CN106625203A - Chemical mechanical grinding method - Google Patents

Chemical mechanical grinding method Download PDF

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Publication number
CN106625203A
CN106625203A CN201610996811.0A CN201610996811A CN106625203A CN 106625203 A CN106625203 A CN 106625203A CN 201610996811 A CN201610996811 A CN 201610996811A CN 106625203 A CN106625203 A CN 106625203A
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CN
China
Prior art keywords
cmp
wafer
dielectric layer
layer
carried out
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610996811.0A
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Chinese (zh)
Inventor
桂辉辉
周小红
李大鹏
周小云
万先进
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhan Xinxin Semiconductor Manufacturing Co Ltd
Original Assignee
Wuhan Xinxin Semiconductor Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuhan Xinxin Semiconductor Manufacturing Co Ltd filed Critical Wuhan Xinxin Semiconductor Manufacturing Co Ltd
Priority to CN201610996811.0A priority Critical patent/CN106625203A/en
Publication of CN106625203A publication Critical patent/CN106625203A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B37/00Lapping machines or devices; Accessories
    • B24B37/04Lapping machines or devices; Accessories designed for working plane surfaces
    • B24B37/042Lapping machines or devices; Accessories designed for working plane surfaces operating processes therefor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02041Cleaning
    • H01L21/02057Cleaning during device manufacture
    • H01L21/0206Cleaning during device manufacture during, before or after processing of insulating layers
    • H01L21/02065Cleaning during device manufacture during, before or after processing of insulating layers the processing being a planarization of insulating layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3105After-treatment
    • H01L21/31051Planarisation of the insulating layers
    • H01L21/31053Planarisation of the insulating layers involving a dielectric removal step
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
    • H01L21/3205Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
    • H01L21/321After treatment
    • H01L21/32115Planarisation
    • H01L21/3212Planarisation by chemical mechanical polishing [CMP]

Abstract

The invention provides a chemical mechanical grinding method. The chemical mechanical grinding method comprises the steps that a to-be-ground wafer is provided, and the wafer comprises a semiconductor substrate, an interlevel dielectric layer formed on the semiconductor substrate, grooves formed in the interlevel dielectric layer and metal interconnecting layers formed on the interlevel dielectric layer and in the grooves; the metal interconnecting layers are subjected to first chemical mechanical grinding, and part of the metal interconnecting layers are removed; the metal interconnecting layers are subjected to second chemical mechanical grinding, and the metal connecting layer on the interlevel dielectric layer is completely removed; the interlevel dielectric layer is subjected to third chemical mechanical grinding; third chemical mechanical grinding comprises a washing step; a corrosion inhibitor is adopted for washing the wafer, metal exposed within the wait time is prevented from being oxidized, and therefore the risk of dendrite defects is reduced, and the performance of a semiconductor device is improved; and meanwhile the wait time of the wafer in the third chemical mechanical grinding process is reduced.

Description

The method of cmp
Technical field
The present invention relates to field of semiconductor manufacture, more particularly to a kind of method of cmp.
Background technology
With the development of semiconductor technology, the diminution of device size, to the flat of semiconductor devices metal interconnecting layer surface Change degree requires more and more higher.Cmp (CMP) is a kind of planarization that can meet multilayer wiring requirement, chemistry Mechanical lapping is the combination of chemistry and mechanical effect, in material surface to be ground, because there is chemical reaction spy is generated Given layer, then mechanically removes this certain layer.
Existing chemical mechanical polishing device generally comprises three cmp sub-devices, such as sub-device 1, sub- dress 2 are put with sub-device 3, three sub-devices carry out mechanical lapping to different wafers, and each wafer is required for Jing simultaneously Crossing three sub-devices carries out three cmps.For example, it is formed with the semiconductor lining of interlayer dielectric layer and copper interconnection layer Bottom, the sub-device 1 carries out first time cmp, removes most copper interconnection layer, and this process grinding rate compares Hurry up, be a kind of rough lapping mode, then carry out second cmp using sub-device 2, remove the interlayer dielectric layer Copper on surface, then carries out third time cmp using 3 pairs of interlayer dielectric layers of sub-device.
The sub-device 1 is completed after a grinding wafer, and the wafer is moved to the sub-device 2 and is ground, while Sub-device 1 carries out the grinding of next wafer, and afterwards sub-device 3 carries out the grinding of the wafer, and sub-device 2 carries out next wafer Grinding, sub-device 1 carries out the grinding of next one wafer, and three sub-devices are ground to different wafers simultaneously, but The milling time total more than sub-device 3 with total milling time of sub-device 2 of sub-device 1, therefore, in sub-device 3, grind in master One section of stand-by period is needed before mill, and due to the grinding of sub-device 2, the copper metal exposed in wait is easily by oxygen Change, the semiconductor for ultimately forming can be caused to form dendron defect (Dendrites Defect).
Therefore, the stand-by period of third time cmp how is reduced, the generation for reducing dendron defect is this area The technical problem of technical staff's urgent need to resolve.
The content of the invention
It is an object of the invention to provide a kind of method of cmp, reduces brilliant in third time cmp The round stand-by period, reduce the generation of dendron defect.
A kind of method of cmp is the technical scheme is that, is comprised the following steps:
Wafer to be ground is provided, the wafer includes that Semiconductor substrate, formation interlayer on the semiconductor substrate are situated between Matter layer, the groove being formed in the interlayer dielectric layer and the gold being formed on the interlayer dielectric layer and in the groove Category interconnection layer;
The first cmp is carried out to the metal interconnection layer, the part metal interconnection layer is removed;
The second cmp is carried out to the metal interconnection layer, the gold on the interlayer dielectric layer is removed completely Category interconnection layer;
3rd cmp is carried out to the interlayer dielectric layer;
3rd cmp includes a rinsing step:The wafer is rinsed using corrosion inhibiter.
Further, the 3rd cmp includes pre-grinding, main grinding and wafer cleaning.
Further, the rinsing step was carried out before the main grinding.
Further, the rinsing step is carried out with the pre-grinding, main grinding on same grinding pad.
Further, the metal interconnecting layer is copper interconnection layer, and the corrosion inhibiter is copper inhibitor.
Further, the corrosion inhibiter is BTA.
Further, the time that the rinsing step is rinsed is 30s~70s.
Further, described first the total of mechanical lapping, the second cmp and the 3rd cmp is learned Time is suitable.
Further, first cmp, the second cmp and the 3rd cmp are adopted Carried out with the different sub-devices of same chemical mechanical polishing device.
Further, first cmp, the second cmp and the 3rd cmp be simultaneously Carry out, different wafers are ground respectively.
Compared with prior art, the method for the cmp that the present invention is provided, third time is carried out to interlayer dielectric layer Cmp, the grinding includes a rinsing step, and metal interconnecting layer is rinsed using corrosion inhibiter, prevents when waiting The interior metal for exposing is oxidized, and so as to reduce the risk that dendron defect occurs, improves the performance of semiconductor devices;Together When reduce stand-by period of the wafer in third time chemical mechanical planarization process.
Description of the drawings
The schematic flow sheet of the method for the cmp that Fig. 1 is provided by one embodiment of the invention.
Each step structural representation of the method for the cmp that Fig. 2~Fig. 5 is provided by one embodiment of the invention.
Specific embodiment
To make present disclosure more clear understandable, below in conjunction with Figure of description, present disclosure is done into one Step explanation.Certainly the specific embodiment is the invention is not limited in, general replacement well known to the skilled artisan in the art is also contained Lid is within the scope of the present invention.
Secondly, the present invention has carried out detailed statement using schematic diagram, when present example is described in detail, for the ease of saying Bright, schematic diagram, should not be to this as restriction of the invention not according to general ratio partial enlargement.
The present invention core concept be:Third time cmp is carried out to interlayer dielectric layer, the grinding includes a punching Step is washed, metal interconnecting layer is rinsed using corrosion inhibiter, prevent the metal exposed within the stand-by period to be oxidized, so as to The risk that dendron defect occurs is reduced, the performance of semiconductor devices is improve;Wafer is reduced simultaneously in the chemical machine of third time Stand-by period in tool process of lapping.
The schematic flow sheet of the method for the cmp that Fig. 1 is provided by one embodiment of the invention, as shown in figure 1, The present invention proposes a kind of method of cmp, comprises the following steps:
Step S01:Wafer to be ground is provided, the wafer includes Semiconductor substrate, formed on the semiconductor substrate Interlayer dielectric layer, the groove that is formed in the interlayer dielectric layer and be formed on the interlayer dielectric layer and described recessed Metal interconnecting layer in groove;
Step S02:The first cmp is carried out to the metal interconnection layer, the part metal interconnection layer is removed;
Step S03:The second cmp is carried out to the metal interconnection layer, the institute on the interlayer dielectric layer is removed State metal interconnecting layer;
Step S04:3rd cmp is carried out to the interlayer dielectric layer;3rd cmp includes One rinsing step:The metal interconnection layer is rinsed using corrosion inhibiter..
Each step structural representation of the method for the cmp that Fig. 2~4 provide for one embodiment of the invention, please join Examine shown in Fig. 1, and with reference to Fig. 2~Fig. 4, the method for describing cmp proposed by the present invention in detail:
In step S01, there is provided wafer to be ground 10, the wafer 10 includes Semiconductor substrate 11, is formed in described half Interlayer dielectric layer 12 on conductor substrate 11, the groove 13 being formed in the interlayer dielectric layer 12 and it is formed in the layer Between metal interconnecting layer 14 on dielectric layer 12 and in the groove 13, as shown in Figure 2.
In the present embodiment the Semiconductor substrate 11 may include any semi-conducting material, the semi-conducting material may include but It is not limited to:Si, SiC, SiGe, SiGeC, Ge alloy, GeAs, InAs, InP, and other III-V or II-VI group compound half Conductor.The Semiconductor substrate 11 includes various isolation structures, such as fleet plough groove isolation structure.The Semiconductor substrate 11 may be used also Partly led with the layering including organic semiconductor or such as SiGe (SGOI) on Si/SiGe, silicon-on-insulator (SOI) or insulator Body.Various semiconductor devices can also be formed in the Semiconductor substrate 11.
The interlayer dielectric layer 12, can be low k dielectric (interlayer dielectric layer of formation is low k dielectric), may be used also Think ultra low k dielectric materials (interlayer dielectric layer of formation is ultra-low-k dielectric layer).Generally adopt chemical gaseous phase spin coating proceeding (SOG), prepared by whirl coating technology or chemical vapour deposition technique.
The metal interconnecting layer 14 is preferably copper interconnection layer, can be formed using dual damascene process.First, to interlayer Dielectric layer 12 is performed etching, and produces the groove 13 for mosaic technology, is then followed by deposited metal barrier layer and copper seed layer (figure Not shown in), then copper interconnection layer 14 is formed in interlayer dielectric layer 12 and groove 13, can be ripe using those skilled in the art institute The various suitable technology known, such as physical gas-phase deposition or electroplating technology.Each step due to forming wafer 10 Suddenly prior art is, therefore not to repeat here.
In step S02, the first cmp is carried out to the metal interconnection layer 14, remove the part metal mutual Connection layer 14, as shown in Figure 3.In the present embodiment, most metal interconnecting layer 14 is removed, this process grinding rate ratio is very fast, It is a kind of rough lapping mode.
In step S03, the second cmp is carried out to the metal interconnection layer 14, the interlayer is removed completely and is situated between The metal interconnecting layer 14 on matter layer 12, as shown in Figure 4.
In order to avoid during the thinner thickness of remaining metal interconnection layer 14, continuing to adopt first on the interlayer dielectric layer 11 This rough lapping of cmp can cause scratch to crystal column surface, therefore need to carry out the second mechanical lapping.Described second changes Mechanical lapping is fine lapping.Second cmp removes completely the remaining gold on the interlayer dielectric layer 11 Category interconnection layer 14, and expose the metal interconnection layer 14 in groove.The grinding rate of second cmp is less than institute State the grinding rate of the first cmp.
In step S04, the 3rd cmp is carried out to the interlayer dielectric layer, as shown in Figure 5.Described 3rd changes Learning mechanical lapping includes a rinsing step:The wafer 10 is rinsed using corrosion inhibiter.
3rd cmp mainly includes pre-grinding, main grinding and wafer cleaning, is carrying out main grinding Before carry out rinsing step.Preferably, the corrosion inhibiter is BTA (BTA), for protecting the copper interconnection layer 14 for exposing, Prevent wafer 10 from aoxidizing within the stand-by period, to prevent the generation of dendron defect.
First cmp, the second cmp and the 3rd cmp adopt same chemistry The sub-device of mechanical lapping equipment is carried out, such as described cmp includes sub-device one, sub-device two and sub-device three, The sub-device one, sub-device two and sub-device three carry out respectively the first cmp, the second cmp and 3rd cmp.First cmp, the second cmp and the 3rd cmp are simultaneously Carry out, different wafers are ground respectively, i.e., described sub-device one, sub-device two are carried out from sub-device San Tong method to different wafers Grinding.For example:A pair wafers to be ground of sub-device carry out after the first cmp, moving to sub-device two, while Wafer two moves to sub-device one;Sub-device two carries out the second cmp to wafer one, while a pair of wafers of sub-device Two carry out the first cmp;Then wafer one moves to sub-device three, and wafer two moves to sub-device two, while wafer Three move to sub-device one, and sub-device three carries out the 3rd cmp to wafer one, and sub-device two carries out to wafer two Two cmps, a pair of wafers of sub-device three carry out the first cmp, wafer one complete cmp it Afterwards, having follow-up wafer constantly carries out cmp.
First cmp and the second chemical-mechanical grinding liquid also mainly include pre-grinding, main grinding and crystalline substance The steps such as circle cleaning.Because the first cmp grinds with the total time of the second cmp more than the 3rd chemical machinery The total time of mill, but the main grinding of three cmps is carried out simultaneously, therefore, in the 3rd cmp Step is rinsed before main grinding, it is possible to reduce the stand-by period of wafer in the 3rd cmp, prevent what is exposed Copper is oxidized, and then prevents the generation of dendron defect.And due to the flushing carried out using buffer, while reduce other lacking Fall into the risk for producing.
In the 3rd cmp, the rinsing step is enterprising in same grinding pad with the pre-grinding, main grinding OK, i.e., after pre-grinding is carried out, step is directly rinsed, then directly carries out main grinding, wafer is not moved.
The time that the rinsing step is rinsed is 30s~70s, such as 30s, 50s or 70s so that the first time Learn the total time of mechanical lapping, the second cmp and the 3rd cmp quite, or three chemical machineries Grinding total time is identical.It is understood that the time that the rinsing step is rinsed is not limited in 30s~70s, can With according to the difference of the 3rd cmp and the total time of the first cmp and the second cmp come It is determined that.
In sum, the method for the cmp that the present invention is provided, the side of the cmp that the present invention is provided Method, to interlayer dielectric layer third time cmp is carried out, and the grinding includes a rinsing step, mutual to metal using corrosion inhibiter Even layer is rinsed, and prevents the metal exposed within the stand-by period to be oxidized, so as to reduce the risk that dendron defect occurs, Improve the performance of semiconductor devices;Reduce stand-by period of the wafer in third time chemical mechanical planarization process simultaneously.
Foregoing description is only the description to present pre-ferred embodiments, not to any restriction of the scope of the invention, this Any change, modification that the those of ordinary skill in bright field does according to the disclosure above content, belong to the protection of claims Scope.

Claims (10)

1. a kind of method of cmp, it is characterised in that comprise the following steps:
Wafer to be ground is provided, the wafer include Semiconductor substrate, formed interlayer dielectric layer on the semiconductor substrate, The groove being formed in the interlayer dielectric layer and the metal interconnection being formed on the interlayer dielectric layer and in the groove Layer;
The first cmp is carried out to the metal interconnection layer, the part metal interconnection layer is removed;
The second cmp is carried out to the metal interconnection layer, the metal removed completely on the interlayer dielectric layer is mutual Connect layer;
3rd cmp is carried out to the interlayer dielectric layer;
3rd cmp includes a rinsing step:The wafer is rinsed using corrosion inhibiter.
2. the method for cmp as claimed in claim 1, it is characterised in that the 3rd cmp includes Pre-grinding, main grinding and wafer cleaning.
3. the method for cmp as claimed in claim 2, it is characterised in that carried out before the main grinding described Rinsing step.
4. the method for cmp as claimed in claim 3, it is characterised in that the rinsing step and the beforehand research Mill, main grinding are carried out on same grinding pad.
5. the method for cmp as claimed in claim 1, it is characterised in that the metal interconnecting layer is copper interconnection Layer, the corrosion inhibiter is copper inhibitor.
6. the method for cmp as claimed in claim 5, it is characterised in that the corrosion inhibiter is BTA.
7. the method for cmp as claimed in claim 1, it is characterised in that the rinsing step be rinsed when Between be 30s~70s.
8. the method for cmp as claimed in claim 1, it is characterised in that described first learn mechanical lapping, second The total time of cmp and the 3rd cmp is suitable.
9. the method for cmp as claimed in claim 8, it is characterised in that first cmp, Two cmps and the 3rd cmp are carried out using the different sub-devices of same chemical mechanical polishing device.
10. the method for cmp as claimed in claim 9, it is characterised in that first cmp, Two cmps are carried out simultaneously with the 3rd cmp, and different wafers are ground respectively.
CN201610996811.0A 2016-11-11 2016-11-11 Chemical mechanical grinding method Pending CN106625203A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110328561A (en) * 2018-03-30 2019-10-15 长鑫存储技术有限公司 The preparation method of chemical and mechanical grinding method, system and metal plug
CN113649945A (en) * 2021-10-20 2021-11-16 杭州众硅电子科技有限公司 Wafer polishing device
CN114121647A (en) * 2022-01-24 2022-03-01 澳芯集成电路技术(广东)有限公司 Method for improving chemical mechanical polishing efficiency

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Publication number Priority date Publication date Assignee Title
CN1458672A (en) * 2002-05-13 2003-11-26 台湾积体电路制造股份有限公司 Method for reducing defect of chemical and mechanical grinding to produce coppor and grinding slurry residual
CN101664899A (en) * 2008-09-05 2010-03-10 中芯国际集成电路制造(上海)有限公司 Chemical mechanical polishing method
CN102569170A (en) * 2010-12-29 2012-07-11 中芯国际集成电路制造(北京)有限公司 Manufacturing method of interconnection structure
CN105081958A (en) * 2014-05-23 2015-11-25 中芯国际集成电路制造(上海)有限公司 Chemical mechanical polishing method
CN105097425A (en) * 2014-04-18 2015-11-25 中芯国际集成电路制造(上海)有限公司 Chemical mechanical polishing method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1458672A (en) * 2002-05-13 2003-11-26 台湾积体电路制造股份有限公司 Method for reducing defect of chemical and mechanical grinding to produce coppor and grinding slurry residual
CN101664899A (en) * 2008-09-05 2010-03-10 中芯国际集成电路制造(上海)有限公司 Chemical mechanical polishing method
CN102569170A (en) * 2010-12-29 2012-07-11 中芯国际集成电路制造(北京)有限公司 Manufacturing method of interconnection structure
CN105097425A (en) * 2014-04-18 2015-11-25 中芯国际集成电路制造(上海)有限公司 Chemical mechanical polishing method
CN105081958A (en) * 2014-05-23 2015-11-25 中芯国际集成电路制造(上海)有限公司 Chemical mechanical polishing method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110328561A (en) * 2018-03-30 2019-10-15 长鑫存储技术有限公司 The preparation method of chemical and mechanical grinding method, system and metal plug
CN113649945A (en) * 2021-10-20 2021-11-16 杭州众硅电子科技有限公司 Wafer polishing device
CN114121647A (en) * 2022-01-24 2022-03-01 澳芯集成电路技术(广东)有限公司 Method for improving chemical mechanical polishing efficiency
CN114121647B (en) * 2022-01-24 2022-04-22 澳芯集成电路技术(广东)有限公司 Method for improving chemical mechanical polishing efficiency

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Application publication date: 20170510