CN105860770B - A kind of allochroic paint - Google Patents
A kind of allochroic paint Download PDFInfo
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- CN105860770B CN105860770B CN201610454081.1A CN201610454081A CN105860770B CN 105860770 B CN105860770 B CN 105860770B CN 201610454081 A CN201610454081 A CN 201610454081A CN 105860770 B CN105860770 B CN 105860770B
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- allochroic paint
- iodide
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/26—Thermosensitive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of allochroic paint, including component A and B component, B component is curing agent, component A is composed of the epoxy resin of 50 80% (weight percent), 5 40% response type solvent, 2 30% filler, 0.05 15% auxiliary agent, 2 20% off-color material and 0.01 0.03% antishrinking agent, wherein, contain CoCl in the component of off-color material2, Ag, Cu or Hg iodide, the antishrinking agent is graphene, the present invention overcomes original allochroic paint colour change function poor, the shortcomings that with volatile solvent, solid content reach 100%, and this coating does not have the discharge of organic solvent and chemical emulsifier, vary with temperature color-sensitive, so that difference of the building with temperature, and different colors is presented, realize the purpose beautified the environment.
Description
Technical field
The design paint field of the present invention is related to temperature and changes the coating of color.
Background technology
At present, the electrochromic substance in allochroic paint is generally added to the formulation for coating material of resin composition in the form of microcapsules
In, pass through temperature or illumination variation so that physics or chemical change occur for the off-color material in capsule, so as to which paint film be made to be in
Existing different color, referred to as allochroic paint.Due to coating in film forming procedure along with resin solidification crosslinking and solvent
Volatilization, resin crosslinked has different degrees of contraction, and along with such contraction, the discoloration microcapsules in formulation for coating material will
By pressure break, so as to cause the destruction of allochroic paint colour change function.On the other hand, either common coating or allochroic paint, one
As organic solvent or chemical emulsifier containing volatilization, all can be organic molten during coating application and later stage film harden
Agent or the discharge of emulsifier, cause environmental pollution.
It is learnt from presently disclosed allochroic paint factory formula, the resin that is used from coating divides, and is divided into solvent type discoloration
Coating and aqueous allochroic paint.Wherein solvent based coating uses oil-soluble resin, contains in formula and is not involved in the organic molten of reaction
Agent, organic solvent (VOC) can be evaporate into air during the drying and consolidating of coating, cause atmosphere pollution, welding.Water
Property coating use water-base resin, although without the discharge of VOC, containing being useful for the emulsifiers of emulsifying resins in formula, though
So itself and it is non-volatile, but it is also a kind of organic matter for being not involved in crosslinking coatings curing reaction, exposes to the sun and rain or grows
Phase is exposed in air, this emulsifier can slowly separate out, equally cause environmental pollution.
Invention content
For contraction of the coating in the solidification process that forms a film and the discharge of organic solvent, the present invention is molten using response type
The shortcomings that agent and resistance contracting agent are added in coating system, overcome traditional allochroic paint, reaches and beautifies the environment, energy saving
Purpose.
A kind of allochroic paint, including component A and B component, B component is curing agent, it is characterized in that：Component A is by 50-80%
The epoxy resin of (weight percent), the response type solvent of 5-40%, the filler of 2-30%, 0.05-15% auxiliary agent, 2-20%
Off-color material and 0.01-0.03% antishrinking agents be composed, wherein, contain CoCl in the component of off-color material2、Ag、Cu
Or the iodide of Hg.The off-color material is by hexa and CoCl2, Ag, Cu or Hg iodide mix or
Person is CoCl2, Ag, Cu or Hg iodide mix.
The off-color material is mixed by the iodide of hexa and CoCl2, Ag, Cu or Hg.Can also be
It is mixed by dimethyl diaminophenazine chloride and the iodide of CoCl2, Ag, Cu or Hg.
The preferential dosage of off-color material of the present invention is the 2-10% (weight percent) of component A；The response type is molten
Agent is the mixture of one or more of alkyl glycidyl ether, epoxy propane butyl ether, siloxanes, benzyl alcohol, is preferably
Dosage accounts for the 5-10% (weight percent) of component A；The filler is blanc fixe, precipitated calcium carbonate, powdered whiting, silicon
The mixture of one or more of diatomaceous earth, kaolin, talcum powder, aerosil is preferably the 5- that dosage accounts for component A
10%；Auxiliary agent is the mixture of wetting dispersing agent and antifoaming agent, is preferably the 0.1-1% that dosage accounts for component A.
100 parts of component A of the present invention, 20-80 parts of B component.
Antishrinking agent of the present invention is graphene.
Coating temperature sensor provided by the invention changes color, when summer temperature is higher, skin painting color
Become light color, effective reflected sunlight reduces indoor temperature, reduces air conditioning electricity consumption.When winter temperature is relatively low, outside building
Wall color becomes dark, creates an aesthetic feeling, and the effectively effect for the amount of absorbing solar energy, and improves indoor temperature, saves for thermal energy consumption.
The invention reside in a kind of allochroic paint is disclosed, the shortcomings that original allochroic paint is with volatile solvent is overcome, solid content reaches
100%.Meanwhile this coating does not have the discharge of organic solvent and chemical emulsifier, can change color with temperature so that building
Object and is presented different colors, realizes the purpose beautified the environment with the difference of temperature.
Specific embodiment
Coating provided by the invention is mixed by component A and B component, and wherein B component is the curing agent of this coating.
For coating provided by the present invention using epoxy resin as major ingredient, domestic E51 asphalt mixtures modified by epoxy resin can be selected in the epoxy resin used
The combination of one or more of fat, DOW of America ED28 epoxy resin, Dutch shell EP828 epoxy resin, dosage A
The 50-88% (weight percent) of component.
Response type solvent of the present invention and resin have the similar molecular structure in part, can effectively reduce resin and glue
Degree, and the reactivity as resin is kept, when encountering resin curing agent, can be formed big with curing agent cross-linking reaction
Molecular network structure film forming cures, and does not have any organic emission in film forming procedure.
Below by specific embodiment to the present invention.
Example one：Preparing reddish yellow coating composition composition has
Component A forms：
Epoxy resin：800kg；
Butyl glycidyl ether：79kg；
Benzyl alcohol：18kg；
Blanc fixe：60kg；
Aerosil：5kg；
The mixture 35kg of the iodide of dimethyl diaminophenazine chloride, hexa and Hg；
Wetting dispersing agent：4.499kg；
Antifoaming agent：2kg；
Antishrinking agent：0.001kg.
B component：
1784 curing agent 35kg
The coating gradually becomes yellow with temperature raising between 25 DEG C -28 DEG C from red.
Example two：Prepare powder grey paint component composition
Component A forms：
Epoxy resin ED28：800kg
Epoxy propane butyl ether：250kg；
Benzyl alcohol：136kg；
Powdered whiting：200kg；
Aerosil：10kg；
The iodide of dimethyl diaminophenazine chloride+Ag：150kg；
Wetting dispersing agent：5.999kg；
Antifoaming agent：10kg；
Antishrinking agent：0.001kg.
B component：
1784 curing agent 620kg
The coating gradually becomes grey with temperature raising between 35 DEG C -38 DEG C from pink colour.
Example three：The component for preparing reddish blue coating is formed
Component A forms：
Epoxy resin E51：800kg；
Siloxanes：180kg；
Benzyl alcohol：25kg；
Talcum powder：130kg；
Aerosil：15kg；
Hexa+CoCl2Iodide) 180kg；
Wetting dispersing agent：8.998kg；
Antifoaming agent：16kg；
Antishrinking agent：0.002kg.
B component：
1784 curing agent 670kg
The coating gradually becomes blue with temperature raising between 50 DEG C -53 DEG C from red.
The present invention can also prepare colour mixture coating, example four
Component A forms：
Epoxy resin E51：800kg；
Siloxanes：100kg；
Butyl glycidyl ether：150kg；
Precipitated calcium carbonate：220kg；
Hexa+CoCl2Iodide+Cu iodide 220kg；
Wetting dispersing agent：3.998kg；
Antifoaming agent：8kg；
Antishrinking agent：0.002kg.
B component：
1784 curing agent 900kg.
Present invention ingredient used when preparing coating is not limited only to above-described embodiment and lifts materials and combination, is also not necessarily limited to
State numerical value determined by embodiment.
Response type solvent of the present invention is alkyl glycidyl ether, one kind in epoxy propane butyl ether, siloxanes, benzyl alcohol
Or several mixtures, dosage be component A 5-30%, but its more preferably codomain be 5-10% (weight percent).
The raw material that filler of the present invention uses is except above-mentioned blanc fixe, powdered whiting, precipitated calcium carbonate, gas phase dioxy
Outside SiClx, talcum powder, also diatomite, kaolin take one of which or several combinations, and dosage is the 2-30% of component A,
But its more preferably 5-10% of dosage for component A.
The off-color material that the present invention uses is with dimethyl diaminophenazine chloride, hexa, CoCl2Iodide, Ag iodide,
The mixture of one or more of the iodide of Cu, the iodide of Hg.CoCl can singly be used2, Ag, Cu or Hg iodide in
One kind, wherein two or more metal iodide can also be chosen and mixed colours.But find dimethyl diaminophenazine chloride or six through many experiments
One or more of methenamine and above-mentioned metal iodide are used in mixed way more excellent than metal iodide color is used alone.
The dosage of off-color material can account for the 2-20% of component A, but more preferably dosage is 2-10%.
The auxiliary agent that the present invention uses is wetting dispersing agent and antifoaming agent, and dosage is the 0.05-15% of component A.More preferably
Dosage is 0.05-2%.
For the antishrinking agent that the present invention uses for graphene, dosage can be 0.01-0.03%.
1784 epoxy hardeners that curing agent in B component of the present invention is produced especially suitable for U.S.'s gas companies.Also may be used
To be used by the use of one kind in fatty amine, polyetheramine, imidazoles or a first mixture as curing agent.Component A and B component of the present invention
Consumption proportion be component A：B component=100：20-80 (important ratio), best ratio are 100：30-50.
The preparation method of coating of the present invention is：Response type solvent is added in reaction kettle first, stirring at normal temperature curing
60min；Then epoxy resin is added in continue to stir 15min；Filler, wetting dispersing agent, antifoaming agent are sequentially added, antishrinking agent fills
Divide and stir evenly；Fineness is ground to less than 25 microns by three-roll grinder, is added in off-color material and is stirred through high speed dispersor
The component A of even i.e. structure cost paint；Distribute suitable curing agent, when use, which first mixes component A with B component, is brushed or sprayed
It applies.
The invention reside in a kind of allochroic paint is disclosed, the shortcomings that original allochroic paint is with volatile solvent, discoloration are overcome
Microcapsules will not be destroyed during resin solidification, and solid content reaches 100%.Meanwhile this coating do not have it is organic molten
Agent and the discharge of chemical emulsifier can change color so that with the difference of temperature and different face is presented in building with temperature
Color realizes the purpose beautified the environment.
Claims (8)
1. a kind of allochroic paint, including component A and B component, B component is curing agent, it is characterized in that：A groups are by weight percentage
By the epoxy resin of 50-80%, the response type solvent of 5-40%, the filler of 2-30%, the auxiliary agent of 0.05-15%, 2-20%
Off-color material, 0.01-0.03% antishrinking agents are composed, wherein, the off-color material is with dimethyl diaminophenazine chloride and/or hexa-methylene
Tetramine and the iodide of CoCl2, the iodide of Ag, the iodide of Cu, Hg one or more of iodide iodide mix
It forms.
2. allochroic paint as described in claim 1, it is characterized in that：The dosage of the off-color material is A groups by weight percentage
The 2-10% divided.
3. allochroic paint as described in claim 1, it is characterized in that：The response type solvent is alkyl glycidyl ether, epoxy third
The mixture of one or more of alkane butyl ether, siloxanes, benzyl alcohol, dosage account for the 5- of component A by weight percentage
10%.
4. allochroic paint as described in claim 1, it is characterized in that：The filler is blanc fixe, precipitated calcium carbonate, heavy carbon
The mixture of one or more of sour calcium, diatomite, kaolin, talcum powder, aerosil, dosage account for the 5- of component A
10% weight percent.
5. allochroic paint as claimed in claim 4, it is characterized in that：Auxiliary agent is the mixture of wetting dispersing agent and antifoaming agent, dosage
Account for the 0.1-1% weight percent of component A.
6. the allochroic paint as described in claim 1 or 5, it is characterized in that：100 parts by weight of component A, B component 20-80 parts by weight.
7. allochroic paint as described in claim 1, it is characterized in that：The antishrinking agent is graphene.
8. allochroic paint as claimed in claim 6, it is characterized in that：The antishrinking agent is graphene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610454081.1A CN105860770B (en) | 2016-06-22 | 2016-06-22 | A kind of allochroic paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610454081.1A CN105860770B (en) | 2016-06-22 | 2016-06-22 | A kind of allochroic paint |
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| CN105860770A CN105860770A (en) | 2016-08-17 |
| CN105860770B true CN105860770B (en) | 2018-06-19 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109666376A (en) * | 2018-12-28 | 2019-04-23 | 陕西理工大学 | One kind can stimuli responsive colour change function coating and its preparation method and application |
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|---|---|---|---|---|
| CN106905833A (en) * | 2017-04-05 | 2017-06-30 | 山西大学 | A kind of environmentally friendly allochroic paint with alarm function and preparation method thereof |
| CN106939509B (en) * | 2017-05-10 | 2019-05-28 | 苏州市海朋电子商务有限公司 | Garment Steamer Machine drain valve |
| CN107868559A (en) * | 2017-11-28 | 2018-04-03 | 河北晨阳工贸集团有限公司 | Formula, preparation method and its application method of a kind of water-based antiultraviolet allochroic paint of fabric |
| CN108976993A (en) * | 2018-07-30 | 2018-12-11 | 广东福临门世家智能家居有限公司 | A kind of oiliness insulating moulding coating |
| CN109395676A (en) * | 2018-10-11 | 2019-03-01 | 扬州市祥华新材料科技有限公司 | Cobalt ammonium salt low-temp reversible temperature becomes microscapsule powder and water-based ink and preparation method and application |
| CN110975773A (en) * | 2019-12-17 | 2020-04-10 | 肇庆市海特复合材料技术研究院 | Preparation method of epoxy resin microcapsule with self-repairing function |
| CN112745727A (en) * | 2020-12-29 | 2021-05-04 | 上海戎科特种装备有限公司 | Novel self-adaptive camouflage coating and preparation method and application thereof |
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| CN101760111A (en) * | 2009-11-30 | 2010-06-30 | 北方涂料工业研究设计院 | 300 DEG C-800 DEG C pleochromatic irreversible thermopaint |
| CN105131789A (en) * | 2015-09-23 | 2015-12-09 | 深圳大禹防水工程有限公司 | Cured type waterproof protective and thermochromic paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101401222B1 (en) * | 2013-11-07 | 2014-05-28 | 김태웅 | A reversible changeable coating composition and a method thereof |
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2016
- 2016-06-22 CN CN201610454081.1A patent/CN105860770B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101760111A (en) * | 2009-11-30 | 2010-06-30 | 北方涂料工业研究设计院 | 300 DEG C-800 DEG C pleochromatic irreversible thermopaint |
| CN105131789A (en) * | 2015-09-23 | 2015-12-09 | 深圳大禹防水工程有限公司 | Cured type waterproof protective and thermochromic paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109666376A (en) * | 2018-12-28 | 2019-04-23 | 陕西理工大学 | One kind can stimuli responsive colour change function coating and its preparation method and application |
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| CN105860770A (en) | 2016-08-17 |
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Effective date of registration: 20201209 Address after: 528100 2nd floor, workshop 1, block 63, datangyuan a, Sanshui District, Foshan City, Guangdong Province Patentee after: Guangdong Tai Feng environmental protection coatings Limited by Share Ltd. Address before: 063000 No. 38 Hua Yan Road, North Tangshan City Road, Hebei Patentee before: TANGSHAN College |