CN106614598A - Insecticide and application thereof - Google Patents
Insecticide and application thereof Download PDFInfo
- Publication number
- CN106614598A CN106614598A CN201611246638.9A CN201611246638A CN106614598A CN 106614598 A CN106614598 A CN 106614598A CN 201611246638 A CN201611246638 A CN 201611246638A CN 106614598 A CN106614598 A CN 106614598A
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- CN
- China
- Prior art keywords
- insecticide
- isopropenyl
- cyclohexene
- methyl
- nylar
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
Abstract
The invention relates to an insecticide, and belongs to the technical field of insect prevention through plants. The insecticide comprises effective components and insecticide-acceptable auxiliary materials, wherein the effective components include d-limonene and pyriproxyfen. The insecticidal efficacy of the insecticide obtained through compounding the d-limonene and the pyriproxyfen is obviously improved; the medication cost is low; and the control effect can reach 95.7%.
Description
Technical field
The present invention relates to botanical insect-proof technical field, more particularly to a kind of insecticide and its application.
Background technology
Scale insect, red spider, Bemisia tabaci, aphid, diamondback moth, beet armyworm are the primary pests of fruit tree and vegetables, at present,
Preventing and treating the major pharmaceutical agent of the class pest has Buprofezin, Envidor, Hexythiazox, imidacloprid, pymetrozine, diafenthiuron, Biphenthrin, height
The chemical pesticides such as effect lambda-cyhalothrin, AVM, emamectin benzoate.Although chemical pesticide is made that very big tribute for agricultural production
Offer, but its toxicity is higher, remain in plant more, and can penetrate in soil, river, underground water, affect people's body
Health, reduces soil quality, causes environmental pollution.
As people are to environment and healthy growing interest, China's agricultural production is just from scalar type to quality and safety
Type changes, and the cultivated area of the crop such as organic orchard, organic vegetable is also to increase year by year, and prior art does not have been reported that a kind of pin
To fruit tree and the insecticide of the primary pest of vegetables.
The content of the invention
It is an object of the invention to provide a kind of insecticide and its application, the insecticide insecticidal effect that the present invention is provided is obvious
Improve, drug cost is low, preventive effect is high.
The invention provides a kind of insecticide, including active ingredient and the acceptable auxiliary material of insecticide；
The active ingredient includes (R)-4-isopropenyl-1-methyl-1-cyclohexene and Nylar.
Preferably, the weight/mass percentage composition of the active ingredient is 0.01～80%.
Preferably, the (R)-4-isopropenyl-1-methyl-1-cyclohexene and the mass ratio of Nylar are 1：(0.1～10).
Preferably, the (R)-4-isopropenyl-1-methyl-1-cyclohexene and the mass ratio of Nylar are 1：(0.8～7).
Preferably, the formulation of the insecticide includes solid dosage forms and liquid dosage form.
Preferably, when the formulation of the insecticide is solid dosage forms, the auxiliary material includes solid carrier and auxiliary agent；Institute
Solid carrier is stated including mineral matter.
Preferably, when the formulation of the insecticide is liquid dosage form, the auxiliary material includes solvent and auxiliary agent；It is described molten
Agent includes water and/or organic reagent.
Preferably, the auxiliary agent is adjusted independently selected from surfactant, thickener, defoamer, antifreeze, pH value
Agent, warning agent and preservative.
Present invention also offers application of the insecticide described in above-mentioned technical proposal in preventing and treating fruit tree and vegetables insect pest.
Preferably, the amount of application of the insecticide be 3～200 grams per mu or milliliter.
The invention provides a kind of insecticide and its application, including active ingredient and the acceptable auxiliary material of insecticide；It is described
Active ingredient includes (R)-4-isopropenyl-1-methyl-1-cyclohexene and Nylar.By the combination of biological components (R)-4-isopropenyl-1-methyl-1-cyclohexene and chemical constituent Nylar, this Shen
Please insecticide synergistic effect it is strong, good disinsection effect can be to scale insect, red spider, Bemisia tabaci, aphid, diamondback moth, beet armyworm
Good preventive and therapeutic effect is played Deng fruit tree and vegetables insect pest.Test result indicate that, the application insecticide preventive effect is up to 95.7%.
Specific embodiment
The invention provides a kind of insecticide, including active ingredient and the acceptable auxiliary material of insecticide；
The active ingredient includes (R)-4-isopropenyl-1-methyl-1-cyclohexene and Nylar.
The insecticide that the present invention is provided includes active ingredient, in the present invention, the weight/mass percentage composition of the active ingredient
Preferably 0.01～80%, more preferably 15～70%, most preferably 35～60%.
In the present invention, the (R)-4-isopropenyl-1-methyl-1-cyclohexene and the mass ratio of Nylar are 1：(0.1～10), more preferably 1：(0.8～
7), most preferably 1：(3～5).
The insecticide that the present invention is provided includes the acceptable auxiliary material of insecticide of surplus, species of the present invention to the auxiliary material
Without special restriction, those skilled in the art can be according to the suitable supplementary product kind agent consumption of the dosage form selection of insecticide.
In the present invention, the formulation of the insecticide includes solid dosage forms and liquid dosage form.The present invention is to the insecticide
Concrete formulation there is no special restriction, using insecticide formulation well known to those skilled in the art, such as soluble liquid,
Suspension emulsion, suspending agent, wettable powder, oil-suspending agent and missible oil etc..
In the present invention, when the insecticide formulation be solid dosage forms when, the auxiliary material preferably include solid carrier and
Auxiliary agent；The solid carrier preferably includes mineral matter.The present invention does not have special restriction to the mineral matter, using this area skill
Natural mineral matter known to art personnel or artificial synthesized mineral matter, the such as natural mineral matter include kaolin, talcum, swollen
Profit soil and attapulgite one or more, the artificial synthesized mineral matter includes white carbon and/or silicate.The present invention is to described
The source of solid carrier is using the commercially available prod of above-mentioned solid carrier well known to those skilled in the art without special restriction
Can.
In the present invention, when the formulation of the insecticide is liquid dosage form, the auxiliary material preferably includes solvent and auxiliary agent；
The solvent preferably includes water and/or organic reagent.Organic solvent of the present invention preferably include varsol, alcohols solvent,
One or more in ketones solvent, amine solvent, ether solvent and vegetable oil；It is molten that the varsol preferably includes aromatic hydrocarbons
Agent, chlorinated aromatic hydrocarbons class solvent, alkane solvents or hydrocarbon mixture solvent.In the present invention, the aromatic hydrocarbon solvent is preferably two
Toluene；Chlorinated aromatic hydrocarbons class solvent is preferably chlorobenzene；Alkane solvents are preferably atoleine；Hydrocarbon mixture solvent is preferably solvent
Oil；Alcohols solvent is preferably methyl alcohol and/or ethanol；Ketones solvent is preferably cyclohexanone；Amine solvent be preferably monoethanolamine and/or
Dimethylformamide；Ethers is preferably petroleum ether；Vegetable oil be preferably the one kind in corn oil, cottonseed oil and sec-Butyl Acetate or
It is several.The present invention without special restriction, above-mentioned is had to the source of above-mentioned organic solvent using well known to those skilled in the art
The commercially available prod of machine solvent.
In the present invention, the auxiliary agent in the solid dosage forms and liquid dosage form independently selected from surfactant, thickener,
Defoamer, antifreeze, pH value regulator, warning agent and preservative.
In the present invention, the surfactant preferably includes AEO, APES, many
Styrene phenol APEO, talan phenol poly-formaldehyde condensate APEO, NPE first
Aldehyde condensate, castor oil polyoxyethylene ether, polyoxyethylene polyoxypropylene block polyether, aliphatic acid polyethenoxy ether, sorbitol ester
APEO, APG APG, organosilicone polyoxyethylene ether, tallow amine APEO, calcium dodecyl benzene sulfonate, sulphur
Acid esters salt, Sulfonates, sulphosuccinates, polycarboxylate, phosphate ester salt, modified terminal olefine sulfonate, modified nonyl phenol
APEO, the sulfate-reducing conditions sodium sulfonate containing polyoxyethylene ether group, nonionic Pluronic PE 6800 and modified
Carboxylate complex in one or more.The present invention, without special restriction, is adopted to the source of above-mentioned surfactant
The commercially available prod of above-mentioned surfactant well known to those skilled in the art.
In the present invention, the thickener preferably includes carboxymethyl alcohol, polyvinyl alcohol, polyvinyl acetate, xanthans, bright
One or more in glue, gum arabic, phenolic resin, shellac, carboxymethylcellulose calcium, sodium alginate and organobentonite.
The present invention originating without special restriction to above-mentioned thickener, using the city of above-mentioned thickener well known to those skilled in the art
Sell product.
In the present invention, the defoamer preferably include silicone, C8～10 aliphatic alcohols, phosphoric acid ester, C10～20 satisfy
With one or more in fatty acid and amide-type defoamer；The silicone defoamer preferably includes modified polyoxy silane；
C8～10 aliphatic alcohols the defoamer preferably includes higher aliphatic polyethers；The phosphoric acid ester defoamer preferably includes phosphoric acid
Tributyl；C10～20 saturated fat acids the defoamer is preferably capric acid.The present invention is to the source of above-mentioned defoamer without spy
Different restriction, using the commercially available prod of above-mentioned defoamer well known to those skilled in the art.
In the present invention, the antifreeze preferably includes ethylene glycol and/or glycerine.The present invention to the ethylene glycol, third
Triol source without special restriction, using ethylene glycol well known to those skilled in the art, the commercially available prod of glycerine.
The present invention does not have special restriction to the species of the pH adjusting agent, is adjusted using pH well known to those skilled in the art
One or more in section agent, such as oxalic acid, citric acid, sodium carbonate and NaOH.The present invention is to the pH adjusting agent
Originate without special restriction, using the commercially available prod of pH adjusting agent well known to those skilled in the art.
Warning agent of the present invention preferably includes acid red, rhodamine toner, light blue or emerald.The present invention is to the warning agent
Source without special restriction, using acid red well known to those skilled in the art, rhodamine toner, light blue, emerald commercially available
Product.
In the present invention, the preservative preferably includes Sodium Benzoate and/or 2,6 BHTs.The present invention is right
The Sodium Benzoate, 2,6 BHTs source without special restriction, using benzene well known to those skilled in the art
Sodium formate, the commercially available prod of 2,6 BHTs.
The present invention does not have special restriction to the method for producing insecticide, is killed using well known to those skilled in the art
The preparation method of worm agent, such as carries out conventional mixing by active ingredient with solvent, auxiliary material.
Present invention also offers application of the insecticide described in above-mentioned technical proposal in preventing and treating fruit tree and vegetables insect pest.It is described
Insect pest preferably include one or more in scale insect, red spider, Bemisia tabaci, aphid, diamondback moth, beet armyworm caused by fruit tree
With vegetables insect pest.
The present invention does not have special restriction to the application process of the insecticide, is such as applied using foliage-spray or root.
In the present invention, the amount of application of the insecticide be 3～200 grams per mu or milliliter, more preferably per mu 10～150 grams or milli
Rise.
The insecticide that the present invention is provided is further described in detail with reference to specific embodiment, the technology of the present invention
Scheme includes but is not limited to following examples.
Embodiment 1
60% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene soluble liquid
Each material quality score ratio is as follows：Nylar 30%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 30%, phosphoric acid ester compound emulsifying agent
10%th, ethylene glycol 4%, organic silicon defoamer 0.3% and water surplus are supplied.By each active compound, ethylene glycol, defoamer and water during operation
Add reactor, heating stirring dissolving 30min to add emulsifier for mixing 30min, stand 2 hours, obtain final product 60% Nylar
(R)-4-isopropenyl-1-methyl-1-cyclohexene soluble liquid.
Embodiment 2
20% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene soluble liquid
Each material quality score ratio is as follows：Nylar 10%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 10%, phosphoric acid ester compound emulsifying agent
10%th, ethylene glycol 4%, organic silicon defoamer 0.3% and water surplus are supplied.By each active compound, ethylene glycol, defoamer and water during operation
Add reactor, heating stirring dissolving 30min to add emulsifier for mixing 30min, stand 2 hours, obtain final product 20% Nylar
(R)-4-isopropenyl-1-methyl-1-cyclohexene soluble liquid.
Embodiment 3
40% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene soluble liquid
Each material quality score ratio is as follows：Nylar 30%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 10%, phosphoric acid ester compound emulsifying agent
10%th, ethylene glycol 4%, organic silicon defoamer 0.3% and water surplus are supplied.By each active compound, ethylene glycol, defoamer and water during operation
Add reactor, heating stirring dissolving 30min to add emulsifier for mixing 30min, stand 2 hours, obtain final product 40% Nylar
(R)-4-isopropenyl-1-methyl-1-cyclohexene soluble liquid.
Embodiment 4
15% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene soluble liquid
Each material quality score ratio is as follows：Nylar 10%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 5%, phosphoric acid ester compound emulsifying agent 10%,
Ethylene glycol 4%, organic silicon defoamer 0.3% and water surplus are supplied.Each active compound, ethylene glycol, defoamer and water are added during operation
Reactor, heating stirring dissolving 30min, adds emulsifier for mixing 30min, stands 2 hours, obtains final product 15% Nylar d- lemons
Lemon alkene soluble liquid.
Embodiment 5
50% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspension emulsion
Each material quality score ratio is as follows：Nylar 25%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 25%, phosphoric acid ester compound emulsifying agent 8%,
Polycarboxylic acid salt's compound 4%, nonionic Pluronic PE 6800 3%, alkyl naphthalene sulfonic acid condensation polymer sodium salt 1%, aluminium-magnesium silicate
0.5%th, ethylene glycol 4%, sec-Butyl Acetate 15%, organic silicon defoamer 0.3%, Sodium Benzoate 0.5% and water surplus are supplied.Behaviour
First by (R)-4-isopropenyl-1-methyl-1-cyclohexene, phosphoric acid ester compound emulsifying agent and sec-Butyl Acetate and part water emulsification pretreatment when making, then by Nylar
Remaining each raw material shears 10min in another reactor, and (R)-4-isopropenyl-1-methyl-1-cyclohexene emulsification shearing finished product is finally added pyrrole by sand milling about 2 hours
50% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspension emulsion is obtained final product in propyl ether suspending agent.
Embodiment 6
20% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspension emulsion
Each material quality score ratio is as follows：Nylar 15%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 5%, phosphoric acid ester compound emulsifying agent 8%,
Polycarboxylic acid salt's compound 4%, nonionic Pluronic PE 6800 3%, alkyl naphthalene sulfonic acid condensation polymer sodium salt 1%, aluminium-magnesium silicate
0.5%th, ethylene glycol 4%, sec-Butyl Acetate 15%, organic silicon defoamer 0.3%, Sodium Benzoate 0.5% and water surplus are supplied.Behaviour
First by (R)-4-isopropenyl-1-methyl-1-cyclohexene, phosphoric acid ester compound emulsifying agent and sec-Butyl Acetate and part water emulsification pretreatment when making, then by Nylar
Remaining each raw material shears 10min in another reactor, and (R)-4-isopropenyl-1-methyl-1-cyclohexene emulsification shearing finished product is finally added pyrrole by sand milling about 2 hours
20% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspension emulsion is obtained final product in propyl ether suspending agent.
Embodiment 7
18% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspension emulsion
Each material quality score ratio is as follows：Nylar 8%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 10%, phosphoric acid ester compound emulsifying agent 8%,
Polycarboxylic acid salt's compound 4%, nonionic Pluronic PE 6800 3%, alkyl naphthalene sulfonic acid condensation polymer sodium salt 1%, aluminium-magnesium silicate
0.5%th, ethylene glycol 4%, sec-Butyl Acetate 15%, organic silicon defoamer 0.3%, Sodium Benzoate 0.5% and water surplus are supplied.Behaviour
First by (R)-4-isopropenyl-1-methyl-1-cyclohexene, phosphoric acid ester compound emulsifying agent and sec-Butyl Acetate and part water emulsification pretreatment when making, then by Nylar
Remaining each raw material shears 10min in another reactor, and (R)-4-isopropenyl-1-methyl-1-cyclohexene emulsification shearing finished product is finally added pyrrole by sand milling about 2 hours
18% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspension emulsion is obtained final product in propyl ether suspending agent.
Embodiment 8
25% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspension emulsion
Each material quality score ratio is as follows：Nylar 15%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 10%, phosphoric acid ester compound emulsifying agent 8%,
Polycarboxylic acid salt's compound 4%, nonionic Pluronic PE 6800 3%, alkyl naphthalene sulfonic acid condensation polymer sodium salt 1%, aluminium-magnesium silicate
0.5%th, ethylene glycol 4%, sec-Butyl Acetate 15%, organic silicon defoamer 0.3%, Sodium Benzoate 0.5% and water surplus are supplied.Behaviour
First by (R)-4-isopropenyl-1-methyl-1-cyclohexene, phosphoric acid ester compound emulsifying agent and sec-Butyl Acetate and part water emulsification pretreatment when making, then by Nylar
Remaining each raw material shears 10min in another reactor, and (R)-4-isopropenyl-1-methyl-1-cyclohexene emulsification shearing finished product is finally added pyrrole by sand milling about 2 hours
25% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspension emulsion is obtained final product in propyl ether suspending agent.
Embodiment 9
7% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspending agent
Each material quality score ratio is as follows：Nylar 5%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 2%, polycarboxylic acid salt's compound 6%, nonionic
Pluronic PE 6800 4%, alkyl naphthalene sulfonic acid condensation polymer sodium salt 1%, aluminium-magnesium silicate 0.5%, ethylene glycol 4%, organosilicon froth breaking
Agent 0.3%, Sodium Benzoate 0.5% and water surplus are supplied.Each raw material is added in modulation kettle during operation, with the water amount of supplying, shearing
10min, sand milling about 2 hours stirs froth breaking, obtains final product 7% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspending agent.
Embodiment 10
50% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspending agent
Each material quality score ratio is as follows：Nylar 25%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 25%, polycarboxylic acid salt's compound 6%, it is non-from
Sub- Pluronic PE 6800 4%, alkyl naphthalene sulfonic acid condensation polymer sodium salt 1%, aluminium-magnesium silicate 0.5%, ethylene glycol 4%, organosilicon disappear
Infusion 0.3%, Sodium Benzoate 0.5% and water surplus are supplied.Each raw material is added in modulation kettle during operation, with the water amount of supplying, is cut
10min is cut, sand milling about 2 hours stirs froth breaking, obtains final product 50% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspending agent.
Embodiment 11
16% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspending agent
Each material quality score ratio is as follows：Nylar 8%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 8%, polycarboxylic acid salt's compound 6%, nonionic
Pluronic PE 6800 4%, alkyl naphthalene sulfonic acid condensation polymer sodium salt 1%, aluminium-magnesium silicate 0.5%, ethylene glycol 4%, organosilicon froth breaking
Agent 0.3%, Sodium Benzoate 0.5% and water surplus are supplied.Each raw material is added in modulation kettle during operation, with the water amount of supplying, shearing
10min, sand milling about 2 hours stirs froth breaking, obtains final product 16% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspending agent.
Embodiment 12
28% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspending agent
Each material quality score ratio is as follows：Nylar 20%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 8%, polycarboxylic acid salt's compound 6%, it is non-from
Sub- Pluronic PE 6800 4%, alkyl naphthalene sulfonic acid condensation polymer sodium salt 1%, aluminium-magnesium silicate 0.5%, ethylene glycol 4%, organosilicon disappear
Infusion 0.3%, Sodium Benzoate 0.5% and water surplus are supplied.Each raw material is added in modulation kettle during operation, with the water amount of supplying, is cut
10min is cut, sand milling about 2 hours stirs froth breaking, obtains final product 28% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspending agent.
Embodiment 13
40% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene wettable powder
Each material quality score ratio is as follows：Nylar 30%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 10%, lauryl sodium sulfate 3%, lignin
Sodium sulfonate 3.5%, alkylnaphthalene sulfonate 7%, white carbon 12%, aluminium-magnesium silicate 1%, kaolin surplus are supplied.Will be each during operation
Jing fluid bed airflow millings equipment is crushed after raw material is mixed, and after mixing, obtains final product 40% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene wettable powder
Agent.
Embodiment 14
60% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene wettable powder
Each material quality score ratio is as follows：Nylar 50%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 10%, lauryl sodium sulfate 3%, lignin
Sodium sulfonate 3.5%, alkylnaphthalene sulfonate 7%, white carbon 12%, aluminium-magnesium silicate 1%, kaolin surplus are supplied.Will be each during operation
Jing fluid bed airflow millings equipment is crushed after raw material is mixed, and after mixing, obtains final product 60% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene wettable powder
Agent.
Embodiment 15
60% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene wettable powder
Each material quality score ratio is as follows：Nylar 50%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 10%, lauryl sodium sulfate 3%, lignin
Sodium sulfonate 3.5%, alkylnaphthalene sulfonate 7%, white carbon 12%, aluminium-magnesium silicate 1%, kaolin surplus are supplied.Will be each during operation
Jing fluid bed airflow millings equipment is crushed after raw material is mixed, and after mixing, obtains final product 60% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene wettable powder
Agent.
Embodiment 16
60% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene wettable powder
Each material quality score ratio is as follows：Nylar 50%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 10%, lauryl sodium sulfate 3%, lignin
Sodium sulfonate 3.5%, alkylnaphthalene sulfonate 7%, white carbon 12%, aluminium-magnesium silicate 1%, kaolin surplus are supplied.Will be each during operation
Jing fluid bed airflow millings equipment is crushed after raw material is mixed, and after mixing, obtains final product 60% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene wettable powder
Agent.
Embodiment 17
14% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene oil-suspending agent
Each material quality score ratio is as follows：Nylar 7%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 7%, polycarboxylate 1%, polyester-type high molecular form
Face activating agent is supplied with extraordinary emulsifier mixture 12%, organobentonite 2.5%, soybean oil surplus.By soybean oil during operation
In pumping into the cutting kettle of cleaning, under shearing condition, dispersion emulsifier is gradually added, dissolving is complete, active compound is dividedly in some parts and is cut
In cutting kettle, entering one-level sand mill and two grades of sand mills after adding thickener, shearing uniform carries out sand milling, obtains final product 14% pyrrole third
Ether (R)-4-isopropenyl-1-methyl-1-cyclohexene oil-suspending agent.Embodiment 18
30% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene oil-suspending agent
Each material quality score ratio is as follows：Nylar 15%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 15%, polycarboxylate 1%, polyester-type macromolecule
Surfactant is supplied with extraordinary emulsifier mixture 12%, organobentonite 2.5%, soybean oil surplus.By soybean during operation
Oil pump enters in the cutting kettle of cleaning, under shearing condition, is gradually added dispersion emulsifier, and dissolving is complete, and active compound is dividedly in some parts
In cutting kettle, entering one-level sand mill and two grades of sand mills after adding thickener, shearing uniform carries out sand milling, obtains final product 15% pyrrole third
Ether (R)-4-isopropenyl-1-methyl-1-cyclohexene oil-suspending agent.
Embodiment 19
20% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene oil-suspending agent
Each material quality score ratio is as follows：Nylar 15%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 5%, polycarboxylate 1%, polyester-type macromolecule
Surfactant is supplied with extraordinary emulsifier mixture 12%, organobentonite 2.5%, soybean oil surplus.By soybean during operation
Oil pump enters in the cutting kettle of cleaning, under shearing condition, is gradually added dispersion emulsifier, and dissolving is complete, and active compound is dividedly in some parts
In cutting kettle, entering one-level sand mill and two grades of sand mills after adding thickener, shearing uniform carries out sand milling, obtains final product 20% pyrrole third
Ether (R)-4-isopropenyl-1-methyl-1-cyclohexene oil-suspending agent.
Embodiment 20
18% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene oil-suspending agent
Each material quality score ratio is as follows：Nylar 12%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 6%, polycarboxylate 1%, polyester-type macromolecule
Surfactant is supplied with extraordinary emulsifier mixture 12%, organobentonite 2.5%, soybean oil surplus.By soybean during operation
Oil pump enters in the cutting kettle of cleaning, under shearing condition, is gradually added dispersion emulsifier, and dissolving is complete, and active compound is dividedly in some parts
In cutting kettle, entering one-level sand mill and two grades of sand mills after adding thickener, shearing uniform carries out sand milling, obtains final product 18% pyrrole third
Ether (R)-4-isopropenyl-1-methyl-1-cyclohexene oil-suspending agent.
Embodiment 21
26% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene missible oil
Each material quality score ratio is as follows：Nylar 16%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 10%, castor oil polyoxyethylene ether 6%, sorb
Alcohol ester APEO 4%, solvent naphtha is supplied.By each active compound, solvent naphtha reactor during operation, heating stirring dissolving 30min is treated
All dissolvings add emulsifier for mixing 30min, stand 2 hours, obtain final product 26% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene missible oil.
Embodiment 22
25% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene missible oil
Each material quality score ratio is as follows：Nylar 10%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 15%, castor oil polyoxyethylene ether 6%, sorb
Alcohol ester APEO 4%, solvent naphtha is supplied.By each active compound, solvent naphtha reactor during operation, heating stirring dissolving 30min is treated
All dissolvings add emulsifier for mixing 30min, stand 2 hours, obtain final product 25% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene missible oil.
Embodiment 23
30% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene missible oil
Each material quality score ratio is as follows：Nylar 112%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 18%, castor oil polyoxyethylene ether 6%, mountain
Pears alcohol ester APEO 4%, solvent naphtha is supplied.By each active compound, solvent naphtha reactor during operation, heating stirring dissolving 30min,
Treat that all dissolving adds emulsifier for mixing 30min, stands 2 hours, obtain final product 30% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene missible oil.
Embodiment 24
50% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene missible oil
Each material quality score ratio is as follows：Nylar 25%, (R)-4-isopropenyl-1-methyl-1-cyclohexene 25%, castor oil polyoxyethylene ether 6%, sorb
Alcohol ester APEO 4%, solvent naphtha is supplied.By each active compound, solvent naphtha reactor during operation, heating stirring dissolving 30min is treated
All dissolvings add emulsifier for mixing 30min, stand 2 hours, obtain final product 50% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene missible oil.
Comparative example 1
The scale insect test of preventing and treating oranges and tangerines
Sample A：20% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene soluble liquid (embodiment 2), Weierda Chemical Co., Ltd., Zhejiang；
Control：5%d- limonenes water solubility liquor (Weierda Chemical Co., Ltd., Zhejiang)；(Zhejiang Weir reaches 10% Nylar missible oil
Chemical Co., Ltd.).
For studying thing：Mandarin tree (precious long)；Target object：Scale insect (loses point to be situated between)；Place：Beilun,Ningbo City, Zhejiang Province
Area Wu；Cell is arranged：2 plants of each cell, is arranged using random district's groups, and 7 process are set altogether, often processes 4 repetitions；During dispenser
Phase：The nymph full incidence period dispenser of 2 ages；Spraying time and number of times：On July 27th, 2016, dispenser is once；Investigation method：Adjust per cell
2 plants of mandarin trees are looked into, per plant by east, south, west, north, the middle shell borer population fixed 5 tips of causing harm, investigate on the tip and on blade；As a result
As shown in table 1：
Drug effect computational methods：
The sample A of table 1 prevents and treats oranges and tangerines scale insect result of the test
Conclusion：Sample A tri- has good prevention effect to oranges and tangerines scale insect for examination concentration, average preventive effect 80.9%～
90.8%, to compare in comparison medicament, prevention effect is above comparison medicament in the case that consumption is reduced.
Comparative example 2
The red spider test of preventing and treating strawberry
Sample B：7% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene suspending agent (embodiment 9), Weierda Chemical Co., Ltd., Zhejiang；Control：
5%d- limonenes water solubility liquor (Weierda Chemical Co., Ltd., Zhejiang)；(Zhejiang Weir has 10% Nylar missible oil up to chemical industry
Limit company).
For studying thing：Strawberry；Target object：Red spider；Place：Area of Yuhang in Zhejiang Tang Qi towns；Cell is arranged：Each cell
5 square metres of area, is arranged using random district's groups, and 7 process are set altogether, often processes 4 repetitions；Dispenser period：Red spider ovum incubates Sheng
Phase dispenser；Spraying time and number of times：On October 24th, 2016, dispenser is once；Investigation method：Fix per cell within 7 days after dispenser and adjust
Look into louvre blade medicine insect population number；As a result it is as shown in table 2：
The sample B of table 2 prevents and treats strawberry red spider result of the test
Conclusion：Sample B tri- has good prevention effect to strawberry red spider for examination concentration, average preventive effect 88.2%～
94.8%, prevention effect is above comparison medicament.
Comparative example 3
The Bemisia tabaci test of preventing and treating tomato
Sample C：20% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene oil-suspending agent (embodiment 19), Weierda Chemical Co., Ltd., Zhejiang；
Control：5%d- limonenes water solubility liquor (Weierda Chemical Co., Ltd., Zhejiang)；(Zhejiang Weir reaches 10% Nylar missible oil
Chemical Co., Ltd.).
For studying thing：Tomato；Target object：Bemisia tabaci (2～3 age)；Place：Wenzhou District of Zhejiang Province Cangnan；Cell is arranged：Each
6 square metres of plot area, is arranged using random district's groups, and 7 process are set altogether, often processes 4 repetitions；Dispenser period：Bemisia tabaci is low
Age nymph dispenser；Spraying time and number of times：On September 10th, 2016, dispenser is once；Investigation method：Consolidate per cell within 7 days after dispenser
Set the tone and look into louvre blade insect population number；As a result it is as shown in table 3：
The sample C of table 3 prevents and treats tomato Bemisia tabaci result of the test
Conclusion：Sample C tri- has good prevention effect to tomato Bemisia tabaci for examination concentration, average preventive effect 84.1%～
93.4%, to compare in comparison medicament, prevention effect is above comparison medicament in the case that mu consumption is reduced.
Comparative example 4
Preventing and treating Cucumber blight test
Sample D：26% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene missible oil (embodiment 21), Weierda Chemical Co., Ltd., Zhejiang；Control：
5%d- limonenes water solubility liquor (Weierda Chemical Co., Ltd., Zhejiang)；(Zhejiang Weir has 10% Nylar missible oil up to chemical industry
Limit company).
For studying thing：Cucumber；Target object：Aphid；Place：Area of Yuhang in Zhejiang Qiaosi；Cell is arranged：Each plot area
5 square metres, arranged using random district's groups, 7 process are set altogether, often process 4 repetitions；Dispenser period：Cucumber blight low instar nymphs
Phase dispenser；Spraying time and number of times：On July 20th, 2016, dispenser is once；Investigation method：Investigation is fixed per cell within 7 days after dispenser
Louvre blade medicine insect population number；As a result it is as shown in table 4：
The sample D of table 4 preventing and treating Cucumber blight tests
Conclusion：Sample D tri- has good prevention effect to Cucumber blight for examination concentration, average preventive effect 88.9%～
95.7%, to compare in comparison medicament, prevention effect is above comparison medicament in the case that mu consumption is reduced.
Comparative example 5
Preventing and treating Laphygma exigua Hubner test
Sample E：20% Nylar (R)-4-isopropenyl-1-methyl-1-cyclohexene soluble liquid (embodiment 2), Weierda Chemical Co., Ltd., Zhejiang；
Control：5%d- limonenes water solubility liquor (Weierda Chemical Co., Ltd., Zhejiang)；(Zhejiang Weir reaches 10% Nylar missible oil
Chemical Co., Ltd.).
For studying thing：Wild cabbage；Target object：Beet armyworm；Place：Hangzhou Qiaosi town；Cell is arranged：Each cell face
10 square metres of product, is arranged using random district's groups, and 6 process are set altogether, often processes 4 repetitions；Dispenser period：Beet armyworm low age children
The worm phase；Spraying time and number of times：On June 2nd, 2016, dispenser is once；Investigation method：, the investigation of fixed point singling, diagonal per cell
5 points sample, 2 plants per totally 10 plants, respectively 7 days borer populations living before investigation dispenser and after dispenser；As a result it is as shown in table 5：
The sample E of table 5 prevents and treats Laphygma exigua Hubner result of the test
Conclusion：Sample E tri- has good prevention effect to Laphygma exigua Hubner for examination concentration, and average preventive effect is 85.9%
～93.1%, to compare in comparison medicament, prevention effect is above comparison medicament in the case that mu consumption is reduced.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of insecticide, including active ingredient and the acceptable auxiliary material of insecticide；
The active ingredient includes (R)-4-isopropenyl-1-methyl-1-cyclohexene and Nylar.
2. insecticide according to claim 1, it is characterised in that the weight/mass percentage composition of the active ingredient is 0.01～
80%.
3. insecticide according to claim 1 and 2, it is characterised in that the (R)-4-isopropenyl-1-methyl-1-cyclohexene is with the mass ratio of Nylar
1：(0.1～10).
4. insecticide according to claim 3, it is characterised in that the (R)-4-isopropenyl-1-methyl-1-cyclohexene is 1 with the mass ratio of Nylar：
(0.8～7).
5. insecticide according to claim 1, it is characterised in that the formulation of the insecticide includes solid dosage forms and liquid
Formulation.
6. insecticide according to claim 5, it is characterised in that when the formulation of the insecticide is solid dosage forms, institute
Auxiliary material is stated including solid carrier and auxiliary agent；The solid carrier includes mineral matter.
7. insecticide according to claim 5, it is characterised in that when the formulation of the insecticide is liquid dosage form, institute
Auxiliary material is stated including solvent and auxiliary agent；The solvent includes water and/or organic reagent.
8. the insecticide according to claim 6 or 7, it is characterised in that the auxiliary agent independently selected from surfactant, increase
Thick dose, defoamer, antifreeze, pH value regulator, warning agent and preservative.
9. application of the insecticide described in claim 1～8 any one in preventing and treating fruit tree and vegetables insect pest.
10. application according to claim 9, it is characterised in that the amount of application of the insecticide be 3～200 grams per mu or
Milliliter.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611246638.9A CN106614598A (en) | 2016-12-29 | 2016-12-29 | Insecticide and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611246638.9A CN106614598A (en) | 2016-12-29 | 2016-12-29 | Insecticide and application thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN106614598A true CN106614598A (en) | 2017-05-10 |
Family
ID=58837127
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611246638.9A Pending CN106614598A (en) | 2016-12-29 | 2016-12-29 | Insecticide and application thereof |
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| Country | Link |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108849933A (en) * | 2018-06-13 | 2018-11-23 | 惠州市锦恒工业模具设计合伙企业(普通合伙) | A kind of composition pesticide containing (R)-4-isopropenyl-1-methyl-1-cyclohexene and paichongding |
| CN109221109A (en) * | 2018-09-17 | 2019-01-18 | 福建新农大正生物工程有限公司 | A kind of Synergistic mite killing composition containing avermectin |
| EP3729965A4 (en) * | 2017-12-20 | 2021-09-08 | Ishihara Sangyo Kaisha, Ltd. | Pest control composition and pest control method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5942525A (en) * | 1995-05-11 | 1999-08-24 | Ecto Development Corporation | Spot treatment of animals with pyriproxyfen and an insecticide |
| WO2002089584A1 (en) * | 2001-05-09 | 2002-11-14 | Medicis Pharmaceutical Corporation | Ectoparasiticidal compositions and methods of their use |
| CN101120675A (en) * | 2006-08-08 | 2008-02-13 | 李建林 | Highly effective environment-friendly type biological insecticide |
-
2016
- 2016-12-29 CN CN201611246638.9A patent/CN106614598A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5942525A (en) * | 1995-05-11 | 1999-08-24 | Ecto Development Corporation | Spot treatment of animals with pyriproxyfen and an insecticide |
| WO2002089584A1 (en) * | 2001-05-09 | 2002-11-14 | Medicis Pharmaceutical Corporation | Ectoparasiticidal compositions and methods of their use |
| CN101120675A (en) * | 2006-08-08 | 2008-02-13 | 李建林 | Highly effective environment-friendly type biological insecticide |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3729965A4 (en) * | 2017-12-20 | 2021-09-08 | Ishihara Sangyo Kaisha, Ltd. | Pest control composition and pest control method |
| CN108849933A (en) * | 2018-06-13 | 2018-11-23 | 惠州市锦恒工业模具设计合伙企业(普通合伙) | A kind of composition pesticide containing (R)-4-isopropenyl-1-methyl-1-cyclohexene and paichongding |
| CN109221109A (en) * | 2018-09-17 | 2019-01-18 | 福建新农大正生物工程有限公司 | A kind of Synergistic mite killing composition containing avermectin |
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