CN106590097A - Powder coating for shell of electric rice cooker and preparation method thereof - Google Patents

Powder coating for shell of electric rice cooker and preparation method thereof Download PDF

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Publication number
CN106590097A
CN106590097A CN201611100911.7A CN201611100911A CN106590097A CN 106590097 A CN106590097 A CN 106590097A CN 201611100911 A CN201611100911 A CN 201611100911A CN 106590097 A CN106590097 A CN 106590097A
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CN
China
Prior art keywords
parts
pigment
epoxy resin
modified phenolic
phenolic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611100911.7A
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Chinese (zh)
Inventor
曾凡跃
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qinnan District Productivity Promotion Center Qinzhou
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Qinnan District Productivity Promotion Center Qinzhou
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qinnan District Productivity Promotion Center Qinzhou filed Critical Qinnan District Productivity Promotion Center Qinzhou
Priority to CN201611100911.7A priority Critical patent/CN106590097A/en
Publication of CN106590097A publication Critical patent/CN106590097A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a powder coating for a shell of an electric rice cooker and a preparation method thereof. The powder coating consists of the following formula components in parts by mass: 30-50 parts of epoxy resin, 8-10 parts of tetraethylammonium tetrafluoroborate, 6-8 parts of talc powder, 1-3 parts of rosin modified phenolic resin, 2-4 parts of trifluoroacetylacetone cobalt, 2-6 parts of silicone oil, 4-8 parts of hexamethylenediamine, 1-3 parts of p-tert-pentylphenol, 6-10 parts of titanium dioxide, 5-7 parts of dicumyl peroxide, 10-12 parts of kaolin, 7-9 parts of paraffin, 3-5 parts of methyl methacrylate, and 1-2 parts of pigment. The powder coating disclosed by the invention has the advantages of being high-temperature-resistant, good in flame retardance, good in insulating property, low in curing temperature, short in curing time, good in film coating leveling property, strong in adhesion force, good in film coating appearance, acid and alkali resistant, capable of purifying indoor air, capable of being used on household appliances including electromagnetic ovens, microwave ovens, baking ovens, electric rice cookers and the like.

Description

A kind of electric cooker shell powdery paints and preparation method thereof
Technical field
The present invention relates to paint field, in particular to a kind of electric cooker shell powdery paints and preparation method thereof.
Background technology
With the progress and the development of modern industry of modern science and technology so that problem of environmental pollution becomes increasingly to dash forward Go out, it gives people class itself and environment for the survival of mankind causes greatly threat.Traditional coating was either being manufactured Substantial amounts of poisonous and hazardous waste gas and waste water can be produced in journey or in using work progress, they can be to environment, air And water resource is polluted, especially solvent based coating can discharge VOC (VOC) to big in work progress In gas, its amount has reached more than 50% and has caused serious second to pollute.This problem causes the attention of many industrial countries. Powdery paints has obtained extensive in recent years in terms of various fields particularly coated metal as a class environmental type coating Using.
Powdery paints often using organic resins such as epoxy, polyester, acrylic acid, polyurethane as matrix, due to by matrix resin The impact and restriction of self structure, these conventional powdery paints have weak point in some performances, result in what is used Limitation.
The content of the invention
The invention provides a kind of electric cooker shell powdery paints and preparation method thereof, not only using effect is steady for the present invention Fixed, resistance to corrosion is strong, surface is not easily damaged, and with good wear-resisting and stampability energy, can significantly extend use It is life-span, safe to the human body nontoxic.
For achieving the above object, the present invention provides following technical scheme:
A kind of electric cooker shell powdery paints and preparation method thereof, is made up of following mass fraction formula components:Epoxy Resin 30-50 parts, ttraethylammonium tetrafluoroborate 8-10 parts, Pulvis Talci 6-8 parts, rosin modified phenolic resin 1-3 parts, trifluoroacetyl third Ketone cobalt 2-4 parts, silicone oil 2-6 parts, hexamethylene diamine 4-8 parts, p-tert-amylphenol 1-3 parts, titanium dioxide 6-10 parts, cumyl peroxide 5-7 parts, Kaolin 10-12 parts, paraffin 7-9 parts, methyl methacrylate 3-5 parts, pigment 1-2 parts.
Further:It is made up of following mass fraction formula components:30 parts of epoxy resin, 8 parts of ttraethylammonium tetrafluoroborate, Talcum 6 parts of powder, 1 part of rosin modified phenolic resin, 2 parts of trifluoroacetylacetone (TFA) cobalt, 2 parts of silicone oil, 4 parts of hexamethylene diamine, p-tert-amylphenol 1 Part, 6 parts of titanium dioxide, 5 parts of cumyl peroxide, 10 parts of Kaolin, 7 parts of paraffin, 3 parts of methyl methacrylate, 1 part of pigment.
Further:It is made up of following mass fraction formula components:40 parts of epoxy resin, 9 parts of ttraethylammonium tetrafluoroborate, Talcum 7 parts of powder, 2 parts of rosin modified phenolic resin, 3 parts of trifluoroacetylacetone (TFA) cobalt, 4 parts of silicone oil, 6 parts of hexamethylene diamine, p-tert-amylphenol 2 Part, 8 parts of titanium dioxide, 6 parts of cumyl peroxide, 11 parts of Kaolin, 8 parts of paraffin, 4 parts of methyl methacrylate, pigment 1.5 Part.
Further:It is made up of following mass fraction formula components:50 parts of epoxy resin, 10 parts of ttraethylammonium tetrafluoroborate, cunning 8 parts of stone powder, 3 parts of rosin modified phenolic resin, 4 parts of trifluoroacetylacetone (TFA) cobalt, 6 parts of silicone oil, 8 parts of hexamethylene diamine, p-tert-amylphenol 3 Part, 10 parts of titanium dioxide, 7 parts of cumyl peroxide, 12 parts of Kaolin, 9 parts of paraffin, 5 parts of methyl methacrylate, 2 parts of pigment.
Further:Preparation method of the present invention has following steps:
Step one, first by 100-120 DEG C of epoxy resin, rosin modified phenolic resin and pigment heating 2-3 hours;
Step 2, step one is placed into soak in 8-10% sodium hydroxide solutions 3-4 hours, pulled out, deionized water Rinse as neutrality;
Step 3, add surplus stock in step 2,1.5-2.5 hours, 50-60 point of insulation are stirred at 60-80 DEG C Clock;
Step 4, drying, crush, and make superfines and have both obtained finished product.
The invention has the beneficial effects as follows:
1st, the present invention has high temperature resistant, good flame resistance, good insulating, while solidification temperature is low;
2nd, hardening time is short, film good leveling property, and adhesive force is strong, appearance of film is good, acid and alkali-resistance;
3rd, can purify the air of a room, can be used on the household appliances such as electromagnetic oven, microwave oven, baking box, electric cooker.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention Embodiment, the every other embodiment obtained under the premise of creative work is not made by those of ordinary skill in the art, all Belong to the scope of protection of the invention.
Embodiment one:
A kind of electric cooker shell powdery paints is made up of following mass fraction formula components:Epoxy resin 30-50 parts, four Fluoboric acid triethylammonium tetrakis 8-10 parts, Pulvis Talci 6-8 parts, rosin modified phenolic resin 1-3 parts, trifluoroacetylacetone (TFA) cobalt 2-4 parts, silicone oil 2-6 parts, hexamethylene diamine 4-8 parts, p-tert-amylphenol 1-3 parts, titanium dioxide 6-10 parts, cumyl peroxide 5-7 parts, Kaolin 10-12 parts, paraffin 7-9 parts, methyl methacrylate 3-5 parts, pigment 1-2 parts.
Embodiment two:
A kind of electric cooker shell powdery paints is made up of following mass fraction formula components:30 parts of epoxy resin, tetrafluoro 8 parts of boric acid triethylammonium tetrakis, 6 parts of Pulvis Talci, 1 part of rosin modified phenolic resin, 2 parts of trifluoroacetylacetone (TFA) cobalt, 2 parts of silicone oil, hexamethylene diamine 4 Part, 1 part of p-tert-amylphenol, 6 parts of titanium dioxide, 5 parts of cumyl peroxide, 10 parts of Kaolin, 7 parts of paraffin, methacrylic acid 3 parts of methyl ester, 1 part of pigment.
Embodiment three:
A kind of electric cooker shell powdery paints is made up of following mass fraction formula components:40 parts of epoxy resin, tetrafluoro 9 parts of boric acid triethylammonium tetrakis, 7 parts of Pulvis Talci, 2 parts of rosin modified phenolic resin, 3 parts of trifluoroacetylacetone (TFA) cobalt, 4 parts of silicone oil, hexamethylene diamine 6 Part, 2 parts of p-tert-amylphenol, 8 parts of titanium dioxide, 6 parts of cumyl peroxide, 11 parts of Kaolin, 8 parts of paraffin, methacrylic acid 4 parts of methyl ester, 1.5 parts of pigment.
Example IV:
A kind of electric cooker shell powdery paints is made up of following mass fraction formula components:50 parts of epoxy resin, tetrafluoro 10 parts of boric acid triethylammonium tetrakis, 8 parts of Pulvis Talci, 3 parts of rosin modified phenolic resin, 4 parts of trifluoroacetylacetone (TFA) cobalt, 6 parts of silicone oil, hexamethylene diamine 8 parts, 3 parts of p-tert-amylphenol, 10 parts of titanium dioxide, 7 parts of cumyl peroxide, 12 parts of Kaolin, 9 parts of paraffin, metering system 5 parts of sour methyl ester, 2 parts of pigment.
Embodiment five:
A kind of preparation method preparation method of electric cooker shell powdery paints comprises the steps:
Step one, first by 100-120 DEG C of epoxy resin, rosin modified phenolic resin and pigment heating 2-3 hours;
Step 2, step one is placed into soak in 8-10% sodium hydroxide solutions 3-4 hours, pulled out, deionized water Rinse as neutrality;
Step 3, add surplus stock in step 2,1.5-2.5 hours, 50-60 point of insulation are stirred at 60-80 DEG C Clock;
Step 4, drying, crush, and make superfines and have both obtained finished product.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of description is only that those skilled in the art should for clarity Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art Understandable other embodiment.

Claims (5)

1. a kind of electric cooker shell powdery paints, it is characterised in that:It is made up of following mass fraction formula components:
Epoxy resin 30-50 parts, ttraethylammonium tetrafluoroborate 8-10 parts, Pulvis Talci 6-8 parts, rosin modified phenolic resin 1-3 parts, three Acetyl fluoride acetone cobalt 2-4 parts, silicone oil 2-6 parts, hexamethylene diamine 4-8 parts, p-tert-amylphenol 1-3 parts, titanium dioxide 6-10 parts, peroxidating Diisopropylbenzene (DIPB) 5-7 parts, Kaolin 10-12 parts, paraffin 7-9 parts, methyl methacrylate 3-5 parts, pigment 1-2 parts.
2. a kind of electric cooker shell powdery paints according to claim 1, it is characterised in that:Matched somebody with somebody by following mass fraction Side is into being grouped into:
30 parts of epoxy resin, 8 parts of ttraethylammonium tetrafluoroborate, 6 parts of Pulvis Talci, 1 part of rosin modified phenolic resin, trifluoroacetylacetone (TFA) 2 parts of cobalt, 2 parts of silicone oil, 4 parts of hexamethylene diamine, 1 part of p-tert-amylphenol, 6 parts of titanium dioxide, 5 parts of cumyl peroxide, Kaolin 10 Part, 7 parts of paraffin, 3 parts of methyl methacrylate, 1 part of pigment.
3. a kind of electric cooker shell powdery paints according to claim 1, it is characterised in that:Matched somebody with somebody by following mass fraction Side is into being grouped into:
40 parts of epoxy resin, 9 parts of ttraethylammonium tetrafluoroborate, 7 parts of Pulvis Talci, 2 parts of rosin modified phenolic resin, trifluoroacetylacetone (TFA) 3 parts of cobalt, 4 parts of silicone oil, 6 parts of hexamethylene diamine, 2 parts of p-tert-amylphenol, 8 parts of titanium dioxide, 6 parts of cumyl peroxide, Kaolin 11 Part, 8 parts of paraffin, 4 parts of methyl methacrylate, 1.5 parts of pigment.
4. a kind of electric cooker shell powdery paints according to claim 1, it is characterised in that:Matched somebody with somebody by following mass fraction Side is into being grouped into:
50 parts of epoxy resin, 10 parts of ttraethylammonium tetrafluoroborate, 8 parts of Pulvis Talci, 3 parts of rosin modified phenolic resin, trifluoroacetyl third 4 parts of ketone cobalt, 6 parts of silicone oil, 8 parts of hexamethylene diamine, 3 parts of p-tert-amylphenol, 10 parts of titanium dioxide, 7 parts of cumyl peroxide, Kaolin 12 parts, 9 parts of paraffin, 5 parts of methyl methacrylate, 2 parts of pigment.
5. a kind of a kind of preparation method of electric cooker shell powdery paints according to claim 1, it is characterised in that:Bag Include following steps:
Step one, first by 100-120 DEG C of epoxy resin, rosin modified phenolic resin and pigment heating 2-3 hours;
Step 2, step one is placed into soak in 8-10% sodium hydroxide solutions 3-4 hours, pulled out, deionized water is rinsed For neutrality;
Step 3, add surplus stock in step 2,1.5-2.5 hours are stirred at 60-80 DEG C, 50-60 minutes are incubated;
Step 4, drying, crush, and make superfines and have both obtained finished product.
CN201611100911.7A 2016-12-05 2016-12-05 Powder coating for shell of electric rice cooker and preparation method thereof Pending CN106590097A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN106590097A true CN106590097A (en) 2017-04-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107234403A (en) * 2017-07-29 2017-10-10 合肥海宝节能科技有限公司 A kind of manufacture method of environment protection type box

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103122159A (en) * 2012-12-27 2013-05-29 南通市海顺化工有限公司 Metallic paint
CN105860776A (en) * 2016-06-08 2016-08-17 合肥市燕美粉末涂料有限公司 Powder coating for washing machine shell and preparation method of powder coating
CN105907251A (en) * 2016-06-08 2016-08-31 合肥市燕美粉末涂料有限公司 Powder paint for outer shell of electric cooker and preparing method of powder paint
CN105949956A (en) * 2016-06-08 2016-09-21 合肥市燕美粉末涂料有限公司 Powder coating for computer mainframe shell and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103122159A (en) * 2012-12-27 2013-05-29 南通市海顺化工有限公司 Metallic paint
CN105860776A (en) * 2016-06-08 2016-08-17 合肥市燕美粉末涂料有限公司 Powder coating for washing machine shell and preparation method of powder coating
CN105907251A (en) * 2016-06-08 2016-08-31 合肥市燕美粉末涂料有限公司 Powder paint for outer shell of electric cooker and preparing method of powder paint
CN105949956A (en) * 2016-06-08 2016-09-21 合肥市燕美粉末涂料有限公司 Powder coating for computer mainframe shell and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107234403A (en) * 2017-07-29 2017-10-10 合肥海宝节能科技有限公司 A kind of manufacture method of environment protection type box

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