CN101492263A - Wax shale gray slag base polymer gelled material - Google Patents
Wax shale gray slag base polymer gelled material Download PDFInfo
- Publication number
- CN101492263A CN101492263A CNA2008101100976A CN200810110097A CN101492263A CN 101492263 A CN101492263 A CN 101492263A CN A2008101100976 A CNA2008101100976 A CN A2008101100976A CN 200810110097 A CN200810110097 A CN 200810110097A CN 101492263 A CN101492263 A CN 101492263A
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- CN
- China
- Prior art keywords
- shale
- industrial
- slag base
- wax
- lime
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/04—Heat treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/026—Oil shale cements
Abstract
The invention relates to a cementing material of an oil shale clinker matrix polymer and a preparation method thereof, and belongs to the field of environment-friendly materials. The cementing material comprises the following components in percentage by weight: 30 to 70 percent of oil shale clinker with the particle diameter of 200 meshes, 0 to 70 percent of low-temperature calcined kaolin with particle diameter of 200 meshes, 0 to 10 percent of calcium lime with the fineness of 150 meshes, 5 to 30 percent of P32.5 cement, and 5 to 10 percent of exciting agent, wherein the exciting agent is a mixed solution of industrial sodium silicate of which modulus M is 3.3 and industrial alkali. The cementing material can replace the prior cementing material gypsum and cement, and is suitable for manufacturing stone imitated artworks, embossing wall bricks, sculptures and ground tiles for building decoration and products such as hollow bricks, light bricks, and the like for building materials. The cementing material has low cost and performance superior to the prior material.
Description
The present invention relates to main component is geopolymer gelling material of resinous shale lime-ash and preparation method thereof.This gelling material adopts the waste-resinous shale lime-ash that produces in the Mining Group empyreumatic oil process of Fushun as main raw material, kaolin and cement with low temperature calcination serve as to strengthen raw material, add unslaked lime and an amount of exciting agent material, as sodium hydroxide or potassium hydroxide, make through stirrer blending and stirring certain hour.
Technical field
The gelling material preparation method who the present invention relates to belongs to the light-weight building material technology, is specifically related to a kind of preparation and using method of mineral waste residue base geological polymer material.
Background technology
The resinous shale lime-ash is the product after the oil shale distillation, belongs to the waste of slag class, and bulk deposition causes serious environmental to pollute and the wasting of resources.At present, the treatment process of resinous shale lime-ash is mainly landfill, piles up, owing to as yet sophisticated method of comprehensive utilization is not arranged, therefore, not only surrounding enviroment is caused big detrimentally affect, is again a kind of huge wasting of resources simultaneously.
Summary of the invention
The present invention provide a kind of with the resinous shale lime-ash as major ingredient, by adding other auxiliary material, as metakaolin, cement etc. under the effect of exciting agent, are produced a kind of method of resinous shale lime-ash based cementitious material.As handling by dyeing, forming processes can be produced various home decoration materials and light material of construction.
Product behind the oil shale retorting oil refining, we are referred to as the resinous shale lime-ash, because its quality is softer, and contains certain oil component, are not suitable for making and have the higher-strength material of construction.But the resinous shale lime-ash has stronger activity after calcining, and the method that can excite by alkali is produced the geology polymer material with higher-strength.
From the basis of studying suitable product-forming and research and development type material; development research goes out by the geology polymer material of resinous shale lime-ash as major ingredient; on the basis of satisfying the material different mechanical properties; seek rationally to utilize to discard resinous shale lime-ash resource, have great importance for saving resource and environment protection aspect.The research and development of Wax shale gray slag base matter polymer materials have been demonstrated fully concrete enforcement to the theory of material, sustainable development of resource, are maximization and the reasonableness utilizations that material resources is utilized.
Geopolymer of the present invention is meant the inorganic polymer that the resinous shale lime-ash forms under the effect of exciting agent and auxiliary material.
Now in conjunction with the accompanying drawings the present invention is described in further detail.
Accompanying drawing 1 is a process flow sheet of the present invention, and accompanying drawing 2 is material preparation process schemas of the present invention.With reference to the accompanying drawings the present invention is done detailed description below.
Technical scheme of the present invention is as follows:
A kind of Wax shale gray slag base matter polymeric material is a kind of preparation method for moulding and light building material, comprises material composition, Production and application, it is characterized in that: its concrete manufacturing process comprises:
A, with the oil shale waste slag grinding, cross 200 mesh sieves, form active powder;
B, with industrial kaolin, heat 800 ℃ of calcinings, be incubated 4 hours, cross 200 mesh sieves behind the ball milling, form active powder;
C, of the present invention consisting of: by weight, particle diameter is 200 purpose oil shale waste slags 30～70%, and particle diameter is 200 orders Low temperature calcination kaolin 0～70%, fineness is 150 purpose quick limes 0～10%, P32.5 cement 5%～30 %, exciting agent 5～10%, exciting agent are the industrial metasilicate of modulus M=3.3 and the mixed liquor of industrial soda. With above-mentioned Dry powder material mix grinding 30 minutes in ball mill adds water 5～25% again, and mix and blend 2 minutes obtains slurry.
Its application process is as follows:
A, the method by the system of turning over are ready to plaster mould;
B, produce slurry;
C, rapidly slurry is poured in the plaster mould;
D, slurry solidify the demoulding after 24 hours, place after 48 hours for 20 ℃ to become hydraulicity geopolymer complex body, form Wax shale gray slag base matter polymer composites product;
Matrix material of the present invention is compared with traditional material, has following advantage:
A, Wax shale gray slag base matter polymer composites be a kind of be the type material that major ingredient is compounded to form by the resinous shale lime-ash, have better hardness, toughness and economy;
B Wax shale gray slag base matter polymer composites need not calcining in solidification process, with low cost, has mechanical property preferably.
C, Wax shale gray slag base matter polymkeric substance, the plasticity-in solidification process is strong, can carry out manual processing to it, be particularly conducive to make by hand, industry pattern design, product appearance design, be fit to the exploitation and the low-volume copying of complex model;
D, Wax shale gray slag base matter polymer composites use are very extensive.Be suitable for preparing living model, statue, decorative fresco, wall ornamentation, archaeology model, building birds-eye view, sand table model and various architectural hollow brick, light cinder brick, haydite etc.
According to the making processes of above-mentioned Wax shale gray slag base matter polymer composites as can be known, the present invention is a kind of preparation method of advanced composite material.Its manufacture craft is easy, and the scope of application is extensive, and products production is cheap, and economic and social benefit is huge.
Embodiment
As expect and please undertaken the composite maulding material of different performance by the prescription of table one and the material preparation process flow process of figure two.
Embodiment 1
With the resinous shale lime-ash of weight ratio 37% and 31% calcined kaolin, 17% cement, 5% unslaked lime, 4% industrial soda blend after mixing, adds 8% exciting agent, and above-mentioned materials is added water 5～25%, mixes and stirs 2 minutes, obtains composite mortar.This composite maulding material solidifies the back gray, pigmentable, and quality is hard, and plasticity-is good.
Embodiment 2
With the resinous shale lime-ash of weight ratio 47% and 21% calcined kaolin, 15% cement, 4% unslaked lime, 3% industrial soda blend after mixing, adds 8% exciting agent, and above-mentioned materials is added water 5～25%, mixes and stirs 2 minutes, obtains composite mortar.This composite maulding material solidifies the back gray, pigmentable, and quality is hard, and plasticity-is good.
Embodiment 3
With the resinous shale lime-ash of weight ratio 58% and 10% calcined kaolin, 17% cement, 4% unslaked lime, 4% industrial soda blend after mixing, adds 7% exciting agent, and above-mentioned materials is added water 5～25%, mixes and stirs 2 minutes, obtains composite mortar.This composite maulding material is Dark grey after solidifying, pigmentable, and quality is hard, and plasticity-is good.
Embodiment 4
With the resinous shale lime-ash and 15% cement of weight ratio 68%, 3% unslaked lime, 5% industrial soda blend after mixing, adds 9% exciting agent, and above-mentioned materials is added water 5～25%, mixes and stirs 2 minutes, obtains composite mortar.This composite maulding material is black after solidifying, and quality is harder, and plasticity-is good.
The composition of table 1 matrix material and performance
Claims (5)
1. a Wax shale gray slag base polymer gelled material is a kind of material preparation method that is used for building operation, comprises material composition, making and application, it is characterized in that: its concrete making processes comprises:
A, utilize oil shale residues as main raw material, waste residue is crossed 200 mesh sieves through ball milling after 30 minutes, oil shale residues is the waste behind the oil shale oil-refining.
B, utilize industrial kaolin, 800 ℃ of calcinings 4 hours, ball milling is crossed 200 mesh sieves after 30 minutes, form active powder;
B, utilize water glass and waste lye as alkali-activator, water glass is the byproduct of industrial preparation aluminum oxide, and alkali lye is industrial waste alkali lye;
C, levigated resinous shale lime-ash, metakaolin, small amount of cement is even in stirrer for mixing after mixing, adds the alkali-activator for preparing in advance, accounts for 8% of material total mass
D, utilize plaster mould, with the composite mortar cast wherein, slurry solidifies the demoulding after 4 hours, places after 48 hours for 20 ℃ to become hydraulicity geopolymer, forms Wax shale gray slag base matter polymer composites product.
2. Wax shale gray slag base matter polymer composites preparation method according to claim 1, it is characterized in that resinous shale lime-ash weight ratio 30～70%, calcined kaolin 0～70%, cement 5～30%, unslaked lime 0～10%, the industrial metasilicate 5～15% of industrial soda modulus M=3.3.
3. Wax shale gray slag base matter polymer composites preparation method according to claim 1 is characterized in that resinous shale lime-ash in the matrix material is the waste behind the oil shale retorting oil refining.
4. Wax shale gray slag base matter polymer composites preparation method according to claim 1 is characterized in that industrial kaolin in the matrix material through heating 800 ℃ of calcinings, is incubated processing in 4 hours.
5. Wax shale gray slag base matter polymer composites preparation method according to claim 1 is characterized in that material adds water 5～25% by proportioning, mixes and stirs 2 minutes, casting.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101100976A CN101492263A (en) | 2008-06-04 | 2008-06-04 | Wax shale gray slag base polymer gelled material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101100976A CN101492263A (en) | 2008-06-04 | 2008-06-04 | Wax shale gray slag base polymer gelled material |
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| CN101492263A true CN101492263A (en) | 2009-07-29 |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2011072777A1 (en) * | 2009-12-16 | 2011-06-23 | Outotec Oyj | Process for producing geopolymers |
| CN102108020A (en) * | 2010-12-13 | 2011-06-29 | 抚顺矿业集团有限责任公司 | Method for preparing paste filling material by using oil shale waste residue |
| CN102877553A (en) * | 2012-10-17 | 2013-01-16 | 肖和平 | Energy storage thermal insulation building material |
| CN101735841B (en) * | 2009-12-03 | 2013-03-27 | 张玉山 | Oil shale powder slag cold-pressing balls and preparation method thereof |
| CN103073205A (en) * | 2013-02-04 | 2013-05-01 | 连云港金红矿业有限公司 | Preparation method of omphacite geopolymer material |
| CN103274645A (en) * | 2013-05-24 | 2013-09-04 | 杭州电子科技大学 | Preparation method of circuit board nonmetal material reinforced geological polymer |
| CN103502175A (en) * | 2011-03-18 | 2014-01-08 | 埃克洛普有限公司 | A process for the production of binders |
| CN104003631A (en) * | 2014-06-16 | 2014-08-27 | 临沧师范高等专科学校 | Portland cement with lignite germanium tailings as main raw material and preparing method of Portland cement |
| CN104098281A (en) * | 2013-04-03 | 2014-10-15 | 神华集团有限责任公司 | Geopolymer composition, geopolymer material and preparation method thereof |
| CN104446357A (en) * | 2014-11-04 | 2015-03-25 | 东莞深圳清华大学研究院创新中心 | Glazed tile |
| CN106997808A (en) * | 2017-05-17 | 2017-08-01 | 同济大学 | A kind of ultracapacitor and its preparation based on graphene/silicon aluminum binder materials |
| CN107140893A (en) * | 2017-06-21 | 2017-09-08 | 中民筑友科技投资有限公司 | A kind of active dry mash, decorative panel, the preparation method of prefabricated component and prefabricated component |
| CN109970378A (en) * | 2019-04-16 | 2019-07-05 | 山东大学 | Based on Synergy and carbonization/high-temperature technology solid waste based cementitious material preparation process |
| CN110818340A (en) * | 2019-11-28 | 2020-02-21 | 内蒙古高等级公路建设开发有限责任公司 | Anti-cracking cement mixture and preparation method thereof |
| CN114262184A (en) * | 2022-02-11 | 2022-04-01 | 湖州职业技术学院(湖州广播电视大学)(湖州社区大学) | Geopolymer mortar and preparation method thereof |
| CN115626784A (en) * | 2022-09-19 | 2023-01-20 | 甘肃路桥建设集团有限公司 | Preparation method and application of oil shale semicoke-based gel material and gel product |
| CN116891364A (en) * | 2023-09-11 | 2023-10-17 | 石家庄铁道大学 | Reinforced steel slag base polymer and preparation method thereof |
-
2008
- 2008-06-04 CN CNA2008101100976A patent/CN101492263A/en active Pending
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735841B (en) * | 2009-12-03 | 2013-03-27 | 张玉山 | Oil shale powder slag cold-pressing balls and preparation method thereof |
| AU2010333402B2 (en) * | 2009-12-16 | 2014-11-27 | Metso Metals Oy | Process for producing geopolymers |
| EA021195B1 (en) * | 2009-12-16 | 2015-04-30 | Ототек Оюй | Process for producing geopolymers |
| WO2011072777A1 (en) * | 2009-12-16 | 2011-06-23 | Outotec Oyj | Process for producing geopolymers |
| US8523998B2 (en) | 2009-12-16 | 2013-09-03 | Outotec Oyj | Process for producing geopolymers |
| CN102725242A (en) * | 2009-12-16 | 2012-10-10 | 奥图泰有限公司 | Process for producing geopolymers |
| CN102108020A (en) * | 2010-12-13 | 2011-06-29 | 抚顺矿业集团有限责任公司 | Method for preparing paste filling material by using oil shale waste residue |
| CN102108020B (en) * | 2010-12-13 | 2012-11-14 | 抚顺矿业集团有限责任公司 | Method for preparing paste filling material by using oil shale waste residue |
| CN103502175A (en) * | 2011-03-18 | 2014-01-08 | 埃克洛普有限公司 | A process for the production of binders |
| CN102877553B (en) * | 2012-10-17 | 2014-05-07 | 肖和平 | Energy storage thermal insulation building material |
| CN102877553A (en) * | 2012-10-17 | 2013-01-16 | 肖和平 | Energy storage thermal insulation building material |
| CN103073205B (en) * | 2013-02-04 | 2014-07-16 | 连云港金红矿业有限公司 | Preparation method of omphacite geopolymer material |
| CN103073205A (en) * | 2013-02-04 | 2013-05-01 | 连云港金红矿业有限公司 | Preparation method of omphacite geopolymer material |
| CN104098281A (en) * | 2013-04-03 | 2014-10-15 | 神华集团有限责任公司 | Geopolymer composition, geopolymer material and preparation method thereof |
| CN103274645A (en) * | 2013-05-24 | 2013-09-04 | 杭州电子科技大学 | Preparation method of circuit board nonmetal material reinforced geological polymer |
| CN103274645B (en) * | 2013-05-24 | 2014-12-17 | 杭州电子科技大学 | Preparation method of circuit board nonmetal material reinforced geological polymer |
| CN104003631A (en) * | 2014-06-16 | 2014-08-27 | 临沧师范高等专科学校 | Portland cement with lignite germanium tailings as main raw material and preparing method of Portland cement |
| CN104003631B (en) * | 2014-06-16 | 2016-08-24 | 临沧师范高等专科学校 | Germanium tailings portland cement as primary raw material and preparation method thereof is carried with brown coal |
| CN104446357A (en) * | 2014-11-04 | 2015-03-25 | 东莞深圳清华大学研究院创新中心 | Glazed tile |
| CN106997808A (en) * | 2017-05-17 | 2017-08-01 | 同济大学 | A kind of ultracapacitor and its preparation based on graphene/silicon aluminum binder materials |
| CN107140893A (en) * | 2017-06-21 | 2017-09-08 | 中民筑友科技投资有限公司 | A kind of active dry mash, decorative panel, the preparation method of prefabricated component and prefabricated component |
| CN107140893B (en) * | 2017-06-21 | 2019-09-20 | 中民筑友科技投资有限公司 | A kind of decorative panel |
| CN109970378A (en) * | 2019-04-16 | 2019-07-05 | 山东大学 | Based on Synergy and carbonization/high-temperature technology solid waste based cementitious material preparation process |
| CN110818340A (en) * | 2019-11-28 | 2020-02-21 | 内蒙古高等级公路建设开发有限责任公司 | Anti-cracking cement mixture and preparation method thereof |
| CN114262184A (en) * | 2022-02-11 | 2022-04-01 | 湖州职业技术学院(湖州广播电视大学)(湖州社区大学) | Geopolymer mortar and preparation method thereof |
| CN115626784A (en) * | 2022-09-19 | 2023-01-20 | 甘肃路桥建设集团有限公司 | Preparation method and application of oil shale semicoke-based gel material and gel product |
| CN116891364A (en) * | 2023-09-11 | 2023-10-17 | 石家庄铁道大学 | Reinforced steel slag base polymer and preparation method thereof |
| CN116891364B (en) * | 2023-09-11 | 2023-11-14 | 石家庄铁道大学 | Reinforced steel slag base polymer and preparation method thereof |
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Open date: 20090729 |