CN106592257A - Silk cloth suitable for ink-jet printing output and manufacturing method of silk cloth - Google Patents

Silk cloth suitable for ink-jet printing output and manufacturing method of silk cloth Download PDF

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Publication number
CN106592257A
CN106592257A CN201611064693.6A CN201611064693A CN106592257A CN 106592257 A CN106592257 A CN 106592257A CN 201611064693 A CN201611064693 A CN 201611064693A CN 106592257 A CN106592257 A CN 106592257A
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China
Prior art keywords
silk
coating
ink
parts
inkjet printing
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Pending
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CN201611064693.6A
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Chinese (zh)
Inventor
陆建辉
王玉丰
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JIANGSU GEMEI HIGH-TECH DEVELOPMENT Co Ltd
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JIANGSU GEMEI HIGH-TECH DEVELOPMENT Co Ltd
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Priority to CN201611064693.6A priority Critical patent/CN106592257A/en
Publication of CN106592257A publication Critical patent/CN106592257A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/06—Animal fibres, e.g. hair, wool, silk

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The invention discloses silk cloth suitable for ink-jet printing output. The silk cloth comprises three layers of structures including a base material, a bottom coating and an ink absorption coating. The manufacturing method comprises steps as follows: a preparation process of a bottom coating liquid; a preparation process of ink absorption coating paint; a coating preparation process of the silk cloth. The coated silk cloth comprises three layers of structures including the base material, the bottom coating and the ink absorption coating, the base material is real silk cloth or imitated silk cloth, the bottom coating has a function of connecting the base material and the ink absorption coating, the binding firmness of the base material and the ink absorption coating is improved, the ink absorption coating has printing and developing functions, and high-quality image output is realized.

Description

A kind of silk of suitable inkjet printing output and preparation method thereof
Technical field
The invention belongs to new material technology field, application is digital ink-jet output medium field, and in particular to a kind of Silk of suitable inkjet printing output and preparation method thereof.
Background technology
Silk scroll calligraphy and painting art is one piece of rarity of China's culture and arts succession.With the ripe of large-scale inkjet technology and The production domesticization of new print media material makes that high art is popular to be achieved, and artistic pictures, high-end copy art product are come into Huge numbers of families.Silk scroll paintings cannot be realized replicating due to being difficult to find that suitable output medium, all the time using ink-jet output technology Make.
The content of the invention
Goal of the invention：The present invention provides a kind of silk of suitable inkjet printing output and preparation method thereof, with real silk silk Or Silk silk is base material, transparent underlayer and translucent ink-absorbed coated layer are coated by scratching coating process, retain silk surface While woven design, reaching can adopt inkjet technology to export the purpose of application.
Technical scheme：A kind of silk of suitable inkjet printing output, the silk is made up of three-decker：Base material, primary coat Coating and ink-absorbed coated layer；
Described primary coat coating by following component by weight：
Water 70-90 parts；
Defoamer 0.1-0.5 parts；
Pure-acrylic emulsion 10-18 parts；
Association thickener 1-5 parts；
Described ink-absorbed coated layer by following component by weight：
Nano aluminium oxide 18-25 parts；
Polyvinyl alcohol 1-5 parts；
Sour 0.5-2 parts；
Cosolvent 10-20 parts；
Defoamer 0.1-0.2 parts；
Water 20-60 parts.
As optimization：In the primary coat coating：The defoamer is polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxy second One kind in alkene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
As optimization：In the primary coat coating：The vitrification point of the pure-acrylic emulsion is -10 DEG C -0 DEG C.
As optimization：In the primary coat coating：The association thickener is non-ionic polyurethane association thickener.
As optimization：In the ink-absorbed coated layer：The initial particle of the nano aluminium oxide be less than 30 nanometers, crystal formation be α- Al2O3Or γ-Al2O3., preferably γ-Al2O3。
As optimization：In the ink-absorbed coated layer：The degree of polymerization >=2400 of the polyvinyl alcohol, the degree of polymerization is bigger, addition It is fewer, can indirectly increase the consumption of aluminum oxide, and then blotting rate of drying is improved, alcoholysis degree can be 88% and 99%, preferably 88% alcohol The polyvinyl alcohol of Xie Du.
As optimization：In the ink-absorbed coated layer：It is described sour for nitric acid, hydrochloric acid, one or two mixtures of sulfuric acid.
As optimization：In the ink-absorbed coated layer：The cosolvent be isopropanol, n-butanol, ethanol, dimethylformamide, One or more mixtures in diethyl monobutyl ether acetate.
As optimization：In the ink-absorbed coated layer：The defoamer be tributyl phosphate, silicone emulsion, high-carbon polyol fatty acid Ester complexes, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxy Propylene polyoxyethylene glycerol ether, dimethyl silicone polymer one or more mixtures.
A kind of preparation method of the silk of the suitable inkjet printing output described in basis, comprises the steps：
（1）The preparation technology of primary coat coating solution：
Defoamer, pure-acrylic emulsion are added to the water after disperseing 30-90 minutes at a high speed, stand 15-30 minute froth breakings, slowly stirred Thickener is added dropwise under conditions of mixing, final viscosity is controlled in 2500-3000 centipoises, stand-by；
（2）The preparation technology of ink-absorbed coated layer coating：
Polyvinyl alcohol is first dissolved into the aqueous solution of 7%-10% by metering under the conditions of 80-95 DEG C, it is stand-by；By acid, cosolvent, disappear Infusion and aluminum oxide are successively added in remaining water, at a high speed dispersion 20-60 minutes, to it translucent aqueous dispersions are become, The stand-by poly-vinyl alcohol solution of dissolving is subsequently adding, 10-30 minutes are slowly stirred, is filtered, froth breaking is stand-by；
（3）The coating preparation technology of silk：
Primary coat will be quantitatively prepared on needle plate type coating machine using the straight scraper of contact and be coated in silk surface, at 60-100 DEG C Under the conditions of heated-air drying, butt coating weight control recycles contact straight scraper coating blotting to apply at 3-8 gram/m, then Material, 90-140 DEG C of drying, face coating 2-3 time, butt coating weight control is at 15-25 gram/m.
Beneficial effect：Coating silk in the present invention is made up of three-decker：Base material, primary coat coating and ink-absorbed coated layer, base Material is real silk silk or Silk silk, and primary coat coating plays a part of to connect base material and ink-absorbed coated layer, improves its binding strength, Ink-absorbed coated layer plays printing coloration, realizes that image high-quality is exported.Each test event such as table 1 below of canvas of the present invention It is shown.
Table 1 each project testing table
。
Specific embodiment
With reference to specific embodiment, the present invention will be described in detail.
Specific embodiment one：
A kind of silk of suitable inkjet printing output, the silk is made up of three-decker：Base material, primary coat coating and blotting are applied Layer；
Described primary coat coating by following component by weight：
70 parts of water；
0.1 part of defoamer；
10 parts of pure-acrylic emulsion；
1 part of association thickener；
Described ink-absorbed coated layer by following component by weight：
18 parts of nano aluminium oxide；
1 part of polyvinyl alcohol；
0.5 part of acid；
10 parts of cosolvent；
0.1 part of defoamer；
20 parts of water.
In the primary coat coating：The defoamer is polyoxyethylene polyoxypropylene pentaerythrite ether.The pure-acrylic emulsion Vitrification point is -10 DEG C.The association thickener is non-ionic polyurethane association thickener.
In the ink-absorbed coated layer：The initial particle of the nano aluminium oxide is less than 30 nanometers, and crystal formation is α-Al2O3。
The degree of polymerization >=2400 of the polyvinyl alcohol, the degree of polymerization is bigger, and addition is fewer, can indirectly increase the use of aluminum oxide Amount, and then blotting rate of drying is improved, alcoholysis degree is 88%.The acid is nitric acid.The cosolvent is isopropanol.The froth breaking Agent is tributyl phosphate, silicone emulsion.
A kind of preparation method of the silk of the suitable inkjet printing output described in basis, comprises the steps：
（1）The preparation technology of primary coat coating solution：
Defoamer, pure-acrylic emulsion are added to the water after disperseing 30 minutes at a high speed, 15 minutes froth breakings are stood, in the bar being slowly stirred Thickener is added dropwise under part, final viscosity is controlled in 2500 centipoises, stand-by；
（2）The preparation technology of ink-absorbed coated layer coating：
Polyvinyl alcohol is first dissolved into 7% aqueous solution by metering under the conditions of 80 DEG C, it is stand-by；By acid, cosolvent, defoamer and Aluminum oxide is successively added in remaining water, and at a high speed dispersion 20 minutes, to it translucent aqueous dispersions are become, and are subsequently adding molten The stand-by poly-vinyl alcohol solution of solution, is slowly stirred 10 minutes, filters, and froth breaking is stand-by；
（3）The coating preparation technology of silk：
Primary coat will be quantitatively prepared on needle plate type coating machine using the straight scraper of contact and be coated in silk surface, in 60 DEG C of conditions Lower heated-air drying, butt coating weight control recycles the straight scraper of contact to coat blotting coating at 3 grams/m, then, 90 DEG C Drying, face coating 2 times, butt coating weight control is at 15 grams/m.
Specific embodiment two：
A kind of silk of suitable inkjet printing output, the silk is made up of three-decker：Base material, primary coat coating and blotting are applied Layer；
Described primary coat coating by following component by weight：
90 parts of water；
0.5 part of defoamer；
18 parts of pure-acrylic emulsion；
5 parts of association thickener；
Described ink-absorbed coated layer by following component by weight：
25 parts of nano aluminium oxide；
5 parts of polyvinyl alcohol；
2 parts of acid；
20 parts of cosolvent；
0.2 part of defoamer；
60 parts of water.
In the primary coat coating：The defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether.The vitrifying of the pure-acrylic emulsion Temperature is 0 DEG C.The association thickener is non-ionic polyurethane association thickener.
In the ink-absorbed coated layer：The initial particle of the nano aluminium oxide is less than 30 nanometers, and crystal formation is γ-Al2O3。
The degree of polymerization >=2400 of the polyvinyl alcohol, the degree of polymerization is bigger, and addition is fewer, can indirectly increase the use of aluminum oxide Amount, and then blotting rate of drying is improved, alcoholysis degree is 99%.The acid is hydrochloric acid.The cosolvent be n-butanol, ethanol.It is described Defoamer is the fatty acid ester compounded thing of higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether.
A kind of preparation method of the silk of the suitable inkjet printing output described in basis, comprises the steps：
（1）The preparation technology of primary coat coating solution：
Defoamer, pure-acrylic emulsion are added to the water after disperseing 90 minutes at a high speed, 30 minutes froth breakings are stood, in the bar being slowly stirred Thickener is added dropwise under part, final viscosity is controlled in 3000 centipoises, stand-by；
（2）The preparation technology of ink-absorbed coated layer coating：
Polyvinyl alcohol is first dissolved into 10% aqueous solution by metering under the conditions of 95 DEG C, it is stand-by；By acid, cosolvent, defoamer and Aluminum oxide is successively added in remaining water, and at a high speed dispersion 60 minutes, to it translucent aqueous dispersions are become, and are subsequently adding molten The stand-by poly-vinyl alcohol solution of solution, is slowly stirred 30 minutes, filters, and froth breaking is stand-by；
（3）The coating preparation technology of silk：
Primary coat will be quantitatively prepared on needle plate type coating machine using the straight scraper of contact and be coated in silk surface, in 100 DEG C of bars Heated-air drying under part, butt coating weight control recycles the straight scraper of contact to coat blotting coating at 8 grams/m, then, 140 DEG C of drying, face coating 3 times, butt coating weight control is at 25 grams/m.
Specific embodiment three：
A kind of silk of suitable inkjet printing output, the silk is made up of three-decker：Base material, primary coat coating and blotting are applied Layer；
Described primary coat coating by following component by weight：
80 parts of water；
0.3 part of defoamer；
14 parts of pure-acrylic emulsion；
3 parts of association thickener；
Described ink-absorbed coated layer by following component by weight：
22 parts of nano aluminium oxide；
3 parts of polyvinyl alcohol；
1 part of acid；
16 parts of cosolvent；
0.16 part of defoamer；
40 parts of water.
In the primary coat coating：The defoamer is polypropylene glycerol aether.The vitrification point of the pure-acrylic emulsion for- 6℃.The association thickener is non-ionic polyurethane association thickener.
In the ink-absorbed coated layer：The initial particle of the nano aluminium oxide is less than 30 nanometers, and crystal formation is γ-Al2O3。
The degree of polymerization >=2400 of the polyvinyl alcohol, the degree of polymerization is bigger, and addition is fewer, can indirectly increase the use of aluminum oxide Amount, and then blotting rate of drying is improved, alcoholysis degree can be 88% and 99%.The acid is sulfuric acid.The cosolvent is dimethyl methyl Acid amides, diethyl monobutyl ether acetate.The defoamer be polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, poly- two Methylsiloxane.
A kind of preparation method of the silk of the suitable inkjet printing output described in basis, comprises the steps：
（1）The preparation technology of primary coat coating solution：
Defoamer, pure-acrylic emulsion are added to the water after disperseing 60 minutes at a high speed, 22 minutes froth breakings are stood, in the bar being slowly stirred Thickener is added dropwise under part, final viscosity is controlled in 2800 centipoises, stand-by；
（2）The preparation technology of ink-absorbed coated layer coating：
Polyvinyl alcohol is first dissolved into 8% aqueous solution by metering under the conditions of 92 DEG C, it is stand-by；By acid, cosolvent, defoamer and Aluminum oxide is successively added in remaining water, and at a high speed dispersion 40 minutes, to it translucent aqueous dispersions are become, and are subsequently adding molten The stand-by poly-vinyl alcohol solution of solution, is slowly stirred 20 minutes, filters, and froth breaking is stand-by；
（3）The coating preparation technology of silk：
Primary coat will be quantitatively prepared on needle plate type coating machine using the straight scraper of contact and be coated in silk surface, in 80 DEG C of conditions Lower heated-air drying, butt coating weight control recycles the straight scraper of contact to coat blotting coating at 6 grams/m, then, and 120 DEG C drying, face apply coating 2 times, butt coating weight control is at 21 grams/m.
Coating silk in the present invention is made up of three-decker：Base material, primary coat coating and ink-absorbed coated layer, base material is real silk thin,tough silk Cloth or Silk silk, primary coat coating plays a part of to connect base material and ink-absorbed coated layer, improves its binding strength, and ink-absorbed coated layer rises To coloration is printed, realize that image high-quality is exported.
The present invention is not limited to above-mentioned preferred forms, and anyone can show that other are various under the enlightenment of the present invention The product of form, however, make any change in its shape or structure, it is every with skill identical or similar to the present application Art scheme, is within the scope of the present invention.

Claims (10)

1. the silk that a kind of suitable inkjet printing is exported, it is characterised in that：The silk is made up of three-decker：Base material, primary coat Coating and ink-absorbed coated layer；
Described primary coat coating by following component by weight：
Water 70-90 parts；
Defoamer 0.1-0.5 parts；
Pure-acrylic emulsion 10-18 parts；
Association thickener 1-5 parts；
Described ink-absorbed coated layer by following component by weight：
Nano aluminium oxide 18-25 parts；
Polyvinyl alcohol 1-5 parts；
Sour 0.5-2 parts；
Cosolvent 10-20 parts；
Defoamer 0.1-0.2 parts；
Water 20-60 parts.
2. the silk that suitable inkjet printing according to claim 1 is exported, it is characterised in that：In the primary coat coating：Institute Defoamer is stated in polyoxyethylene polyoxypropylene pentaerythrite ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether It is a kind of.
3. the silk that suitable inkjet printing according to claim 1 is exported, it is characterised in that：In the primary coat coating：Institute The vitrification point for stating pure-acrylic emulsion is -10 DEG C -0 DEG C.
4. the silk that suitable inkjet printing according to claim 1 is exported, it is characterised in that：In the primary coat coating：Institute Association thickener is stated for non-ionic polyurethane association thickener.
5. the silk that suitable inkjet printing according to claim 1 is exported, it is characterised in that：In the ink-absorbed coated layer：Institute The initial particle of nano aluminium oxide is stated less than 30 nanometers, crystal formation is α-Al2O3Or γ-Al2O3., preferably γ-Al2O3。
6. the silk that suitable inkjet printing according to claim 1 is exported, it is characterised in that：In the ink-absorbed coated layer：Institute The degree of polymerization >=2400 of polyvinyl alcohol are stated, the degree of polymerization is bigger, and addition is fewer, can indirectly increase the consumption of aluminum oxide, Jin Erti High blotting rate of drying, alcoholysis degree can be 88% and 99%, preferably the polyvinyl alcohol of 88% alcoholysis degree.
7. the silk that suitable inkjet printing according to claim 1 is exported, it is characterised in that：In the ink-absorbed coated layer：Institute Acid is stated for nitric acid, hydrochloric acid, one or two mixtures of sulfuric acid.
8. the silk that suitable inkjet printing according to claim 1 is exported, it is characterised in that：In the ink-absorbed coated layer：Institute Cosolvent is stated for isopropanol, n-butanol, ethanol, dimethylformamide, one or more mixing in diethyl monobutyl ether acetate Thing.
9. the silk that suitable inkjet printing according to claim 1 is exported, it is characterised in that：In the ink-absorbed coated layer：Institute Defoamer is stated for tributyl phosphate, the fatty acid ester compounded thing of silicone emulsion, higher alcohols, polyoxyethylene polyoxypropylene pentaerythrite Ether, polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether and polyoxyethylene polyoxypropylene glycerin ether, dimethyl silicone polymer One or more mixtures.
10. a kind of preparation method of the silk of suitable inkjet printing output according to claim 1, it is characterised in that：Bag Include following steps：
（1）The preparation technology of primary coat coating solution：
Defoamer, pure-acrylic emulsion are added to the water after disperseing 30-90 minutes at a high speed, stand 15-30 minute froth breakings, slowly stirred Thickener is added dropwise under conditions of mixing, final viscosity is controlled in 2500-3000 centipoises, stand-by；
（2）The preparation technology of ink-absorbed coated layer coating：
Polyvinyl alcohol is first dissolved into the aqueous solution of 7%-10% by metering under the conditions of 80-95 DEG C, it is stand-by；By acid, cosolvent, disappear Infusion and aluminum oxide are successively added in remaining water, at a high speed dispersion 20-60 minutes, to it translucent aqueous dispersions are become, The stand-by poly-vinyl alcohol solution of dissolving is subsequently adding, 10-30 minutes are slowly stirred, is filtered, froth breaking is stand-by；
（3）The coating preparation technology of silk：
Primary coat will be quantitatively prepared on needle plate type coating machine using the straight scraper of contact and be coated in silk surface, at 60-100 DEG C Under the conditions of heated-air drying, butt coating weight control recycles contact straight scraper coating blotting to apply at 3-8 gram/m, then Material, 90-140 DEG C of drying, face coating 2-3 time, butt coating weight control is at 15-25 gram/m.
CN201611064693.6A 2016-11-28 2016-11-28 Silk cloth suitable for ink-jet printing output and manufacturing method of silk cloth Pending CN106592257A (en)

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