CN103602201B - A kind of thermal-curable acrylic resin coating - Google Patents
A kind of thermal-curable acrylic resin coating Download PDFInfo
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- CN103602201B CN103602201B CN201310590281.6A CN201310590281A CN103602201B CN 103602201 B CN103602201 B CN 103602201B CN 201310590281 A CN201310590281 A CN 201310590281A CN 103602201 B CN103602201 B CN 103602201B
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- acrylic resin
- resin coating
- curable acrylic
- thermal
- butanols
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Abstract
The invention discloses a kind of thermal-curable acrylic resin coating. In weight portion, the present invention is composed of the following components: styrene: 40～60, ethyl acrylate: 30～50, maleic anhydride: 3～5, polyacrylamide: 10～20, butyl methacrylate: 3～6, butanols: 100～200, dibenzoyl peroxide: 2～4, methyl methacrylate: 20～30, the formalin of 37% weight concentration: 20～40, dimethylbenzene: 10～30. Compared with prior art, the present invention has following beneficial effect: (1) has good chemicals-resistant and decay resistance; (2) there is good UV resistant performance and impact strength.
Description
Technical field
The invention belongs to technical field of coatings, more specifically relate to a kind of thermal-curable acrylic resinCoating.
Background technology
Because hardness and the physical and chemical performance of acrylic resin paint are fine, therefore, except being used in family expensesOutside the industrial circle such as electrical equipment, automobile, be also widely used in hardware, woodenware, plastics, buildingThe fields such as decoration.
Summary of the invention
The object of the invention is to overcome the deficiency that prior art exists, a kind of heat curing-type third is providedOlefin(e) acid cold coating.
For achieving the above object, the present invention has taked following technical scheme:
A kind of thermal-curable acrylic resin coating, in weight portion, composed of the following components:
Styrene: 40～60, ethyl acrylate: 30～50, maleic anhydride: 3～5,
Polyacrylamide: 10～20, butyl methacrylate: 3～6, butanols: 100～200,
Dibenzoyl peroxide: 2～4, methyl methacrylate: 20～30,
The formalin of 37% weight concentration: 20～40, dimethylbenzene: 10～30.
The preparation method of described thermal-curable acrylic resin coating, comprises following technical step:
(1) by styrene, methyl methacrylate, ethyl acrylate and methacrylic acid fourthEster mixes, and stirs;
(2) polyacrylamide, dibenzoyl peroxide and butanols are mixed, dispersed with stirring is equalEven;
(3) product of step (1) and step (2) is mixed, be placed in reactor, addHeat, to 100～120 DEG C, is reacted 2～3 hours;
(4) be cooled to 50～60 DEG C, add maleic anhydride and formalin, disperse allEven;
(5) be warming up to 100～120 DEG C, add all the other components, react 2～3 hours;
(6) get final product to obtain finished product after being cooled to room temperature.
Compared with prior art, the present invention has following beneficial effect:
(1) there is good chemicals-resistant and decay resistance;
(2) there is good UV resistant performance and impact strength.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
A kind of thermal-curable acrylic resin coating, in weight portion, composed of the following components:
Styrene: 50, ethyl acrylate: 40, maleic anhydride: 4,
Polyacrylamide: 16, butyl methacrylate: 4, butanols: 160,
Dibenzoyl peroxide: 3, methyl methacrylate: 25,
The formalin of 37% weight concentration: 30, dimethylbenzene: 20.
The preparation method of described thermal-curable acrylic resin coating, comprises following technical step:
(1) by styrene, methyl methacrylate, ethyl acrylate and methacrylic acid fourthEster mixes, and stirs;
(2) polyacrylamide, dibenzoyl peroxide and butanols are mixed, dispersed with stirring is equalEven;
(3) product of step (1) and step (2) is mixed, be placed in reactor, addHeat, to 110 DEG C, is reacted 2 hours;
(4) be cooled to 60 DEG C, add maleic anhydride and formalin, be uniformly dispersed;
(5) be warming up to 100 DEG C, add all the other components, react 3 hours;
(6) get final product to obtain finished product after being cooled to room temperature.
Claims (1)
1. a thermal-curable acrylic resin coating, is characterized in that, in weight portion, byFollowing component composition:
Styrene: 40～60, ethyl acrylate: 30～50, maleic anhydride: 3～5,
Polyacrylamide: 10～20, butyl methacrylate: 3～6, butanols: 100～200,
Dibenzoyl peroxide: 2～4, methyl methacrylate: 20～30,
The formalin of 37% weight concentration: 20～40, dimethylbenzene: 10～30;
The preparation method of described thermal-curable acrylic resin coating, comprises following technical step:
(1) by styrene, methyl methacrylate, ethyl acrylate and methacrylic acid fourthEster mixes, and stirs;
(2) polyacrylamide, dibenzoyl peroxide and butanols are mixed, dispersed with stirring is even;
(3) product of step (1) and step (2) is mixed, be placed in reactor, heatingTo 100～120 DEG C, react 2～3 hours;
(4) be cooled to 50～60 DEG C, add maleic anhydride and formalin, disperse allEven;
(5) be warming up to 100～120 DEG C, add all the other components, react 2～3 hours;
(6) get final product to obtain finished product after being cooled to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310590281.6A CN103602201B (en) | 2013-11-20 | 2013-11-20 | A kind of thermal-curable acrylic resin coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310590281.6A CN103602201B (en) | 2013-11-20 | 2013-11-20 | A kind of thermal-curable acrylic resin coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103602201A CN103602201A (en) | 2014-02-26 |
| CN103602201B true CN103602201B (en) | 2016-05-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310590281.6A Active CN103602201B (en) | 2013-11-20 | 2013-11-20 | A kind of thermal-curable acrylic resin coating |
Country Status (1)
| Country | Link |
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| CN (1) | CN103602201B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104974574A (en) * | 2015-06-30 | 2015-10-14 | 苏州洋杰电子有限公司 | Insulating paint for electronic component and preparation method thereof |
| CN107652728A (en) * | 2016-07-23 | 2018-02-02 | 天津市新丽华色材有限责任公司 | A kind of super hydrophilic glass clear dope |
| CN106893381B (en) * | 2017-03-31 | 2019-07-02 | 辽宁三环树脂有限公司 | A kind of methacrylate modified reactive resin |
| CN113583526A (en) * | 2021-07-26 | 2021-11-02 | 畅的新材料科技（上海）有限公司 | Stain-resistant self-repairing coating and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60260661A (en) * | 1984-05-01 | 1985-12-23 | Aisin Chem Co Ltd | Acrylic resin coating composition |
| CN1317021A (en) * | 1998-08-06 | 2001-10-10 | 阿克佐诺贝尔公司 | Dialkyl peroxide compound and process using such for initiating chamical reaction |
| KR20100050220A (en) * | 2008-11-05 | 2010-05-13 | 제일모직주식회사 | (meth)acrylate copolymer and thermoplastic resin composition comprising thereof |
| CN102206309A (en) * | 2011-04-18 | 2011-10-05 | 广东同步化工股份有限公司 | Thermosetting acrylic resin for electrogilding oil and preparation method thereof |
| CN102766238A (en) * | 2012-08-13 | 2012-11-07 | 佛山市高明同德化工有限公司 | High-adhesion thermoset acrylic resin and preparation method thereof |
-
2013
- 2013-11-20 CN CN201310590281.6A patent/CN103602201B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60260661A (en) * | 1984-05-01 | 1985-12-23 | Aisin Chem Co Ltd | Acrylic resin coating composition |
| CN1317021A (en) * | 1998-08-06 | 2001-10-10 | 阿克佐诺贝尔公司 | Dialkyl peroxide compound and process using such for initiating chamical reaction |
| KR20100050220A (en) * | 2008-11-05 | 2010-05-13 | 제일모직주식회사 | (meth)acrylate copolymer and thermoplastic resin composition comprising thereof |
| CN102206309A (en) * | 2011-04-18 | 2011-10-05 | 广东同步化工股份有限公司 | Thermosetting acrylic resin for electrogilding oil and preparation method thereof |
| CN102766238A (en) * | 2012-08-13 | 2012-11-07 | 佛山市高明同德化工有限公司 | High-adhesion thermoset acrylic resin and preparation method thereof |
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|---|---|
| CN103602201A (en) | 2014-02-26 |
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| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Fang Bin Inventor before: Lu Zhiqiang |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20160414 Address after: 363107 Fujian city of Longhai province Zhangzhou Taiwanese Investment Zone jiaomei Town Long Industrial Park Applicant after: Formosan Union Chemical Corporation (Fujian) Address before: Wuxing District of Zhejiang city in Huzhou province 313000 eight Li Dian Zhen Zhang Jia Dai Cun Dong Shi Road No. 111-112 Applicant before: Huzhou Zhong Chen Construction Company Limited |
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