CN105860770A - Discoloring paint - Google Patents

Discoloring paint Download PDF

Info

Publication number
CN105860770A
CN105860770A CN201610454081.1A CN201610454081A CN105860770A CN 105860770 A CN105860770 A CN 105860770A CN 201610454081 A CN201610454081 A CN 201610454081A CN 105860770 A CN105860770 A CN 105860770A
Authority
CN
China
Prior art keywords
component
paint
agent
iodide
allochroic paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610454081.1A
Other languages
Chinese (zh)
Other versions
CN105860770B (en
Inventor
张建生
赵玥
李海花
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong Tai Feng environmental protection coatings Limited by Share Ltd.
Original Assignee
Tangshan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tangshan University filed Critical Tangshan University
Priority to CN201610454081.1A priority Critical patent/CN105860770B/en
Publication of CN105860770A publication Critical patent/CN105860770A/en
Application granted granted Critical
Publication of CN105860770B publication Critical patent/CN105860770B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004—Reflecting paints; Signal paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/26—Thermosensitive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a discoloring paint. The discoloring paint comprises a component A and a component B. The component B is a curing agent. The component A is composed of the following ingredients in percentage by weight: 50-80% of epoxy resin, 5-40% of reactive solvent, 2-30% of filler, 0.05-15% of aid, 2-20% of discoloring material and 0.01-0.03% of anti-shrink agent. The discoloring material contains CoCl2 and iodide of Ag, Cu or Hg. The anti-shrink agent is graphene. The discoloring paint overcomes the defects of poor discoloring function and existence of volatile solvents in the original discoloring paint. The solid content reaches 100%. The paint does not have the emissions of any organic solvent or chemical emulsifier, and is sensitive in color along with the temperature changes, so that the building has different colors along with the air temperature, thereby achieving the goal of beautifying the environment.

Description

A kind of allochroic paint
Technical field
The design paint field of the present invention, relates to the coating changing color with temperature.
Background technology
At present, the electrochromic substance in allochroic paint typically joins in the formulation for coating material of resin composition with the form of microcapsule, logical Excess temperature or illumination variation so that the off-color material generation physics in capsule or chemical change, so that paint film presents not Same color, referred to as allochroic paint.Owing to coating cross-links and the volatilization of solvent along with resin solidification in film forming procedure, Resin crosslinks knows from experience the contraction having in various degree, and along with such contraction, the variable color microcapsule in formulation for coating material will be pressed Split, thus cause the destruction of allochroic paint colour change function.On the other hand, either common coating or allochroic paint, typically During organic solvent containing volatilization or chemical emulsifier, coating application and the hardening of later stage film, all can there is organic solvent Or the discharge of emulsifying agent, causes environmental pollution.
Learning from presently disclosed allochroic paint factory formula, the resin used from coating divides, and is divided into solvent-borne type allochroic paint With aqueous allochroic paint.Wherein solvent based coating uses oil-soluble resin, contains the organic solvent being not involved in reaction in formula, During the drying and consolidating of coating, organic solvent (VOC) can evaporate in air, causes atmospheric pollution, welding. Water paint uses water-base resin, although without the discharge of VOC, but containing the emulsifying for emulsifying resins in formula Agent, although itself is the most non-volatile, but it is also a kind of Organic substance being not involved in crosslinking coatings curing reaction, exposes to the sun and rain Or being exposed to for a long time in air, this emulsifying agent can slowly dissociate out, causes environmental pollution equally.
Summary of the invention
For coating contraction in film forming solidification process, and the discharge of organic solvent, the present invention use response type solvent with And opposing contracting agent joins in coating system, the shortcoming overcoming tradition allochroic paint, reach to beautify the environment, save the energy Purpose.
A kind of allochroic paint, including component A and B component, B component is firming agent, it is characterized in that: component A is by 50-80% The epoxy resin of (percentage by weight), the response type solvent of 5-40%, the filler of 2-30%, the auxiliary agent of 0.05-15%, 2-20% Off-color material and 0.01-0.03% antishrinking agent combine, wherein, containing CoCl in the component of off-color material2、Ag、 The iodide of Cu or Hg.Described off-color material is by hexamethylenetetramine and CoCl2, Ag, Cu or Hg iodide mix Conjunction forms, or CoCl2, the iodide of Ag, Cu or Hg mix.
Described off-color material is mixed by the iodide of hexamethylenetetramine with CoCl2, Ag, Cu or Hg.Can also be Mixed by the iodide of dimethyl diaminophenazine chloride with CoCl2, Ag, Cu or Hg.
The 2-10% that preferential consumption is component A (percentage by weight) of off-color material of the present invention；Described response type solvent For the mixture of one or more in alkyl glycidyl ether, epoxy propane butyl ether, siloxanes, benzyl alcohol, it is preferably Consumption accounts for the 5-10% (percentage by weight) of component A；Described filler is blanc fixe, precipitated calcium carbonate, heavy carbonic acid The mixture of one or more in calcium, kieselguhr, Kaolin, Pulvis Talci, aerosil, is preferably consumption and accounts for A The 5-10% of component；Auxiliary agent is the mixture of wetting dispersing agent and defoamer, is preferably consumption and accounts for the 0.1-1% of component A.
Component A of the present invention 100 parts, B component 20-80 part.
Antishrinking agent of the present invention is Graphene.
The coating temperature sensor changes colour that the present invention provides, when summer temperature is higher, skin painting color becomes Light color, effective reflected sunlight, reduces indoor temperature, reduces idle call electricity.When winter temperature is relatively low, outside building Wall color becomes dark, creates an aesthetic feeling, and the effect effectively absorbed solar energy, and improves indoor temperature, saves for heat energy Consumption.The invention reside in open a kind of allochroic paint, overcome original allochroic paint with the shortcoming of volatile solvent, solids content Reach 100%.Meanwhile, this coating does not has the discharge of organic solvent and chemical emulsifier, can change color with temperature, Make building with the difference of temperature, and present different colors, it is achieved the purpose beautified the environment.
Detailed description of the invention
The coating that the present invention provides is mixed by component A and B component, and wherein B component is the firming agent of this coating.
Coating provided by the present invention is with epoxy resin as major ingredient, and the epoxy resin of use can be selected for domestic E51 epoxy resin, LG-DOW ED28 epoxy resin, one or more combinations in Holland's shell EP828 epoxy resin, its consumption is The 50-88% (percentage by weight) of component A.
Response type solvent of the present invention has the molecular structure that part is similar to resin, it is possible to effectively reduce resin viscosity, and Keep the reactivity as resin, when running into resin curing agent, macromole can be formed with firming agent cross-linking reaction Network structure film forming solidifies, and does not has any organic emission in film forming procedure.
Below by specific embodiment to the present invention.
Example one: preparation reddish yellow coating composition is constituted to be had
Component A forms:
Epoxy resin: 800kg；
Butyl glycidyl ether: 79kg；
Benzyl alcohol: 18kg；
Blanc fixe: 60kg；
Aerosil: 5kg；
The mixture 35kg of the iodide of dimethyl diaminophenazine chloride, hexamethylenetetramine and Hg；
Wetting dispersing agent: 4.499kg；
Defoamer: 2kg；
Antishrinking agent: 0.001kg.
B component:
1784 firming agent 35kg
Described coating raises with temperature between 25 DEG C-28 DEG C and is gradually become yellow from redness.
Example two: prepare powder grey paint component and constitute
Component A forms:
Epoxy resin ED28:800kg
Epoxy propane butyl ether: 250kg；
Benzyl alcohol: 136kg；
Ground calcium carbonate: 200kg；
Aerosil: 10kg；
The iodide of dimethyl diaminophenazine chloride+Ag: 150kg；
Wetting dispersing agent: 5.999kg；
Defoamer: 10kg；
Antishrinking agent: 0.001kg.
B component:
1784 firming agent 620kg
Described coating raises with temperature between 35 DEG C-38 DEG C and is gradually become Lycoperdon polymorphum Vitt from pink colour.
Example three: the component of preparation reddish blue coating is constituted
Component A forms:
Epoxy resin E51:800kg；
Siloxanes: 180kg；
Benzyl alcohol: 25kg；
Pulvis Talci: 130kg；
Aerosil: 15kg；
Hexamethylenetetramine+CoCl2Iodide) 180kg；
Wetting dispersing agent: 8.998kg；
Defoamer: 16kg；
Antishrinking agent: 0.002kg.
B component:
1784 firming agent 670kg
Described coating raises with temperature between 50 DEG C-53 DEG C and is gradually become blue from redness.
The present invention can also prepare colour mixture coating, example four
Component A forms:
Epoxy resin E51:800kg；
Siloxanes: 100kg；
Butyl glycidyl ether: 150kg；
Precipitated calcium carbonate: 220kg；
Hexamethylenetetramine+CoCl2The iodide 220kg of iodide+Cu；
Wetting dispersing agent: 3.998kg；
Defoamer: 8kg；
Antishrinking agent: 0.002kg.
B component:
1784 firming agent 900kg.
Present invention composition used when preparing coating is not limited only to the lifted materials of above-described embodiment and combination, is also not necessarily limited to above-mentioned reality Execute numerical value determined by example.
Response type solvent of the present invention be the one in alkyl glycidyl ether, epoxy propane butyl ether, siloxanes, benzyl alcohol or Several mixture, its consumption is the 5-30% of component A, but its more preferably codomain is 5-10% (percentage by weight).
The raw material that filler of the present invention uses is except above-mentioned blanc fixe, ground calcium carbonate, precipitated calcium carbonate, gas phase titanium dioxide Outside silicon, Pulvis Talci, also kieselguhr, Kaolin, take one of which or several combinations, its consumption is the 2-30% of component A, But its more preferably consumption is the 5-10% of component A.
The off-color material that the present invention uses is with dimethyl diaminophenazine chloride, hexamethylenetetramine, CoCl2Iodide, the iodide of Ag, The iodide of Cu, Hg iodide in the mixture of one or more.Can singly use CoCl2, Ag, Cu or Hg One in iodide, it is also possible to choose wherein two or more metal iodide and mix colours.But in many experiments finds Property is red or hexamethylenetetramine is used in mixed way ratio with one or more in above-mentioned metal iodide and is used alone metal iodide Color is more excellent.The consumption of off-color material can account for the 2-20% of component A, but more preferably consumption is 2-10%.
The auxiliary agent that the present invention uses is wetting dispersing agent and defoamer, and its consumption is the 0.05-15% of component A.More preferably consumption For 0.05-2%.
The antishrinking agent that the present invention uses is Graphene, and its consumption can be 0.01-0.03%.
Firming agent in B component of the present invention is particularly well-suited to 1784 epoxy hardeners that U.S.'s gas companies produces.Can also Use as firming agent with a kind of or first mixture in fatty amine, polyetheramine, imidazoles.Component A of the present invention and B group The consumption proportion divided is component A: B component=100:20-80 (important ratio), best ratio is 100:30-50.
The preparation method of coating of the present invention is: first add in reactor by response type solvent, stirring at normal temperature ripening 60min；It is subsequently adding epoxy resin and continues stirring 15min；It is sequentially added into filler, wetting dispersing agent, defoamer, resisted shrinkage Agent stirs；It is ground to fineness through three-roll grinder and is less than 25 microns, add off-color material through high speed dispersor Stir the component A of i.e. structure cost paint；Distribute appropriate firming agent, first component A is mixed with B component during use Brush or spray.
The invention reside in open a kind of allochroic paint, overcome original allochroic paint with the shortcoming of volatile solvent, the micro-glue of variable color Capsule will not be destroyed during resin solidifies, and solids content reaches 100%.Meanwhile, this coating does not has organic solvent And the discharge of chemical emulsifier, color can be changed with temperature so that building is with the difference of temperature, and presents different Color, it is achieved the purpose beautified the environment.

Claims (10)

1. an allochroic paint, including component A and B component, B component is firming agent, it is characterized in that: component A is by 50-80% The epoxy resin of (percentage by weight), the response type solvent of 5-40%, the filler of 2-30%, the auxiliary agent of 0.05-15%, 2-20% Off-color material and 0.01-0.03% antishrinking agent combine, wherein, containing CoCl in the component of off-color material2、Ag、Cu Or the iodide of Hg.Described off-color material is by hexamethylenetetramine and CoCl2, the iodide of Ag, Cu or Hg mix, Or CoCl2, the iodide of Ag, Cu or Hg mix.
2. as claimed in claim 1 allochroic paint, is characterized in that: described off-color material by hexamethylenetetramine and CoCl2, Ag, The iodide of Cu or Hg mix.
3. as claimed in claim 1 allochroic paint, is characterized in that: described off-color material by dimethyl diaminophenazine chloride and CoCl2, Ag, Cu or The iodide of Hg mix.
4. allochroic paint as described in Claims 2 or 3, is characterized in that: the consumption of described off-color material is the 2-10% of component A (percentage by weight).
5. allochroic paint as claimed in claim 4, is characterized in that: described response type solvent is alkyl glycidyl ether, epoxy third The mixture of one or more in alkane butyl ether, siloxanes, benzyl alcohol, its consumption accounts for the 5-10% (weight percent of component A Than).
6. allochroic paint as claimed in claim 5, is characterized in that: described filler is blanc fixe, precipitated calcium carbonate, heavy The mixture of one or more in calcium carbonate, kieselguhr, Kaolin, Pulvis Talci, aerosil, consumption accounts for component A 5-10%.
7. allochroic paint as claimed in claim 6, is characterized in that: auxiliary agent is the mixture of wetting dispersing agent and defoamer, consumption Account for the 0.1-1% of component A.
8. allochroic paint as described in claim 1 or 7, is characterized in that: component A 100 parts, B component 20-80 part.
9. allochroic paint as claimed in claim 1, is characterized in that: described antishrinking agent is Graphene.
10. allochroic paint as claimed in claim 8, is characterized in that: described antishrinking agent is Graphene.
CN201610454081.1A 2016-06-22 2016-06-22 A kind of allochroic paint Active CN105860770B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610454081.1A CN105860770B (en) 2016-06-22 2016-06-22 A kind of allochroic paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610454081.1A CN105860770B (en) 2016-06-22 2016-06-22 A kind of allochroic paint

Publications (2)

Publication Number Publication Date
CN105860770A true CN105860770A (en) 2016-08-17
CN105860770B CN105860770B (en) 2018-06-19

Family

ID=56649941

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610454081.1A Active CN105860770B (en) 2016-06-22 2016-06-22 A kind of allochroic paint

Country Status (1)

Country Link
CN (1) CN105860770B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106905833A (en) * 2017-04-05 2017-06-30 山西大学 A kind of environmentally friendly allochroic paint with alarm function and preparation method thereof
CN106939509A (en) * 2017-05-10 2017-07-11 苏州市海朋电子商务有限公司 Garment Steamer Machine draining valve
CN107868559A (en) * 2017-11-28 2018-04-03 河北晨阳工贸集团有限公司 Formula, preparation method and its application method of a kind of water-based antiultraviolet allochroic paint of fabric
CN108976993A (en) * 2018-07-30 2018-12-11 广东福临门世家智能家居有限公司 A kind of oiliness insulating moulding coating
CN109395676A (en) * 2018-10-11 2019-03-01 扬州市祥华新材料科技有限公司 Cobalt ammonium salt low-temp reversible temperature becomes microscapsule powder and water-based ink and preparation method and application
CN110975773A (en) * 2019-12-17 2020-04-10 肇庆市海特复合材料技术研究院 Preparation method of epoxy resin microcapsule with self-repairing function
CN112745727A (en) * 2020-12-29 2021-05-04 上海戎科特种装备有限公司 Novel self-adaptive camouflage coating and preparation method and application thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109666376B (en) * 2018-12-28 2020-12-04 陕西理工大学 Stimulus-responsive color-changing functional coating and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101760111A (en) * 2009-11-30 2010-06-30 北方涂料工业研究设计院 300 DEG C-800 DEG C pleochromatic irreversible thermopaint
KR101401222B1 (en) * 2013-11-07 2014-05-28 김태웅 A reversible changeable coating composition and a method thereof
CN105131789A (en) * 2015-09-23 2015-12-09 深圳大禹防水工程有限公司 Cured type waterproof protective and thermochromic paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101760111A (en) * 2009-11-30 2010-06-30 北方涂料工业研究设计院 300 DEG C-800 DEG C pleochromatic irreversible thermopaint
KR101401222B1 (en) * 2013-11-07 2014-05-28 김태웅 A reversible changeable coating composition and a method thereof
CN105131789A (en) * 2015-09-23 2015-12-09 深圳大禹防水工程有限公司 Cured type waterproof protective and thermochromic paint and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄颖: "《特种印刷》", 30 September 2006, 化学工业出版社 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106905833A (en) * 2017-04-05 2017-06-30 山西大学 A kind of environmentally friendly allochroic paint with alarm function and preparation method thereof
CN106939509A (en) * 2017-05-10 2017-07-11 苏州市海朋电子商务有限公司 Garment Steamer Machine draining valve
CN106939509B (en) * 2017-05-10 2019-05-28 苏州市海朋电子商务有限公司 Garment Steamer Machine drain valve
CN107868559A (en) * 2017-11-28 2018-04-03 河北晨阳工贸集团有限公司 Formula, preparation method and its application method of a kind of water-based antiultraviolet allochroic paint of fabric
CN108976993A (en) * 2018-07-30 2018-12-11 广东福临门世家智能家居有限公司 A kind of oiliness insulating moulding coating
CN109395676A (en) * 2018-10-11 2019-03-01 扬州市祥华新材料科技有限公司 Cobalt ammonium salt low-temp reversible temperature becomes microscapsule powder and water-based ink and preparation method and application
CN110975773A (en) * 2019-12-17 2020-04-10 肇庆市海特复合材料技术研究院 Preparation method of epoxy resin microcapsule with self-repairing function
CN112745727A (en) * 2020-12-29 2021-05-04 上海戎科特种装备有限公司 Novel self-adaptive camouflage coating and preparation method and application thereof

Also Published As

Publication number Publication date
CN105860770B (en) 2018-06-19

Similar Documents

Publication Publication Date Title
CN105860770A (en) Discoloring paint
CN101845260B (en) Full-aqueous multicolour paint and preparation method thereof
CN106675355B (en) A kind of water alcohol acid coating and preparation method thereof
CN103497338A (en) Preparation and application method of ionic emulsifier special for epoxy resin in waterborne epoxy coating
CN103232787A (en) Aqueous crackle coating
CN109082184A (en) A kind of elastic emulsion paint of high adhesion force
CN114525062A (en) Plant-based colorful real-stone paint marble-imitated coating and preparation method thereof
CN106085133A (en) A kind of novel aqueous graphite-epoxy alkene anticorrosive paint
CN112778860A (en) Reflective heat-insulation sand-containing multicolor paint
CN107513325B (en) A kind of weather-proof epoxy thickness slurry anticorrosive paint and preparation method thereof
CN104004425A (en) Acrylic acid waterborne polyurethane waterproofing coatings and manufacturing technology thereof
CN107955440A (en) A kind of corrosion-resistant water paint
CN106566349A (en) Low-temperature damping paint
CN113122094A (en) Temperature-sensitive color-changing artistic coating and preparation method thereof
CN109400012A (en) A kind of priming paint and the middle imitative clear-water concrete and preparation method thereof for applying unification
CN106883728A (en) A kind of low VOC wet-heat resistings engineering machinery containing zinc sealing wax
CN106752253A (en) A kind of environment-friendly type dissolving power solvent compositions high
CN104830196B (en) One pack system high film build energy water paint and preparation method thereof
CN102977708B (en) Water-soluble stoving varnish suitable for craft glass products and preparation method thereof
CN107629553B (en) Immiscible color liquid
CN112876918A (en) Photochromic water-based paint and preparation method thereof
CN111534231A (en) Wall coating
CN110157282A (en) A kind of high-performance heat-insulating anti-corrosive coating
CN108864872A (en) Aqueous pottery stone coating and preparation method thereof
CN114702885B (en) Quick-drying water-based paint

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20201209

Address after: 528100 2nd floor, workshop 1, block 63, datangyuan a, Sanshui District, Foshan City, Guangdong Province

Patentee after: Guangdong Tai Feng environmental protection coatings Limited by Share Ltd.

Address before: 063000 No. 38 Hua Yan Road, North Tangshan City Road, Hebei

Patentee before: TANGSHAN College

TR01 Transfer of patent right