CN106009948A - Anti-aging butadiene styrene rubber heat-insulation and water-proof coating and preparation method thereof - Google Patents

Anti-aging butadiene styrene rubber heat-insulation and water-proof coating and preparation method thereof Download PDF

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Publication number
CN106009948A
CN106009948A CN201610559212.2A CN201610559212A CN106009948A CN 106009948 A CN106009948 A CN 106009948A CN 201610559212 A CN201610559212 A CN 201610559212A CN 106009948 A CN106009948 A CN 106009948A
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parts
aging
heat
styrene rubber
mix homogeneously
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乔启信
金自海
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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Publication of CN106009948A publication Critical patent/CN106009948A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06—Copolymers with styrene
    • C09D109/08—Latex
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses anti-aging butadiene styrene rubber heat-insulation and water-proof coating which is prepared from the following raw materials in parts by weight: 100 parts of a butadiene styrene rubber emulsion, 8 to 10 parts of a chloroprene rubber emulsion, 15 to 20 parts of hydroxyethyl methylacrylate, 8 to 10 parts of alkyl resorcinol formaldehyde resin, 1 to 2 parts of hexamethoxy methyl melamine, 3 to 5 parts of titanium dioxide, 3 to 5 parts of talcum powder, 1 to 2 parts of sodium tripolyphosphate, 2 to 3 parts of tributyl phosphate, 1 to 2 parts of alcohol ester 12, 2 to 13 parts of N,N'-ethylenebis(stearamide), 1 to 2 parts of zinc borate, 12 to 15 parts of ethanediol, 15 to 20 parts of glycerin, 1 to 2 parts of 1,1'-sulfo-di(6-hydroxymethyl-2-naphthol), 2 to 3 parts of di(3,5-bitertiary butyl-4-hydroxy benzyl phosphoric acid ethyl ester) nickel, 8 to 10 parts of hollow glass microspheres and a proper amount of deionized water. The coating disclosed by the invention is excellent in water-proof performance and heat-insulation performance, and high in resistance to aging and ozone aging.

Description

A kind of heat-insulating waterproof coating of aging-resistant butadiene-styrene rubber and preparation method thereof
Technical field
The present invention relates to technical field of coatings, heat-insulating waterproof coating of a kind of aging-resistant butadiene-styrene rubber and preparation method thereof.
Technical background
Due to the irradiation of daylight, in making building, temperature raises, and will increase the energy consumption of air-conditioning.Additionally, industrial premises, prefabricated house or temporary building etc. uses metal foil roof, in the sun, indoor temperature can raise rapidly, in the case of many, uses air conditioner refrigerating to reduce the poor effect of indoor temperature.Indoor temperature is reduced, it is common that practical ways by reducing roof surface temperature.The approach preventing indoor temperature from raising mainly makes outdoor heat (mainly sunlight irradiates the heat produced) the most incoming indoor, and indoor heat the most outwards distributes.
The insulating moulding coating developed at present is broadly divided into 3 classes according to insulating mechanism: isolation-type insulating moulding coating, Radiation Heat-insulated Paint and reflection type thermal insulation coating.Wherein isolation-type insulating moulding coating is that the high thermal resistance by coating self realizes heat insulation a kind of coating.Being coated with during coating application and dress up certain thickness, generally 5-20mm, after abundant dry solidification, owing to after material drying and forming-film, thermal conductivity is the least, therefore coating has the ability of certain hot-fluid transmission of slowing down.Present this kind of coating is experiencing one by industry heat-insulation and heat-preservation to the transformation of building heat insulation, but owing to there is the defect that own material structure is brought, contraction as dry in arid cycle is big, hydroscopicity is big, and dicoration on the low side to the adhesion strength of body of wall remains to be further improved, and limits the range of this kind of coating.
The patent No. 201510887384.8 discloses a kind of water proof rubber material, it is made up of the raw material of following weight portion: polyethylene terephthalate 7-8, trioctyl lemon acid 3-4, Colophonium 1-2, polyacrylonitrile 24-27, sodium diacetate 1-2, graphite 12-13, fly ash micro-sphere 3-4, sodium lauryl sulphate 0.7-1, LNBR 42-55, methacrylic acid 0.6-1, nitrile rubber 52-60, butadiene-styrene rubber 20-25, Nano silica sol 5-6, tetramethylthiuram disulfide 3-4, diethylene glycol 2-3, VAE emulsion 6-8, active hargil 14-16, Barium metatitanate. 5-7, magnesium hydroxide 7-9, calcium propionate 0.2-0.3；The present invention uses the water proof rubber material obtained by above-mentioned formula, although have good water resistance, but effect of heat insulation is poor, is not suitable for making the water-repellent paint on roof.
Summary of the invention
It is an object of the invention to provide heat-insulating waterproof coating of a kind of aging-resistant butadiene-styrene rubber and preparation method thereof
To achieve these goals, the present invention adopts the following technical scheme that
nullA kind of heat-insulating waterproof coating of aging-resistant butadiene-styrene rubber，It is characterized in that，It is prepared from by the raw material of following weight portion: SBR emulsion 100 parts、Neoprene latex 8-10 part、Hydroxyethyl methylacrylate 15-20 part、Alkyl resorcinol formaldehyde resin 8-10 part、HMMM 1-2 part、Titanium dioxide 3-5 part、Pulvis Talci 3-5 part、Sodium tripolyphosphate 1-2 part、Tributyl phosphate 2-3 part、Alcohol ester 12 1-2 part、N，N '-ethylene bis stearamide 2-3 part、Firebrake ZB 1-2 part、Ethylene glycol 12-15 part、Glycerol 15-20 part、1,1'-thiobis (6-methylol-beta naphthal) 1-2 part、Double (3,5 di-t-butyl-4 hydroxybenzyl phosphate mono ethyl esters) nickel 2-3 part、Hollow glass micropearl 8-10 part、Deionized water is appropriate.
The heat-insulating waterproof coating of described aging-resistant butadiene-styrene rubber, it is characterised in that it is prepared from by following steps:
(1) titanium dioxide, Pulvis Talci are put in ball mill and turned/min with rotational speed of ball-mill for 2400-2800, temperature is 80-90 DEG C, carry out ball milling 30-40min, add glass microballoon, stirring 20-30min, add sodium tripolyphosphate, tributyl phosphate, alcohol ester 12 continuation stirring 10-20min, form the mixed powder of surface active；
(2) deionized water of 3-5 times amount will be added after hydroxyethyl methylacrylate, alkyl resorcinol formaldehyde resin, HMMM mix homogeneously, microwave heating 10-20min is carried out with the frequency of 5000-20000MHz, then with liquid nitrogen rapid cooling to 15-25 DEG C of prepared neoprene modification liquid；By neoprene modification liquid, mixed powder and neoprene latex mix homogeneously, rise high-temperature to 50-60 DEG C, continuously stirred 6-8h, obtain acrylic acid modified neoprene latex；
(3) by N, N '-ethylene bis stearamide, Firebrake ZB join in the mixed solvent of ethylene glycol, glycerol, mix homogeneously；Add 1,1'-thiobis (6-methylol-beta naphthal) and double (3,5 di-t-butyl-4 hydroxybenzyl phosphate mono ethyl ester) nickel, mix homogeneously；Add in the deionized water being equivalent to mixed powder weight portion 2-3 times, stir, it is then slowly added into acrylic acid modified neoprene latex, with 700-800 turn/speed of min stirring 40-60min after, move to homogenizer, / Rate Dispersion the 30-40min of min is turned, it is thus achieved that mixed slurry with 3500-4000；
(4) mixed slurry, SBR emulsion are added together mix homogeneously in change-can mixer, adjusted viscosity, after filtration, become heat-insulating waterproof coating coating.
The particle diameter of described hollow glass micropearl is 80-100 m.
The excellent effect of the present invention is: the addition of neoprene latex, and butadiene-styrene rubber synergism, is to improve the elongation at break of heat-insulating waterproof coating and low temperature flexibility；First glass microballoon is carried out surface active, be redispersed in neoprene latex, increase its dispersibility in butadiene-styrene rubber, utilize the countless cavitys of tiny hollow glass micropearl to form thermal insulation layer and stop conduction of heat, improve the heat-proof quality of coating；Utilize acrylic acid modified neoprene latex, increase neoprene and the compatibility of butadiene-styrene rubber, significantly improve the intensity of material and resistance to water and with concrete, the bonding force of cement mortar basic unit；N, N '-ethylene bis stearamide, 1,1'-thiobis (6-methylol-beta naphthal), double (3,5 di-t-butyl-4 hydroxybenzyl phosphate mono ethyl esters) nickel can react with neoprene, form double bond, make it will not migrate in rubber matrix, improve antioxygenic property and the ozonisation performance of coating；The heat-insulating waterproof coating that the present invention provides, cheap, have good effect of heat insulation, ageing resistace and daylighting degree and easy construction concurrently simultaneously, have a good application prospect.
Detailed description of the invention
The heat-insulating waterproof coating of the aging-resistant butadiene-styrene rubber of the present embodiment, it is prepared from by the raw material of following weight portion: SBR emulsion 100 parts, neoprene latex 8 parts, hydroxyethyl methylacrylate 15 parts, alkyl resorcinol formaldehyde resin 8 parts, HMMM 1 part, titanium dioxide 3 parts, Pulvis Talci 5 parts, sodium tripolyphosphate 2 parts, tributyl phosphate 3 parts, alcohol ester 12 parts, N, N '-ethylene bis stearamide 2 parts, Firebrake ZB 2 parts, ethylene glycol 15 parts, glycerol 15 parts, 1, 1'-thiobis (6-methylol-beta naphthal) 2 parts, double (3, 5 di-t-butyl-4 hydroxybenzyl phosphate mono ethyl esters) 3 parts of nickel, hollow glass micropearl 10 parts, deionized water is appropriate.
The heat-insulating waterproof coating of the aging-resistant butadiene-styrene rubber of the present embodiment, it is prepared from by following steps:
(1) titanium dioxide, Pulvis Talci being put in ball mill with rotational speed of ball-mill is 2800 turns/min, temperature is 90 DEG C, carry out ball milling 40min, add glass microballoon, stirring 30min, add sodium tripolyphosphate, tributyl phosphate, alcohol ester 12 continuation stirring 20min, form the mixed powder of surface active；
(2) deionized water of 5 times amount will be added after hydroxyethyl methylacrylate, alkyl resorcinol formaldehyde resin, HMMM mix homogeneously, microwave heating 20min is carried out with the frequency of 5000MHz, then with the prepared neoprene modification liquid of liquid nitrogen rapid cooling to 25 DEG C；By neoprene modification liquid, mixed powder and neoprene latex mix homogeneously, rise high-temperature to 60 DEG C, continuously stirred 8h, obtain acrylic acid modified neoprene latex；
(3) by N, N '-ethylene bis stearamide, Firebrake ZB join in the mixed solvent of ethylene glycol, glycerol, mix homogeneously；Add 1,1'-thiobis (6-methylol-beta naphthal) and double (3,5 di-t-butyl-4 hydroxybenzyl phosphate mono ethyl ester) nickel, mix homogeneously；Add in the deionized water being equivalent to mixed powder weight portion 3 times, stir, be then slowly added into acrylic acid modified neoprene latex, after stirring 40min with the speed of 800 turns/min, move to homogenizer, with the Rate Dispersion 30min of 4000 turns/min, it is thus achieved that mixed slurry；
(4) mixed slurry, SBR emulsion are added together mix homogeneously in change-can mixer, adjusted viscosity, after filtration, become heat-insulating waterproof coating coating.
The coating appearance that the present invention produces normally, without precipitation, without caking, is tested the most without exception by Water Resistance Test in 160 hours, alkaline resistance test in 50 hours, 10000 abrasion resistances；Artificial ageing resistance is tested: 2000 hours non-foaming, does not peels off, flawless.

Claims (3)

  1. null1. the heat-insulating waterproof coating of an aging-resistant butadiene-styrene rubber，It is characterized in that，It is prepared from by the raw material of following weight portion: SBR emulsion 100 parts、Neoprene latex 8-10 part、Hydroxyethyl methylacrylate 15-20 part、Alkyl resorcinol formaldehyde resin 8-10 part、HMMM 1-2 part、Titanium dioxide 3-5 part、Pulvis Talci 3-5 part、Sodium tripolyphosphate 1-2 part、Tributyl phosphate 2-3 part、Alcohol ester 12 1-2 part、N，N '-ethylene bis stearamide 2-3 part、Firebrake ZB 1-2 part、Ethylene glycol 12-15 part、Glycerol 15-20 part、1,1'-thiobis (6-methylol-beta naphthal) 1-2 part、Double (3,5 di-t-butyl-4 hydroxybenzyl phosphate mono ethyl esters) nickel 2-3 part、Hollow glass micropearl 8-10 part、Deionized water is appropriate.
  2. 2. according to the heat-insulating waterproof coating of the aging-resistant butadiene-styrene rubber described in claim 1, it is characterised in that it is prepared from by following steps:
    (1) titanium dioxide, Pulvis Talci are put in ball mill and turned/min with rotational speed of ball-mill for 2400-2800, temperature is 80-90 DEG C, carry out ball milling 30-40min, add glass microballoon, stirring 20-30min, add sodium tripolyphosphate, tributyl phosphate, alcohol ester 12 continuation stirring 10-20min, form the mixed powder of surface active；
    (2) deionized water of 3-5 times amount will be added after hydroxyethyl methylacrylate, alkyl resorcinol formaldehyde resin, HMMM mix homogeneously, microwave heating 10-20min is carried out with the frequency of 5000-20000MHz, then with liquid nitrogen rapid cooling to 15-25 DEG C of prepared neoprene modification liquid；By neoprene modification liquid, mixed powder and neoprene latex mix homogeneously, rise high-temperature to 50-60 DEG C, continuously stirred 6-8h, obtain acrylic acid modified neoprene latex；
    (3) by N, N '-ethylene bis stearamide, Firebrake ZB join in the mixed solvent of ethylene glycol, glycerol, mix homogeneously；Add 1,1'-thiobis (6-methylol-beta naphthal) and double (3,5 di-t-butyl-4 hydroxybenzyl phosphate mono ethyl ester) nickel, mix homogeneously；Add in the deionized water being equivalent to mixed powder weight portion 2-3 times, stir, it is then slowly added into acrylic acid modified neoprene latex, with 700-800 turn/speed of min stirring 40-60min after, move to homogenizer, / Rate Dispersion the 30-40min of min is turned, it is thus achieved that mixed slurry with 3500-4000；
    (4) mixed slurry, SBR emulsion are added together mix homogeneously in change-can mixer, adjusted viscosity, after filtration, become heat-insulating waterproof coating coating.
  3. 3. according to the preparation method of the heat-insulating waterproof coating of the aging-resistant butadiene-styrene rubber described in claim 2, it is characterised in that the particle diameter of described hollow glass micropearl is 80-100 m.
CN201610559212.2A 2016-07-18 2016-07-18 Anti-aging butadiene styrene rubber heat-insulation and water-proof coating and preparation method thereof Withdrawn CN106009948A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102206445A (en) * 2011-05-23 2011-10-05 开平市日固力涂料有限公司 Heat insulating coating surface glue and heat insulating coating
CN103524815A (en) * 2013-08-26 2014-01-22 无锡市金盛助剂厂 Styrene butadiene rubber emulsion modifying agent
CN105462087A (en) * 2016-01-25 2016-04-06 永嘉县伟诚橡胶工贸有限公司 Rubber anti-aging agent and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102206445A (en) * 2011-05-23 2011-10-05 开平市日固力涂料有限公司 Heat insulating coating surface glue and heat insulating coating
CN103524815A (en) * 2013-08-26 2014-01-22 无锡市金盛助剂厂 Styrene butadiene rubber emulsion modifying agent
CN105462087A (en) * 2016-01-25 2016-04-06 永嘉县伟诚橡胶工贸有限公司 Rubber anti-aging agent and preparation method thereof

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