CN106085017A - A kind of heat-insulating waterproof coating of butadiene-styrene rubber not chapped and preparation method thereof - Google Patents
A kind of heat-insulating waterproof coating of butadiene-styrene rubber not chapped and preparation method thereof Download PDFInfo
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- CN106085017A CN106085017A CN201610560853.XA CN201610560853A CN106085017A CN 106085017 A CN106085017 A CN 106085017A CN 201610560853 A CN201610560853 A CN 201610560853A CN 106085017 A CN106085017 A CN 106085017A
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- parts
- heat
- waterproof coating
- insulating waterproof
- butadiene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D109/00—Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09D109/06—Copolymers with styrene
- C09D109/08—Latex
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The heat-insulating waterproof coating of a kind of butadiene-styrene rubber not chapped, is made up of the raw material of following weight portion: SBR emulsion 100 parts, neoprene latex 8 10 parts, hydroxyethyl methylacrylate 15 20 parts, alkyl resorcinol formaldehyde resin 8 10 parts, HMMM 12 parts, montmorillonite 35 parts, zinc oxide 35 parts, trioctyl lemon acid 12 parts, tributyl phosphate 23 parts, Colophonium 12 parts, N ethyl n ' diphenyl-para-phenylene diamine 23 parts, hydroxymethyl cellulose 12 parts, hollow glass micropearl 8 10 parts, deionized water be appropriate.The heat-insulating waterproof coating that the present invention provides, cheap, have good effect of heat insulation and daylighting degree and easy construction concurrently simultaneously, have a good application prospect.
Description
Technical field
The present invention relates to technical field of coatings, the heat-insulating waterproof coating of a kind of butadiene-styrene rubber not chapped and system thereof
Preparation Method.
Technical background
Due to the irradiation of daylight, in making building, temperature raises, and will increase the energy consumption of air-conditioning.Additionally, industrial premises, work
Dynamic room or temporary building etc. uses metal foil roof, and in the sun, indoor temperature can raise rapidly, in the case of many,
Air conditioner refrigerating is used to reduce the poor effect of indoor temperature.Indoor temperature is reduced by reducing roof surface temperature, it is common that
Practical ways.The approach preventing indoor temperature from raising mainly makes outdoor heat, and (mainly sunlight irradiates generation
Heat) the most incoming indoor, and indoor heat the most outwards distributes.
The insulating moulding coating developed at present is broadly divided into 3 classes according to insulating mechanism: isolation-type insulating moulding coating, radiation type heat-insulation are coated with
Material and reflection type thermal insulation coating.Wherein isolation-type insulating moulding coating is that the high thermal resistance by coating self realizes heat insulation a kind of painting
Material.Being coated with during coating application and dress up certain thickness, generally 5-20mm, after abundant dry solidification, owing to material is dried to
After film, thermal conductivity is the least, and therefore coating has the ability of certain hot-fluid transmission of slowing down.Present this kind of coating is experiencing one
By industry heat-insulation and heat-preservation to the transformation of building heat insulation, but owing to there is the defect that own material structure is brought, such as dry week
Phase dry contraction is big, and hydroscopicity is big, and dicoration on the low side to the adhesion strength of body of wall remains to be further improved, and limits this kind of
The range of coating.
The patent No. 201510887384.8 discloses a kind of water proof rubber material, the raw material of following weight portion prepare system
Become: polyethylene terephthalate 7-8, trioctyl lemon acid 3-4, Colophonium 1-2, polyacrylonitrile 24-27, sodium diacetate 1-2,
Graphite 12-13, fly ash micro-sphere 3-4, sodium lauryl sulphate 0.7-1, LNBR 42-55, methacrylic acid 0.6-
1, nitrile rubber 52-60, butadiene-styrene rubber 20-25, Nano silica sol 5-6, tetramethylthiuram disulfide 3-4, diethylene glycol 2-3,
VAE emulsion 6-8, active hargil 14-16, Barium metatitanate. 5-7, magnesium hydroxide 7-9, calcium propionate 0.2-0.3；The present invention uses above-mentioned joining
Water proof rubber material obtained by side, although have good water resistance, but effect of heat insulation is poor, is not suitable for making the anti-of roof
Water paint.
Summary of the invention
It is an object of the invention to provide a kind of heat-insulating waterproof coating of butadiene-styrene rubber not chapped and preparation method thereof.
To achieve these goals, the present invention adopts the following technical scheme that
The heat-insulating waterproof coating of a kind of butadiene-styrene rubber not chapped, it is characterised in that it is by the raw material preparation of following weight portion
Become: SBR emulsion 100 parts, neoprene latex 8-10 part, hydroxyethyl methylacrylate 15-20 part, alkyl-resorcin
Formaldehyde resin 8-10 part, HMMM 1-2 part, montmorillonite 3-5 part, zinc oxide 3-5 part, trioctyl lemon acid
1-2 part, tributyl phosphate 2-3 part, Colophonium 1-2 part, N-ethyl-N'-diphenyl-para-phenylene diamine 2-3 part, hydroxymethyl cellulose 1-2
Part, hollow glass micropearl 8-10 part, deionized water are appropriate.
The heat-insulating waterproof coating of the described butadiene-styrene rubber not chapped, it is characterised in that it is prepared from by following steps:
(1) montmorillonite, zinc oxide being put in ball mill and turn/min with rotational speed of ball-mill for 2400-2800, temperature is 80-90 DEG C,
Carrying out ball milling 30-40min, add glass microballoon, stir 20-30min, addition trioctyl lemon acid, tributyl phosphate, Colophonium continue
The continuous stirring 10-20min that continues, the mixed powder of formation surface active；
(2) by after hydroxyethyl methylacrylate, alkyl resorcinol formaldehyde resin, HMMM mix homogeneously
Add the deionized water of 3-5 times amount, carry out microwave heating 10-20min with the frequency of 5000-20000MHz, then with liquid nitrogen rapidly
It is cooled to 15-25 DEG C of prepared neoprene modification liquid；Neoprene modification liquid, mixed powder and neoprene latex are mixed
Uniformly, rise high-temperature to 50-60 DEG C, continuously stirred 6-8h, obtain acrylic acid modified neoprene latex；
(3) N-ethyl-N'-diphenyl-para-phenylene diamine, hydroxymethyl cellulose are added to be equivalent to mixed powder weight portion 2-3 times
In deionized water, stir, be then slowly added into acrylic acid modified neoprene latex, turn/the speed of min with 700-800
After degree stirring 40-60min, move to homogenizer, turn/Rate Dispersion the 30-40min of min with 3500-4000, it is thus achieved that mixing
Slurry；
(4) mixed slurry, SBR emulsion are added together mix homogeneously in change-can mixer, adjusted viscosity, become after filtration
Heat-insulating waterproof coating coating.
The particle diameter of described hollow glass micropearl is 80-100 m.
The excellent effect of the present invention is: the addition of neoprene latex, and butadiene-styrene rubber synergism, be in order to improve every
The elongation at break of hot water-repellent paint and low temperature flexibility；First glass microballoon is carried out surface active, be redispersed in neoprene breast
In liquid, increase its dispersibility in butadiene-styrene rubber, utilize the countless cavitys of tiny hollow glass micropearl to form thermal insulation layer resistance
Only conduction of heat, improves the heat-proof quality of coating；Utilize acrylic acid modified neoprene latex, increase neoprene and butadiene-styrene rubber
The compatibility, significantly improve the intensity of material and resistance to water and with concrete, the bonding force of cement mortar basic unit；N-ethyl-
The addition of N'-diphenyl-para-phenylene diamine can improve the flex cracking resistance of coating, antioxygenic property and comprehensive ageing-resistant performance；The present invention
The heat-insulating waterproof coating provided, cheap, have good effect of heat insulation and daylighting degree and easy construction concurrently simultaneously, have good
Application prospect.
Detailed description of the invention
The heat-insulating waterproof coating of the butadiene-styrene rubber not chapped of the present embodiment, it is by the raw material preparation of following weight portion
Become: SBR emulsion 100 parts, neoprene latex 8 parts, hydroxyethyl methylacrylate 20 parts, alkyl resorcinol formaldehyde tree
8 parts of fat, HMMM 2 parts, montmorillonite 5 parts, zinc oxide 3 parts, trioctyl lemon acid 2 parts, tributyl phosphate 3
Part, Colophonium 2 parts, N-ethyl-N'-diphenyl-para-phenylene diamine 3 parts, hydroxymethyl cellulose 2 parts, hollow glass micropearl 10 parts, deionization
Water is appropriate.
The heat-insulating waterproof coating of the butadiene-styrene rubber not chapped of the present embodiment, it is prepared from by following steps:
(1) montmorillonite, zinc oxide being put in ball mill with rotational speed of ball-mill is 2800 turns/min, and temperature is 90 DEG C, carries out ball milling
40min, adds glass microballoon, stirs 30min, adds trioctyl lemon acid, tributyl phosphate, Colophonium continuation stirring
20min, forms the mixed powder of surface active；
(2) by after hydroxyethyl methylacrylate, alkyl resorcinol formaldehyde resin, HMMM mix homogeneously
Add the deionized water of 5 times amount, carry out microwave heating 20min with the frequency of 20000MHz, then with liquid nitrogen rapid cooling to 25 DEG C
The neoprene modification liquid prepared；By neoprene modification liquid, mixed powder and neoprene latex mix homogeneously, rise high-temperature
To 60 DEG C, continuously stirred 8h, obtain acrylic acid modified neoprene latex；
(3) N-ethyl-N'-diphenyl-para-phenylene diamine, hydroxymethyl cellulose are added to be equivalent to going of mixed powder weight portion 3 times
In ionized water, stir, be then slowly added into acrylic acid modified neoprene latex, stir with the speed of 800 turns/min
After 60min, move to homogenizer, with the Rate Dispersion 30min of 4000 turns/min, it is thus achieved that mixed slurry；
(4) mixed slurry, SBR emulsion are added together mix homogeneously in change-can mixer, adjusted viscosity, become after filtration
Heat-insulating waterproof coating coating.
The coating appearance that the present invention produces is normal, without precipitation, without caking, by Water Resistance Test in 160 hours, 50 hours resistance to
Alkalescence test, 10000 abrasion resistances are tested the most without exception；Artificial ageing resistance is tested: 2000 hours non-foaming, does not peels off, nothing
Crackle.
Claims (3)
1. the heat-insulating waterproof coating of the butadiene-styrene rubber not chapped, it is characterised in that it is prepared by the raw material of following weight portion
Form: SBR emulsion 100 parts, neoprene latex 8-10 part, hydroxyethyl methylacrylate 15-20 part, alkyl resorsinols two
Fluosite 8-10 part, HMMM 1-2 part, montmorillonite 3-5 part, zinc oxide 3-5 part, citric acid three are pungent
Ester 1-2 part, tributyl phosphate 2-3 part, Colophonium 1-2 part, N-ethyl-N'-diphenyl-para-phenylene diamine 2-3 part, hydroxymethyl cellulose 1-2
Part, hollow glass micropearl 8-10 part, deionized water are appropriate.
2. according to the heat-insulating waterproof coating of the butadiene-styrene rubber not chapped described in claim 1, it is characterised in that it is by as follows
Step is prepared from:
(1) montmorillonite, zinc oxide being put in ball mill and turn/min with rotational speed of ball-mill for 2400-2800, temperature is 80-90 DEG C,
Carrying out ball milling 30-40min, add glass microballoon, stir 20-30min, addition trioctyl lemon acid, tributyl phosphate, Colophonium continue
The continuous stirring 10-20min that continues, the mixed powder of formation surface active；
(2) by after hydroxyethyl methylacrylate, alkyl resorcinol formaldehyde resin, HMMM mix homogeneously
Add the deionized water of 3-5 times amount, carry out microwave heating 10-20min with the frequency of 5000-20000MHz, then with liquid nitrogen rapidly
It is cooled to 15-25 DEG C of prepared neoprene modification liquid；Neoprene modification liquid, mixed powder and neoprene latex are mixed
Uniformly, rise high-temperature to 50-60 DEG C, continuously stirred 6-8h, obtain acrylic acid modified neoprene latex；
(3) N-ethyl-N'-diphenyl-para-phenylene diamine, hydroxymethyl cellulose are added to be equivalent to mixed powder weight portion 2-3 times
In deionized water, stir, be then slowly added into acrylic acid modified neoprene latex, turn/the speed of min with 700-800
After degree stirring 40-60min, move to homogenizer, turn/Rate Dispersion the 30-40min of min with 3500-4000, it is thus achieved that mixing
Slurry；
(4) mixed slurry, SBR emulsion are added together mix homogeneously in change-can mixer, adjusted viscosity, become after filtration
Heat-insulating waterproof coating coating.
3., according to the preparation method of the heat-insulating waterproof coating of the butadiene-styrene rubber not chapped described in claim 2, its feature exists
In, the particle diameter of described hollow glass micropearl is 80-100 m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610560853.XA CN106085017A (en) | 2016-07-18 | 2016-07-18 | A kind of heat-insulating waterproof coating of butadiene-styrene rubber not chapped and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610560853.XA CN106085017A (en) | 2016-07-18 | 2016-07-18 | A kind of heat-insulating waterproof coating of butadiene-styrene rubber not chapped and preparation method thereof |
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| CN201610560853.XA Withdrawn CN106085017A (en) | 2016-07-18 | 2016-07-18 | A kind of heat-insulating waterproof coating of butadiene-styrene rubber not chapped and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1587310A (en) * | 2004-07-02 | 2005-03-02 | 杨太龙 | Water-proof liquid rubber |
| CN101648794A (en) * | 2009-09-21 | 2010-02-17 | 吕海涛 | Dry-type heat-insulating waterproof coating |
| CN102557966A (en) * | 2011-12-23 | 2012-07-11 | 中国石油化工股份有限公司 | Method for preparing anti-aging agent differential temperature programmed desorption (DTPD) |
| CN103524815A (en) * | 2013-08-26 | 2014-01-22 | 无锡市金盛助剂厂 | Styrene butadiene rubber emulsion modifying agent |
| CN104073067A (en) * | 2014-06-20 | 2014-10-01 | 吴江华诚复合材料科技有限公司 | Methylcellulose multicolor coating |
| CN104559571A (en) * | 2015-01-10 | 2015-04-29 | 安徽省东瑞装饰材料有限公司 | Waterborne bactericidal antifouling antirust paint and preparation method thereof |
-
2016
- 2016-07-18 CN CN201610560853.XA patent/CN106085017A/en not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1587310A (en) * | 2004-07-02 | 2005-03-02 | 杨太龙 | Water-proof liquid rubber |
| CN101648794A (en) * | 2009-09-21 | 2010-02-17 | 吕海涛 | Dry-type heat-insulating waterproof coating |
| CN102557966A (en) * | 2011-12-23 | 2012-07-11 | 中国石油化工股份有限公司 | Method for preparing anti-aging agent differential temperature programmed desorption (DTPD) |
| CN103524815A (en) * | 2013-08-26 | 2014-01-22 | 无锡市金盛助剂厂 | Styrene butadiene rubber emulsion modifying agent |
| CN104073067A (en) * | 2014-06-20 | 2014-10-01 | 吴江华诚复合材料科技有限公司 | Methylcellulose multicolor coating |
| CN104559571A (en) * | 2015-01-10 | 2015-04-29 | 安徽省东瑞装饰材料有限公司 | Waterborne bactericidal antifouling antirust paint and preparation method thereof |
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Application publication date: 20161109 |