CN104527255A - Ink-jet printing transfer-printing paper for silk and preparation method of ink-jet printing transfer-printing paper for silk - Google Patents

Ink-jet printing transfer-printing paper for silk and preparation method of ink-jet printing transfer-printing paper for silk Download PDF

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Publication number
CN104527255A
CN104527255A CN201510034372.0A CN201510034372A CN104527255A CN 104527255 A CN104527255 A CN 104527255A CN 201510034372 A CN201510034372 A CN 201510034372A CN 104527255 A CN104527255 A CN 104527255A
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China
Prior art keywords
transfer
silk
printing
paper
layer
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CN201510034372.0A
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Chinese (zh)
Inventor
夏艳
单昶
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TRANSFLUID NEW MATERIALS (SUZHOU) Co Ltd
TRANSFLUID NEW MATERIALS SUZHOU CO Ltd
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TRANSFLUID NEW MATERIALS (SUZHOU) Co Ltd
TRANSFLUID NEW MATERIALS SUZHOU CO Ltd
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Priority to CN201510034372.0A priority Critical patent/CN104527255A/en
Publication of CN104527255A publication Critical patent/CN104527255A/en
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Abstract

The invention discloses ink-jet printing transfer-printing paper for silk and a preparation method of the ink-jet printing transfer-printing paper for the silk. The transfer-printing paper comprises base paper, a blocking layer and a transfer-printing layer which are superimposed from bottom to top, wherein the blocking layer can be coated by the base paper by using a coating machine and is used for blocking ink in the transfer-printing layer from permeating towards the paper-fiber direction; the transfer-printing layer is an ink accepting layer and enables the silk to be bonded together. The ink-jet printing transfer-printing paper disclosed by the invention has the advantages that printing is carried out on silk fabrics, and fabrics do not need to be pretreated, so that the use is convenient; simultaneously, a product with the print transferring is rich in style, vivid in pattern and bright in color, and the original texture of the silks is maintained still.

Description

A kind of inkjet printing transfer paper for silk and preparation method thereof
Technical field
The invention belongs to printing technology field, particularly a kind of inkjet printing transfer paper for silk and preparation method thereof.
Background technology
Silk is a kind of high-end product, and the requirement for silk printrng is higher, and traditional printing and dyeing cannot be printed and dyed out exquisite pattern.Straight spray printing dye and transfer printing and dyeing two kinds of Digital Dyeing techniques of having occurred at present, exquisite pattern of can printing and dyeing out on silk.On silk during straight spray printing dye, need silk fabrics to carry out pre-treatment starching, if starching is uneven will produce substandard products, scrappage is higher.Transfer printing and dyeing comprise cold transfer printing and hot transfer printing, as the cold-transfer printing mentioned in Chinese patent 200710040431.0 need fabric is moistening after transfer printing again, but due to fabric moistening time humidity be difficult to control, there is the phenomenon of border bleeding sometimes, occur the phenomenon of uneven color sometimes; As heat transfer printing paper in Chinese patent 201210017739.4, owing to adding catalyst alkali, can turn to be yellow after silk transfer, this transfer paper also adds coating agent as polyamide, polyethylene, polyurethane etc. in addition, this kind of material can penetrate into silk inside when hot transfer printing, can do not wash out completely, the feel of silk can be changed.
Summary of the invention
The object of this invention is to provide a kind of inkjet printing transfer paper for silk, cannot to print and dye out the problem of exquisite pattern to solve the traditional printing and dyeing existed in prior art.
For achieving the above object, the present invention is by the following technical solutions:
For an inkjet printing transfer paper for silk, this transfer paper is made up of the base paper superposed successively from top to bottom, barrier layer and transfer printing layer.
Preferably, the hygroscopicity value of described base paper is 20 ~ 150g/m 2.
Preferably, described barrier layer is water-soluble resin.
Preferably, described water-soluble resin is butadiene-styrene latex, ethylene-vinyl acetate copolymer, any one or a few mixture mixed with arbitrary proportion of polyurethane.
Preferably, the coating weight dry weight on described barrier layer is 1 ~ 30g/m 2.
Preferably, described transfer printing layer is divided into two classes, and Class A transfer printing layer comprises ink absorber, dry filler, and Class B transfer printing layer comprises ink absorber, reaction promoter, dry filler.
Preferably, described Class A transfer printing layer is applicable to active ink transfer printing silk, and its raw materials by weight comprises following component:
Carboxymethyl cellulose 2 ~ 20%
Hydrophobic starch 5 ~ 30%
Bleeding agent 1 ~ 10%
Surplus is water.
Preferably, described Class B transfer printing layer is applicable to acid ink transfer printing silk, and its raw materials by weight comprises following component:
Modified starch 10 ~ 50%
Polyacrylic acid 10 ~ 50%
Citric acid 1 ~ 10%
Hydrophobic starch 1 ~ 10%
Bleeding agent 1 ~ 10%
SiO 22~8%
Surplus is water.
Present invention also offers a kind of preparation method of the inkjet printing transfer paper for silk, its technical scheme is as follows:
For a preparation method for the inkjet printing transfer paper of silk, adopt the mode of film transfer to be coated with one deck barrier layer on base paper, after the drying of barrier layer, cover base paper surface; Be coated with one deck transfer printing layer over the barrier layer again.
Another object of the present invention is to provide a kind of transfer printing layer of the inkjet printing transfer paper for silk, and it can adopt following two kinds of technical schemes:
For a transfer printing layer for the inkjet printing transfer paper of silk, its raw materials by weight comprises following component:
Carboxymethyl cellulose 2 ~ 20%
Hydrophobic starch 5 ~ 30%
Bleeding agent 1 ~ 10%
Surplus is water.
For a transfer printing layer for the inkjet printing transfer paper of silk, its raw materials by weight comprises following component:
Modified starch 10 ~ 50%
Polyacrylic acid 10 ~ 50%
Citric acid 1 ~ 10%
Hydrophobic starch 1 ~ 10%
Bleeding agent 1 ~ 10%
SiO 22~8%
Surplus is water.
Above-mentioned two kinds of transfer printing layers can be applicable to printing ink and print.
Silk inkjet printing transfer paper described in patent of the present invention has many good qualities: this transfer paper can the clear pattern of inkjet printing, and transfer printing layer is applicable to active ink and acid ink carrys out transfer printing silk; This transfer paper has one deck barrier layer that ink can be stoped toward the infiltration of paper machine direction when gas steams, and improve ink offset rate and ink and silk are fully reacted, transfer printing is bright-colored.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention;
Wherein, 1 is base paper, and 2 is barrier layer, and 3 is transfer printing layer.
Detailed description of the invention
The technological means realized for making the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with detailed description of the invention, setting forth the present invention further.
For an inkjet printing transfer paper for silk, this transfer paper is made up of the base paper 1 superposed successively from top to bottom, barrier layer 2 and transfer printing layer 3.
The hygroscopicity value of base paper 1 is 20 ~ 150g/m 2.
Barrier layer 2 is water-soluble resin.
Water-soluble resin is butadiene-styrene latex, ethylene-vinyl acetate copolymer, any one or a few mixture mixed with arbitrary proportion of polyurethane.
The coating weight dry weight on barrier layer is 1 ~ 30g/m 2.
Transfer printing layer is divided into two classes, and Class A transfer printing layer comprises ink absorber, dry filler, and Class B transfer printing layer comprises ink absorber, reaction promoter, dry filler.
Class A transfer printing layer is applicable to active ink transfer printing silk, and its raw materials by weight comprises following component:
Carboxymethyl cellulose 2 ~ 20%
Hydrophobic starch 5 ~ 30%
Bleeding agent 1 ~ 10%
Surplus is water.
Class B transfer printing layer is applicable to acid ink transfer printing silk, and its raw materials by weight comprises following component:
Modified starch 10 ~ 50%
Polyacrylic acid 10 ~ 50%
Citric acid 1 ~ 10%
Hydrophobic starch 1 ~ 10%
Bleeding agent 1 ~ 10%
SiO 22~8%
Surplus is water.
Below in conjunction with specific embodiment, the present invention will be further described.
embodiment 1
Base paper 3 be quantitatively 90g/m 2, hygroscopicity value is 100g/m 2, adopt the mode of film transfer to be coated with one deck barrier layer on base paper, barrier layer selects solid content to be the butadiene-styrene latex of 50%, and cover base paper surface after drying, dry-coated amount is about 1g/m 2; Be coated with one deck transfer printing layer over the barrier layer again, this transfer printing layer is applicable to active ink transfer printing silk, and transfer printing layer formula is by weight percentage:
Carboxymethyl cellulose 2%
Hydrophobic starch 15%
Bleeding agent 5%
Surplus is water.
embodiment 2
Base paper 3 be quantitatively 80g/m 2, hygroscopicity value is 150g/m 2, adopt the mode of film transfer to be coated with one deck barrier layer on base paper, barrier layer selects solid content to be the polyurethane of 25%, and cover base paper surface after drying, dry-coated amount is about 5g/m 2; Be coated with one deck transfer printing layer over the barrier layer again, this transfer printing layer is applicable to active ink transfer printing silk, and transfer printing layer formula is by weight percentage:
Carboxymethyl cellulose 20%
Hydrophobic starch 5%
Bleeding agent 1%
Surplus is water.
embodiment 3
Base paper 3 be quantitatively 70g/m 2, hygroscopicity value is 20g/m 2, adopt the mode of film transfer to be coated with one deck barrier layer on base paper, barrier layer selects solid content to be the ethylene-vinyl acetate copolymer of 40%, and cover base paper surface after drying, dry-coated amount is about 10g/m 2; Be coated with one deck transfer printing layer over the barrier layer again, this transfer printing layer is applicable to active ink transfer printing silk, and transfer printing layer formula is by weight percentage:
Carboxymethyl cellulose 20%
Hydrophobic starch 5%
Bleeding agent 10%
Surplus is water.
embodiment 4
Base paper 3 be quantitatively 70g/m 2, hygroscopicity value is 20g/m 2, adopt the mode of film transfer to be coated with one deck barrier layer on base paper, barrier layer selects solid content to be the butadiene-styrene latex of 50%, and cover base paper surface after drying, dry-coated amount is about 10g/m 2; Be coated with one deck transfer printing layer over the barrier layer again, this transfer printing layer is applicable to acid ink transfer printing silk, and transfer printing layer formula is by weight percentage:
Modified starch 50%
Polyacrylic acid 10%
Citric acid 10%
Hydrophobic starch 5%
Bleeding agent 1%
SiO 24%。
Surplus is water.
embodiment 5
Base paper 3 be quantitatively 80g/m 2, hygroscopicity value is 150g/m 2, adopt the mode of film transfer to be coated with one deck barrier layer on base paper, barrier layer selects solid content to be the polyurethane of 25%, and cover base paper surface after drying, dry-coated amount is about 10g/m 2; Be coated with one deck transfer printing layer over the barrier layer again, this transfer printing layer is applicable to acid ink transfer printing silk, and transfer printing layer formula is by weight percentage:
Modified starch 10%
Polyacrylic acid 50%
Citric acid 1%
Hydrophobic starch 10%
Bleeding agent 10%
SiO 22%。
Surplus is water.
embodiment 6
Base paper 3 be quantitatively 90g/m 2, hygroscopicity value is 90g/m 2, adopt the mode of film transfer to be coated with one deck barrier layer on base paper, barrier layer selects solid content to be the ethylene-vinyl acetate copolymer of 40%, and cover base paper surface after drying, dry-coated amount is about 5g/m 2; Be coated with one deck transfer printing layer over the barrier layer again, this transfer printing layer is applicable to acid ink transfer printing silk, and transfer printing layer formula is by weight percentage:
Modified starch 25%
Polyacrylic acid 30%
Citric acid 5%
Hydrophobic starch 1%
Bleeding agent 5%
SiO 28%。
Surplus is water.
More than show and describe general principle of the present invention and principal character and advantage of the present invention.The technical staff of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and description just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.

Claims (10)

1. for an inkjet printing transfer paper for silk, it is characterized in that: this transfer paper is made up of the base paper superposed successively from top to bottom, barrier layer and transfer printing layer.
2., as claimed in claim 1 for the inkjet printing transfer paper of silk, it is characterized in that: the hygroscopicity value of described base paper is 20 ~ 150g/m 2; The coating weight dry weight on described barrier layer is 1 ~ 30g/m 2.
3., as claimed in claim 1 for the inkjet printing transfer paper of silk, it is characterized in that: described barrier layer is water-soluble resin.
4. as claimed in claim 3 for the inkjet printing transfer paper of silk, it is characterized in that: described water-soluble resin is butadiene-styrene latex, ethylene-vinyl acetate copolymer, any one or a few mixture mixed with arbitrary proportion of polyurethane.
5. as claimed in claim 1 for the inkjet printing transfer paper of silk, it is characterized in that: described transfer printing layer is divided into two classes, the raw material of Class A transfer printing layer comprises ink absorber, dry filler, and the raw material of Class B transfer printing layer comprises ink absorber, reaction promoter, dry filler.
6., as claimed in claim 5 for the inkjet printing transfer paper of silk, it is characterized in that: described Class A transfer printing layer is applicable to active ink transfer printing silk, and its raw materials by weight comprises following component:
Carboxymethyl cellulose 2 ~ 20%
Hydrophobic starch 5 ~ 30%
Bleeding agent 1 ~ 10%
Surplus is water.
7., as claimed in claim 5 for the inkjet printing transfer paper of silk, it is characterized in that: described Class B transfer printing layer is applicable to acid ink transfer printing silk, and its raw materials by weight comprises following component:
Modified starch 10 ~ 50%
Polyacrylic acid 10 ~ 50%
Citric acid 1 ~ 10%
Hydrophobic starch 1 ~ 10%
Bleeding agent 1 ~ 10%
SiO 22~8%
Surplus is water.
8. for a preparation method for the inkjet printing transfer paper of silk, it is characterized in that: adopt the mode of film transfer to be coated with one deck barrier layer on base paper, after the drying of barrier layer, cover base paper surface; Be coated with one deck transfer printing layer over the barrier layer again.
9. for a transfer printing layer for the inkjet printing transfer paper of silk, it is characterized in that: its raw materials by weight comprises following component:
Carboxymethyl cellulose 2 ~ 20%
Hydrophobic starch 5 ~ 30%
Bleeding agent 1 ~ 10%
Surplus is water.
10. for a transfer printing layer for the inkjet printing transfer paper of silk, it is characterized in that: its raw materials by weight comprises following component:
Modified starch 10 ~ 50%
Polyacrylic acid 10 ~ 50%
Citric acid 1 ~ 10%
Hydrophobic starch 1 ~ 10%
Bleeding agent 1 ~ 10%
SiO 22~8%
Surplus is water.
CN201510034372.0A 2015-01-23 2015-01-23 Ink-jet printing transfer-printing paper for silk and preparation method of ink-jet printing transfer-printing paper for silk Pending CN104527255A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106592257A (en) * 2016-11-28 2017-04-26 江苏格美高科技发展有限公司 Silk cloth suitable for ink-jet printing output and manufacturing method of silk cloth
CN107264103A (en) * 2016-04-08 2017-10-20 全斯福新材料(苏州)有限公司 The method of fabric double-side transfer printed
CN107476128A (en) * 2017-07-17 2017-12-15 山东华泰纸业股份有限公司 A kind of production technology of environment-friendly digital transfer paper
CN107663398A (en) * 2016-07-29 2018-02-06 华南理工大学 A kind of bio-based quick-drying thermal dye sublimation transfer printing paper and preparation method thereof and coating composition and its fine holes coating for cooperateing with structure
CN110341337A (en) * 2019-08-14 2019-10-18 苏州市清华技术研究所 A kind of layer structure and ink-jet hollow out printing method for textile ink-jet hollow out stamp
CN110857541A (en) * 2018-08-22 2020-03-03 全斯福新材料(苏州)有限公司 Low-expansion-ratio flat transfer paper

Citations (6)

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Publication number Priority date Publication date Assignee Title
WO1997042040A1 (en) * 1996-05-04 1997-11-13 Tullis Russell Brittains Decalcomania Papers Limited Decalcomania
CN1315906A (en) * 1998-07-29 2001-10-03 W·A·桑德斯造纸科尔登霍夫有限公司 Transfer paper for ink-jet printing
JP2004114670A (en) * 2002-09-27 2004-04-15 Sanryu:Kk Sublimation transfer film for ink jet
US20060088674A1 (en) * 2004-10-27 2006-04-27 Hladik Molly L Ultraviolet curable barrier layers
CN201358402Y (en) * 2009-02-10 2009-12-09 祥和彩瓷制造(上海)有限公司 Transfer paper suitable for silk transfer
CN201411595Y (en) * 2008-11-26 2010-02-24 单昶 Transfer paper for natural fibre fabric

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997042040A1 (en) * 1996-05-04 1997-11-13 Tullis Russell Brittains Decalcomania Papers Limited Decalcomania
CN1315906A (en) * 1998-07-29 2001-10-03 W·A·桑德斯造纸科尔登霍夫有限公司 Transfer paper for ink-jet printing
JP2004114670A (en) * 2002-09-27 2004-04-15 Sanryu:Kk Sublimation transfer film for ink jet
US20060088674A1 (en) * 2004-10-27 2006-04-27 Hladik Molly L Ultraviolet curable barrier layers
CN201411595Y (en) * 2008-11-26 2010-02-24 单昶 Transfer paper for natural fibre fabric
CN201358402Y (en) * 2009-02-10 2009-12-09 祥和彩瓷制造(上海)有限公司 Transfer paper suitable for silk transfer

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107264103A (en) * 2016-04-08 2017-10-20 全斯福新材料(苏州)有限公司 The method of fabric double-side transfer printed
CN107663398A (en) * 2016-07-29 2018-02-06 华南理工大学 A kind of bio-based quick-drying thermal dye sublimation transfer printing paper and preparation method thereof and coating composition and its fine holes coating for cooperateing with structure
CN106592257A (en) * 2016-11-28 2017-04-26 江苏格美高科技发展有限公司 Silk cloth suitable for ink-jet printing output and manufacturing method of silk cloth
CN107476128A (en) * 2017-07-17 2017-12-15 山东华泰纸业股份有限公司 A kind of production technology of environment-friendly digital transfer paper
CN110857541A (en) * 2018-08-22 2020-03-03 全斯福新材料(苏州)有限公司 Low-expansion-ratio flat transfer paper
CN110341337A (en) * 2019-08-14 2019-10-18 苏州市清华技术研究所 A kind of layer structure and ink-jet hollow out printing method for textile ink-jet hollow out stamp
CN110341337B (en) * 2019-08-14 2022-07-05 苏州市清华技术研究所 Layer structure for fabric ink-jet hollow printing and ink-jet hollow printing method

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