CN103275266B - A kind of water soluble acrylic resin and preparation method thereof - Google Patents
A kind of water soluble acrylic resin and preparation method thereof Download PDFInfo
- Publication number
- CN103275266B CN103275266B CN201310197494.2A CN201310197494A CN103275266B CN 103275266 B CN103275266 B CN 103275266B CN 201310197494 A CN201310197494 A CN 201310197494A CN 103275266 B CN103275266 B CN 103275266B
- Authority
- CN
- China
- Prior art keywords
- acrylic resin
- water soluble
- soluble acrylic
- initiator
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000004925 Acrylic resin Substances 0.000 title claims abstract description 32
- 229920000178 Acrylic resin Polymers 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims description 13
- 239000003999 initiator Substances 0.000 claims abstract description 21
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- -1 Hexafluorobutyl Chemical group 0.000 claims abstract description 9
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 9
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims abstract description 9
- OZCWUNHGNVXCCO-UHFFFAOYSA-N oxiran-2-ylmethyl hydrogen carbonate Chemical group OC(=O)OCC1CO1 OZCWUNHGNVXCCO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims description 12
- 238000010792 warming Methods 0.000 claims description 12
- OZDGMOYKSFPLSE-UHFFFAOYSA-N 2-Methylaziridine Chemical group CC1CN1 OZDGMOYKSFPLSE-UHFFFAOYSA-N 0.000 claims description 6
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 2
- 238000009835 boiling Methods 0.000 abstract description 8
- 238000007493 shaping process Methods 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 239000013557 residual solvent Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000006115 industrial coating Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of water soluble acrylic resin, described water soluble acrylic resin is prepared from by each component of following mass fraction: methyl methacrylate 30-35 part, vinylformic acid 6-10 part, hydroxyethyl methylacrylate 10-15 part, vinylbenzene 3-5 part, dimethylbenzene 2-4 part, tertiary carbonic acid glycidyl ester 2-5 part, Hexafluorobutyl mathacrylate 2-4 part, initiator 0.3-0.5 part, linking agent 0.5-0.8 part.The water soluble acrylic resin that the present invention prepares has high resistance to boiling water, smear shaping product glossiness good, there is superior surface property and beautiful gloss, there is good clarity and color developing, and its film has good hardness, weathering resistance, the demand of people can well be met.
Description
Technical field
The invention belongs to paint field, be specifically related to a kind of water soluble acrylic resin and preparation method thereof.
Background technology
At present, environment-friendly type coating has had in decorations field and has applied very widely.Along with the development of society, the continuous enhancing of people's environmental consciousness, the theory that is day by day deep, healthy, environmental protection of international trade contact is also incorporated in industrial coating field gradually, and this also has higher requirement to industrial coating.
Compared with traditional solvent based coating, water soluble paint has that price is low, use safety, saving resource and the energy, reduces the advantage such as environmental pollution and public hazards, because becoming the Main way of current development coatings industry.Water soluble acrylic resin's coating is because having that levelling is good, gloss is high, film forming is good and the plurality of advantages such as film compactness is good, the safe reliability in construction solidification process can be significantly improved, and remain the advantage of solvent type acrylic resin coating in mechanical property, barrier propterty and decorate properties etc., become with fastest developing speed in water soluble paint, that kind is maximum pollution-free coating.
Summary of the invention
The invention provides a kind of water soluble acrylic resin, for this reason, the present invention also provides its preparation method.
The invention provides a kind of water soluble acrylic resin, described water soluble acrylic resin is prepared from by each component of following mass fraction: methyl methacrylate 30-35 part, vinylformic acid 6-10 part, hydroxyethyl methylacrylate 10-15 part, vinylbenzene 3-5 part, dimethylbenzene 2-4 part, tertiary carbonic acid glycidyl ester 2-5 part, Hexafluorobutyl mathacrylate 2-4 part, initiator 0.3-0.5 part, linking agent 0.5-0.8 part.
Further, described water soluble acrylic resin is prepared from by each component of following mass fraction: methyl methacrylate 32 parts, 8 parts, vinylformic acid, hydroxyethyl methylacrylate 12 parts, vinylbenzene 4 parts, dimethylbenzene 3 parts, tertiary carbonic acid glycidyl ester 4 parts, Hexafluorobutyl mathacrylate 3 parts, initiator 0.4 part, linking agent 0.6 part.
Further, described initiator is at least one in di-t-butyl peroxide, dicumyl peroxide, peroxidized t-butyl perbenzoate.
Further, described linking agent is methylaziridine.
Second object of the present invention is to provide the preparation method of above-mentioned water soluble acrylic resin, step is as follows: in reaction vessel, add vinylformic acid, vinylbenzene and initiator, stirring and evenly mixing, be warming up to 60-80 DEG C, residual solvent is added reaction vessel, is warming up to 120-130 DEG C, stir 4 hours, be down to room temperature, obtain water soluble acrylic resin.
The water soluble acrylic resin that the present invention prepares has high resistance to boiling water, smear shaping product glossiness good, there is superior surface property and beautiful gloss, there is good clarity and color developing, and its film has good hardness, weathering resistance, the demand of people can well be met.
Embodiment
Following embodiment is convenient to understand the present invention better, but does not limit the present invention.Experimental technique in following embodiment, if no special instructions, is ordinary method.
embodiment 1
The formula of water soluble acrylic resin of the present invention is as follows:
Methyl methacrylate 32kg, vinylformic acid 8kg, hydroxyethyl methylacrylate 12kg, vinylbenzene 4kg, dimethylbenzene 3kg, tertiary carbonic acid glycidyl ester 4kg, Hexafluorobutyl mathacrylate 3kg, initiator 0.4kg, linking agent 0.6kg.
Wherein, initiator is di-t-butyl peroxide, and linking agent is methylaziridine.
The preparation method of water soluble acrylic resin of the present invention is as follows:
In reaction vessel, add vinylformic acid 8kg, vinylbenzene 4kg and initiator 0.4kg, stirring and evenly mixing, is warming up to 60-80 DEG C, and residual solvent is added reaction vessel, is warming up to 120-130 DEG C, stirs 4 hours, is down to room temperature, obtains water soluble acrylic resin.
embodiment 2
The formula of water soluble acrylic resin of the present invention is as follows:
Methyl methacrylate 30kg, vinylformic acid 6kg, hydroxyethyl methylacrylate 10kg, vinylbenzene 3kg, dimethylbenzene 2kg, tertiary carbonic acid glycidyl ester 2kg, Hexafluorobutyl mathacrylate 2kg, initiator 0.3kg, linking agent 0.5kg.
Wherein, initiator is di-t-butyl peroxide, and linking agent is methylaziridine.
The preparation method of water soluble acrylic resin of the present invention is as follows:
In reaction vessel, add vinylformic acid 6kg, vinylbenzene 3kg and initiator 0.3kg, stirring and evenly mixing, is warming up to 60-80 DEG C, and residual solvent is added reaction vessel, is warming up to 120-130 DEG C, stirs 4 hours, is down to room temperature, obtains water soluble acrylic resin.
embodiment 3
The formula of water soluble acrylic resin of the present invention is as follows:
Methyl methacrylate 35kg, vinylformic acid 10kg, hydroxyethyl methylacrylate 15kg, vinylbenzene 5kg, dimethylbenzene 4kg, tertiary carbonic acid glycidyl ester 5kg, Hexafluorobutyl mathacrylate 4kg, initiator 0.5kg, linking agent 0.8kg.
Wherein, initiator is di-t-butyl peroxide, and linking agent is methylaziridine.
The preparation method of water soluble acrylic resin of the present invention is as follows:
In reaction vessel, add vinylformic acid 10kg, vinylbenzene 5kg and initiator 0.5kg, stirring and evenly mixing, is warming up to 60-80 DEG C, and residual solvent is added reaction vessel, is warming up to 120-130 DEG C, stirs 4 hours, is down to room temperature, obtains water soluble acrylic resin.
embodiment 4
The formula of water soluble acrylic resin of the present invention is as follows:
Methyl methacrylate 32kg, vinylformic acid 6kg, hydroxyethyl methylacrylate 15kg, vinylbenzene 3kg, dimethylbenzene 3kg, tertiary carbonic acid glycidyl ester 4kg, Hexafluorobutyl mathacrylate 3kg, initiator 0.3kg, linking agent 0.5kg.
Wherein, initiator is di-t-butyl peroxide, and linking agent is methylaziridine.
The preparation method of water soluble acrylic resin of the present invention is as follows:
In reaction vessel, add vinylformic acid 6kg, vinylbenzene 3kg and initiator 0.3kg, stirring and evenly mixing, is warming up to 60-80 DEG C, and residual solvent is added reaction vessel, is warming up to 120-130 DEG C, stirs 4 hours, is down to room temperature, obtains water soluble acrylic resin.
Embodiment 1-4 is done resistance to boiling water experiment, obtains:
Embodiment 1 resistance to boiling water 18 hours
Embodiment 2 resistance to boiling water 16 hours
Embodiment 3 resistance to boiling water 15 hours
Embodiment 4 resistance to boiling water 14 hours.
Visible, water soluble acrylic resin of the present invention has good resistance to boiling water.Smear shaping product with it and there is good glossiness, there is good hardness simultaneously.
Last it is noted that the foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. the preparation method of water soluble acrylic resin, step is as follows: in reaction vessel, add vinylformic acid, vinylbenzene and initiator, stirring and evenly mixing, be warming up to 60-80 DEG C, surplus stock is added reaction vessel, is warming up to 120-130 DEG C, stir 4 hours, be down to room temperature, obtain water soluble acrylic resin; Described water soluble acrylic resin is prepared from by each component of following mass fraction: methyl methacrylate 30-35 part, vinylformic acid 6-10 part, hydroxyethyl methylacrylate 10-15 part, vinylbenzene 3-5 part, dimethylbenzene 2-4 part, tertiary carbonic acid glycidyl ester 2-5 part, Hexafluorobutyl mathacrylate 2-4 part, initiator 0.3-0.5 part, linking agent 0.5-0.8 part.
2. preparation method according to claim 1, is characterized in that: described water soluble acrylic resin is prepared from by each component of following mass fraction: methyl methacrylate 32 parts, 8 parts, vinylformic acid, hydroxyethyl methylacrylate 12 parts, vinylbenzene 4 parts, dimethylbenzene 3 parts, tertiary carbonic acid glycidyl ester 4 parts, Hexafluorobutyl mathacrylate 3 parts, initiator 0.4 part, linking agent 0.6 part.
3. preparation method according to claim 1, is characterized in that: described initiator is at least one in di-t-butyl peroxide, dicumyl peroxide, peroxidized t-butyl perbenzoate.
4. preparation method according to claim 1, is characterized in that: described linking agent is methylaziridine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310197494.2A CN103275266B (en) | 2013-05-24 | 2013-05-24 | A kind of water soluble acrylic resin and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310197494.2A CN103275266B (en) | 2013-05-24 | 2013-05-24 | A kind of water soluble acrylic resin and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103275266A CN103275266A (en) | 2013-09-04 |
| CN103275266B true CN103275266B (en) | 2016-01-06 |
Family
ID=49057903
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310197494.2A Active CN103275266B (en) | 2013-05-24 | 2013-05-24 | A kind of water soluble acrylic resin and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103275266B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674144B (en) * | 2017-05-05 | 2019-10-01 | 南昌大学 | A kind of exterior coating preparation method of water soluble acrylic resin |
| CN110066357B (en) * | 2019-04-19 | 2021-08-27 | 黄山金质丽科技有限公司 | Fluorine-containing super-lubricating water-based acrylic resin, preparation method and water-based paint |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5225505A (en) * | 1989-12-21 | 1993-07-06 | Atochem | Acrylic copolymers and their use as coatings |
| CN101121770A (en) * | 2006-08-11 | 2008-02-13 | 上海市涂料研究所 | Water acrylic resin and preparing method thereof |
| CN101457005A (en) * | 2008-12-25 | 2009-06-17 | 浙江环达漆业集团有限公司 | Method for preparing hydroxyl acrylic acid water dispersoid |
| CN101935425A (en) * | 2010-09-16 | 2011-01-05 | 江门市制漆厂有限公司 | Modified polyurethane (PU) acrylic resin and preparation method thereof |
| CN102838707A (en) * | 2012-09-19 | 2012-12-26 | 江阴恒兴涂料有限公司 | High-performance water-soluble acrylic resin and preparation method thereof |
| CN103102446A (en) * | 2013-03-01 | 2013-05-15 | 湖北乾兴化工有限公司 | Hydroxylated acrylic resin for automobile refinishing varnish and preparation method of hydroxylated acrylic resin |
-
2013
- 2013-05-24 CN CN201310197494.2A patent/CN103275266B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5225505A (en) * | 1989-12-21 | 1993-07-06 | Atochem | Acrylic copolymers and their use as coatings |
| CN101121770A (en) * | 2006-08-11 | 2008-02-13 | 上海市涂料研究所 | Water acrylic resin and preparing method thereof |
| CN101457005A (en) * | 2008-12-25 | 2009-06-17 | 浙江环达漆业集团有限公司 | Method for preparing hydroxyl acrylic acid water dispersoid |
| CN101935425A (en) * | 2010-09-16 | 2011-01-05 | 江门市制漆厂有限公司 | Modified polyurethane (PU) acrylic resin and preparation method thereof |
| CN102838707A (en) * | 2012-09-19 | 2012-12-26 | 江阴恒兴涂料有限公司 | High-performance water-soluble acrylic resin and preparation method thereof |
| CN103102446A (en) * | 2013-03-01 | 2013-05-15 | 湖北乾兴化工有限公司 | Hydroxylated acrylic resin for automobile refinishing varnish and preparation method of hydroxylated acrylic resin |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103275266A (en) | 2013-09-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102627902B (en) | Nanometer reinforced aqueous acrylic acid modified epoxy primer-topcoat anticorrosion paint coating and preparation method thereof | |
| CN104109450A (en) | Graphene anticorrosive powder paint and preparation method thereof | |
| CN102190847B (en) | Manufacture method for flame-retardant heat-insulation acrylic sheet | |
| CN103059696A (en) | Powder coating containing modified sepiolite powder and preparing method thereof | |
| CN102816482A (en) | Water-based nano reinforced anti-cracking building paint | |
| CN103275266B (en) | A kind of water soluble acrylic resin and preparation method thereof | |
| CN102659976A (en) | Novel aqueous light-cured alicyclic epoxy acrylic acid emulsion and preparation method thereof | |
| CN104212215A (en) | Long-acting corrosion resistant coating and preparation method thereof | |
| CN103525278B (en) | A kind of photocuring hammer paint | |
| CN103911057A (en) | Waterborne surface coating for three-rolling and one-baking process and preparation method thereof | |
| CN103601870A (en) | Epoxy resin for low-gloss powder paint, and preparation method and application thereof | |
| CN103602201B (en) | A kind of thermal-curable acrylic resin coating | |
| CN104532221A (en) | Chromium-free aluminum alloy passivator, preparation method thereof and aluminum alloy passivating method | |
| CN103897109A (en) | Acrylic modified polysiloxane resin and paint containing same | |
| CN103483893A (en) | Waterproof paint and preparation method thereof | |
| CN103923549A (en) | One-component water-based finish coating made from acrylic amino resin and preparation method of coating | |
| CN104178019B (en) | A kind of pottery photocureable coating | |
| CN104087114A (en) | Fireproof ceramic aluminum veneer | |
| CN105062247A (en) | Fluorocarbon emulsion resin waterproof coating | |
| CN106243965A (en) | A kind of glass baseplate water paint and preparation method thereof | |
| CN104058704B (en) | A kind of antibacterial water-tight concrete and preparation method thereof | |
| CN105348435A (en) | Preparing method of modified water-based acrylic emulsion, water-based acrylic composite resin finish paint and preparing method of water-based acrylic composite resin finish paint | |
| CN104673084A (en) | Novel ultraviolet cured acrylic coating for ceramics | |
| CN110358417A (en) | A kind of stainless steel PCM plate and its production technology | |
| CN104004432A (en) | Anticorrosive functional priming paint of switch cabinet, and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151202 Address after: 214000 Xinhua Road, Wuxi province national high tech Industrial Development Zone, No. innovation Creative Industrial Park, building, room 109, B, China, Jiangsu Applicant after: JIANGSU GAOBO ZHIRONG TECHNOLOGY Co.,Ltd. Address before: Xishan District of Beizhen tin Zhang Jing Yao Tang Wan 214000 Jiangsu city of Wuxi Province Applicant before: WUXI HUAMING CHEMICAL Co.,Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wang Wen Inventor before: Chen Guoliang |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160927 Address after: 519000 Guangdong city of Zhuhai province Gaolan Fine Chemical Zone weft eight road southwest period Patentee after: KITO CHEMICAL Co.,Ltd. Address before: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20160927 Address after: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: 214000 Xinhua Road, Wuxi province national high tech Industrial Development Zone, No. innovation Creative Industrial Park, building, room 109, B, China, Jiangsu Patentee before: JIANGSU GAOBO ZHIRONG TECHNOLOGY Co.,Ltd. |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A water-soluble acrylic resin and its preparation method Effective date of registration: 20231213 Granted publication date: 20160106 Pledgee: China Postal Savings Bank Co.,Ltd. Zhuhai Doumen Branch Pledgor: KITO CHEMICAL Co.,Ltd. Registration number: Y2023980071382 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |