CN106973957A - A kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl - Google Patents

A kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl Download PDF

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Publication number
CN106973957A
CN106973957A CN201710157129.7A CN201710157129A CN106973957A CN 106973957 A CN106973957 A CN 106973957A CN 201710157129 A CN201710157129 A CN 201710157129A CN 106973957 A CN106973957 A CN 106973957A
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cyhalofop
butyl
oil
ketone sulphur
fluorine ketone
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Inventor
毕亚玲
王曹阳
谷刚
李鹏程
黄伟东
聂碧辉
李阳阳
李部
李雷
孙勇胜
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Anhui University of Science and Technology
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Anhui University of Science and Technology
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Priority to CN201710157129.7A priority Critical patent/CN106973957A/en
Publication of CN106973957A publication Critical patent/CN106973957A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04Aryloxy-acetic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/661,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]
    • A01N65/44Poaceae or Gramineae [Grass family], e.g. bamboo, lemon grass or citronella grass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Natural Medicines & Medicinal Plants (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, it is made up of the component of following mass percent:Fluorine ketone sulphur grass amine 5~10%, cyhalofop-butyl 8~15%, eucalyptus oil 3~6%, donaxine 2~4%, emulsifying agent 11~13%, dispersant 1~2%, stabilizer 0.5~1%, synergist 0.5~1%, organic solvent 10~20%, surplus supplies 100% with methyl oleate.The dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl of the present invention shows obvious synergy or addition, the herbicidal effect of composition is significantly improved than single dose, and due to the addition of plant source herbicidal constituents in formula, reduce the dosage of agricultural chemicals, cost is reduced, while decreasing environmental pollution.

Description

A kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl
Technical field
The invention belongs to technical field of pesticide, and in particular to a kind of dispersible oil containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl Suspending agent.
Background technology
Dispersible oil-suspending agent be using vegetable oil as decentralized medium, it is environmentally friendly, be watered be sprayed at after plant surface glue The property, plate-out ability and good penetrability, resistance of rainwater washing against, the lasting period are long, so as to improve agricultural chemicals utilization rate, play synergistic effect, can Effective ingredient consumption is reduced, it is cost-effective.
Fluorine ketone sulphur grass amine belongs to sulfonamides herbicide, is a kind of rice terrace wide spectrum processing selective herbicide, after dispenser Via plant root and Foliage Absorption, worked by suppressing acetolactic acid, to grassy weed barnyard grass, broad leaved weed Eclipta prostrata, nutgrass flatsedge Section's difformed galingale herb has good preventive effect;Cyhalofop-butyl belongs to fragrant phenoxy phenoxy propionic acid absorbability translocated herbicide, by The site absorptions such as stem, leaf, the bud scale of plant, and conducted through dredging tissue from absorption site to other organs, destroy plant Internal structure and physiological equilibrium, cause weeds dead, in addition, cyhalofop-butyl is efficient to moleplant seed, barnyard grass, and prevent a variety of grass family Weeds, such as lady's-grass, Paspalum distichum, green bristlegrass, eleusine indica, amur foxtail, but it is invalid to sedge weed and broad leaved weed.
Therefore, can be in the case of smaller consumption, to rice terrace in the urgent need to developing a kind of new herbicides Interior most of weeds play a role.
The content of the invention
A kind of Herbicidal combinations containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl that the present invention is provided, are solved in the prior art A kind of herbicide is used alone, it is impossible to once prevent and kill off a variety of weeds and cause the problem of many weeds develop immunity to drugs.
The invention provides a kind of Herbicidal combinations containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, by following mass percent Component be made:Fluorine ketone sulphur grass amine 5~10%, cyhalofop-butyl 8~15%, eucalyptus oil 3~6%, donaxine 2~4%, emulsifying agent 11~13%, dispersant 1~2%, stabilizer 0.5~1%, synergist 0.5~1%, organic solvent 10~20%, use oleic acid first Ester supplies 100%.
It is preferred that, the Herbicidal combinations containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl by following mass percent component It is made:Fluorine ketone sulphur grass amine 10%, cyhalofop-butyl 10%, eucalyptus oil 5%, donaxine 3%, emulsifying agent 13%, dispersant 1.5%, Stabilizer 0.6%, synergist 0.5%, organic solvent 15%, 100% is supplied with methyl oleate.
It is preferred that, the eucalyptus oil is prepared according to following steps:
Crushed after folium eucalypti is dried in the shade, obtain folium eucalypti powder, folium eucalypti powder is added into alembic, then toward add in alembic equivalent to The cellulase of folium eucalypti powder weight 1%, then adds water until submergence folium eucalypti powder, folium eucalypti powder soaks after 5h in water, extracted Liquid;Then it is passed through vapor from the bottom of alembic to heat extract solution, gas-phase product is collected after extract solution boiling;Collect 1h, obtains mixed vapour, and mixed vapour is condensed by condenser, oil water mixture is obtained;Oil water mixture is by oil Separator is separated, and obtains folium eucalypti crude oil;Folium eucalypti crude oil is extracted by extractor, after layering, and the upper strata separated is i.e. For eucalyptus oil.
It is preferred that, the emulsifying agent is AEO, phenethyl phenol polyethenoxy ether, DBSA One or more in calcium, alkylaryl polyoxyethylene polyoxypropylene ether again.
It is preferred that, the dispersant be fatty alcohol ethylene oxide adduct phosphate, lignin and its derivative sulfonate, One or more in aliphatic acid ethane additive product phosphate, polyvinyl alcohol, 1-METHYLPYRROLIDONE, polyethylene glycol.
It is preferred that, one kind in the stabilizer organobentonite, cresyl glycidyl ether.
It is preferred that, the synergist is one kind in ammonium sulfate, methyl Synergistic Phosphorus.
It is preferred that, the organic solvent is the one or more in dimethylbenzene, cyclohexanone, ethylene glycol, solvent naphtha.
The dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl of the present invention can use generally in the art Prepared by method, such as:
Step 1, weigh the careless amine of fluorine ketone sulphur of respective amount, it is cyhalofop-butyl, eucalyptus oil, donaxine, emulsifying agent, dispersant, steady Determine agent, synergist, organic solvent, methyl oleate;
Step 2, the raw material weighed in step 1 is added into mixing kettle, stirring is well mixed it, obtains mixture;
Step 3, the mixture obtained in step 2 is placed in sand mill and carries out ultramicro grinding, control average grain diameter micro- for 3 Rice, ultramicro grinding is finished, that is, obtains the dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl.
Compared with prior art, the beneficial effects of the present invention are:
1) the dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl that the present invention is provided, in certain ratio range Its interior synergy shows obvious synergy or addition, and the herbicidal effect of composition is significantly improved than single dose, drop The low dosage of agricultural chemicals, reduces cost.
2) two kinds of single doses containing the careless amine of fluorine ketone sulphur and the dispersible oil-suspending agent of cyhalofop-butyl that the present invention is provided effectively into Divide different with mechanism of action, the application of composition can delay or overcome the generation of herbicide resistance, be conducive to agricultural synthesis to administer.
3) removed in the dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl that the present invention is provided added with plant Careless agent eucalyptus oil, donaxine, on the one hand can be with the herbicide effect for merging the careless amine of promotion fluorine ketone sulphur and cyhalofop-butyl, another aspect The consumption of chemical herbicide can be reduced, so as to reduce the infringement to rice terrace.
Embodiment
In order that those skilled in the art more fully understand that technical scheme can be practiced, with reference to specific The invention will be further described for embodiment, but illustrated embodiment is not as a limitation of the invention.
Experimental method described in various embodiments of the present invention and reagent, are conventional method and conventional examination unless otherwise specified Agent.
Embodiment 1
A kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, by the component system of following mass percent Into:Fluorine ketone sulphur grass amine 8%, cyhalofop-butyl 12%, eucalyptus oil 3%, donaxine 4%, calcium dodecyl benzene sulfonate 3%, fatty alcohol APEO 8%, polyvinyl alcohol 1%, organobentonite 0.8%, ammonium sulfate 0.8%, solvent naphtha 20%, are mended with methyl oleate Foot 100%;
Wherein, eucalyptus oil is prepared according to following steps:
Crushed after folium eucalypti is dried in the shade, obtain folium eucalypti powder, folium eucalypti powder is added into alembic, then toward add in alembic equivalent to The cellulase of folium eucalypti powder weight 1%, then adds water until submergence folium eucalypti powder, folium eucalypti powder soaks after 5h in water, extracted Liquid;Then it is passed through vapor from the bottom of alembic to heat extract solution, collects gas-phase product after extract solution boiling, collect 1h, obtains mixed vapour;Mixed vapour is condensed by condenser, oil water mixture is obtained;Oil water mixture is by oil Separator is separated, and obtains folium eucalypti crude oil;Folium eucalypti crude oil is extracted by extractor, after layering, and the upper strata separated is i.e. For eucalyptus oil;
Wherein, the preparation method of the dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl is as follows:
Step 1, fluorine ketone sulphur careless amine, 12% cyhalofop-butyl, 3% eucalyptus oil, 4% that mass percent is 8% are weighed Donaxine, 3% calcium dodecyl benzene sulfonate, 8% AEO, 1% polyvinyl alcohol, 0.8% have Machine bentonite, 0.8% ammonium sulfate, 20% solvent naphtha, and supply 100% with methyl oleate;
Step 2, the careless amine of the fluorine ketone sulphur weighed in step 1, cyhalofop-butyl, eucalyptus oil, donaxine, ten are added into mixing kettle Dialkyl benzene sulfonic acids calcium, AEO, polyvinyl alcohol, organobentonite, ammonium sulfate, solvent naphtha, methyl oleate, are stirred Mix, be well mixed it, obtain mixture;
Step 3, the mixture in step 2 is placed in sand mill and carries out ultramicro grinding, and control scattered oil-suspending agent Average grain diameter is 3 microns, and ultramicro grinding, which is finished, obtains the dispersible oil suspension containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl Agent.
Embodiment 2
A kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, by the component system of following mass percent Into:Fluorine ketone sulphur grass amine 10%, cyhalofop-butyl 10%, eucalyptus oil 5%, donaxine 3%, calcium dodecyl benzene sulfonate 3%, phenethyl Phenol polyethenoxy ether 10%, 1-METHYLPYRROLIDONE 1.5%, organobentonite 0.6%, methyl Synergistic Phosphorus 0.5%, ethylene glycol 15%, supply 100% with methyl oleate;
Wherein, the extracting method of eucalyptus oil and the preparation method be the same as Example 1 of dispersible oil-suspending agent.
Embodiment 3
A kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, by the component system of following mass percent Into:Fluorine ketone sulphur grass amine 5%, cyhalofop-butyl 15%, eucalyptus oil 6%, donaxine 2%, calcium dodecyl benzene sulfonate 3%, alkyl virtue Base polyoxyethylene polyoxypropylene ether 9%, polyethylene glycol 2%, organobentonite 1.0%, ammonium sulfate 1%, cyclohexanone 10%, with oil Sour methyl esters supplies 100%;
Wherein, the extracting method of eucalyptus oil and the preparation method be the same as Example 1 of dispersible oil-suspending agent.
Embodiment 1-3 has prepared the dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, actually makes In, every mu weighs 300 grams of dispersible oil-suspending agents and is watered after 30 liters uniform cauline leaf spraying.Before dispenser, first have to draining or Shallow seated groundwater is released, native epiliminion is less than 1cm, weeds are completely exposed after the water surface, dispenser and are poured water again after 24-48h, prevents new miscellaneous Grass is sprouted.
Prevented and treated using the embodiment 1-3 dispersible oil-suspending agents containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl prepared The field efficacy experiment of paddy field weed, for verifying that annual gramineous weed, broad-leaved are miscellaneous in embodiment 1-3 preventing and treating rice terraces The effect of grass and sedge weed, while being contrasted with the careless amine single dose of fluorine ketone sulphur and cyhalofop-butyl single dose, determines each reality The prevention effect of example is applied, specific experiment process and result are as follows:
1st, reagent agent:
Three kinds of Herbicidal combinations in embodiment 1-3.
2nd, comparison medicament:
19% fluorine ketone sulphur grass amine suspending agent and the dispersible oil-suspending agent of 20% cyhalofop-butyl.
3rd, for studying thing:
Transplanted rice field, grows fine, robust plant, without other pest and disease damages.
4th, control object:
Rice terrace annual gramineous weed, broad leaved weed and sedge weed.
5th, experimental method:
According to the area of experimental plot, the good various medicaments of precise are watered after dilution, uniform sprinkling, it is sprayed after 20d, 40d observe weeds death condition, and the activity of weeding of relatively more various medicaments after medicine respectively, and specific experiment the results are shown in Table 1- 3。
Experimental result after 1 field medication of table 20 days
Experimental result after 2 field medication of table 40 days
As can be seen from Table 1 and Table 2, the embodiment 1-3 dispersible oil containing the careless sulfanilamide (SN) of fluorine ketone and cyhalofop-butyl suspends Agent has good preventive effect to rice terrace grass family, broad-leaved and sedge weed, and preventive effect can reach more than 90%, therefore The Herbicidal combinations of the present invention, which not only have, expands herbicidal spectrum, improves the effect of activity of weeding, is also equipped with quick-acting and persistence Advantage.
Safety experiment result of the field medication of table 3 to paddy rice
As shown in Table 3, sprayed the present invention containing the careless amine of fluorine ketone sulphur and the dispersible oil-suspending agent of cyhalofop-butyl after, paddy rice Grow fine, survival rate is 100%, and have no obvious poisoning, the Herbicidal combinations for illustrating the present invention are safe to paddy rice.
The present invention's contains the careless amine of fluorine ketone sulphur and the dispersible oil-suspending agent of cyhalofop-butyl by the careless amine of fluorine ketone sulphur and cyhalofop-butyl Compounding together, possesses obvious synergistic function, also added eucalyptus oil and donaxine both plants in the present invention in addition Material resource herbicide, can further enhance the synergistic effect of drug regimen, and two kinds of less botanical herbicides of toxicity Addition can also reduce the consumption of chemical agent, reduce the influence to soil and environment.The Herbicidal combinations of the present invention are removed Careless effect is significantly improved than single dose, reduces the dosage of agricultural chemicals.In addition, fluorine in the Herbicidal combinations that the present invention is provided Ketone sulphur grass amine is different with the mechanism of action of cyhalofop-butyl, and combination application can delay or overcome the generation of herbicide resistance, be conducive to Agricultural synthesis is administered.
The careless amine of fluorine ketone sulphur added in the present invention is a kind of inhibitor of acetolactate synthetase of high activity, can be very after dispenser Absorbed, and conduct to whole plant by the cauline leaf of weeds soon, suppress plant meristem growth, so that weeds are killed, it is effectively anti- It is simultaneous to control most of broad leaved weeds, sedge weed and other herbicides are produced anti-except barnyard grass in paddy field and other grassy weeds The barnyard grass of property;Cyhalofop-butyl is a kind of fragrant phenoxy phenoxy propionic acid herbicide, has tight security to paddy rice, cyhalofop-butyl is also Uptake and translocation herbicide, is absorbed by the blade and leaf sheath of plant, and bast conduction accumulates the separate living tissue in plant Area, suppresses acetyl-CoA carboxylase, makes aliphatic acid synthesis stopping, and the growth division of cell can not be normally carried out, and membranous system etc. contains Fat structure is destroyed, and finally results in Plant death;Contain Cineole in eucalyptus oil, and Cineole is a kind of monoterpene, is had Higher activity, can coordinate weeding with chemical herbicide;Donaxine is having of producing during evolution of the plants such as barley A kind of alkaloid of allelopathy, it is inhibited to environment plant, and it has the advantages that low toxicity, efficient, low resistance, Available for weeding;Emulsifying agent, dispersant can make various water-soluble, water-insoluble components in formula uniformly be blended in one Rise, so that effect is uniform;Stabilizer can prevent each component from occurring photothermal decomposition or oxidation Decomposition etc.;Synergist can be carried significantly The virulence and drug effect of high herbicidal composition.
, but those skilled in the art once know basic creation although preferred embodiments of the present invention have been described Property concept, then can make other change and modification to these embodiments.So, appended claims are intended to be construed to include excellent Select embodiment and fall into having altered and changing for the scope of the invention.
Obviously, those skilled in the art can carry out the essence of various changes and modification without departing from the present invention to the present invention God and scope.So, if these modifications and variations of the present invention belong to the scope of the claims in the present invention and its equivalent technologies Within be also intended to comprising these change and modification including.

Claims (8)

1. a kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, it is characterised in that by following quality percentage The component of ratio is made:Fluorine ketone sulphur grass amine 5~10%, cyhalofop-butyl 8~15%, eucalyptus oil 3~6%, donaxine 2~4%, emulsification Agent 11~13%, dispersant 1~2%, stabilizer 0.5~1%, synergist 0.5~1%, organic solvent 10~20%, use oleic acid Methyl esters supplies 100%.
2. the dispersible oil-suspending agent according to claim 1 containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, it is characterised in that It is made up of the component of following mass percent:Fluorine ketone sulphur grass amine 10%, cyhalofop-butyl 10%, eucalyptus oil 5%, donaxine 3%, breast Agent 13%, dispersant 1.5%, stabilizer 0.6%, synergist 0.5%, organic solvent 15%, are supplied with methyl oleate 100%.
3. the dispersible oil-suspending agent according to claim 1 or 2 containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, its feature exists In the eucalyptus oil is prepared according to following steps:
Crushed after folium eucalypti is dried in the shade, obtain folium eucalypti powder, folium eucalypti powder is added into alembic, then toward adding equivalent to folium eucalypti in alembic The cellulase of powder weight 1%, then adds water until submerging folium eucalypti powder, folium eucalypti powder is soaked after 5h in water, obtains extract solution;So Vapor is passed through from the bottom of alembic to heat extract solution, collect gas-phase product after extract solution boiling, collect 1h, obtain afterwards To mixed vapour;Mixed vapour is condensed by condenser, oil water mixture is obtained;Oil water mixture passes through water-oil separating Device is separated, and obtains folium eucalypti crude oil;Folium eucalypti crude oil is extracted by extractor, after layering, the upper strata separated as folium eucalypti Oil.
4. the dispersible oil-suspending agent according to claim 3 containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, it is characterised in that The emulsifying agent is AEO, phenethyl phenol polyethenoxy ether, calcium dodecyl benzene sulfonate, alkylaryl polyoxy One or more in propylene APEO.
5. the dispersible oil-suspending agent according to claim 4 containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, it is characterised in that The dispersant is fatty alcohol ethylene oxide adduct phosphate, lignin and its derivative sulfonate, aliphatic acid ethane addition One or more in thing phosphate, polyvinyl alcohol, 1-METHYLPYRROLIDONE, polyethylene glycol.
6. the dispersible oil-suspending agent according to claim 5 containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, it is characterised in that The stabilizer is one kind in organobentonite, cresyl glycidyl ether.
7. the dispersible oil-suspending agent according to claim 6 containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, it is characterised in that The synergist is one kind in ammonium sulfate, methyl Synergistic Phosphorus.
8. the dispersible oil-suspending agent according to claim 7 containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl, it is characterised in that The organic solvent is the one or more in dimethylbenzene, cyclohexanone, ethylene glycol, solvent naphtha.
CN201710157129.7A 2017-03-16 2017-03-16 A kind of dispersible oil-suspending agent containing the careless amine of fluorine ketone sulphur and cyhalofop-butyl Pending CN106973957A (en)

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CN107568252A (en) * 2017-10-11 2018-01-12 三江县稻香山茶油生态发展有限公司 A kind of herbicide in tea oil tree seedling seedbed and preparation method thereof
CN115399331A (en) * 2022-09-13 2022-11-29 浙江威昇作物科技有限公司 Ternary weeding composition and application thereof
CN115399331B (en) * 2022-09-13 2024-07-05 浙江威昇作物科技有限公司 Ternary weeding composition and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104186562A (en) * 2014-08-20 2014-12-10 杨凌农科大无公害农药研究服务中心 Biogenic synergistic compound herbicide containing n-nonanoic acid and preparation method thereof
CN105123707A (en) * 2015-09-06 2015-12-09 北京燕化永乐生物科技股份有限公司 Weeding composition
CN105176688A (en) * 2015-07-17 2015-12-23 王再青 Method for extracting eucalyptus oil

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104186562A (en) * 2014-08-20 2014-12-10 杨凌农科大无公害农药研究服务中心 Biogenic synergistic compound herbicide containing n-nonanoic acid and preparation method thereof
CN105176688A (en) * 2015-07-17 2015-12-23 王再青 Method for extracting eucalyptus oil
CN105123707A (en) * 2015-09-06 2015-12-09 北京燕化永乐生物科技股份有限公司 Weeding composition

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张兴: "《生物农药概览第二版》", 30 April 2011, 中国农业出版社 *
马幻香 等: "气象因素对除草剂施用的影响及施用技术", 《现代农业科技》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107568252A (en) * 2017-10-11 2018-01-12 三江县稻香山茶油生态发展有限公司 A kind of herbicide in tea oil tree seedling seedbed and preparation method thereof
CN115399331A (en) * 2022-09-13 2022-11-29 浙江威昇作物科技有限公司 Ternary weeding composition and application thereof
CN115399331B (en) * 2022-09-13 2024-07-05 浙江威昇作物科技有限公司 Ternary weeding composition and application thereof

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