CN102206445B - Heat insulating coating surface glue and heat insulating coating - Google Patents
Heat insulating coating surface glue and heat insulating coating Download PDFInfo
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- CN102206445B CN102206445B CN 201110132597 CN201110132597A CN102206445B CN 102206445 B CN102206445 B CN 102206445B CN 201110132597 CN201110132597 CN 201110132597 CN 201110132597 A CN201110132597 A CN 201110132597A CN 102206445 B CN102206445 B CN 102206445B
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- 239000003292 glue Substances 0.000 title claims abstract description 40
- 239000011248 coating agent Substances 0.000 title claims abstract description 37
- 238000000576 coating method Methods 0.000 title claims abstract description 37
- 238000009413 insulation Methods 0.000 claims abstract description 27
- 229920005989 resin Polymers 0.000 claims description 39
- 239000011347 resin Substances 0.000 claims description 39
- 239000000843 powder Substances 0.000 claims description 30
- 239000011159 matrix material Substances 0.000 claims description 24
- 229920001971 elastomer Polymers 0.000 claims description 22
- 239000004922 lacquer Substances 0.000 claims description 20
- 238000010422 painting Methods 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 18
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 12
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical group CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 12
- 239000003822 epoxy resin Substances 0.000 claims description 12
- 229920000647 polyepoxide Polymers 0.000 claims description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 12
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 11
- 239000012752 auxiliary agent Substances 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 9
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- -1 aldehyde ketone Chemical class 0.000 claims description 6
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000000395 magnesium oxide Substances 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 235000010215 titanium dioxide Nutrition 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 241001595840 Margarites Species 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229920003180 amino resin Polymers 0.000 claims description 3
- 239000011324 bead Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052630 margarite Inorganic materials 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 9
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000012298 atmosphere Substances 0.000 abstract description 2
- 239000003317 industrial substance Substances 0.000 abstract description 2
- 239000011247 coating layer Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 6
- 230000032683 aging Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- 238000002310 reflectometry Methods 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- AEEAZFQPYUMBPY-UHFFFAOYSA-N [I].[W] Chemical compound [I].[W] AEEAZFQPYUMBPY-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000005494 tarnishing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses heat insulating coating surface glue for insulating heat through reflection and heat conversion. Based on reflection and heat insulation, a heat converting material is added into the heat insulating coating surface glue, after being absorbed by a coating layer, part of unreflected heat energy can be converted by the heat converting material into radiant energy to be released into the atmosphere, thus, 98% of heat from the sun can be insulated. The invention also provides a heat insulating coating which comprises the surface glue, intermediate glue and bottom glue, has excellent heat insulating performance, and can be used for remarkably reducing the temperature of buildings, industrial chemicals tanks and various equipments requiring heat insulation and reducing the energy consumption for temperature reduction.
Description
Technical field
The present invention relates to a kind of coating, be specifically related to a kind of by heat insulation lacquer painting glue and the thermal insulating coating of reflection with the isolated heat of thermal conversion.
Background technology
Because envrionment temperature continues to rise and the energy consumption problem, heat-insulating and energy-saving has become a social concern that attracts people's attention.Traditional cooling and insulating method with spray water and brushing silver paint because complex operation, energy consumption are large, and easily causes equipment corrosion, reduces the work-ing life of equipment, can not satisfy the demand of cooling and insulating far away.So lagging material has wide market outlook.Lagging material of the prior art is generally the weighting material that has high-reflectivity by adding, and makes the coating of its formation have high-reflectivity, reduces the surface temperature of object by reflection, produces heat-blocking action thereby further reduce internal temperature.Because the reflectivity of these lagging materials all can not reach 100%, therefore still can the coated Surface absorption of some heat that is not reflected, and put aside in coating inner by thermaltransmission mode, time one is long, the heat energy of savings is more and more, the coating temperature raises, and easily causes staining of coating, thereby affects effect of heat insulation.
Summary of the invention
For solving the shortcoming that exists in prior art, the invention provides a kind of heat insulation lacquer painting glue.In addition, the invention also discloses a kind of thermal insulating coating that is consisted of by above-mentioned heat insulation lacquer painting glue and intermediate rubber, primer.
The technical solution used in the present invention is:
A kind of heat insulation lacquer painting glue contains properties-correcting agent vinyl cyanide expanding powder 15～20 weight parts, matrix material 40～65 weight parts, color stuffing 20～25 weight parts, solvent 20～35 weight parts.
Preferably, described heat insulation lacquer painting glue also contains auxiliary agent dibutyl phthalate 3～8 weight parts.
Preferably, described matrix material is any one or more than one the combination in chlorinated rubber resin, butadiene styrene rubber resin, 422# maleficent acid resin, chloroprene rubber resin, epoxy resin, aldehyde ketone resin, aminoresin.
Preferably, described color stuffing is any one or more than one the combination in rutile titanium white powder, coating margarite powder, ceramic fine bead, silicon carbide.
Preferably, described solvent is any one or more than one the combination in dimethylbenzene, N-BUTYL ACETATE.
Preferably, described matrix material is comprised of chlorinated rubber resin 20～40 weight parts, butadiene styrene rubber resin 5～10 weight parts, 422# maleficent acid resin 6～10 weight parts.
Preferably, described matrix material is comprised of chlorinated rubber resin 30～40 weight parts, chloroprene rubber resin 20～25 weight parts, epoxy resin 2～5 weight parts.
A kind of thermal insulating coating is made of face glue, intermediate rubber and primer, wherein:
Described glue is above-mentioned heat insulation lacquer painting glue;
Described intermediate rubber contains properties-correcting agent vinyl cyanide expanding powder 10
～20 weight parts, matrix material 25～35 weight parts, color stuffing 20～45 weight parts, solvent 30～40 weight parts;
Described primer contains matrix material 30～40 weight parts, color stuffing 20～45 weight parts, auxiliary agent 6～13 weight parts, solvent 35～45 weight parts.
Preferably, the matrix material in described intermediate rubber is organosilicon modified crylic acid resin and E44 epoxy resin; Color stuffing is any one or more than one the combination in rutile titanium white powder, zinc oxide, nano level magnesium oxide, nanometer grade silica, nano silicone calcium powder, nano level silicic acid aluminium powder; Solvent is any one or more than one the combination in ethanol, vinyl acetic monomer.
Preferably, the matrix material in described primer is any one or more than one the combination in chloroprene rubber resin, HCPE, aldehyde ketone resin, E44 epoxy resin; Color stuffing is any one or more than one the combination in red iron oxide, mica iron oxide red, aluminium triphosphate, process white, super fine magnesia; Auxiliary agent is any one or more than one the combination in clorafin, dibutyl phthalate, urotropine; Solvent is any one or more than one the combination in dimethylbenzene, N-BUTYL ACETATE, vinyl acetic monomer.
The present invention has following beneficial effect:
(1) heat insulation lacquer painting glue of the present invention, on the basis that adds emission and lagging material, having added the thermal conversion material, is exactly in the situation that the most of heat energy of reflection, and the heat energy that is not reflected of part can be by the thermal conversion material in coating, it is the vinyl cyanide expanding powder, be converted into radiating capacity and discharge into the atmosphere, not accumulation of heat of coating has improved the effect of heat insulation of coating widely, and coating is difficult for tarnishing, and has extended the work-ing life of coating;
(2) thermal insulating coating of the present invention is to be made of heat insulating and corrosion primer, low heat conduction intermediate rubber and high reflection resistant face glue, and this thermal insulating coating can be by reflection and thermal conversion isolated 98
%From the heat of sunlight, can be used for significantly reducing the temperature of the heat insulation equipment of buildings, industrial chemicals tank and various needs, reduce the cooling power consumption.
(3) thermal insulating coating anti-corrosion capability of the present invention is strong, and acid-fast alkali-proof can not only play heat insulation effect, can also play certain provide protection to buildings and equipment, increases the service life.
Embodiment
The technical solution used in the present invention is:
A kind of heat insulation lacquer painting glue contains properties-correcting agent vinyl cyanide expanding powder 15～20 weight parts, matrix material 40～65 weight parts, color stuffing 20～25 weight parts, solvent 20～35 weight parts.
Preferably, described heat insulation lacquer painting glue also contains auxiliary agent dibutyl phthalate 3～8 weight parts.
Preferably, described matrix material is any one or more than one the combination in chlorinated rubber resin, butadiene styrene rubber resin, 422# maleficent acid resin, chloroprene rubber resin, epoxy resin, aldehyde ketone resin, aminoresin.
Preferably, described color stuffing is any one or more than one the combination in rutile titanium white powder, coating margarite powder, ceramic fine bead, silicon carbide.
Preferably, described solvent is any one or more than one the combination in dimethylbenzene, N-BUTYL ACETATE.
Preferably, described matrix material is comprised of chlorinated rubber resin 20～40 weight parts, butadiene styrene rubber resin 5～10 weight parts, 422# maleficent acid resin 6～10 weight parts.
Preferably, described matrix material is comprised of chlorinated rubber resin 30～40 weight parts, chloroprene rubber resin 20～25 weight parts, epoxy resin 2～5 weight parts.
A kind of thermal insulating coating is made of face glue, intermediate rubber and primer, wherein:
Described glue is above-mentioned heat insulation lacquer painting glue;
Described intermediate rubber contains properties-correcting agent vinyl cyanide expanding powder 10
～20 weight parts, matrix material 25
～35 weight parts, color stuffing 20～45 weight parts, solvent 30～40 weight parts;
Described primer contains matrix material 30～40 weight parts, color stuffing 20～45 weight parts, auxiliary agent 6～13 weight parts, solvent 35～45 weight parts.
Preferably, the matrix material in described intermediate rubber is organosilicon modified crylic acid resin and E44 epoxy resin; Color stuffing is any one or more than one the combination in rutile titanium white powder, zinc oxide, nano level magnesium oxide, nanometer grade silica, nano silicone calcium powder, nano level silicic acid aluminium powder; Solvent is any one or more than one the combination in ethanol, vinyl acetic monomer.
Preferably, the matrix material in described primer is any one or more than one the combination in chloroprene rubber resin, HCPE, aldehyde ketone resin, E44 epoxy resin; Color stuffing is any one or more than one the combination in red iron oxide, mica iron oxide red, aluminium triphosphate, process white, super fine magnesia; Auxiliary agent is any one or more than one the combination in clorafin, dibutyl phthalate, urotropine; Solvent is any one or more than one the combination in dimethylbenzene, N-BUTYL ACETATE, vinyl acetic monomer.
Vinyl cyanide expanding powder in the present invention is a kind of nano level hollow expanding powder of vinyl cyanide, available from Japan loose tail Co., Ltd., and model SP10, commodity are called the hollow expanding powder.
Below in conjunction with example, the present invention is further described in detail, but is not limited to this.
Embodiment 1
Table 1 is a preferred version of thermal insulating coating of the present invention, and wherein face glue is a preferred version of heat insulation lacquer painting glue of the present invention:
Embodiment 2
Table 2 is a preferred version of thermal insulating coating of the present invention, and wherein face glue is a preferred version of heat insulation lacquer painting glue of the present invention:
Embodiment 3
Table 3 is a preferred version of thermal insulating coating of the present invention, and wherein face glue is a preferred version of heat insulation lacquer painting glue of the present invention:
Embodiment 4
Table 4 is a preferred version of thermal insulating coating of the present invention, and wherein face glue is a preferred version of heat insulation lacquer painting glue of the present invention:
Embodiment 5
Table 5 is a preferred version of thermal insulating coating of the present invention, and wherein face glue is a preferred version of heat insulation lacquer painting glue of the present invention:
Each component of face glue of above-mentioned 1-5 embodiment after dissolving, mixing, modification, grinding, filtration, is obtained high reflection resistant face glue; Each component of intermediate rubber of above-mentioned 1-5 embodiment after dissolving, mixing, modification, grinding, filtration, is obtained low heat conduction intermediate rubber; Each component of primer of above-mentioned 1-5 embodiment after dissolving, mixing, modification, grinding, filtration, is obtained the heat insulating and corrosion primer.
Performance test: the thermal insulating coating to embodiment 1-5 preparation carries out performance test, and test result is listed in table 6.
The artificial ageing resistance test: (reference standard GB/T1865-1997) carries out the ageing-resistant performance test in artificial ageing-resistant storehouse, compare with the acrylic enamel of buying better performances, the ageing-resistant processing of control sample 600h has the phenomenon of fading, and the ageing-resistant processing of specimen of the present invention 1000h paint film is unchanged.
Heat insulating temperature difference testing: the thermal insulating coating of embodiment 1-5 preparation is coated on the steel plate box outside surface of 0.5 * 0.5 * 0.5m, and steel plate thickness is 5mm, and film thickness is 100 μ m.Be placed on respectively vertical irradiation 30min under the tungsten-iodine lamp bulb the test specimens case of brushing with reference to sample case (brush common silver paint powder), the distance at adjusting bulb and casing top makes in casing upper surface temperature 30min to reach 60 ℃.After being completed, record respectively the test specimens case and with reference to the temperature of sample case inside.Result shows, the internal temperature of test specimens case illustrates that than with reference to the internal temperature low (20 ± 2) of sample case ℃ thermal insulating coating of the present invention has significant effect of heat insulation.
Claims (6)
1. heat insulation lacquer painting glue, it is characterized in that: it contains properties-correcting agent vinyl cyanide expanding powder 15～20 weight parts, matrix material 40～65 weight parts, color stuffing 20～25 weight parts, solvent 20～35 weight parts, auxiliary agent 3～8 weight parts;
Described vinyl cyanide expanding powder is the Japanese loose tail SP10 of Co., Ltd. hollow expanding powder;
Described matrix material is any one or more than one the combination in chlorinated rubber resin, butadiene styrene rubber resin, 422# maleficent acid resin, chloroprene rubber resin, epoxy resin, aldehyde ketone resin, aminoresin;
Described color stuffing is any one or more than one the combination in rutile titanium white powder, coating margarite powder, ceramic fine bead, silicon carbide;
Described solvent is any one or more than one the combination in dimethylbenzene, N-BUTYL ACETATE;
Described auxiliary agent is dibutyl phthalate.
2. a kind of heat insulation lacquer painting glue according to claim 1, it is characterized in that: described matrix material is comprised of chlorinated rubber resin 20～40 weight parts, butadiene styrene rubber resin 5～10 weight parts, 422# maleficent acid resin 6～10 weight parts.
3. a kind of heat insulation lacquer painting glue according to claim 1, it is characterized in that: described matrix material is comprised of chlorinated rubber resin 30～40 weight parts, chloroprene rubber resin 20～25 weight parts, epoxy resin 2～5 weight parts.
4. thermal insulating coating, it is characterized in that: it is made of face glue, intermediate rubber and primer, wherein,
Described glue is the described heat insulation lacquer painting glue of claim 1～3 any one;
Described intermediate rubber contains properties-correcting agent vinyl cyanide expanding powder 10
～20 weight parts, matrix material 25
～35 weight parts, color stuffing 20～45 weight parts, solvent 30～40 weight parts; Described vinyl cyanide expanding powder is the Japanese loose tail SP10 of Co., Ltd. hollow expanding powder;
Described primer contains matrix material 30～40 weight parts, color stuffing 20～45 weight parts, auxiliary agent 6～13 weight parts, solvent 35～45 weight parts.
5. a kind of thermal insulating coating according to claim 4, it is characterized in that: the matrix material in described intermediate rubber is organosilicon modified crylic acid resin and E44 epoxy resin; Color stuffing is any one or more than one the combination in rutile titanium white powder, zinc oxide, nano level magnesium oxide, nanometer grade silica, nano silicone calcium powder, nano level silicic acid aluminium powder; Solvent is any one or more than one the combination in ethanol, vinyl acetic monomer.
6. a kind of thermal insulating coating according to claim 4, it is characterized in that: the matrix material in described primer is any one or more than one the combination in chloroprene rubber resin, HCPE, aldehyde ketone resin, E44 epoxy resin; Color stuffing is any one or more than one the combination in red iron oxide, mica iron oxide red, aluminium triphosphate, process white, super fine magnesia; Auxiliary agent is any one or more than one the combination in clorafin, dibutyl phthalate, urotropine; Solvent is any one or more than one the combination in dimethylbenzene, N-BUTYL ACETATE, vinyl acetic monomer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110132597 CN102206445B (en) | 2011-05-23 | 2011-05-23 | Heat insulating coating surface glue and heat insulating coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110132597 CN102206445B (en) | 2011-05-23 | 2011-05-23 | Heat insulating coating surface glue and heat insulating coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102206445A CN102206445A (en) | 2011-10-05 |
| CN102206445B true CN102206445B (en) | 2013-06-05 |
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|---|---|---|---|
| CN 201110132597 Expired - Fee Related CN102206445B (en) | 2011-05-23 | 2011-05-23 | Heat insulating coating surface glue and heat insulating coating |
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| CN106009948A (en) * | 2016-07-18 | 2016-10-12 | 安徽朗凯奇建材有限公司 | Anti-aging butadiene styrene rubber heat-insulation and water-proof coating and preparation method thereof |
| CN109619728B (en) * | 2018-12-27 | 2021-02-02 | 南通市第一人民医院 | Foreskin excision operation trousers |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101875805A (en) * | 2010-05-31 | 2010-11-03 | 刘昆虎 | Reflection type thermal insulation waterproof coating |
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| GB0223471D0 (en) * | 2002-10-10 | 2002-11-13 | Kalantar Ali | Heat insulation coatings used in the prevention of corrosion under insulation |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101875805A (en) * | 2010-05-31 | 2010-11-03 | 刘昆虎 | Reflection type thermal insulation waterproof coating |
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