-03-02 2012-09-26 佛山市章氏兄弟建材有限公司 Manufacturing method of underglaze flashing K gold glazed brick
CN102690131B (en) * 2012-03-02 2013-10-30 佛山市章氏兄弟建材有限公司 Manufacturing method of underglaze flashing K gold glazed brick
CN103373861B (en) * 2012-04-17 2015-11-04 陈满坚 A kind of metallizing throws glaze ceramic tile and preparation method thereof
CN103373861A (en) * 2012-04-17 2013-10-30 陈满坚 Metallized polished glazed ceramic tile and preparation method thereof
CN103922812A (en) * 2014-04-21 2014-07-16 佛山市金丝玉玛装饰材料有限公司 Matte-underglazed glazed brick and fabrication process thereof
CN103922812B (en) * 2014-04-21 2015-06-10 佛山市金丝玉玛装饰材料有限公司 Matte-underglazed glazed brick and fabrication process thereof
CN104140296A (en) * 2014-08-01 2014-11-12 佛山市东鹏陶瓷有限公司 Polished crystal tile manufacturing method and polished crystal tile prepared through same
CN104108958A (en) * 2014-08-01 2014-10-22 佛山市东鹏陶瓷有限公司 Microcrystalline glass-ceramic composite panel manufacturing method and product thereof
CN104108958B (en) * 2014-08-01 2016-02-03 佛山市东鹏陶瓷有限公司 Manufacture method of a kind of glass-ceramic clad plate and products thereof
CN107141025A (en) * 2017-07-07 2017-09-08 佛山市章氏兄弟建材有限公司 A kind of marble plating metal modelled after an antique throws the preparation method of glaze Ceramic Tiles
CN107602152A (en) * 2017-09-28 2018-01-19 禹州市正玉钧窑有限公司 A kind of pottery is with bluish white glaze and the technique for preparing pottery with bluish white glaze using pottery
CN107602152B (en) * 2017-09-28 2021-04-13 禹州市正玉钧窑有限公司 Green and white glaze for Jun porcelain and process for preparing Jun porcelain by using green and white glaze for Jun porcelain
CN109574712A (en) * 2018-12-30 2019-04-05 佛山市章氏兄弟建材有限公司 A kind of composite plating glazed tile and preparation method thereof
CN109605555A (en) * 2018-12-30 2019-04-12 佛山市章氏兄弟建材有限公司 A kind of composite plating underglaze colour glazed tile and preparation method thereof

Also Published As

Publication number Publication date
CN1274633C (en) 2006-09-13

Similar Documents

Publication Publication Date Title
CN1274633C (en) Metal plated and polished ceramic products and their manufacture
CN110357668A (en) A kind of full throwing glaze Ceramic Tiles and preparation method thereof with graininess flashing ornaments
CN100337972C (en) Process for making a chinaware
CN101157542B (en) Production technique for ceramic title having semitransparent reflecting decorative surface
CN107200554A (en) A kind of preparation technology of antifouling sheen Dali stone ceramic tile
CN110577415A (en) ceramic tile with antique surface stone texture effect and manufacturing process thereof
CN110845252B (en) Special blank large-particle combined digital cloth archaized brick and preparation method thereof
CN103373861B (en) A kind of metallizing throws glaze ceramic tile and preparation method thereof
CN101497538A (en) Process for producing stereo semi-polished ornamental porcelain archaizing brick with lithophane
CN111499396B (en) Metal texture porcelain plate with prominent bright/matte contrast
CN2752261Y (en) Metallized polished glazing ceramic product
CN101591962A (en) Fambe glaze-polished brick and production method thereof
JPH10114576A (en) Three-dimensional ceramic artificial granite and marble and their production
KR20100138750A (en) Manufacturing method for pottery decorated with chilbo adornment and pottery thereby
CN109608207A (en) A kind of entire body is without glaze Dali stone ceramic tile and its manufacturing method
CN102120705B (en) Preparation method of fambed ceramic tile
CN1300042C (en) Ceramic tile and mosaic and their production process
CN1736922A (en) Ornamental glaze and its normal temperature implement method
CN201437627U (en) Ceramic tile with concave-convex polished in-glaze decoration
CN205398479U (en) Antibiotic ceramic tile
CN203999394U (en) A kind of glazed brick of throwing
CN111976359A (en) Method for inlaying gold and silver decorations on purple pottery of construction water
CN109397496A (en) A method of building the multi-level color mud heap carving of water purple pottery
CN102218960B (en) Manufacture method for polished electrooptic mirror face ceramic product
CN215757083U (en) Porcelain plate with glittering grain effect

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Foshan individuality ceramic tile Co., Ltd.

Assignor: Chen Manjian

Contract fulfillment period: 2008.3.9 to 2018.3.8

Contract record no.: 2008440000036

Denomination of invention: Metal plated and polished ceramic products and their manufacture

Granted publication date: 20060913

License type: Exclusive license

Record date: 20080310

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.3.9 TO 2018.3.8

Name of requester: PERSONALIZED TILES CO., LTD., FUSHAN CITY

Effective date: 20080310

EC01 Cancellation of recordation of patent licensing contract

Assignee: Foshan individuality ceramic tile Co., Ltd.

Assignor: Chen Manjian

Contract record no.: 2008440000036

Date of cancellation: 20131112

LICC Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20170622

Address after: 528000 casserole workshop, No. 29 Yuejin Road, Chancheng District, Foshan, Guangdong, Shiwan

Patentee after: Foshan Pui Pui culture Ceramics Co., Ltd.

Address before: 528031 No. 2 Yuejin Road, Guangdong, Foshan, 403, Shiwan

Patentee before: Chen Manjian

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20060913

Termination date: 20201013