CN106588401A - Chitosan nutrient soil - Google Patents
Chitosan nutrient soil Download PDFInfo
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- CN106588401A CN106588401A CN201710103344.9A CN201710103344A CN106588401A CN 106588401 A CN106588401 A CN 106588401A CN 201710103344 A CN201710103344 A CN 201710103344A CN 106588401 A CN106588401 A CN 106588401A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G24/00—Growth substrates; Culture media; Apparatus or methods therefor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses chitosan nutrient soil. The chitosan nutrient soil is prepared from, by weight, 100-140 parts of humus, 15-25 parts of protein mud, 8-16 parts of furfural residue, 28-43 parts of pig manure, 10-18 parts of bone powder, 8-16 parts of vinegar residue, 6-14 parts of calcium-magnesium-phosphate fertilizer, 9-18 parts of ammonium nitrate, 18-25 parts of calcium ammonium nitrate, 1.5-2.5 parts of EDTA manganese chelate, 1.8-2.6 parts of diaminoferric xanthohumate, 3.7-4.8 parts of borax, 8-16 parts of sepiolite powder, 5-9 parts of flyash, 3-7 parts of kieselguhr, 18-29 parts of chitosan, 4-8 parts of calcined kaolin and 18-22 parts of modified soybean pulp. The chitosan nutrient soil is low in cost, high in aquosity and capable of effectively adsorbing soil nutrient components, has an antibacterial effect and brings rich nutrient substances to plants.
Description
Technical field
The present invention relates to Nutrition Soil technical field, more particularly to a kind of shitosan Nutrition Soil.
Background technology
Shitosan is that the chitin being widely present by nature is obtained through deacetylation, and chemical name is poly- Fructus Vitis viniferae
Osamine (1-4) -2- amino-B-D glucoses, from 1859, Frenchman Rouget was obtained first after shitosan, this natural polymer
The premium properties such as the biological functionality and the compatibility, blood compatibility, safety, microbic resolvability of son are extensive by all trades and professions
Concern, in many necks such as medicine, food, chemical industry, cosmetics, water process, METAL EXTRACTION and recovery, biochemical and biomedical engineering
The applied research in domain achieves major progress.Shitosan is natural plant nutrient growth promoter -- the raw material of foliage fertilizer, is gathered by shell
The foliage fertilizer of sugar compounding, can give plant insecticide, disease-resistant, play a part of fertilizer, animals and plants in soil can be decomposed again residual
Body and minor metallic element, so as to be converted into the nutrient of plant.There is no document report that shitosan is used for into Nutrition Soil at present
Prepare.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of shitosan Nutrition Soil, low cost, the property of water-bearing
It is good, energy active adsorption ASI systematic approach, and the effect with antibacterial, while also abundant nutrient substance can be carried out to vegetational zone.
A kind of shitosan Nutrition Soil proposed by the present invention, its raw material includes by weight:Fertile soil 100-140 parts, albumen
Mud 15-25 parts, alditol slag 8-16 part, pig manure 28-43 parts, bone meal 10-18 parts, vinegar 8-16 parts, calcium magnesium phosphate 6-14 parts, nitric acid
Ammonium 9-18 parts, calcium ammonium nitrate 18-25 parts, EDTA Chelated Manganese 1.5-2.5 parts, yellow humic acid diamine ferrum 1.8-2.6 parts, Borax 3.7-
4.8 parts, sepiolite powder 8-16 parts, flyash 5-9 parts, kieselguhr 3-7 parts, shitosan 18-29 parts, calcined kaolin 4-8 parts change
Property bean cake 18-22 parts.
Preferably, modified bean pulp is prepared using following technique:By guar gum, sodium hydroxide mix homogeneously, hydrogen peroxide is added
Sealing stirring, adds ethanol solution to stir, and adds vinylacetate, methyl methacrylate intensification stirring, regulation system
PH value adds polyamide polyamines, shitosan water mixing and stirring in neutrality, adds epoxychloropropane intensification stirring, adds bean
The dregs of rice, corn starch, water are mixed, and add sodium hydroxide to continue to stir, and in neutrality, spray drying is modified regulation system
Bean cake.
Preferably, modified bean pulp is prepared using following technique:By guar gum, sodium hydroxide mix homogeneously, hydrogen peroxide is added
Sealing stirring 80-120min, whipping temp is 60-70 DEG C, adds ethanol solution to stir, and adds vinylacetate, methyl
Acrylic acid methyl ester. is warming up to 115-122 DEG C of stirring 29-55min, and regulation system pH value adds polyamide polyamines, shell to gather in neutrality
Sucrose solution mixing and stirring, adds epoxychloropropane to be warming up to 83-88 DEG C of stirring 48-59min, adds bean cake, corn starch, water
1.5-2.5h is mixed, whipping temp is 70-83 DEG C, add sodium hydroxide to continue to stir 2.2-3.6h, regulation system is to being in
Neutrality, spray drying obtains modified bean pulp.
Preferably, modified bean pulp is prepared using following technique:By weight by 12-18 part guar gums, 50-80 part 0.8-
1.2mol/L sodium hydroxide mix homogeneously, adds 7-11 part dioxygens water-stop stirring 80-120min, and whipping temp is 60-70 DEG C,
Add 50-90 parts concentration to stir for 25-35wt% ethanol solution, add 4-8 part vinylacetates, 2-7 part methacrylic acids
Methyl ester is warming up to 115-122 DEG C of stirring 29-55min, and regulation system pH value adds 6-9 part polyamide polyamines, 3-7 parts in neutrality
Shitosan water mixing and stirring, adds 9-12 part epoxychloropropane to be warming up to 83-88 DEG C of stirring 48-59min, adds 45-65
Part bean cake, 27-43 part corn starchs, 250-280 parts water mix 1.5-2.5h, and whipping temp is 70-83 DEG C, adds 9-15
Part sodium hydroxide continues to stir 2.2-3.6h, and to being in neutral, spray drying obtains modified bean pulp to regulation system.
In modified bean pulp, after guar gum is using hydrogen peroxide oxidation process, through vinylacetate, methyl methacrylate
Grafting is processed, and wearability is good, good dispersion mix homogeneously with polyamide polyamines, shitosan and with epoxychloropropane ring-opening reaction,
Further coordinate with bean cake, corn starch, not only nutrient substance enriches, and bonding strength is high, it is wear-resisting with have excellent water-resistance, cost
Low, raw material is wide.
Preferably, fertile soil, albumen mud, alditol slag, pig manure, bone meal, the weight ratio of vinegar are 110-112:17-23:10-
14:30-40:12-16:10-18.
Preferably, the weight ratio of Borax, sepiolite powder, flyash, kieselguhr, shitosan, calcined kaolin, modified bean pulp
For 4-4.4:10-14:7-8:6-6.7:20-22:5-7:20-21.
Low cost of the present invention, the property of water-bearing is good, energy active adsorption ASI systematic approach, and the effect with antibacterial, while
Abundant nutrient substance can be carried out to vegetational zone.The present invention is using modified bean pulp and bamboo charcoal, sepiolite powder, calcined kaolin, diatom
Soil, Borax, flyash coordinate, and by proportioning rationally between control each component, nutrient can be carried out with reference to the regulation of fertilizer requirement of plant
Release, and it is internal containing a large amount of middle trace element and mineral, it is not only free from environmental pollution after degraded, and can continue to carry plant
For nutrient, intergranular space preferably provides support for the growth course of plant after granulating, and not broken, friction resistant pole
It is good;Albumen mud, bone meal, alditol slag, pig manure, vinegar coordinate, not only containing abundant plant crude fiber, beneficial to plant seedlings to battalion
Foster quick absorption, and the organic matter machine acid of Nutrition Soil can be improved, promote the growth of rice shoot.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of shitosan Nutrition Soil proposed by the present invention, its raw material includes by weight:100 parts of fertile soil, 25 parts of albumen mud, sugar
8 parts of aldehyde slag, 43 parts of pig manure, 10 parts of bone meal, 16 parts of vinegar, 6 parts of calcium magnesium phosphate, 18 parts of ammonium nitrate, 18 parts of calcium ammonium nitrate, EDTA chelas
Close 2.5 parts of manganese, 1.8 parts of yellow humic acid diamine ferrum, 4.8 parts of Borax, 8 parts of sepiolite powder, 9 parts of flyash, 3 parts of kieselguhr, shitosan
29 parts, 4 parts of calcined kaolin, 22 parts of modified bean pulp.
Modified bean pulp is prepared using following technique:12 parts of guar gums, 80 parts of 0.8mol/L sodium hydroxide are mixed by weight
Close uniform, add 11 parts of dioxygen water-stops to stir 80min, whipping temp is 70 DEG C, adds 50 parts of concentration to be 35wt% ethanol solution
Stir, add 4 parts of vinylacetates, 7 parts of methyl methacrylates to be warming up to 115 DEG C of stirring 55min, regulation system pH value
In neutrality, 6 parts of polyamide polyamines, 7 parts of shitosan water mixing and stirrings are added, add 9 parts of epoxychloropropane to be warming up to 88 DEG C
Stirring 48min, adds 65 parts of bean cake, 27 parts of corn starchs, 280 parts of water to mix 1.5h, and whipping temp is 83 DEG C, adds 9
Part sodium hydroxide continues to stir 3.6h, and to being in neutral, spray drying obtains modified bean pulp to regulation system.
Embodiment 2
A kind of shitosan Nutrition Soil proposed by the present invention, its raw material includes by weight:140 parts of fertile soil, 15 parts of albumen mud, sugar
16 parts of aldehyde slag, 28 parts of pig manure, 18 parts of bone meal, 8 parts of vinegar, 14 parts of calcium magnesium phosphate, 9 parts of ammonium nitrate, 25 parts of calcium ammonium nitrate, EDTA chelas
Close 1.5 parts of manganese, 2.6 parts of yellow humic acid diamine ferrum, 3.7 parts of Borax, 16 parts of sepiolite powder, 5 parts of flyash, 7 parts of kieselguhr, shitosan
18 parts, 8 parts of calcined kaolin, 18 parts of modified bean pulp.
Modified bean pulp is prepared using following technique:18 parts of guar gums, 50 parts of 1.2mol/L sodium hydroxide are mixed by weight
Close uniform, add 7 parts of dioxygen water-stops to stir 120min, whipping temp is 60 DEG C, adds 90 parts of concentration to be 25wt% ethanol solution
Stir, add 8 parts of vinylacetates, 2 parts of methyl methacrylates to be warming up to 122 DEG C of stirring 29min, regulation system pH value
In neutrality, 9 parts of polyamide polyamines, 3 parts of shitosan water mixing and stirrings are added, add 12 parts of epoxychloropropane to be warming up to 83 DEG C
Stirring 59min, adds 45 parts of bean cake, 43 parts of corn starchs, 250 parts of water to mix 2.5h, and whipping temp is 70 DEG C, adds 15
Part sodium hydroxide continues to stir 2.2h, and to being in neutral, spray drying obtains modified bean pulp to regulation system.
Embodiment 3
A kind of shitosan Nutrition Soil proposed by the present invention, its raw material includes by weight:110 parts of fertile soil, 23 parts of albumen mud, sugar
10 parts of aldehyde slag, 40 parts of pig manure, 12 parts of bone meal, 18 parts of vinegar, 10 parts of calcium magnesium phosphate, 14 parts of ammonium nitrate, 20 parts of calcium ammonium nitrate, EDTA
2.2 parts of Chelated Manganese, 2 parts of yellow humic acid diamine ferrum, 4.4 parts of Borax, 10 parts of sepiolite powder, 8 parts of flyash, 6 parts of kieselguhr, shitosan
22 parts, 5 parts of calcined kaolin, 21 parts of modified bean pulp.
Modified bean pulp is prepared using following technique:By weight by 14 parts of guar gums, 70 parts of 1mol/L sodium hydroxide mixing
Uniformly, add 10 parts of dioxygen water-stops to stir 100min, whipping temp is 67 DEG C, add 60 parts of concentration to be 32wt% ethanol solution
Stir, add 5 parts of vinylacetates, 6 parts of methyl methacrylates to be warming up to 118 DEG C of stirring 50min, regulation system pH value
In neutrality, 7 parts of polyamide polyamines, 6 parts of shitosan water mixing and stirrings are added, add 10 parts of epoxychloropropane to be warming up to 86 DEG C
Stirring 50min, adds 60 parts of bean cake, 30 parts of corn starchs, 270 parts of water to mix 2h, and whipping temp is 80 DEG C, adds 12 parts
Sodium hydroxide continues to stir 3.2h, and in neutrality, spray drying obtains modified bean pulp to regulation system.
Embodiment 4
A kind of shitosan Nutrition Soil proposed by the present invention, its raw material includes by weight:112 parts of fertile soil, 17 parts of albumen mud, sugar
14 parts of aldehyde slag, 30 parts of pig manure, 16 parts of bone meal, 10 parts of vinegar, 12 parts of calcium magnesium phosphate, 10 parts of ammonium nitrate, 22 parts of calcium ammonium nitrate, EDTA
1.8 parts of Chelated Manganese, 2.4 parts of yellow humic acid diamine ferrum, 4 parts of Borax, 14 parts of sepiolite powder, 7 parts of flyash, 6.7 parts of kieselguhr, shell gathers
20 parts of sugar, 7 parts of calcined kaolin, 20 parts of modified bean pulp.
Modified bean pulp is prepared using following technique:16 parts of guar gums, 60 parts of 1.1mol/L sodium hydroxide are mixed by weight
Close uniform, add 8 parts of dioxygen water-stops to stir 110min, whipping temp is 65 DEG C, adds 80 parts of concentration to be 28wt% ethanol solution
Stir, add 7 parts of vinylacetates, 4 parts of methyl methacrylates to be warming up to 120 DEG C of stirring 30min, regulation system pH value
In neutrality, 8 parts of polyamide polyamines, 4 parts of shitosan water mixing and stirrings are added, add 11 parts of epoxychloropropane to be warming up to 84 DEG C
Stirring 55min, adds 50 parts of bean cake, 40 parts of corn starchs, 260 parts of water to mix 2.3h, and whipping temp is 75 DEG C, adds 14
Part sodium hydroxide continues to stir 2.8h, and to being in neutral, spray drying obtains modified bean pulp to regulation system.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (6)
1. a kind of shitosan Nutrition Soil, it is characterised in that its raw material includes by weight:Fertile soil 100-140 parts, albumen mud
15-25 parts, alditol slag 8-16 part, pig manure 28-43 parts, bone meal 10-18 parts, vinegar 8-16 parts, calcium magnesium phosphate 6-14 parts, ammonium nitrate
9-18 parts, calcium ammonium nitrate 18-25 parts, EDTA Chelated Manganese 1.5-2.5 parts, yellow humic acid diamine ferrum 1.8-2.6 parts, Borax 3.7-4.8
Part, sepiolite powder 8-16 parts, flyash 5-9 parts, kieselguhr 3-7 parts, shitosan 18-29 parts, calcined kaolin 4-8 parts are modified
Bean cake 18-22 parts.
2. shitosan Nutrition Soil according to claim 1, it is characterised in that modified bean pulp is prepared using following technique:By melon
That glue, sodium hydroxide mix homogeneously, add the stirring of dioxygen water-stop, add ethanol solution to stir, addition vinylacetate,
Methyl methacrylate heats up and stirs, and regulation system pH value adds polyamide polyamines, shitosan water to mix in neutrality
It is even, add epoxychloropropane to heat up and stir, add bean cake, corn starch, water to mix, add sodium hydroxide to continue stirring,
To in neutrality, spray drying obtains modified bean pulp to regulation system.
3. shitosan Nutrition Soil according to claim 1, it is characterised in that modified bean pulp is prepared using following technique:By melon
That glue, sodium hydroxide mix homogeneously, add dioxygen water-stop stirring 80-120min, and whipping temp is 60-70 DEG C, adds ethanol
Solution stirring is uniform, adds vinylacetate, methyl methacrylate to be warming up to 115-122 DEG C of stirring 29-55min, adjusts body
It is pH value in neutrality, adds polyamide polyamines, shitosan water mixing and stirring, adds epoxychloropropane to be warming up to 83-88 DEG C
Stirring 48-59min, adds bean cake, corn starch, water to mix 1.5-2.5h, and whipping temp is 70-83 DEG C, adds hydrogen-oxygen
Change sodium to continue to stir 2.2-3.6h, in neutrality, spray drying obtains modified bean pulp to regulation system.
4. shitosan Nutrition Soil according to claim 1, it is characterised in that modified bean pulp is prepared using following technique:By weight
12-18 part guar gums, 50-80 part 0.8-1.2mol/L sodium hydroxide mix homogeneously are added 7-11 part dioxygen water-stops by amount part
Stirring 80-120min, whipping temp is 60-70 DEG C, adds 50-90 parts concentration to stir for 25-35wt% ethanol solution, plus
Enter 4-8 part vinylacetates, 2-7 part methyl methacrylates and be warming up to 115-122 DEG C of stirring 29-55min, regulation system pH value
In neutrality, 6-9 part polyamide polyamines, 3-7 part shitosan water mixing and stirrings are added, add 9-12 parts epoxychloropropane to heat up
To 83-88 DEG C of stirring 48-59min, 45-65 part bean cake, 27-43 part corn starchs, 250-280 parts water is added to mix 1.5-
2.5h, whipping temp is 70-83 DEG C, adds 9-15 parts sodium hydroxide to continue to stir 2.2-3.6h, and regulation system is in neutrality, spray
Mist is dried to obtain modified bean pulp.
5. shitosan Nutrition Soil according to claim 1, it is characterised in that fertile soil, albumen mud, alditol slag, pig manure, bone
Powder, the weight ratio of vinegar are 110-112:17-23:10-14:30-40:12-16:10-18.
6. shitosan Nutrition Soil according to claim 1, it is characterised in that Borax, sepiolite powder, flyash, kieselguhr, shell
Polysaccharide, calcined kaolin, the weight ratio of modified bean pulp are 4-4.4:10-14:7-8:6-6.7:20-22:5-7:20-21.
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CN201710103344.9A CN106588401A (en) | 2017-02-24 | 2017-02-24 | Chitosan nutrient soil |
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CN201710103344.9A CN106588401A (en) | 2017-02-24 | 2017-02-24 | Chitosan nutrient soil |
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107080107A (en) * | 2017-05-09 | 2017-08-22 | 全椒县鮰鱼养殖专业合作社 | A kind of feed of Gai Shan Channel-catfish meat quality of fish |
CN107125451A (en) * | 2017-05-10 | 2017-09-05 | 郑其全 | It is a kind of to reduce the feed of the ewe incidence of disease |
CN107156432A (en) * | 2017-05-09 | 2017-09-15 | 全椒县鮰鱼养殖专业合作社 | A kind of mixed feed of Cu Jin Channel-catfish fishes growth |
CN107183338A (en) * | 2017-05-11 | 2017-09-22 | 全椒县鮰鱼养殖专业合作社 | A kind of feed of Gai Shan Channel-catfish fish local flavors |
CN107212163A (en) * | 2017-05-10 | 2017-09-29 | 郑其全 | A kind of mixed feed for promoting sheep quickly to increase weight |
CN107353089A (en) * | 2017-07-19 | 2017-11-17 | 合肥申沃园艺有限公司 | A kind of Composite nutrient soil for potted plant |
CN107602227A (en) * | 2017-09-26 | 2018-01-19 | 安庆市望马楼生态农业发展有限公司 | A kind of high mountain oil tea fertilizer of improved soil |
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CN103408381A (en) * | 2013-07-03 | 2013-11-27 | 安徽程翔肥料有限公司 | Special organic/inorganic compound fertilizer for tea and preparation method thereof |
CN104058827A (en) * | 2014-05-28 | 2014-09-24 | 马鞍山市心洲葡萄专业合作社 | Special biological organic complex fertilizer for growth of camphor tree and preparation method thereof |
CN104387172A (en) * | 2014-11-11 | 2015-03-04 | 罗宇 | Special insecticide-fertilizer for preventing and controlling actinonema rosae |
CN105993756A (en) * | 2016-04-21 | 2016-10-12 | 芜湖格林美提子生态园有限公司 | Planting method for mulberry |
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CN103408381A (en) * | 2013-07-03 | 2013-11-27 | 安徽程翔肥料有限公司 | Special organic/inorganic compound fertilizer for tea and preparation method thereof |
CN104058827A (en) * | 2014-05-28 | 2014-09-24 | 马鞍山市心洲葡萄专业合作社 | Special biological organic complex fertilizer for growth of camphor tree and preparation method thereof |
CN104387172A (en) * | 2014-11-11 | 2015-03-04 | 罗宇 | Special insecticide-fertilizer for preventing and controlling actinonema rosae |
CN105993756A (en) * | 2016-04-21 | 2016-10-12 | 芜湖格林美提子生态园有限公司 | Planting method for mulberry |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107080107A (en) * | 2017-05-09 | 2017-08-22 | 全椒县鮰鱼养殖专业合作社 | A kind of feed of Gai Shan Channel-catfish meat quality of fish |
CN107156432A (en) * | 2017-05-09 | 2017-09-15 | 全椒县鮰鱼养殖专业合作社 | A kind of mixed feed of Cu Jin Channel-catfish fishes growth |
CN107125451A (en) * | 2017-05-10 | 2017-09-05 | 郑其全 | It is a kind of to reduce the feed of the ewe incidence of disease |
CN107212163A (en) * | 2017-05-10 | 2017-09-29 | 郑其全 | A kind of mixed feed for promoting sheep quickly to increase weight |
CN107183338A (en) * | 2017-05-11 | 2017-09-22 | 全椒县鮰鱼养殖专业合作社 | A kind of feed of Gai Shan Channel-catfish fish local flavors |
CN107353089A (en) * | 2017-07-19 | 2017-11-17 | 合肥申沃园艺有限公司 | A kind of Composite nutrient soil for potted plant |
CN107602227A (en) * | 2017-09-26 | 2018-01-19 | 安庆市望马楼生态农业发展有限公司 | A kind of high mountain oil tea fertilizer of improved soil |
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