JP3192847U - Structure of thermal transfer recording sheet - Google Patents

Structure of thermal transfer recording sheet Download PDF

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JP3192847U
JP3192847U JP2014003312U JP2014003312U JP3192847U JP 3192847 U JP3192847 U JP 3192847U JP 2014003312 U JP2014003312 U JP 2014003312U JP 2014003312 U JP2014003312 U JP 2014003312U JP 3192847 U JP3192847 U JP 3192847U
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thermal transfer
recording sheet
coating layer
transfer recording
ink
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▲しょう▼銘杉
陳栄坤
黄孟新
周純暉
張▲ちょう▼偉
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Cheng Loong Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0355Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the macromolecular coating or impregnation used to obtain dye receptive properties

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  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Coloring (AREA)
  • Decoration By Transfer Pictures (AREA)

Abstract

【課題】基材が感熱転写インクを過度に吸収するのを防止し、優れた彩度及びグラデーションが得られる感熱転写記録シートの構造を提供する。【解決手段】感熱転写記録シートは、基材120、及び基材に設置される浸透用孔142を有する塗布層140を備える。塗布層は無機顔料、澱粉誘導体、ケイ素化合物、セルロース誘導体、及び高分子樹脂の混合構成の塗布溶液を含む。溶液が塗布されて乾燥した後、塗布層の無機顔料間の顆粒の隙間に浸透用孔が形成される。浸透用孔により塗布層及び基材に浸透される感熱転写インク160の一部が制限され、インクの付着力が増強される。また、インクの乾燥速度を維持させつつ、転写されるインクが不足する事態を回避する。【選択図】図3PROBLEM TO BE SOLVED: To provide a structure of a thermal transfer recording sheet which prevents a base material from excessively absorbing a thermal transfer ink and can obtain excellent saturation and gradation. A thermal transfer recording sheet includes a base material 120 and a coating layer 140 having permeation holes 142 installed in the base material. The coating layer contains a coating solution having a mixed composition of an inorganic pigment, a starch derivative, a silicon compound, a cellulose derivative, and a polymer resin. After the solution is applied and dried, permeation pores are formed in the gaps between the granules between the inorganic pigments in the coating layer. The permeation holes limit a part of the heat-sensitive transfer ink 160 that permeates the coating layer and the base material, and the adhesive force of the ink is enhanced. In addition, while maintaining the drying speed of the ink, it is possible to avoid a situation in which the ink to be transferred is insufficient. [Selection diagram] Fig. 3

Description

本考案は、感熱転写インクが設置される感熱転写記録シートの構造に関する。   The present invention relates to the structure of a thermal transfer recording sheet on which thermal transfer ink is installed.

従来の紡織品にパターンを設置する方法としては、網版印刷(Halftone)、染色仕上加工(dyeing and finishing)、及び噴霧塗装(spray)等の技術が常用される。   As a conventional method for setting a pattern on a textile product, techniques such as halftone printing, dyeing and finishing, and spray coating are commonly used.

しかしながら、前述した従来の印刷技術では、網版印刷の方法は先ず製版が行われるが、印刷速度が遅く、色彩ではハーフトーンの表現が劣っており、紡織品のパターンが硬くなり、水洗いするとすぐに脱色した。染色仕上加工の場合、大量の染色の注文に対しては適しているが、単一色でしか染色できないため、近年商品が個性化を強めるなか、少量で多様な製品を効率良く製造することが求められ、染色仕上加工は停滞を続けている。このほか、噴霧塗装には製版は必要ないが、先に基材の表面の塗布層に処理を施し、パターンを基材に噴霧塗装せねばならず、作業工程が煩雑で器材及び製造コストも高い。   However, in the conventional printing technique described above, the halftone printing method is first performed by plate making, but the printing speed is slow, the halftone expression is poor in color, the textile pattern becomes hard, and immediately after washing with water. Decolorized. Dye finish processing is suitable for orders for large quantities of dyeing, but can only be dyed with a single color, so in recent years, as products have become more individualized, it has been required to efficiently produce a variety of products in small quantities. As a result, dyeing finishing has been stagnant. In addition, plate making is not necessary for spray coating, but the coating layer on the surface of the base material must first be processed and the pattern must be spray-coated on the base material. The work process is complicated and equipment and manufacturing costs are high. .

また、業界では上述の工法の欠点を改善させ、基材(衣類)本来の柔軟度を維持し、パターンの色彩のグラデーション表現を増加させ、パターンの脱色を防ぐため、感熱転写技術が提案された。従来の感熱転写では感熱特性を有する染料(インク)を摂氏200度まで加熱させ、染料(インク)を固体から気体へと変化させる。気化した染料(インク)を基材或いは転写物の繊維中に浸透させ、温度が低下すると染料(インク)は元の固体に戻り、パターンが形成される。   In the industry, thermal transfer technology was proposed to improve the above-mentioned disadvantages of the construction method, maintain the original flexibility of the base material (clothing), increase the gradation expression of the color of the pattern, and prevent the pattern from decoloring. . In the conventional thermal transfer, a dye (ink) having thermal characteristics is heated to 200 degrees Celsius to change the dye (ink) from solid to gas. When the vaporized dye (ink) penetrates into the substrate or the fiber of the transferred material and the temperature is lowered, the dye (ink) returns to the original solid and a pattern is formed.

さらに、感熱転写の染料(インク)は繊維に浸透し、粘着感が無く、生地の通気性に優れる等の長所を有し、洗濯に強く脱色しにくく、色彩が落ちにくく、彩度及び鮮やかさが有効的に保持され、更にグラデーションや陰影等のディテールを表現させる。感熱転写技術は衣類の基材のパターンの印刷に普遍的に応用される。   In addition, thermal transfer dyes (inks) have the advantages of penetrating into the fibers, no stickiness, and excellent breathability of the fabric, being strong against washing, hard to decolorize, difficult to lose color, saturation and vividness Is effectively retained, and details such as gradation and shadow are expressed. Thermal transfer technology is universally applied to printing patterns on clothing substrates.

感熱転写技術の実施方式は、図4及び図5に示すように、即ち、器具により直接出力される以外、感熱転写インク922は予め設計されたパターン920が基材940に設置されるのが広く普及し、低価格で使用者に多様な個性化の選択肢を更に与え、DIYの趣向性もあり、メーカーも少量で多様な製品を高速に製造できる。然しながら、感熱転写インク922が基材940に設置されると、基材940に過度に吸収されやすく、使用者が基材940のパターン920を基材(図示せず)に転写する場合、感熱転写インク922が過度に吸収されているため、転写される感熱転写インク922が不足し、パターン920の色合いが予期した通りにならなかった。   As shown in FIGS. 4 and 5, the thermal transfer technology is implemented in a manner that a thermal transfer ink 922 is provided with a pre-designed pattern 920 on a substrate 940 except that it is directly output by an instrument. It is widespread, provides users with various options for personalization at a low price, has a DIY preference, and allows manufacturers to manufacture a wide variety of products at low speeds. However, when the thermal transfer ink 922 is installed on the base material 940, it is easily absorbed by the base material 940, and when the user transfers the pattern 920 of the base material 940 to the base material (not shown), the thermal transfer is performed. Since the ink 922 was excessively absorbed, the thermal transfer ink 922 transferred was insufficient, and the color of the pattern 920 did not become as expected.

そこで、本考案者は上記の欠点が改善可能と考えられ、鋭意検討を重ねた結果、合理的設計で上記の課題を効果的に改善する本考案の感熱転写記録シートの構造の提案に到った。   Therefore, the present inventor is considered to be able to improve the above-mentioned drawbacks, and as a result of intensive studies, the inventors have arrived at the proposal of the structure of the thermal transfer recording sheet of the present invention that effectively improves the above-mentioned problems by rational design. It was.

本考案は、このような従来の問題に鑑みてなされたものである。本考案の主な目的は、上述の問題を解決するために、感熱転写記録シートの構造を提供することにある。つまり、感熱転写インクが基材に設置される際に、基材が感熱転写インクを過度に吸収するのを防止し、感熱転写インクの転写時に感熱転写インクが不足して彩度及びグラデーションが優れない等の欠点を改善する。   The present invention has been made in view of such conventional problems. The main object of the present invention is to provide a structure of a thermal transfer recording sheet in order to solve the above-mentioned problems. That is, when the thermal transfer ink is installed on the substrate, it prevents the substrate from excessively absorbing the thermal transfer ink, and when transferring the thermal transfer ink, the thermal transfer ink is insufficient and the saturation and gradation are excellent. Improve the shortcomings such as not.

上述した課題を解決し、目的を達成するために、本考案に係る感熱転写記録シートの構造は、基材と、前記基材に設置されると共に複数の浸透用孔を有する塗布層を備えることを特徴とする。   In order to solve the above-described problems and achieve the object, the structure of the thermal transfer recording sheet according to the present invention includes a base material and a coating layer that is installed on the base material and has a plurality of penetration holes. It is characterized by.

換言すれば、上述の構造の構成により、感熱転写インクの担体とすると、浸透用孔により塗布層及び基材に浸透される感熱転写インクの一部が制限され、感熱転写インクの付着力が強化され、感熱転写インクの乾燥速度を維持しつつ、従来の感熱転写インクでは基材に直接設置される際に、基材に過度に吸収され、転写時に感熱転写インクが不足し、転写される完成品の色彩の濃淡が不足する等の欠点を解決する。   In other words, due to the configuration of the above structure, when the thermal transfer ink carrier is used, a part of the thermal transfer ink that permeates the coating layer and the substrate is limited by the permeation holes, and the adhesion of the thermal transfer ink is enhanced. In the conventional thermal transfer ink, the thermal transfer ink is excessively absorbed by the base material when it is directly installed on the base material while the thermal transfer ink is dried. To solve the disadvantages such as lack of color shade of the product.

本考案によれば、従来の技術では感熱転写インクの不足のために彩度及びグラデーションが劣る等の欠点が改善される。   According to the present invention, the prior art improves the disadvantages such as inferior saturation and gradation due to the lack of thermal transfer ink.

本考案の第一実施形態に係る感熱転写記録シートの構造を説明する断面模式図である。It is a cross-sectional schematic diagram explaining the structure of the thermal transfer recording sheet which concerns on 1st embodiment of this invention. 本考案の第一実施形態に係る感熱転写記録シートの構造を説明する断面模式図である。It is a cross-sectional schematic diagram explaining the structure of the thermal transfer recording sheet which concerns on 1st embodiment of this invention. 本考案の第一実施形態に係る感熱転写記録シートの構造を説明する一部の断面模式図である。It is a partial schematic cross-sectional view for explaining the structure of the thermal transfer recording sheet according to the first embodiment of the present invention. 従来の感熱転写記録シートの構造を示す傾斜の概略図である。It is the schematic of the inclination which shows the structure of the conventional thermal transfer recording sheet. 従来の感熱転写記録シートの構造を示す一部の断面模式図である。It is a partial schematic cross-sectional view showing the structure of a conventional thermal transfer recording sheet.

考案における好適な実施の形態について、添付図面を参照して説明する。尚、以下に説明する実施の形態は、実用新案登録請求の範囲に記載された本考案の内容を限定するものではない。また、以下に説明される構成の全てが、本考案の必須要件であるとは限らない。
<第一実施形態>
Preferred embodiments of the invention will be described with reference to the accompanying drawings. The embodiment described below does not limit the contents of the present invention described in the claims of the utility model registration. In addition, all the configurations described below are not necessarily essential requirements of the present invention.
<First embodiment>

以下、第一実施形態を図1〜3に基づいて説明する。本考案の感熱転写記録シートの構造は、基材120及び基材120に設置される浸透用孔142を有する塗布層140を備える。こうして、上述の構造の構成により、感熱転写インク160の担体として設置されると、感熱転写インク160は一部のみが浸透用孔142に沿って塗布層140に浸透され、感熱転写インク160の付着力が強化されるほか、感熱転写インク160の乾燥速度を維持させつつ、従来の感熱転写インク160では基材120に設置されると、感熱転写インク160が基材120に過度に吸収されてしまい、転写される感熱転写インク160が不足し、完成品の色彩の濃淡が不足する等の欠点を解決する。   Hereinafter, the first embodiment will be described with reference to FIGS. The structure of the thermal transfer recording sheet of the present invention includes a base material 120 and a coating layer 140 having a permeation hole 142 installed in the base material 120. Thus, when the thermal transfer ink 160 is installed as a carrier of the above-described structure, only a part of the thermal transfer ink 160 is permeated into the coating layer 140 along the permeation holes 142, and the thermal transfer ink 160 is attached. In addition to enhancing the adhesion, when the conventional thermal transfer ink 160 is installed on the base material 120 while maintaining the drying speed of the thermal transfer ink 160, the thermal transfer ink 160 is excessively absorbed by the base material 120. This solves the shortcomings such as insufficient thermal transfer ink 160 to be transferred and insufficient shade of color of the finished product.

上述の塗布層140は無機顔料、澱粉誘導体、ケイ素化合物、セルロース誘導体、及び高分子樹脂の混合構成の塗布溶液を含む。無機顔料の粒径のため、溶液が基材120に塗布されて乾燥した後、塗布層140の無機顔料間の顆粒の隙間に浸透用孔142が形成され、感熱転写インク160の一部がこれら浸透用孔に浸透される。実施の際は、無機顔料は硫酸バリウム、じゃがいも粉、カオリン、チャコ、或いは亜鉛顔料の内の何れか1つ、ないしはそれらの組合せから選択される。   The coating layer 140 includes a coating solution having a mixed structure of an inorganic pigment, a starch derivative, a silicon compound, a cellulose derivative, and a polymer resin. Due to the particle size of the inorganic pigment, after the solution is applied to the substrate 120 and dried, the permeation holes 142 are formed in the gaps between the inorganic pigments of the coating layer 140, and a part of the thermal transfer ink 160 is formed. It penetrates into the penetration hole. In practice, the inorganic pigment is selected from any one of barium sulfate, potato powder, kaolin, chaco, or zinc pigment, or a combination thereof.

また、上述の澱粉誘導体には粉質誘導体、酵素改質澱粉誘導体、化学改質澱粉誘導体から選択される。上述のケイ素化合物はカオリン、雲母、ベントナイト、或いはコピアポ石の内の何れか1つ、或いはそれらの組合せから選択される。   The starch derivative is selected from powdery derivatives, enzyme-modified starch derivatives, and chemically-modified starch derivatives. The above-mentioned silicon compound is selected from any one of kaolin, mica, bentonite, and copiapolite, or a combination thereof.

上述のセルロース誘導体はニトロセルロース、アセチルセルロース、メチルセルロース、カルボキシメチルセルロース、及びエチルセルロースの内の何れか1つ、或いはそれらの組合せから選択される。   The cellulose derivative is selected from any one of nitrocellulose, acetylcellulose, methylcellulose, carboxymethylcellulose, and ethylcellulose, or a combination thereof.

さらに、上述の高分子樹脂はアルキド樹脂(Alkyd resins)、不飽和樹脂(unsaturated Resins)、エポキシ樹脂(Epoxy Resins、EP)、シリコン樹脂(Silicone Resins、SI)、フタル酸ジアリル樹脂(Diallyl Phthalate Resins、DAP)、ポリ塩化ビニルPolyvinyl Chloride、H(CH2CHCl)Nh、PVC)、ポリビニルアルコール(Polyvinyl Alcohol H[CH2CH(OH)]nH、PVA)、ポリスチレン(Polystyrene、 H[CH(C6H5)CH2)]nH、PS)、ポリプロピレン(PolyPropylence H[CH(CH3)CH2)]nH、PP)、アクリル樹脂(Acrylic Resins)、ABS(Acrylonitrile-butadiene-Styrene、ABS)、ポリ酢酸ビニル(Polyvinyl Acetate、PVAC)、及びポリアミド(Polyamide、PA)の内の何れか1つ、或いはそれらの組合せから選択される。   Further, the above-mentioned polymer resins are alkyd resins, unsaturated resins, epoxy resins (Epoxy Resins, EP), silicon resins (Silicone Resins, SI), diallyl phthalate resins (Diallyl Phthalate Resins, DAP), Polyvinyl Chloride, H (CH2CHCl) Nh, PVC), polyvinyl alcohol (Polyvinyl Alcohol H [CH2CH (OH)] nH, PVA), polystyrene (Polystyrene, H [CH (C6H5) CH2)] nH, PS), polypropylene (PolyPropylence H [CH (CH3) CH2)] nH, PP), acrylic resin (Acrylic Resins), ABS (Acrylonitrile-butadiene-Styrene, ABS), polyvinyl acetate (Polyvinyl Acetate, PVAC), and polyamide It is selected from any one of (Polyamide, PA) or a combination thereof.

上述したように、本考案の好ましい第一実施形態の感熱転写記録シートの構造の各部材の説明に続いて、本考案の装設方式及び使用の特徴を以下に説明する。まず、塗布層140が基材120に設置される。設置方式は先に無機顔料、澱粉誘導体、ケイ素化合物、セルロース誘導体及び高分子樹脂の混合構成の溶液が1平方メートルあたり約0.1〜30μmの量塗布され、基材120に均等に塗布されて形成される。使用者は印刷設備を用い感熱転写インク160を予め設計されたパターン或いは文字として塗布層140に印刷させ、感熱転写インク160の一部は塗布層140の浸透用孔142を経由して塗布層140及び基材120に浸透され、感熱転写インク160が乾燥した後にパターンを有する感熱転写紙が形成される(図示せず)。   As described above, following the description of each member of the structure of the thermal transfer recording sheet according to the first preferred embodiment of the present invention, the installation method and the features of use of the present invention will be described below. First, the coating layer 140 is installed on the substrate 120. The installation method is previously formed by applying a mixed solution of inorganic pigment, starch derivative, silicon compound, cellulose derivative and polymer resin in an amount of about 0.1 to 30 μm per square meter and evenly applied to the substrate 120. Is done. The user uses the printing facility to print the thermal transfer ink 160 on the coating layer 140 as a predesigned pattern or character, and a part of the thermal transfer ink 160 passes through the permeation hole 142 of the coating layer 140. Then, the thermal transfer paper having a pattern is formed after being penetrated into the substrate 120 and drying the thermal transfer ink 160 (not shown).

こうして、使用者は感熱転写インク160が構成されるパターンを所定の基材(例えば、紡織品、図示せず)に転写する場合、パターンを有する感熱転写紙を基材の所定の位置に設置させ、加熱設備(図示せず)により摂氏約200度で加熱し、塗布層140の感熱転写インク160を気体化させ、基材の表面に嵌入させる。加熱設備から取り出され冷却されると、感熱転写インク160は気体から固体に変化し基材に結合する。   Thus, when the user transfers the pattern formed of the thermal transfer ink 160 to a predetermined substrate (for example, a textile, not shown), the user sets the thermal transfer paper having the pattern at a predetermined position on the substrate, Heating is performed at about 200 degrees Celsius by a heating facility (not shown), and the thermal transfer ink 160 of the coating layer 140 is gasified and fitted into the surface of the substrate. When removed from the heating facility and cooled, the thermal transfer ink 160 changes from gas to solid and binds to the substrate.

本考案の感熱転写記録シートの構造は塗布層140に感熱転写インク160が設置される場合、感熱転写インク160の一部のみが浸透用孔142を経由し塗布層140及び基材120に浸透され、感熱転写インク160が基材120に過度に吸収されるのを防ぎ、感熱転写インク160を塗布層140の基材120に対する他面に十分に保留させる。感熱転写インク160が加熱された後も十分な感熱転写インク160の量を有し、基材の表面に被覆され、感熱転写インク160のパターンの完成品の彩度を確保する。   In the structure of the thermal transfer recording sheet of the present invention, when the thermal transfer ink 160 is installed in the coating layer 140, only a part of the thermal transfer ink 160 is permeated into the coating layer 140 and the substrate 120 through the penetration holes 142. The thermal transfer ink 160 is prevented from being excessively absorbed by the substrate 120, and the thermal transfer ink 160 is sufficiently retained on the other surface of the coating layer 140 with respect to the substrate 120. Even after the thermal transfer ink 160 is heated, it has a sufficient amount of the thermal transfer ink 160 and is coated on the surface of the substrate to ensure the saturation of the finished pattern of the thermal transfer ink 160.

なお、本考案は前述した実施の形態のみに限定されるものではなく、本考案の要旨を逸脱しない範囲において種々の変更が可能であることは勿論である。   Note that the present invention is not limited to the above-described embodiment, and various modifications can be made without departing from the scope of the present invention.

120 基材
140 塗布層
142 浸透用孔
160 感熱転写インク
920 パターン
922 感熱転写インク
940 基材
DESCRIPTION OF SYMBOLS 120 Base material 140 Coating layer 142 Penetration hole 160 Thermal transfer ink 920 Pattern 922 Thermal transfer ink 940 Base material

Claims (7)

感熱転写記録シートの構造において、基材と、
前記基材に設置されると共に複数の浸透用孔を有する塗布層を備えることを特徴とする感熱転写記録シートの構造。
In the structure of the thermal transfer recording sheet,
A structure of a heat-sensitive transfer recording sheet, comprising a coating layer provided on the substrate and having a plurality of permeation holes.
前記塗布層は炭酸カルシウム、澱粉誘導体、ケイ素化合物、セルロース誘導体、及び高分子樹脂の混合構成を含むことを特徴とする、請求項1に記載の感熱転写記録シートの構造。   2. The structure of a thermal transfer recording sheet according to claim 1, wherein the coating layer includes a mixed structure of calcium carbonate, starch derivative, silicon compound, cellulose derivative, and polymer resin. 前記塗布層は硫酸バリウム、澱粉誘導体、ケイ素化合物、セルロース誘導体、及び高分子樹脂の混合構成を含むことを特徴とする、請求項1に記載の感熱転写記録シートの構造。   2. The structure of a thermal transfer recording sheet according to claim 1, wherein the coating layer includes a mixed structure of barium sulfate, starch derivative, silicon compound, cellulose derivative, and polymer resin. 前記塗布層はじゃがいも粉、澱粉誘導体、ケイ素化合物、セルロース誘導体、及び高分子樹脂の混合構成を含むことを特徴とする、請求項1に記載の感熱転写記録シートの構造。   2. The structure of a thermal transfer recording sheet according to claim 1, wherein the coating layer includes a mixed structure of potato powder, starch derivative, silicon compound, cellulose derivative, and polymer resin. 前記塗布層は亜鉛顔料、澱粉誘導体、ケイ素化合物、セルロース誘導体、及び高分子樹脂の混合構成を含むことを特徴とする、請求項1に記載の感熱転写記録シートの構造。   2. The structure of a thermal transfer recording sheet according to claim 1, wherein the coating layer includes a mixed structure of a zinc pigment, a starch derivative, a silicon compound, a cellulose derivative, and a polymer resin. 前記塗布層は無機顔料、澱粉誘導体、ケイ素化合物、セルロース誘導体、及び高分子樹脂の混合構成を含むことを特徴とする、請求項1に記載の感熱転写記録シートの構造。   2. The structure of a thermal transfer recording sheet according to claim 1, wherein the coating layer includes a mixed structure of an inorganic pigment, a starch derivative, a silicon compound, a cellulose derivative, and a polymer resin. 前記ケイ素化合物はカオリン、雲母、ベントナイト、及びコピアポ石の内の何れか1つ、或いはそれらの組合せから選択的に採用されることを特徴とする、請求項2乃至6の内の何れか1項に記載の感熱転写記録シートの構造。   The silicon compound is selected from any one of kaolin, mica, bentonite, and copiapolite, or a combination thereof, according to any one of claims 2 to 6. The structure of a thermal transfer recording sheet as described in 1.
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