CN106630980A - An oil-proof antifouling kitchen ceramic tile - Google Patents
An oil-proof antifouling kitchen ceramic tile Download PDFInfo
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- CN106630980A CN106630980A CN201610927426.0A CN201610927426A CN106630980A CN 106630980 A CN106630980 A CN 106630980A CN 201610927426 A CN201610927426 A CN 201610927426A CN 106630980 A CN106630980 A CN 106630980A
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Abstract
An oil-proof antifouling kitchen ceramic tile is disclosed and belongs to the field of building ceramic materials. The ceramic tile is prepared from quartz sand, spodumene, ground calcium carbonate, talcum powder, olivine, bamboo charcoal powder, potash feldspar, an adhesive and modified gangue. The ceramic tile has characteristics of high strength, low water absorption, capability of being temperature resistant and wear resistant and high self-cleaning performance, can effectively prevent oil stains and other impurities when the ceramic tile is used in kitchens, improves environmental hygiene and has good popularization valve.
Description
Technical field
The invention belongs to building ceramics field, and in particular to a kind of antifouling Ceramic Tiles for kitchen use of oil resistant.
Background technology
Ceramic Tiles are by clay, quartz sand and other inorganic non-metallic raw materials, Jing dispensings, ball milling, powder processed, shaping, burning
The tabular or Bulk ceramic product of the technique productions such as knot, is widely used in decoration with protection building, the metope of structures and ground
Face.With developing rapidly for real estate so that the production and consumption of ceramic tile all gets a larger development.Existing Ceramic Tiles
Oil resistant antifouling property it is poor, especially when kitchen uses, long-term flue dust greasy dirt etc. corrode, cause Ceramic Tiles discoloration, damage
It is bad serious, have impact on the life mood of people.
The content of the invention
The present invention is intended to provide a kind of antifouling Ceramic Tiles for kitchen use of oil resistant, with good antifouling, oil resistant, self-cleaning spy
Property, it is adaptable to lay in kitchen.
The present invention is achieved through the following technical solutions：
A kind of antifouling Ceramic Tiles for kitchen use of oil resistant, are made up of the material of following weight portion：
42 ~ 45 parts of quartz sand, 21 ~ 24 parts of spodumenes, 17 ~ 19 parts of dry powders, 8 ~ 11 parts of talcum powder, 9 ~ 12 parts of olivines, 13 ~ 16
Part bamboo charcoal powder, 22 ~ 25 parts of potassium feldspars, 20 ~ 23 parts of binding agents, 18 ~ 22 parts of modified gangues；The binding agent is by following weight portion
Material make：33 ~ 36 parts of kaolin, 22 ~ 26 parts of attapulgites, 5 ~ 7 parts of hydroxypropyl methyl celluloses, 6 ~ 8 parts of ethoxy first
Base cellulose, 3 ~ 5 parts of benzylcelluloses, 5 ~ 8 parts of konjac glucomannans, 3 ~ 6 parts of cornstarch, 4 ~ 7 parts of polyester fibers, 5 ~ 7 parts of Graphenes,
3 ~ 6 parts of nano titanium oxides；The modified gangue is made up of the material of following weight portion：56 ~ 59 parts of gangues, 17 ~ 19 parts
Vermiculite, 8 ~ 11 parts of medical stones, 6 ~ 8 parts of nano silicons, 5 ~ 7 parts of polypropylene fibres, 4 ~ 6 parts of barium chlorides, 3 ~ 5 parts of calcium chloride.
Further, the preparation method of the binding agent comprises the steps：
（1）Kaolin and attapulgite mixing are put into the hydrochloric acid solution that mass fraction is 8%, after 50 ~ 55min of immersion treatment
Take out, in placing into the sodium hydroxide solution that mass fraction is 10%, take out after 40 ~ 50min of immersion treatment, deionized water punching
It is standby after wash clean；
（2）By step（1）At kaolin after process and attapulgite mixing are put into temperature for calcining under conditions of 830 ~ 860 DEG C
Reason 1 ~ 2h after take out mixture A is standby；
（3）By Graphene and nano titanium oxide, jointly mixing is put into the ammoniacal liquor that mass fraction is 20%, add Graphene and
The hydrazine hydrate of nano titanium oxide gross mass 16%, is stirred continuously 1.5 ~ 1.8h of process, then with 240 ~ 270 revs/min of rotating speed
Filter mixture B is standby；
（4）Hydroxypropyl methyl cellulose, HEMC, benzylcellulose, konjac glucomannan, cornstarch and polyester is fine
It is standby that dimension obtains mixture C after being sufficiently mixed uniformly；
（5）Mixture A, mixture B, mixture C are mixed jointly, 350 mesh are crossed after drying and crushing.In the preparation of binding agent
In, Graphene and nano titanium oxide have been made into graphene/titanium dioxide composite, chemical property by specific mode
Well, be scattered in the inside of Ceramic Tiles, ion channel can be built for metal ion, be easy to the metal of the compositions such as modified gangue from
Son is diffused into glaze layer surface and carries out ion exchange with pollutant, lifts its water solubility, and then has reached effect of anti-soil, and bonds
The overall adhesion strength of agent is high, improves overall compactness, can also improve the self-cleaning of Ceramic Tiles.
Further, the preparation method of the modified gangue comprises the steps：
（1）Gangue is first crushed and is crossed 200 mesh afterwards to obtain colliery powder standby；
（2）By step（1）The colliery powder of gained is put into maceration extract, after ultrasonically treated 18 ~ 22min, is filtered off standby after liquid；
The maceration extract by following weight portion material composition：5 ~ 8 parts of sodium chloride, 4 ~ 6 parts of potassium nitrate, 2 ~ 3 parts of copper sulphate, 1 ~ 2 part of phosphorus
Sour rubidium, 3 ~ 5 parts of zinc sulfate, 1 ~ 2 part of sodium sulfate of polyethenoxy ether of fatty alcohol, 1 ~ 3 part of neopelex, 1 ~ 2 part of list are hard
Glycerol, 150 ~ 170 parts of deionized waters；
（3）By step（2）The same vermiculite of colliery powder, medical stone, nano silicon, polypropylene fibre, barium chloride after process,
Calcium chloride mixes, and 400 mesh are crossed after drying and crushing.Modified gangue is rich in metal ion, and anti-permeability is higher, inhales
Attached property is good, and with binding agent stable frame structure is together form, it is ensured that the stability for using.
Further, frequency when described ultrasonically treated is 42 ~ 45kHz.
A kind of preparation method of the antifouling Ceramic Tiles for kitchen use of oil resistant, comprises the steps：
（1）First ball will be put into after quartz sand, spodumene, dry powder, talcum powder, olivine, bamboo charcoal powder and potassium feldspar jointly mixing
In grinding machine, continuous 2 ~ 2.5h of ball milling crosses 150 mesh standby after taking-up dries pulverizing；
（2）By binding agent, the same step of modified gangue（1）After material after process mixes jointly, in being placed again into ball mill, no
Interception 1 ~ 1.5h of mill, is obtained the slurry being well mixed, then through sieving, after mist projection granulating, in being put into forming machine, control pressure is
93 ~ 95MPa, makes green compact, and 2 ~ 3h is fired under conditions of then green compact being put into 1130 ~ 1160 DEG C, finally cooled down,
Edging.
The present invention has the advantages that：
The present invention has good bond effect with the binding agent of multicomponent co-formulation, it is ensured that the adhesion of each material composition is steady
It is qualitative, overall compactness is improved, and with certain antibacterial, deodorization properties；The modified gangue adsorptivity of addition, antiseepage
Property it is good, the overall intensity of Ceramic Tiles and wearability are improved jointly with binding agent, while it is rich in metal ion, in binding agent
Under building the mating reaction of passage, it can constantly be diffused into glaze layer surface and carry out ion exchange with pollutant, and then improve dirt
The hydrophily of dye thing, enhances oil resistant, resistant characteristic；Coordinate the collective effect of remaining material, the obtained Ceramic Tiles tool of the present invention
There is intensity high, water absorption rate is low, heat-resistant, wear-resistant, the characteristics of self-cleaning is high, for being highly resistant to the impurity such as greasy dirt in kitchen, improve
Environmental sanitation, there is a good promotional value.
Specific embodiment
Embodiment 1
A kind of antifouling Ceramic Tiles for kitchen use of oil resistant, are made up of the material of following weight portion：
42 parts of quartz sands, 21 parts of spodumenes, 17 parts of dry powders, 8 parts of talcum powder, 9 parts of olivines, 13 parts of bamboo charcoal powders, 22 parts of potassium are long
Stone, 20 parts of binding agents, 18 parts of modified gangues；The binding agent is made up of the material of following weight portion：33 parts of kaolin, 22 parts
Attapulgite, 5 parts of hydroxypropyl methyl celluloses, 6 parts of HEMCs, 3 parts of benzylcelluloses, 5 parts of konjac glucomannans, 3 parts
Cornstarch, 4 parts of polyester fibers, 5 parts of Graphenes, 3 parts of nano titanium oxides；The modified gangue by following weight portion thing
Matter is made：56 parts of gangues, 17 parts of vermiculites, 8 parts of medical stones, 6 parts of nano silicons, 5 parts of polypropylene fibres, 4 parts of barium chlorides,
3 parts of calcium chloride.
Further, the preparation method of the binding agent comprises the steps：
（1）Kaolin and attapulgite mixing are put into the hydrochloric acid solution that mass fraction is 8%, are taken after immersion treatment 53min
Go out, in placing into the sodium hydroxide solution that mass fraction is 10%, take out after immersion treatment 45min, deionized water is rinsed well
It is standby afterwards；
（2）By step（1）Kaolin and attapulgite mixing after process is put into temperature for calcination processing under conditions of 850 DEG C
Take out after 1.5h mixture A is standby；
（3）By Graphene and nano titanium oxide, jointly mixing is put into the ammoniacal liquor that mass fraction is 20%, add Graphene and
The hydrazine hydrate of nano titanium oxide gross mass 16%, with 250 revs/min of rotating speed process 1.6h is stirred continuously, and then filtering to mix
Compound B is standby；
（4）Hydroxypropyl methyl cellulose, HEMC, benzylcellulose, konjac glucomannan, cornstarch and polyester is fine
It is standby that dimension obtains mixture C after being sufficiently mixed uniformly；
（5）Mixture A, mixture B, mixture C are mixed jointly, 350 mesh are crossed after drying and crushing.
Further, the preparation method of the modified gangue comprises the steps：
（1）Gangue is first crushed and is crossed 200 mesh afterwards to obtain colliery powder standby；
（2）By step（1）The colliery powder of gained is put into maceration extract, after ultrasonically treated 20min, is filtered off standby after liquid；Institute
State material composition of the maceration extract by following weight portion：7 parts of sodium chloride, 5 parts of potassium nitrate, 2 parts of copper sulphate, 1.5 parts of phosphoric acid rubidiums, 4 parts
Zinc sulfate, 1.5 parts of sodium sulfate of polyethenoxy ether of fatty alcohol, 2 parts of neopelexes, 1.5 parts of glycerin monostearates,
160 parts of deionized waters；
（3）By step（2）The same vermiculite of colliery powder, medical stone, nano silicon, polypropylene fibre, barium chloride after process,
Calcium chloride mixes, and 400 mesh are crossed after drying and crushing.
Further, frequency when described ultrasonically treated is 43kHz.
A kind of preparation method of the antifouling Ceramic Tiles for kitchen use of oil resistant, comprises the steps：
（1）First ball will be put into after quartz sand, spodumene, dry powder, talcum powder, olivine, bamboo charcoal powder and potassium feldspar jointly mixing
In grinding machine, continuous ball milling 2.5h crosses 150 mesh standby after taking-up dries pulverizing；
（2）By binding agent, the same step of modified gangue（1）After material after process mixes jointly, in being placed again into ball mill, no
Interception mill 1.2h, is obtained the slurry being well mixed, then through sieving, after mist projection granulating, in being put into forming machine, control pressure is
94MPa, makes green compact, and 2.5h is fired under conditions of then green compact being put into 1130 ~ 1150 DEG C, is finally cooled down, edging
.
Embodiment 2
A kind of antifouling Ceramic Tiles for kitchen use of oil resistant, are made up of the material of following weight portion：
43 parts of quartz sands, 23 parts of spodumenes, 18 parts of dry powders, 10 parts of talcum powder, 11 parts of olivines, 14 parts of bamboo charcoal powders, 23 parts of potassium
Feldspar, 22 parts of binding agents, 20 parts of modified gangues；The binding agent is made up of the material of following weight portion：35 parts of kaolin, 25
Part attapulgite, 6 parts of hydroxypropyl methyl celluloses, 7 parts of HEMCs, 4 parts of benzylcelluloses, 7 parts of konjac glucomannans, 5
Part cornstarch, 6 parts of polyester fibers, 6 parts of Graphenes, 5 parts of nano titanium oxides；The modified gangue is by following weight portion
Material is made：58 parts of gangues, 18 parts of vermiculites, 10 parts of medical stones, 7 parts of nano silicons, 6 parts of polypropylene fibres, 5 parts of chlorinations
Barium, 4 parts of calcium chloride.Remaining method is with embodiment 1.
Embodiment 3
A kind of antifouling Ceramic Tiles for kitchen use of oil resistant, are made up of the material of following weight portion：
45 parts of quartz sands, 24 parts of spodumenes, 19 parts of dry powders, 11 parts of talcum powder, 12 parts of olivines, 16 parts of bamboo charcoal powders, 25 parts of potassium
Feldspar, 23 parts of binding agents, 22 parts of modified gangues；The binding agent is made up of the material of following weight portion：36 parts of kaolin, 26
Part attapulgite, 7 parts of hydroxypropyl methyl celluloses, 8 parts of HEMCs, 5 parts of benzylcelluloses, 8 parts of konjac glucomannans, 6
Part cornstarch, 7 parts of polyester fibers, 7 parts of Graphenes, 6 parts of nano titanium oxides；The modified gangue is by following weight portion
Material is made：59 parts of gangues, 19 parts of vermiculites, 11 parts of medical stones, 8 parts of nano silicons, 7 parts of polypropylene fibres, 6 parts of chlorinations
Barium, 5 parts of calcium chloride.Remaining method is with embodiment 1.
Comparative example 1
This comparative example 1 compared with Example 1, does not contain Graphene and nano titanium oxide composition in binding agent used, remove
In addition method and step all same.
Comparative example 2
This comparative example 2 does compared with Example 2, not to gangue any modification, i.e., with etc. mass parts common coal
Spoil replaces modified gangue, method and step all same in addition.
Control group
Existing commercially available Ceramic Tiles.
In order to contrast effect of the present invention, antifouling test is carried out to above-mentioned six kinds of Ceramic Tiles, specially：Ceramic Tiles are immersed in
In ink, take out after 8h, 18h is placed in its natural state, then put it into taking-up after immersion 1h in clear water, observe Ceramic Tiles table
The pollution level in face, is represented with scoring.Concrete correction data see the table below 1：
Table 1
| Scoring | |
| Embodiment 1 | 2 |
| Embodiment 2 | 1 |
| Embodiment 3 | 1 |
| Comparative example 1 | 3 |
| Comparative example 2 | 3 |
| Control group | 4 |
Note：Scoring described in upper table 1 is embodied as：1 point represents that there is slight ink marks on surface, is removed with water easy；2 points of expressions
There is obvious ink marks on surface, is removed with water easy；3 points represent that surface ink marks is heavier, and it is more difficult to be removed with water；4 points of expression surface ink markss
Seriously, removed with water difficult.
By upper table 1 as can be seen that the obtained Ceramic Tiles of the present invention have good anti-fouling effect.To embodiment 1, embodiment 2
Tested with 3 preparing ceramic tiles of embodiment, its average rupture strength is 19.2MPa, and water absorption rate is 6.5%, surface average roughness
Degree is not more than 0.07 μm, and overall characteristic is good, and popularizing value is high.
Claims (5)
1. antifouling Ceramic Tiles for kitchen use of a kind of oil resistant, it is characterised in that be made up of the material of following weight portion：
42 ~ 45 parts of quartz sand, 21 ~ 24 parts of spodumenes, 17 ~ 19 parts of dry powders, 8 ~ 11 parts of talcum powder, 9 ~ 12 parts of olivines, 13 ~ 16
Part bamboo charcoal powder, 22 ~ 25 parts of potassium feldspars, 20 ~ 23 parts of binding agents, 18 ~ 22 parts of modified gangues；The binding agent is by following weight portion
Material make：33 ~ 36 parts of kaolin, 22 ~ 26 parts of attapulgites, 5 ~ 7 parts of hydroxypropyl methyl celluloses, 6 ~ 8 parts of ethoxy first
Base cellulose, 3 ~ 5 parts of benzylcelluloses, 5 ~ 8 parts of konjac glucomannans, 3 ~ 6 parts of cornstarch, 4 ~ 7 parts of polyester fibers, 5 ~ 7 parts of Graphenes,
3 ~ 6 parts of nano titanium oxides；The modified gangue is made up of the material of following weight portion：56 ~ 59 parts of gangues, 17 ~ 19 parts
Vermiculite, 8 ~ 11 parts of medical stones, 6 ~ 8 parts of nano silicons, 5 ~ 7 parts of polypropylene fibres, 4 ~ 6 parts of barium chlorides, 3 ~ 5 parts of calcium chloride.
2. a kind of antifouling Ceramic Tiles for kitchen use of oil resistant according to claim 1, it is characterised in that the system of the binding agent
Preparation Method comprises the steps：
（1）Kaolin and attapulgite mixing are put into the hydrochloric acid solution that mass fraction is 8%, after 50 ~ 55min of immersion treatment
Take out, in placing into the sodium hydroxide solution that mass fraction is 10%, take out after 40 ~ 50min of immersion treatment, deionized water punching
It is standby after wash clean；
（2）By step（1）At kaolin after process and attapulgite mixing are put into temperature for calcining under conditions of 830 ~ 860 DEG C
Reason 1 ~ 2h after take out mixture A is standby；
（3）By Graphene and nano titanium oxide, jointly mixing is put into the ammoniacal liquor that mass fraction is 20%, add Graphene and
The hydrazine hydrate of nano titanium oxide gross mass 16%, is stirred continuously 1.5 ~ 1.8h of process, then with 240 ~ 270 revs/min of rotating speed
Filter mixture B is standby；
（4）Hydroxypropyl methyl cellulose, HEMC, benzylcellulose, konjac glucomannan, cornstarch and polyester is fine
It is standby that dimension obtains mixture C after being sufficiently mixed uniformly；
（5）Mixture A, mixture B, mixture C are mixed jointly, 350 mesh are crossed after drying and crushing.
3. a kind of antifouling Ceramic Tiles for kitchen use of oil resistant according to claim 1, it is characterised in that the modified gangue
Preparation method comprise the steps：
（1）Gangue is first crushed and is crossed 200 mesh afterwards to obtain colliery powder standby；
（2）By step（1）The colliery powder of gained is put into maceration extract, after ultrasonically treated 18 ~ 22min, is filtered off standby after liquid；
The maceration extract by following weight portion material composition：5 ~ 8 parts of sodium chloride, 4 ~ 6 parts of potassium nitrate, 2 ~ 3 parts of copper sulphate, 1 ~ 2 part of phosphorus
Sour rubidium, 3 ~ 5 parts of zinc sulfate, 1 ~ 2 part of sodium sulfate of polyethenoxy ether of fatty alcohol, 1 ~ 3 part of neopelex, 1 ~ 2 part of list are hard
Glycerol, 150 ~ 170 parts of deionized waters；
（3）By step（2）The same vermiculite of colliery powder, medical stone, nano silicon, polypropylene fibre, barium chloride after process,
Calcium chloride mixes, and 400 mesh are crossed after drying and crushing.
4. the antifouling Ceramic Tiles for kitchen use of a kind of oil resistant according to claims 3, it is characterised in that at the ultrasound
Frequency during reason is 42 ~ 45kHz.
5. the preparation method of the antifouling Ceramic Tiles for kitchen use of a kind of oil resistant as claimed in claim 1, it is characterised in that include as
Lower step：
（1）First ball will be put into after quartz sand, spodumene, dry powder, talcum powder, olivine, bamboo charcoal powder and potassium feldspar jointly mixing
In grinding machine, continuous 2 ~ 2.5h of ball milling crosses 150 mesh standby after taking-up dries pulverizing；
（2）By binding agent, the same step of modified gangue（1）After material after process mixes jointly, in being placed again into ball mill, no
Interception 1 ~ 1.5h of mill, is obtained the slurry being well mixed, then through sieving, after mist projection granulating, in being put into forming machine, control pressure is
93 ~ 95MPa, makes green compact, and 2 ~ 3h is fired under conditions of then green compact being put into 1130 ~ 1160 DEG C, is finally cooled down, is ground
Side.
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| CN201610927426.0A CN106630980A (en) | 2016-10-29 | 2016-10-29 | An oil-proof antifouling kitchen ceramic tile |
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| CN107459331A (en) * | 2017-08-04 | 2017-12-12 | 池州思群塑胶制品有限公司 | A kind of anti-oxidant kitchen ceramics |
| CN108640667A (en) * | 2018-06-29 | 2018-10-12 | 福建省德化县邦威陶瓷有限公司 | A kind of easy fired light ceramics product and its manufacturing process |
| CN111792912A (en) * | 2017-11-11 | 2020-10-20 | 福建省德化县优扬工艺品有限公司 | Manufacturing process of middle and low temperature fired ceramic product |
| CN113617340A (en) * | 2021-08-18 | 2021-11-09 | 甘肃融万科技有限公司 | Color-changeable bactericidal attapulgite-based deodorizing and dehumidifying agent and preparation method thereof |
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| CN107459331A (en) * | 2017-08-04 | 2017-12-12 | 池州思群塑胶制品有限公司 | A kind of anti-oxidant kitchen ceramics |
| CN111792912A (en) * | 2017-11-11 | 2020-10-20 | 福建省德化县优扬工艺品有限公司 | Manufacturing process of middle and low temperature fired ceramic product |
| CN111792912B (en) * | 2017-11-11 | 2022-07-19 | 福建省德化县优扬工艺品有限公司 | Manufacturing process of middle and low temperature fired ceramic product |
| CN108640667A (en) * | 2018-06-29 | 2018-10-12 | 福建省德化县邦威陶瓷有限公司 | A kind of easy fired light ceramics product and its manufacturing process |
| CN113617340A (en) * | 2021-08-18 | 2021-11-09 | 甘肃融万科技有限公司 | Color-changeable bactericidal attapulgite-based deodorizing and dehumidifying agent and preparation method thereof |
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