CN106591875A - Device for electrolysing seawater by virtue of optical energy to prepare sodium hypochlorite - Google Patents

Device for electrolysing seawater by virtue of optical energy to prepare sodium hypochlorite Download PDF

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Publication number
CN106591875A
CN106591875A CN201611149466.3A CN201611149466A CN106591875A CN 106591875 A CN106591875 A CN 106591875A CN 201611149466 A CN201611149466 A CN 201611149466A CN 106591875 A CN106591875 A CN 106591875A
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China
Prior art keywords
sodium hypochlorite
electrolyzer
anode
luminous energy
seawater
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CN201611149466.3A
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CN106591875B (en
Inventor
李鑫
徐德福
王琪飞
邱子健
朱欢欢
田瀚鑫
曹枚霖
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Shandong hechengzhiyun environmental protection equipment Co.,Ltd.
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Nanjing University of Information Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/24Halogens or compounds thereof
    • C25B1/26Chlorine; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/50Processes
    • C25B1/55Photoelectrolysis
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00Operating or servicing cells
    • C25B15/02Process control or regulation
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/60Constructional parts of cells
    • C25B9/65Means for supplying current; Electrode connections; Electric inter-cell connections
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Automation & Control Theory (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention relates to a device for electrolysing seawater by virtue of optical energy to prepare sodium hypochlorite, and belongs to the technical fields of sodium hypochlorite preparation devices and optical energy utilization. An electrolysis cell is a closed container, a cathode and an anode are fixedly arranged in the electrolysis cell respectively, the cathode is located on the upper part of the electrolysis cell, the anode is located on the lower part of the electrolysis cell, and a diaphragm is transversally arranged between the cathode and the anode. The invention designs a device for electrolysing seawater through photovoltaic power generation to prepare sodium hypochlorite, so as to realize energy conservation and emission reduction, and electrolyse seawater to prepare sodium hypochlorite; power is generated by virtue of a solar panel to provide the electric energy consumed by the electrolysis cell, the natural resources are adequately utilized, the device is clean and pollution-free, and the surrounding environment is protected; hydrogen obtained by electrolysis is taken as a fuel for combustion to provide the energy needed by the evaporation and concentration of seawater, the resources are adequately utilized, and the design is ingenious; and the electrical conductivity is improved due to the ionic concentration of the evaporated and concentrated seawater to achieve the purpose of adequately electrolysing sodium chloride, thus the electrolysis efficiency is increased.

Description

The device of sodium hypochlorite is produced using luminous energy electrolytic seawater
Technical field
The present invention relates to a kind of utilization luminous energy electrolytic seawater produces the device of sodium hypochlorite, belong to sodium hypochlorite and produce dress Put, light-use technical field.
Background technology
With social industrial development and explosive population growth, the energy resource structure based on Fossil fuel needs improvement, the life of the mankind badly Depositing the resource needed for development will provide by ocean, but ocean is not yet made full use of by the mankind.
A kind of existing similar device electrolytic seawater sodium hypochlorite, its principle by cable and motor device to provide exchange Electricity, is converted into kilovolt high voltage direct current and is connected to two electric levels being disposed vertically respectively and carries out electrolytic seawater to generate chlorine by commutator Gas, hydrogen and sodium hydroxide, this process can release amount of heat.Then supercharging equipment is utilized by hydrogen and the mixed gas of chlorine Circulation is passed through in the electrolyzer after cooling, makes chlorine and sodium hydroxide react generation sodium hypochlorite.This device does not only have Hydrogen is isolated, huge potential safety hazard is there is, while there is excessive energy resource consumption.
The content of the invention
The technical problem to be solved is the defect for overcoming prior art, there is provided one kind utilizes luminous energy electrolytic seawater The device of sodium hypochlorite is produced, can be separate by electrolytically generated chlorine, hydrogen, while the energy that concentration process is consumed is by electricity Combustion of hydrogen obtained by solution is provided;Energy resource consumption is reduced by the hydrogen isolated, effectively solution reduces potential safety hazard.
To reach above-mentioned purpose, the present invention provides the device that sodium hypochlorite is produced using luminous energy electrolytic seawater, including electrolysis Pond, negative electrode, anode and barrier film;The electrolyzer is closed vessel, and the negative electrode, the anode are respectively fixedly installed on described In electrolyzer, the negative electrode is located at the top of the electrolyzer, and the anode is located at the bottom of the electrolyzer, and the barrier film is horizontal To being arranged between the negative electrode and the anode.
Preferentially, including evaporation concentration equipment, metal end, pipeline and filter, the top connection of the electrolyzer is described One end of filter, the other end of the filter is by metal end described in the pipeline communication;On the evaporation concentration equipment Stillpot, water inlet, outlet are offered, the outlet connects the bottom left end of the electrolyzer, and the stillpot is opened up In the evaporation concentration equipment bottom;Also include protective cover, the evaporation concentration equipment top offers open a, protection Lid is connected together described open, and a steam outlet is opened up on the protective cover;The metal end includes oxygen air inlet, metal Ring and funnel, offer the hole of multiple equidistantly distributeds around the center of circle on the becket, the becket is fixedly installed on institute Funnel is stated, the funnel bottom seals respectively connection oxygen air inlet and the pipeline.
Preferentially, including several inserts, several described inserts are equidistantly fixedly installed in the filter, The inserts include NaOH powder and gauze, and the NaOH powder is filled in the gauze.
Preferentially, including photovoltaic generating system, the photovoltaic generating system includes solar panels, charging-discharging controller, storage Battery, sinewave output inverter and rectifier bridge;The solar panels electrically connect the charging-discharging controller, and the charge and discharge is automatically controlled Device processed electrically connects the accumulator, and the storage battery connects the sinewave output inverter, the sinewave output inversion Device is connected with the rectifier bridge.
Preferentially, including storage container, the bottom right-hand member of the electrolyzer connects the storage container.
Preferentially, the negative electrode material is ferrum, and the anode material is titanium, is offered on the negative electrode, the anode Multiple mesh of equidistantly distributed;Titanium oxide or ru oxide are covered on the anode, nickel coating is covered on negative electrode..
Preferentially, the barrier film is inorganic-organic hybridization ion exchange membrane.
Preferentially, including YWK automatic temperature control systems and radiator, the YWK automatic temperature control systems include temperature sensor, The temperature sensor is located in the electrolyzer, and the YWK automatic temperature control systems electrically connect the radiator.
Preferentially, including PH detector, the PH detector is fixedly installed on the exit of the filter.
Preferentially, the metal end material is copper.
The beneficial effect that the present invention is reached:
(1)The problems such as potential safety hazard that the present invention exists for traditional handicraft in prior art, energy shortage and seawater utilization, if Count photovoltaic generation electrolytic seawater to produce the device of sodium hypochlorite to realize energy-saving and emission-reduction and electrolytic seawater produces sodium hypochlorite;According to Generate electricity by solar panels and electrolyzer institute consuming electric power is provided, make full use of the Nature energy, cleanliness without any pollution to protect peripheral ring Border;By energy of the electrolysis gained hydrogen for needed for fuel combustion provides evaporation of seawater concentration, resource is made full use of, designed ingenious; Ion concentration contained by sea water after evaporation and concentration improves electric conductivity and reaches the purpose for making Sodium Chloride fully be electrolysed, and improves electricity Solution efficiency;
Sodium hypochlorite, this dress generated and directly chemical reaction in electrolyzer in the sodium hydroxide generated by seawater electrolysises and chlorine there is Put with boundless development prospect, simple structure, energy-conserving and environment-protective, high financial profit is safe and reliable, and development prospect is wide;
(2)Barrier film prevents gaseous chlorine to pass through but to allow hydroxide ion etc. to pass through, and chlorine is effectively ensured and stops in the electrolytic solution With hydroxide ion reaction so that chlorine is sufficiently mixed with solution in electrolyzer and improves electrolytic efficiency;
(3)The running voltage of charging-discharging controller Intelligent adjustment solar panel, makes solar panels always work in V-A characteristics The maximum power point of curve;10-30% is improve to the utilization rate of solar panels generated output, prevent accumulator overcharge and Night accumulator is to beneficial effects such as solar panels back discharge, also overload protection, short-circuit protection, cell anti-reverses.
Description of the drawings
Fig. 1 is the structure chart of the present invention;
Fig. 2 is the structure chart of metal end in the present invention;
Fig. 3 is the structure chart of evaporation concentration equipment in the present invention;
Fig. 4 is the theory diagram of photovoltaic generating system in the present invention;
Fig. 5 is the structure chart of filter in the present invention.
Labelling implication in accompanying drawing, 1- solar panels;2- charging-discharging controllers;3- electrolyzers;4- accumulator;5- sine waves are defeated Go out inverter;6- electric wires;7- rectifier bridges;8- negative electrodes;9- barrier films;10- anodes;11- filters;12- storage containers;13- pipelines; 14- evaporation concentration equipments;15- metal ends;16-PH detectors;17- stillpots;18- oxygen air inlets;19- water inlets;20- water Vapor outlet port;21- outlets;22- inserts.
Specific embodiment
Below in conjunction with the accompanying drawings the invention will be further described.Following examples are only used for clearly illustrating the present invention Technical scheme, and can not be limited the scope of the invention with this.
The present invention provides the device that sodium hypochlorite is produced using luminous energy electrolytic seawater, including electrolyzer 3, negative electrode 8, anode 10 With barrier film 9;The electrolyzer 3 is closed vessel, and the negative electrode 8, the anode 10 are respectively fixedly installed on the electrolyzer 3 Interior, the negative electrode 8 is located at the top of the electrolyzer 3, and the anode 10 is located at the bottom of the electrolyzer 3, and the barrier film 9 is horizontal To being arranged between the negative electrode 8 and the anode 10.
Further, the present invention includes evaporation concentration equipment 14, metal end 15, pipeline 13 and filter 11, described The top of electrolyzer 3 connects one end of the filter 11, and the other end of the filter 11 connects institute by the pipeline 13 State metal end 15;Stillpot 17, water inlet 19, outlet 21, the outlet 21 are offered on the evaporation concentration equipment 14 The bottom left end of the electrolyzer 3 is connected, the stillpot 17 is opened in the bottom of the evaporation concentration equipment 14;Also include protection Lid, the top of the evaporation concentration equipment 14 offer it is one open, the protective cover be connected together it is described open, on the protective cover A steam outlet 20 is opened up, protective cover is opened during summer and is easy to radiating of the present invention, protective cover is shut during winter and opens vapor Outlet 20 is easy to be warmed oneself using vapor;
The metal end 15 includes oxygen air inlet 18, becket and funnel, offers around the center of circle on the becket multiple The hole of equidistantly distributed, the becket is fixedly installed on the funnel, and the funnel bottom seals respectively connection oxygen Air inlet 18 and the pipeline 13, the stillpot 17 is used to store the impurity such as calcium sulfate under precipitating in sea water.
Further, the present invention includes several inserts, and several described inserts are equidistantly fixedly installed on described In filter 11, the inserts present invention includes NaOH powder and gauze, and the NaOH powder is filled in the gauze.With The increase of vapor volumetric concentration, combustion of hydrogen maximum temperature declines, water vapour content change to combustion of hydrogen surge pressure and Burn-off rate has no significant effect, and water vapor concentration has no significant effect when being less than 10% to combustion of hydrogen flame propagation velocity, works as vapor More than 20%, hydrogen flame spread speed is substantially reduced concentration, so need filter 11 to remove vapor subsidiary in hydrogen, Simultaneously filter 11 is prevented because occurring the situation that pin hole causes to have chlorine to be mixed into hydrogen on barrier film.
Further, the present invention includes photovoltaic generating system, the photovoltaic generating system present invention include solar panels 1, Charging-discharging controller 2, accumulator 4, sinewave output inverter 5 and rectifier bridge 7;The solar panels 1 electrically connect the charge and discharge Electric controller 2, the charging-discharging controller 2 electrically connects the accumulator 4, and the accumulator 4 electrically connects the sinewave output Inverter 5, the sinewave output inverter 5 is connected with the rectifier bridge 7.Low-voltage DC is through sinewave output inverter 5 and rectifier bridge 7 be converted into high voltage direct current and provide electric energy for electrolyzer.
The running voltage of charging-discharging controller Intelligent adjustment solar panel, makes solar panels always work in V-A special The maximum power point of linearity curve;Relatively conventional controller for solar, to the utilization rate of solar panels generated output 10- is improve 30%, prevent accumulator from overcharging with night accumulator to solar panels back discharge, also overload protection, short-circuit protection, electricity The beneficial effects such as pond counnter attack.
Further, the present invention includes storage container 12, and the bottom right-hand member of the electrolyzer 3 connects the storage container 12。
Further, the material of the negative electrode 8 is ferrum, and the material of the anode 10 is titanium, on the negative electrode 8, the anode 10 Offer multiple mesh of equidistantly distributed, increase and electrolyte contacts area;On the anode 10 cover titanium oxide or Ru oxide, on negative electrode 8 nickel coating is covered, and is extended electrode life and is improve electrolytic efficiency.
Further, the barrier film 9 is inorganic-organic hybridization ion exchange membrane, and the toughness of barrier film 9 is strong and acid and alkali-resistance, prevents Gaseous chlorine is passed through by but allowing hydroxide ion etc., be effectively ensured chlorine stop it is anti-with hydroxide ion in the electrolytic solution Should.
Further, the present invention includes YWK automatic temperature control systems and radiator, the YWK automatic temperature control systems present invention Including temperature sensor, the temperature sensor is located in the electrolyzer 3, and the YWK automatic temperature control systems electrical connection is described Radiator.YWK-2 temperature control systems are the instrument for water temperature to be monitored and controlled, when the temperature of water temperature is higher than arranges value, System output switching signal, starts fan or other radiating elements and lowers the temperature to monitored system.When water temperature is dropped to requires temperature, System automatically exits from controlled state, closes fan or other radiating elements, stops cooling.
Further, the present invention includes PH detector 16, and the PH detector is fixedly installed on going out for the filter 11 At mouthful.
Further, the material of the metal end 15 is copper.
The problems such as potential safety hazard that the present invention exists for traditional handicraft in prior art, energy shortage and seawater utilization, Devise photovoltaic generation electrolytic seawater to produce the device of sodium hypochlorite to realize energy-saving and emission-reduction and electrolytic seawater produces sodium hypochlorite. The device mainly includes photovoltaic generating system, cell system and evaporation concentration system, generates electricity by solar panels and provides electrolysis Pond institute consuming electric power, by interior energy of the electrolysis gained hydrogen for needed for fuel combustion provides evaporation of seawater concentration.Sea after concentration Ion concentration contained by water improves electric conductivity and reaches the purpose for making Sodium Chloride fully be electrolysed, while the hydroxide generated by seawater electrolysises Sodium hypochlorite generated and directly chemical reaction in electrolyzer in sodium and chlorine there is.This device is rich using solar electrical energy generation electrolysis resource Rich sea water produces sodium hypochlorite, is related to evaporation concentration technique, photovoltaic power generation technology, chlorine industry and the combustion of hydrogen of sea water, All it is to be in starting also or be widely used to the advanced technology for producing of living, solar energy is all clean energy resource with Hydrogen Energy, and its is clear Clean free of contamination feature will replace Fossil fuel as the energy, and this device has boundless development prospect.The device knot Structure is simple, and energy-conserving and environment-protective, high financial profit is safe and reliable, and development prospect is wide.
Daytime, by solar electrical energy generation electric power storage, provides the sea water after energy electrolytic enrichment and generates hydrogen, hydrogen-oxygen for electrolyzer Change sodium and chlorine.It is the confession of evaporation and concentration sea water to filter out the chlorine of remnants, the hydrogen of vapor as fuel through filter 11 Energy.Due to there is barrier film 9, the chlorine generated in anode cannot pass through, it is to avoid explode with hydrogen mixing.Evening is using white Its electric power storage can work on, and finally realize the producing process of whole sodium hypochlorite.
Electrode is set to upper and lower two-layer by the present invention, and anode 10 generates chlorine in electrolyzer bottom, and negative electrode 8 is on electrolyzer Portion generates hydrogen, and by barrier film 9 link that hydrogen circulation is passed through chlorine is avoided, while the hydrogen that negative electrode 8 is generated is from filter 11 are directly separated out.This device first to it carries out concentration lifting with solar energy energy supply in sea water into before electrolyzer Ion concentration strengthens electric conductivity, reduces electrolysis required voltage.The energy that simultaneously concentration process is consumed is by the hydrogen for being electrolysed gained Gas burning is provided, and realization makes full use of to resource.Meanwhile, hydrogen is isolated by barrier film 9, filter 11, effectively solution is reduced Potential safety hazard.
Course of reaction:Sodium Chloride and water electrolysis generate sodium hydroxide, chlorine and hydrogen;Sodium hydroxide and chlorine reaction are generated Sodium Chloride, sodium hypochlorite and water.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, on the premise of without departing from the technology of the present invention principle, some improvement and deformation can also be made, these improve and deform Also should be regarded as protection scope of the present invention.

Claims (10)

1. the device of sodium hypochlorite is produced using luminous energy electrolytic seawater, it is characterised in that including electrolyzer(3), negative electrode(8), sun Pole(10)And barrier film(9);The electrolyzer(3)For closed vessel, the negative electrode(8), the anode(10)Respectively fixation sets Put in the electrolyzer(3)It is interior, the negative electrode(8)Positioned at the electrolyzer(3)Top, the anode(10)Positioned at the electricity Xie Chi(3)Bottom, the barrier film(9)It is horizontally installed on the negative electrode(8)With the anode(10)Between.
2. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that including steaming Send out concentrator(14), metal end(15), pipeline(13)And filter(11), the electrolyzer(3)Top connect the mistake Filter(11)One end, the filter(11)The other end pass through the pipeline(13)Connect the metal end(15);It is described Evaporation concentration equipment(14)On offer stillpot(17), water inlet(19), outlet(21), the outlet(21)Connection institute State electrolyzer(3)Bottom left end, the stillpot(17)It is opened in the evaporation concentration equipment(14)Bottom;Also include protection Lid, the evaporation concentration equipment(14)Top offers one open, and the protective cover is connected together described open, the protective cover On open up a steam outlet(20);The metal end(15)Including oxygen air inlet(18), becket and funnel, the metal The hole of multiple equidistantly distributeds is offered on ring around the center of circle, the becket is fixedly installed on the funnel, the leakage Bucket bottom seals respectively connection oxygen air inlet(18)With the pipeline(13).
3. utilization luminous energy electrolytic seawater according to claim 2 produces the device of sodium hypochlorite, it is characterised in that if including Dry inserts, several described inserts are equidistantly fixedly installed on the filter(11)Interior, the inserts include NaOH powder and gauze, the NaOH powder is filled in the gauze.
4. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that including light Photovoltaic generating system, the photovoltaic generating system includes solar panels(1), charging-discharging controller(2), accumulator(4), sine wave it is defeated Go out inverter(5)And rectifier bridge(7);The solar panels(1)Electrically connect the charging-discharging controller(2), the charge and discharge is automatically controlled Device processed(2)Electrically connect the accumulator(4), the accumulator(4)Electrically connect the sinewave output inverter(5), it is described just String ripple output inverter(5)With the rectifier bridge(7)Series connection.
5. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that including storage Deposit container(12), the electrolyzer(3)Bottom right-hand member connect the storage container(12).
6. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that described the moon Pole(8)Material is ferrum, the anode(10)Material is titanium, the negative electrode(8), the anode(10)On offer equidistantly point Multiple mesh of cloth;The anode(10)Upper covering titanium oxide or ru oxide, negative electrode(8)Upper covering nickel coating.
7. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that it is described every Film(9)For inorganic-organic hybridization ion exchange membrane.
8. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that include YWK automatic temperature control systems and radiator, the YWK automatic temperature control systems include temperature sensor, and the temperature sensor is located at The electrolyzer(3)Interior, the YWK automatic temperature control systems electrically connect the radiator.
9. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that including PH Detector(16), the PH detector is fixedly installed on the filter(11)Exit.
10. utilization luminous energy electrolytic seawater according to claim 2 produces the device of sodium hypochlorite, it is characterised in that described Metal end(15)Material is copper.
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CN111809194A (en) * 2020-05-28 2020-10-23 宁波英德菲尔机械科技有限公司 Portable household hypochlorous acid water manufacturing instrument
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