CN106590202A - Anti-cracking exterior wall coating used for building - Google Patents
Anti-cracking exterior wall coating used for building Download PDFInfo
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- CN106590202A CN106590202A CN201611182879.1A CN201611182879A CN106590202A CN 106590202 A CN106590202 A CN 106590202A CN 201611182879 A CN201611182879 A CN 201611182879A CN 106590202 A CN106590202 A CN 106590202A
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- building
- acrylic acid
- exterior coating
- crack resistence
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of building coating, and in particular relates to an anti-cracking exterior wall coating used for a building. The exterior wall coating comprises the following components in parts by weight: 25-34 parts of styrene-acrylic emulsion, 12-15 parts of methyl acrylate, 10-15 parts of acrylic modified alky resin, 3-5 parts of dimethyl dichlorosilane, 3-5 parts of unsaturated polyester resin, 7-9 parts of bisphenol A diglycidyl ether, 1-3 parts of ground calcium carbonate powder, 2-5 parts of sodium bentonite, 0.5-1.5 parts of sepiolite fiber, 1-1.5 parts of zinc oxide, 3-5 parts of magnesium stearate, 0.3-0.5 part of triglycidyl isocyanurate, 0.3-0.5 part of diethylenetriamine, 5-10 parts of water and 1-3 parts of other auxiliaries. The exterior wall coating provided by the invention has excellent ageing-resistant performance so as to have better anti-cracking performance, has better water resistance so as to be incapable of being damp easily, has stronger bonding power so as to be incapable of falling off easily and has better stability so as to be incapable of cracking easily.
Description
Technical field
The present invention relates to building coating technical field, and in particular to a kind of exterior coating for building of crack resistence.
Background technology
Wall covering is referred to be decorated for building wall and protects, and makes building wall beautiful and clean, while also can rise
To protection building wall, extend the effect of its service life.Wall covering presses building wall classification includes interior wall coating and exterior wall
Coating two large divisions.Interior wall coating focuses on decoration and environmental protection；Exterior coating is focused on protecting and durable.Wall covering except itself
Outside decoration and protective effect, also to rich and varied, fashion, health environment-friendly trend development.It is desirable to decorative effect streamer is overflow
Color magnificent mansion, elegant, romance, warmth；Also it is more desirable to that material itself is pollution-free, health environment-friendly, individual character and rich vertical
Body-sensing.
The wall face of building is mainly decorated and protected to exterior coating, is that building appearance is neat and artistic, so as to reach
The purpose of beautifying urban environment.Can play a part of to protect skin wall simultaneously, extend use time, it is good so as to obtain
Decoration well and protected effect.Decoration of exterior wall is directly exposed to the Nature, undergoes the invasion and attack of wind, rain, Exposure to Sunlight, therefore requires that coating has
Water-fast, guarantor's color, anti-pollution, ageing-resistant and good adhesive force, while should also have, freeze-thaw resistance is good, the spy that film-forming temperature is low
Point.Exterior coating can be protected due to year in year out in the external wall among drenching with rain of exposing to the weather, it is necessary to have good enough
Resistance to water, weatherability, stain resistance and freeze-thaw resistance, just can guarantee that preferable decorative effect and durability.
Current exterior coating is after experience is exposed to the weather, although its ageing resistance enough, but in its theoretical longevity
Within life, but can Jing often have the phenomenon of cracking.A kind of comprehensive life of coating, is not only decided by its theoretical aging resistance
Performance, it is often more important that the anti-cracking performance after constructing with it, the excellent coating of a kind of anti-cracking performance, it is possible to increase coating
Life-span short slab after construction, improves the comprehensive life of coating.
The content of the invention
The invention aims to solve the above problems, there is provided a kind of exterior coating for building of crack resistence.
In order to reach foregoing invention purpose, the present invention is employed the following technical solutions：
A kind of exterior coating for building of crack resistence, the exterior coating count by weight including：Styrene-acrylic emulsion 25-34 parts,
Acrylic acid methyl ester. 12-15 parts, acrylic acid modified alkyd resin 10-15 parts, dimethyldichlorosilane 3-5 parts, unsaturated polyester (UP) tree
Fat 3-5 parts, bisphenol A diglycidyl ether 7-9 parts, dicalcium powder 1-3 parts, sodium bentonite 2-5 parts, sepiolite fibre 0.5-1.5
Part, Zinc Oxide 1-1.5 part, magnesium stearate 3-5 part, isocyanuric acid three-glycidyl ester 0.3-0.5 parts, diethylenetriamines 0.3-
0.5 part, water 5-10 parts, other auxiliary agents 1-3 parts.
Jing is studied, using based on styrene-acrylic emulsion, acrylic acid methyl ester. and acrylic acid modified alkyd resin, by with diformazan
After base dichlorosilane, unsaturated polyester resin and bisphenol A diglycidyl ether compounding, the anti-of exterior coating can be effectively improved and opened
Fragility energy.The cooperation that this case passes through isocyanuric acid three-glycidyl ester and diethylenetriamines, reaches oxidation drying and chemistry is dry
It is dry to combine, the ratio of each component after coating coating can be effectively kept, prevent the organic constituentses in film forming procedure from volatilizing
Degraded.Wherein, dicalcium powder can not only improve the hardness of film forming, and sodium bentonite can be aided in improve the gloss after film forming
And ageing-resistant performance.Meanwhile, sodium bentonite can change the rheological property of coating.The specific surface area of sepiolite fibre is high, hole
Gap rate is big, possesses very strong absorption and catalytic capability, the cohesive force after coating film forming can not only be improved, while can also improve
Adhesion after film forming, it is to avoid cracking, furthermore it is also possible to promote dimethyldichlorosilane, unsaturated polyester resin and bisphenol-A two
The complex role of glycidyl ether.
Further, the unsaturated polyester resin is 80-110.
Further, the exterior coating count by weight including：Styrene-acrylic emulsion 27-30 parts, acrylic acid methyl ester. 13-14
Part, acrylic acid modified alkyd resin 10-12 parts, dimethyldichlorosilane 3-5 parts, unsaturated polyester resin 3-5 parts, bisphenol-A two
Glycidyl ether 7-8 parts, dicalcium powder 1-3 parts, sodium bentonite 2-5 parts, sepiolite fibre 0.5-1.5 parts, Zinc Oxide 1-1.5
Part, magnesium stearate 3-5 part, isocyanuric acid three-glycidyl ester 0.3-0.5 parts, water 5-10 parts, diethylenetriamines 0.3-0.4
Part, other auxiliary agents 1-3 parts.
Further, the exterior coating count by weight including：28 parts of styrene-acrylic emulsion, 14 parts of acrylic acid methyl ester., third
12 parts of diluted acid modified alkyd resin, 3 parts of dimethyldichlorosilane, 4 parts of unsaturated polyester resin, bisphenol A diglycidyl ether 7
Part, 1 part of dicalcium powder, 2 parts of sodium bentonite, 0.5 part of sepiolite fibre, 1.5 parts of Zinc Oxide, 3 parts of magnesium stearate, isocyanuric acid three
0.5 part of ethylene oxidic ester, 7 parts of water, 0.3 part of diethylenetriamines, 1 part of other auxiliary agents.
Further, the weight ratio of the styrene-acrylic emulsion, acrylic acid methyl ester. and acrylic acid modified alkyd resin is 2:1-
1.1:0.8-1。
Further, the exterior coating also includes carboxymethyl cellulose 2-4 parts.
Further, the ratio of the carboxymethyl cellulose and unsaturated polyester resin is 1：1-1.5.
Further, the epoxide number of the bisphenol A diglycidyl ether is 0.48-0.5mol/100g.
Further, concrete preparation process is as follows：According to proportioning by styrene-acrylic emulsion, acrylic acid methyl ester., the modified alcohol of acrylic acid
0.5-1h is stirred at 45-50 DEG C after acid resin mixing, dimethyldichlorosilane, unsaturated polyester resin and bisphenol-A is subsequently adding
Diglycidyl ether, and stir, after being then cooled to 20-25 DEG C, dicalcium powder, sodium bentonite, sepiolite fibre, oxidation
Zinc, magnesium stearate, isocyanuric acid three-glycidyl ester, diethylenetriamines and other auxiliary agents, after stirring, after the regulation that adds water
Obtain finished product.
Further, the carboxymethyl cellulose adds fashionable, mixes with water first.
Compared with prior art, beneficial effect is the present invention：Ageing-resistant performance is excellent, and anti-cracking performance is preferable；Resistance to water
Preferably, it is difficult to become damp and rotten；Cohesive force is stronger, difficult for drop-off；Stability is not preferably, easy to crack.
Specific embodiment
Explanation is further described to technical scheme below by specific embodiment.
If without specified otherwise, the raw material employed in embodiments of the invention is raw material commonly used in the art, implements
Method employed in example, is the conventional method of this area.
A kind of exterior coating for building of crack resistence, the exterior coating count by weight including：Styrene-acrylic emulsion 25-34
Part, acrylic acid methyl ester. 12-15 parts, acrylic acid modified alkyd resin 10-15 parts, dimethyldichlorosilane 3-5 parts, unsaturated polyester (UP)
Resin 3-5 parts, bisphenol A diglycidyl ether 7-9 parts, dicalcium powder 1-3 parts, sodium bentonite 2-5 parts, sepiolite fibre 0.5-
1.5 parts, Zinc Oxide 1-1.5 part, magnesium stearate 3-5 part, isocyanuric acid three-glycidyl ester 0.3-0.5 parts, diethylenetriamines
0.3-0.5 parts, water 5-10 parts, other auxiliary agents 1-3 parts.
Other auxiliary agents be pigment, dispersant, defoamer, levelling agent, light stabilizer, antifungus agent, antibacterial in one kind or
It is various.Preferred scheme is：The weight ratio of styrene-acrylic emulsion, acrylic acid methyl ester. and acrylic acid modified alkyd resin is 2:1-1.1:
0.8-1, and the epoxide number of bisphenol A diglycidyl ether is 0.48-0.5mol/100g.
Embodiment 1：
A kind of exterior coating for building of crack resistence, is specifically allocated according to the following ratio：Styrene-acrylic emulsion 25kg, acrylic acid methyl ester.
12kg, acrylic acid modified alkyd resin 10kg, dimethyldichlorosilane 5kg, unsaturated polyester resin 5kg, bisphenol-A two shrink sweet
Oily ether 9kg, dicalcium powder 1kg, sodium bentonite 2kg, sepiolite fibre 0.5kg, Zinc Oxide 1.5kg, magnesium stearate 5kg, isocyanide
Uric acid three-glycidyl ester 0.5kg, water 5kg, diethylenetriamines 0.3kg, other auxiliary agents 1kg, the unsaturated polyester resin
Acid number be 110, the epoxide number of bisphenol A diglycidyl ether is 0.48-0.5mol/100g.
Embodiment 2：
A kind of exterior coating for building of crack resistence, is specifically allocated according to the following ratio：Styrene-acrylic emulsion 34kg, acrylic acid methyl ester.
15kg, acrylic acid modified alkyd resin 15kg, dimethyldichlorosilane 3kg, unsaturated polyester resin 3kg, bisphenol-A two shrink sweet
Oily ether 7kg, dicalcium powder 3kg, sodium bentonite 5kg, sepiolite fibre 1.5kg, Zinc Oxide 1kg, magnesium stearate 3kg, isocyanide urine
Sour three-glycidyl ester 0.3kg, water 10kg, diethylenetriamines 0.5kg, other auxiliary agents 3kg, the unsaturated polyester resin
Acid number is 80, and the epoxide number of bisphenol A diglycidyl ether is 0.48-0.5mol/100g.
Embodiment 3：
A kind of exterior coating for building of crack resistence, is specifically allocated according to the following ratio：Styrene-acrylic emulsion 27kg, acrylic acid methyl ester.
14kg, acrylic acid modified alkyd resin 12kg, dimethyldichlorosilane 3kg, unsaturated polyester resin 5kg, bisphenol-A two shrink sweet
Oily ether 8kg, dicalcium powder 1kg, sodium bentonite 5kg, sepiolite fibre 1.5kg, Zinc Oxide 1kg, magnesium stearate 5kg, isocyanide urine
Sour three-glycidyl ester 0.5kg, water 5kg, diethylenetriamines 0.4kg, other auxiliary agents 3kg.The unsaturated polyester resin
Acid number is 80, and the epoxide number of bisphenol A diglycidyl ether is 0.48-0.5mol/100g.
Embodiment 4：
A kind of exterior coating for building of crack resistence, is specifically allocated according to the following ratio：Styrene-acrylic emulsion 30kg, acrylic acid methyl ester.
13kg, acrylic acid modified alkyd resin 10kg, dimethyldichlorosilane 5kg, unsaturated polyester resin 3kg, bisphenol-A two shrink sweet
Oily ether 7kg, dicalcium powder 3kg, sodium bentonite 2kg, sepiolite fibre 0.5kg, Zinc Oxide 1.5kg, magnesium stearate 3kg, isocyanide
Uric acid three-glycidyl ester 0.3kg, water 10kg, diethylenetriamines 0.3kg, other auxiliary agents 1kg.The unsaturated polyester resin
Acid number be 110, the epoxide number of bisphenol A diglycidyl ether is 0.48-0.5mol/100g.
Embodiment 5：
A kind of exterior coating for building of crack resistence, is specifically allocated according to the following ratio：Styrene-acrylic emulsion 28kg, acrylic acid methyl ester.
14kg, acrylic acid modified alkyd resin 12kg, dimethyldichlorosilane 3kg, unsaturated polyester resin 4kg, bisphenol-A two shrink sweet
Oily ether 7kg, dicalcium powder 1kg, sodium bentonite 2kg, sepiolite fibre 0.5kg, Zinc Oxide 1.5kg, magnesium stearate 3kg, isocyanide
Uric acid three-glycidyl ester 0.5kg, water 7kg, diethylenetriamines 0.3kg, other auxiliary agents 1kg, carboxymethyl cellulose 3kg.Institute
The acid number for stating unsaturated polyester resin is 80-110, and the epoxide number of bisphenol A diglycidyl ether is 0.48-0.5mol/100g.
The concrete preparation process of above-mentioned finished product is as follows：Styrene-acrylic emulsion, acrylic acid methyl ester., acrylic acid are modified according to proportioning
0.5-1h is stirred at 45-50 DEG C after alkyd resin mixing, dimethyldichlorosilane, unsaturated polyester resin and bis-phenol is subsequently adding
A diglycidyl ethers, and stir, after being then cooled to 20-25 DEG C, dicalcium powder, sodium bentonite, sepiolite fibre, oxygen
Change zinc, magnesium stearate, isocyanuric acid three-glycidyl ester, diethylenetriamines and other auxiliary agents, after stirring, add water regulation
After obtain finished product.Wherein, the carboxymethyl cellulose adds fashionable, mixes with water first.
After the coating of five kinds of embodiments is coated using more than, test result see the table below：
Below the preferred embodiment to inventing is illustrated, but the present invention is not limited to the embodiment, is familiar with this
The technical staff in field can also make modification or the replacement of a variety of equivalents on the premise of without prejudice to the invention spirit, this
The modification of a little equivalents or replacement are all contained in the application claim limited range.
Claims (10)
1. the exterior coating for building of a kind of crack resistence, it is characterised in that the exterior coating count by weight including：Phenylpropyl alcohol
Emulsion 25-34 part, acrylic acid methyl ester. 12-15 parts, acrylic acid modified alkyd resin 10-15 parts, dimethyldichlorosilane 3-5 parts,
Unsaturated polyester resin 3-5 parts, bisphenol A diglycidyl ether 7-9 parts, dicalcium powder 1-3 parts, sodium bentonite 2-5 parts, meerschaum
Fiber 0.5-1.5 parts, Zinc Oxide 1-1.5 part, magnesium stearate 3-5 part, isocyanuric acid three-glycidyl ester 0.3-0.5 parts, water 5-
10 parts, diethylenetriamines 0.3-0.5 parts, other auxiliary agents 1-3 parts.
2. a kind of exterior coating for building of crack resistence according to claim 1, it is characterised in that the unsaturated polyester (UP)
The acid number of resin is 80-110.
3. the exterior coating for building of a kind of crack resistence according to claim 1 and 2, it is characterised in that the exterior wall is applied
Material meter by weight includes：Styrene-acrylic emulsion 27-30 parts, acrylic acid methyl ester. 13-14 parts, acrylic acid modified alkyd resin 10-12
Part, dimethyldichlorosilane 3-5 parts, unsaturated polyester resin resin 3-5 parts, bisphenol A diglycidyl ether 7-8 parts, dicalcium powder
1-3 parts, sodium bentonite 2-5 parts, sepiolite fibre 0.5-1.5 parts, Zinc Oxide 1-1.5 part, magnesium stearate 3-5 part, isocyanide urine
Sour three-glycidyl ester 0.3-0.5 parts, water 5-10 parts, diethylenetriamines 0.3-0.4 parts, other auxiliary agents 1-3 parts.
4. the exterior coating for building of a kind of crack resistence according to claim 1 and 2, it is characterised in that the exterior wall is applied
Material meter by weight includes：28 parts of styrene-acrylic emulsion, 14 parts of acrylic acid methyl ester., 12 parts of acrylic acid modified alkyd resin, dimethyl
3 parts of dichlorosilane, 4 parts of unsaturated polyester resin, 7 parts of bisphenol A diglycidyl ether, 1 part of dicalcium powder, 2 parts of sodium bentonite, sea
0.5 part of afrodite fiber, 1.5 parts of Zinc Oxide, 3 parts of magnesium stearate, 0.5 part of isocyanuric acid three-glycidyl ester, 7 parts of water, two sub- second
0.3 part of base triamine, 1 part of other auxiliary agents.
5. the exterior coating for building of a kind of crack resistence according to claim 1, it is characterised in that the styrene-acrylic emulsion,
The weight ratio of acrylic acid methyl ester. and acrylic acid modified alkyd resin is 2:1-1.1:0.8-1.
6. the exterior coating for building of a kind of crack resistence according to claim 1 and 2, it is characterised in that the exterior wall is applied
Material also includes carboxymethyl cellulose 2-4 parts.
7. a kind of exterior coating for building of crack resistence according to claim 6, it is characterised in that the carboxymethyl cellulose
Element is 1 with the ratio of unsaturated polyester resin：1-1.5.
8. a kind of exterior coating for building of crack resistence according to claim 6, it is characterised in that the carboxymethyl cellulose
It is plain plus fashionable, mix with water first.
9. a kind of exterior coating for building of crack resistence according to claim 1 and 2, it is characterised in that the bisphenol-A two
The epoxide number of glycidyl ether is 0.48-0.5mol/100g.
10. the exterior coating for building of a kind of crack resistence according to claim 1 and 2, it is characterised in that concrete to prepare step
It is rapid as follows：To stir at 45-50 DEG C after styrene-acrylic emulsion, acrylic acid methyl ester., the mixing of acrylic acid modified alkyd resin according to proportioning
0.5-1h, is subsequently adding dimethyldichlorosilane, unsaturated polyester resin and bisphenol A diglycidyl ether, and stirs, so
After be cooled to 20-25 DEG C after, dicalcium powder, sodium bentonite, sepiolite fibre, Zinc Oxide, magnesium stearate, isocyanuric acid three shrink
Glyceride, diethylenetriamines and other auxiliary agents, after stirring, after the regulation that adds water finished product are obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611182879.1A CN106590202B (en) | 2016-12-20 | 2016-12-20 | A kind of exterior coating for building of crack resistence |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611182879.1A CN106590202B (en) | 2016-12-20 | 2016-12-20 | A kind of exterior coating for building of crack resistence |
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| Publication Number | Publication Date |
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| CN106590202A true CN106590202A (en) | 2017-04-26 |
| CN106590202B CN106590202B (en) | 2018-11-09 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1557889A (en) * | 2004-02-10 | 2004-12-29 | 方学平 | Water wall paint for external wall |
| CN103937340A (en) * | 2014-04-22 | 2014-07-23 | 苏州羽帆新材料科技有限公司 | Exterior wall coating material and preparation method thereof |
| CN104962187A (en) * | 2015-06-30 | 2015-10-07 | 山东香山装饰工程有限公司 | Anti-cracking coating and preparation method thereof |
| CN105670407A (en) * | 2016-03-29 | 2016-06-15 | 济南高瑞生物科技有限公司 | Exterior wall latex paint and preparation method thereof |
| CN105802362A (en) * | 2016-05-14 | 2016-07-27 | 李文东 | Weatherproof waterproof paint for exterior wall |
-
2016
- 2016-12-20 CN CN201611182879.1A patent/CN106590202B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1557889A (en) * | 2004-02-10 | 2004-12-29 | 方学平 | Water wall paint for external wall |
| CN103937340A (en) * | 2014-04-22 | 2014-07-23 | 苏州羽帆新材料科技有限公司 | Exterior wall coating material and preparation method thereof |
| CN104962187A (en) * | 2015-06-30 | 2015-10-07 | 山东香山装饰工程有限公司 | Anti-cracking coating and preparation method thereof |
| CN105670407A (en) * | 2016-03-29 | 2016-06-15 | 济南高瑞生物科技有限公司 | Exterior wall latex paint and preparation method thereof |
| CN105802362A (en) * | 2016-05-14 | 2016-07-27 | 李文东 | Weatherproof waterproof paint for exterior wall |
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| Publication number | Publication date |
|---|---|
| CN106590202B (en) | 2018-11-09 |
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