CN206232823U - The device of sodium hypochlorite is produced using luminous energy electrolytic seawater - Google Patents

The device of sodium hypochlorite is produced using luminous energy electrolytic seawater Download PDF

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Publication number
CN206232823U
CN206232823U CN201621367522.6U CN201621367522U CN206232823U CN 206232823 U CN206232823 U CN 206232823U CN 201621367522 U CN201621367522 U CN 201621367522U CN 206232823 U CN206232823 U CN 206232823U
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China
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sodium hypochlorite
electrolytic cell
electrolytic
luminous energy
anode
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CN201621367522.6U
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Chinese (zh)
Inventor
李鑫
徐德福
王琪飞
邱子健
朱欢欢
田瀚鑫
曹枚霖
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Nanjing University of Information Science and Technology
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Nanjing University of Information Science and Technology
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Abstract

The utility model is related to a kind of utilization luminous energy electrolytic seawater to produce the device of sodium hypochlorite, belongs to sodium hypochlorite device for making, light-use technical field.Electrolytic cell is closed vessel, and negative electrode, anode are respectively fixedly installed in electrolytic cell, and negative electrode is located at the top of electrolytic cell, and anode is located at the bottom of electrolytic cell, and barrier film is horizontally installed between negative electrode and anode.The utility model devises photovoltaic generation electrolytic seawater and produces the device of sodium hypochlorite to realize energy-saving and emission-reduction and electrolytic seawater produces sodium hypochlorite;Generated electricity by solar panels and electrolytic cell institute consuming electric power is provided, make full use of the Nature energy, cleanliness without any pollution to protect surrounding enviroment;By electrolysis gained hydrogen for fuel combustion provides the energy needed for evaporation of seawater is concentrated, resource is made full use of, designed ingenious;Electric conductivity is improved by ion concentration contained by the seawater after evaporation and concentration and reach the purpose for making sodium chloride fully be electrolysed, improve electrolytic efficiency.

Description

The device of sodium hypochlorite is produced using luminous energy electrolytic seawater
Technical field
The utility model is related to a kind of utilization luminous energy electrolytic seawater to produce the device of sodium hypochlorite, belongs to sodium hypochlorite and produces Device, light-use technical field.
Background technology
With social industrial development and explosive population growth, the energy resource structure based on fossil fuel needs improvement, the life of the mankind badly Resource needed for depositing development will be provided by ocean, but ocean is not yet made full use of by the mankind.
A kind of existing similar device electrolytic seawater sodium hypochlorite, its principle by cable and motor device to provide exchange Electricity, is converted into kilovolt high voltage direct current and is connected to two electric levels being disposed vertically respectively and carries out electrolytic seawater to generate chlorine by rectifier Gas, hydrogen and NaOH, this process can release amount of heat.Then supercharging equipment is utilized by hydrogen and the mixed gas of chlorine Circulation is passed through in the electrolytic cell after cooling, chlorine and NaOH is reacted generation sodium hypochlorite.This device does not have not only Hydrogen is isolated, huge potential safety hazard is there is, while there is excessive energy resource consumption.
Utility model content
Technical problem to be solved in the utility model is the defect for overcoming prior art, there is provided one kind is using luminous energy electrolysis Seawater produces the device of sodium hypochlorite, can be separate by electrolytically generated chlorine, hydrogen, while the energy that concentration process is consumed Combustion of hydrogen as obtained by electrolysis is provided;Energy resource consumption is reduced by the hydrogen isolated, effectively solution reduces potential safety hazard.
To reach above-mentioned purpose, the utility model provides the device that sodium hypochlorite is produced using luminous energy electrolytic seawater, including Electrolytic cell, negative electrode, anode and barrier film;The electrolytic cell is closed vessel, and the negative electrode, the anode are respectively fixedly installed on In the electrolytic cell, the negative electrode be located at the electrolytic cell top, the anode be located at the electrolytic cell bottom, it is described every Film is horizontally installed between the negative electrode and the anode.
Preferentially, including evaporation concentration equipment, metal end, pipeline and filter, the top connection of the electrolytic cell is described One end of filter, the other end of the filter is by metal end described in the pipeline communication;On the evaporation concentration equipment Stillpot, water inlet, delivery port are offered, the delivery port connects the bottom left end of the electrolytic cell, and the stillpot is opened up In the evaporation concentration equipment bottom;Also include protective cover, the evaporation concentration equipment top offers open a, protection The opening that is connected together is covered, a steam outlet is opened up on the protective cover;The metal end includes oxygen air inlet, metal Ring and funnel, offer the hole of multiple equidistantly distributeds around the center of circle on the becket, the becket is fixedly installed on institute Funnel is stated, the funnel bottom seals connection oxygen air inlet and the pipeline respectively.
Preferentially, including several inserts, several described inserts are equidistantly fixedly installed in the filter, The inserts includes NaOH powder and gauze, and the NaOH powder is filled in the gauze.
Preferentially, including photovoltaic generating system, the photovoltaic generating system includes solar panels, charging-discharging controller, storage Battery, sinewave output inverter and rectifier bridge;The solar panels electrically connect the charging-discharging controller, and the charge and discharge is automatically controlled Device processed electrically connects the battery, and the storage battery connects the sinewave output inverter, the sinewave output inversion Device is connected with the rectifier bridge.
Preferentially, including storage container, the bottom right-hand member of the electrolytic cell connects the storage container.
Preferentially, the negative electrode material is iron, and the anode material is titanium, is offered on the negative electrode, the anode Multiple mesh of equidistantly distributed;Titanium oxide or ru oxide are covered on the anode, nickel coating is covered on negative electrode.
Preferentially, the barrier film is inorganic-organic hybridization amberplex.
Preferentially, including YWK automatic temperature control systems and radiator, the YWK automatic temperature control systems include temperature sensor, The temperature sensor is located in the electrolytic cell, and the YWK automatic temperature control systems electrically connect the radiator.
Preferentially, including PH detector, the PH detector is fixedly installed on the exit of the filter.
Preferentially, the metal end material is copper.
The beneficial effect that the utility model is reached:
(1)The potential safety hazard that the utility model exists for traditional handicraft in the prior art, energy shortage and seawater utilization The problems such as, devise photovoltaic generation electrolytic seawater and produce the device of sodium hypochlorite to realize energy-saving and emission-reduction and electrolytic seawater is produced time Sodium chlorate;Generated electricity by solar panels and electrolytic cell institute consuming electric power is provided, make full use of the Nature energy, cleanliness without any pollution, protection Surrounding enviroment;By electrolysis gained hydrogen for fuel combustion provides the energy needed for evaporation of seawater is concentrated, resource is made full use of, if Meter is ingenious;Electric conductivity is improved by ion concentration contained by the seawater after evaporation and concentration reach the purpose for making sodium chloride fully be electrolysed, Improve electrolytic efficiency;
Directly there is chemical reaction generation sodium hypochlorite in electrolytic cell in the NaOH and chlorine generated by seawater electrolysis, The present apparatus has boundless development prospect, and simple structure, energy-conserving and environment-protective, high financial profit is safe and reliable, and development prospect is wide It is wealthy;
(2)Barrier film prevents gaseous chlorine to pass through but to allow hydroxide ion etc. to pass through, and chlorine is effectively ensured and rests on electrolysis Reacted with hydroxide ion in liquid so that chlorine is sufficiently mixed with solution in electrolytic cell and improves electrolytic efficiency;
(3)The operating voltage of charging-discharging controller Intelligent adjustment solar panel, makes solar panels always work in V-A Characteristic maximum power point;Utilization rate to solar panels generated output improves 10-30%, prevents battery from excessively filling Electricity and night battery to solar panels back discharge, also overload protection, short-circuit protection, the beneficial effect such as cell anti-reverse.
Brief description of the drawings
Fig. 1 is structure chart of the present utility model;
Fig. 2 is the structure chart of metal end in the utility model;
Fig. 3 is the structure chart of evaporation concentration equipment in the utility model;
Fig. 4 is the theory diagram of photovoltaic generating system in the utility model;
Fig. 5 is the structure chart of filter in the utility model.
Implication, 1- solar panels are marked in accompanying drawing;2- charging-discharging controllers;3- electrolytic cells;4- batteries;5- sine waves are defeated Go out inverter;6- electric wires;7- rectifier bridges;8- negative electrodes;9- barrier films;10- anodes;11- filters;12- storage containers;13- pipelines; 14- evaporation concentration equipments;15- metal ends;16-PH detectors;17- stillpots;18- oxygen air inlets;19- water inlets;20- water Vapor outlet port;21- delivery ports;22- inserts.
Specific embodiment
The utility model is further described below in conjunction with the accompanying drawings.Following examples are only used for clearly illustrating this The technical scheme of utility model, and protection domain of the present utility model can not be limited with this.
The utility model provides the device that sodium hypochlorite is produced using luminous energy electrolytic seawater, including electrolytic cell 3, negative electrode 8, sun Pole 10 and barrier film 9;The electrolytic cell 3 is closed vessel, and the negative electrode 8, the anode 10 are respectively fixedly installed on the electricity Solution pond 3 in, the negative electrode 8 be located at the electrolytic cell 3 top, the anode 10 be located at the electrolytic cell 3 bottom, it is described every Film 9 is horizontally installed between the negative electrode 8 and the anode 10.
Further, the utility model includes evaporation concentration equipment 14, metal end 15, pipeline 13 and filter 11, The top of the electrolytic cell 3 connects one end of the filter 11, and the other end of the filter 11 is connected by the pipeline 13 The logical metal end 15;Stillpot 17, water inlet 19, delivery port 21, the water outlet are offered on the evaporation concentration equipment 14 The bottom left end of the connection of mouth 21 electrolytic cells 3, the stillpot 17 is opened in the bottom of the evaporation concentration equipment 14;Also include Protective cover, the top of the evaporation concentration equipment 14 offers one open, and the protective cover is connected together the opening, the protection Cover and open up a steam outlet 20, protective cover is opened during summer and is easy to the utility model to radiate, protective cover is shut during winter and is beaten Boiling water vapor outlet port 20 is easy to be warmed oneself using vapor;
The metal end 15 includes oxygen air inlet 18, becket and funnel, is offered around the center of circle on the becket The hole of multiple equidistantly distributeds, the becket is fixedly installed on the funnel, and the funnel bottom seals connection respectively Oxygen air inlet 18 and the pipeline 13, the stillpot 17 are used to store the impurity such as the calcium sulfate under precipitating in seawater.
Further, the utility model includes several inserts, and several described inserts are equidistantly fixedly installed on In the filter 11, described inserts the utility model includes NaOH powder and gauze, and the NaOH powder is filled in described In gauze.With the increase of vapor volumetric concentration, combustion of hydrogen maximum temperature declines, and water vapour content changes to combustion of hydrogen peak Duty pressure and burn-off rate have no significant effect, and water vapor concentration has no significant effect when being less than 10% to combustion of hydrogen flame propagation velocity, When water vapor concentration is more than 20%, hydrogen flame spread speed is substantially reduced, so subsidiary in needing the removing hydrogen of filter 11 Vapor, while filter 11 prevents the situation for having chlorine to be mixed into hydrogen because occurring pin hole to cause on barrier film.
Further, the utility model includes photovoltaic generating system, and described photovoltaic generating system the utility model is included too Positive energy plate 1, charging-discharging controller 2, battery 4, sinewave output inverter 5 and rectifier bridge 7;The solar panels 1 are electrically connected The charging-discharging controller 2, the charging-discharging controller 2 electrically connects the battery 4, the battery 4 electrically connect it is described just String ripple output inverter 5, the sinewave output inverter 5 is connected with the rectifier bridge 7.Low-voltage DC is defeated by sine wave Go out inverter 5 and rectifier bridge 7 is converted into high voltage direct current for electrolytic cell provides electric energy.
The operating voltage of charging-discharging controller Intelligent adjustment solar panel, makes solar panels always work in V-A special The maximum power point of linearity curve;Relatively conventional controller for solar, the utilization rate to solar panels generated output improves 10- 30%, prevent battery from overcharging with night battery to solar panels back discharge, also overload protection, short-circuit protection, electricity The beneficial effects such as pond counnter attack.
Further, the utility model includes storage container 12, and the bottom right-hand member connection storage of the electrolytic cell 3 is held Device 12.
Further, the material of the negative electrode 8 is iron, and the material of the anode 10 is titanium, on the negative electrode 8, the anode 10 Offer multiple mesh of equidistantly distributed, increase and electrolyte contacts area;On the anode 10 cover titanium oxide or Ru oxide, nickel coating is covered on negative electrode 8, is extended electrode life and is improve electrolytic efficiency.
Further, the barrier film 9 is inorganic-organic hybridization amberplex, and the toughness of barrier film 9 is strong and acid and alkali-resistance, prevents Gaseous chlorine is passed through by but allowing hydroxide ion etc., be effectively ensured chlorine stop it is anti-with hydroxide ion in the electrolytic solution Should.
Further, the utility model includes YWK automatic temperature control systems and radiator, the YWK automatic temperature control systems sheet Utility model includes temperature sensor, and the temperature sensor is located in the electrolytic cell 3, the YWK automatic temperature control systems electricity Connect the radiator.YWK-2 temperature control systems are the instrument for water temperature to be monitored and controlled, when the temperature of water temperature is higher than to set When putting value, system output switching signal starts fan or other radiating elements to monitored system cooling.When water temperature drops to requirement During temperature, system automatically exits from state of a control, closes fan or other radiating elements, stops cooling.
Further, the utility model includes PH detector 16, and the PH detector is fixedly installed on the filter 11 Exit.
Further, the material of the metal end 15 is copper.
The potential safety hazard that the utility model exists for traditional handicraft in the prior art, energy shortage and seawater utilization etc. are asked Topic, devises photovoltaic generation electrolytic seawater and produces the device of sodium hypochlorite to realize energy-saving and emission-reduction and electrolytic seawater produces hypochlorous acid Sodium.The device mainly includes photovoltaic generating system, cell system and evaporation concentration system, is generated electricity by solar panels and provides electricity Solution pond institute consuming electric power, by electrolysis gained hydrogen for fuel combustion provides the interior energy needed for evaporation of seawater is concentrated.By after concentration Ion concentration contained by seawater improves electric conductivity and reaches the purpose for making sodium chloride fully be electrolysed, while the hydrogen-oxygen generated by seawater electrolysis Change sodium and chlorine and chemical reaction generation sodium hypochlorite directly occurs in electrolytic cell.The present apparatus is electrolysed resource using solar power generation Abundant seawater produces sodium hypochlorite, is related to evaporation concentration technique, photovoltaic power generation technology, chlorine industry and the hydrogen of seawater to fire Burn, be all the advanced technology for being in starting also or being widely used to life production, solar energy is all clean energy resource with Hydrogen Energy, its The characteristics of cleanliness without any pollution, will replace fossil fuel as the energy, and the present apparatus has boundless development prospect.The device Simple structure, energy-conserving and environment-protective, high financial profit is safe and reliable, and development prospect is wide.
Daytime, by solar power generation electric power storage, hydrogen, hydrogen-oxygen is generated for electrolytic cell provides the seawater after energy electrolytic enrichment Change sodium and chlorine.The chlorine of remnants, the hydrogen of vapor are filtered out by filter 11 to be supplied to be concentrated by evaporation seawater as fuel Energy.Due to there is barrier film 9, cannot pass through in the chlorine of anode generation, it is to avoid explode with hydrogen mixing.Evening is using white Its electric power storage can work on, and finally realize the producing process of whole sodium hypochlorite.
Electrode is set to upper and lower two-layer by the utility model, and anode 10 generates chlorine in electrolytic cell bottom, and negative electrode 8 is in electrolysis Pond top generates hydrogen, avoids hydrogen by barrier film 9 and circulates and is passed through the link of chlorine, while the hydrogen of the generation of negative electrode 8 is from mistake Filter 11 is directly separated out.The present apparatus with solar energy energy supply, in seawater into first carrying out concentration to it before electrolytic cell Lifting ion concentration enhancing electric conductivity, reduces voltage needed for electrolysis.The energy that concentration process is consumed simultaneously is by electrolysis gained Combustion of hydrogen provide, realization resource is made full use of.Meanwhile, hydrogen is isolated by barrier film 9, filter 11, effectively solution Reduce potential safety hazard.
Course of reaction:Sodium chloride and water electrolysis generation NaOH, chlorine and hydrogen;NaOH and chlorine reaction are generated Sodium chloride, sodium hypochlorite and water.
The above is only preferred embodiment of the present utility model, it is noted that for the common skill of the art For art personnel, on the premise of the utility model know-why is not departed from, some improvement and deformation can also be made, these change Enter and deform also to should be regarded as protection domain of the present utility model.

Claims (10)

1. the device of sodium hypochlorite is produced using luminous energy electrolytic seawater, it is characterised in that including electrolytic cell(3), negative electrode(8), sun Pole(10)And barrier film(9);The electrolytic cell(3)It is closed vessel, the negative electrode(8), the anode(10)Respectively fixation sets Put in the electrolytic cell(3)It is interior, the negative electrode(8)Positioned at the electrolytic cell(3)Top, the anode(10)Positioned at the electricity Xie Chi(3)Bottom, the barrier film(9)It is horizontally installed on the negative electrode(8)With the anode(10)Between.
2. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that including steaming Hair concentrator(14), metal end(15), pipeline(13)And filter(11), the electrolytic cell(3)Top connect the mistake Filter(11)One end, the filter(11)The other end pass through the pipeline(13)Connect the metal end(15);It is described Evaporation concentration equipment(14)On offer stillpot(17), water inlet(19), delivery port(21), the delivery port(21)Connection institute State electrolytic cell(3)Bottom left end, the stillpot(17)It is opened in the evaporation concentration equipment(14)Bottom;Also include protection Lid, the evaporation concentration equipment(14)Top offers one open, and the protective cover is connected together the opening, the protective cover On open up a steam outlet(20);The metal end(15)Including oxygen air inlet(18), becket and funnel, the metal The hole of multiple equidistantly distributeds is offered on ring around the center of circle, the becket is fixedly installed on the funnel, the leakage Bucket bottom seals connection oxygen air inlet respectively(18)With the pipeline(13).
3. utilization luminous energy electrolytic seawater according to claim 2 produces the device of sodium hypochlorite, it is characterised in that if including Dry inserts, several described inserts are equidistantly fixedly installed on the filter(11)Interior, the inserts includes NaOH powder and gauze, the NaOH powder are filled in the gauze.
4. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that including light Photovoltaic generating system, the photovoltaic generating system includes solar panels(1), charging-discharging controller(2), battery(4), sine wave it is defeated Go out inverter(5)And rectifier bridge(7);The solar panels(1)Electrically connect the charging-discharging controller(2), the charge and discharge is automatically controlled Device processed(2)Electrically connect the battery(4), the battery(4)Electrically connect the sinewave output inverter(5), it is described just String ripple output inverter(5)With the rectifier bridge(7)Series connection.
5. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that including storage Deposit container(12), the electrolytic cell(3)Bottom right-hand member connect the storage container(12).
6. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that described the moon Pole(8)Material is iron, the anode(10)Material is titanium, the negative electrode(8), the anode(10)On offer equidistantly point Multiple mesh of cloth;The anode(10)Upper covering titanium oxide or ru oxide, negative electrode(8)Upper covering nickel coating.
7. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that it is described every Film(9)It is inorganic-organic hybridization amberplex.
8. utilization luminous energy electrolytic seawater according to claim 1 produces the device of sodium hypochlorite, it is characterised in that including YWK automatic temperature control systems and radiator, the YWK automatic temperature control systems include temperature sensor, and the temperature sensor is located at The electrolytic cell(3)Interior, the YWK automatic temperature control systems electrically connect the radiator.
9. utilization luminous energy electrolytic seawater according to claim 2 produces the device of sodium hypochlorite, it is characterised in that including PH Detector(16), the PH detector is fixedly installed on the filter(11)Exit.
10. utilization luminous energy electrolytic seawater according to claim 2 produces the device of sodium hypochlorite, it is characterised in that described Metal end(15)Material is copper.
CN201621367522.6U 2016-12-14 2016-12-14 The device of sodium hypochlorite is produced using luminous energy electrolytic seawater Withdrawn - After Issue CN206232823U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106591875A (en) * 2016-12-14 2017-04-26 南京信息工程大学 Device for electrolysing seawater by virtue of optical energy to prepare sodium hypochlorite
CN108249527A (en) * 2018-02-08 2018-07-06 黄山市雅龙智能科技有限公司 A kind of high slat-containing wastewater processing unit
CN108423771A (en) * 2018-03-29 2018-08-21 砺剑防务技术集团有限公司 electrolytic seawater antifouling system
CN109371417A (en) * 2018-12-24 2019-02-22 成都科佑达技术开发有限公司 A kind of sodium hypochlorite electrolytic preparation device
CN111809194A (en) * 2020-05-28 2020-10-23 宁波英德菲尔机械科技有限公司 Portable household hypochlorous acid water manufacturing instrument

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106591875A (en) * 2016-12-14 2017-04-26 南京信息工程大学 Device for electrolysing seawater by virtue of optical energy to prepare sodium hypochlorite
CN106591875B (en) * 2016-12-14 2019-03-12 南京信息工程大学 The device of sodium hypochlorite is produced using luminous energy electrolytic seawater
CN108249527A (en) * 2018-02-08 2018-07-06 黄山市雅龙智能科技有限公司 A kind of high slat-containing wastewater processing unit
CN108423771A (en) * 2018-03-29 2018-08-21 砺剑防务技术集团有限公司 electrolytic seawater antifouling system
CN109371417A (en) * 2018-12-24 2019-02-22 成都科佑达技术开发有限公司 A kind of sodium hypochlorite electrolytic preparation device
CN109371417B (en) * 2018-12-24 2023-10-27 成都科佑达技术开发有限公司 Sodium hypochlorite electrolytic preparation device
CN111809194A (en) * 2020-05-28 2020-10-23 宁波英德菲尔机械科技有限公司 Portable household hypochlorous acid water manufacturing instrument

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