CN106577853A - Chinese herbal medicine control agent for kiwifruit canker and preparation method thereof - Google Patents
Chinese herbal medicine control agent for kiwifruit canker and preparation method thereof Download PDFInfo
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- CN106577853A CN106577853A CN201610999886.4A CN201610999886A CN106577853A CN 106577853 A CN106577853 A CN 106577853A CN 201610999886 A CN201610999886 A CN 201610999886A CN 106577853 A CN106577853 A CN 106577853A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/06—Aluminium; Calcium; Magnesium; Compounds thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D3/00—Calcareous fertilisers
- C05D3/02—Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The invention discloses a Chinese herbal medicine control agent for kiwifruit canker and a preparation method thereof, and belongs to the technical field of Chinese herbal medicine pesticides. The raw materials include 3-8 parts of pomegranate, 3-8 parts of hawthorn leaves, 2-7 parts of garlic, 1-5 parts of konjac, 1-4 parts of polygonatum, 2-5 parts of Lycoris radiata Herb, 2-5 parts of lime, 1-3 parts of cortex lycii radicis, 2-3 parts of Ophiopogon japonicas, 2-5 parts of lemon slices, 3-7 parts of areca nut, 3-7 parts of semen litchi, 3-6 parts of vine of multiflower knotweed, 3-7 parts of water chestnut plant, 3-6 parts of Lysimachia christinae Hance, 1-4 parts of uncaria rhynchophylla, 1-3 parts of Mangnolia officinalis, 2-3 parts of radix dipsaci, 2-4 parts of rhizoma atractylodis and 3-5 parts of ash bark. The preparation method comprises the following steps: raw material treatment, extraction, spray drying, drying and packaging. The raw materials of the Chinese herbal medicine control agent for kiwifruit canker are nature materials and are non-toxic, non-residue and pollution-free. The Chinese herbal medicine control agent is simple in preparation method, easy in operation, low in production cost and easy to use.
Description
Technical field
The invention belongs to pesticide made of Chinese medicinal herbs technical field, more particularly to a kind of agent of Prospect on Kiwifruit Bacterial Canker herbal control and its
Preparation method.
Background technology
Kiwi berry is a kind of nutritious integration of drinking and medicinal herbs health fruit, with nourishing and fit keeping function, clearing away heat and promoting diuresis, fluid dryness
The effects such as.High reputation is enjoyed in the international market, is one of emerging fruit that our times various countries competitively develop.Due to macaque
These nutritive values of peach, the temperature of orchard worker's plantation is constantly raised, but because many orchard workers lack the knowledge of scientific prevention and cure disease,
Cause Chinese gooseberry garden disease more and more to weigh, have a strong impact on the sound development of Kiwi berry industry.
Prospect on Kiwifruit Bacterial Canker is that a kind of disease the most serious is endangered in Kiwi berry disease, canker mostly occur trunk,
At side shoot and its branching, initial stage cortex protuberance, tissue softens, and water soaking mode is in irregular shape in bronzing, spreads to xylem
Rot, later stage slightly drying shrinkage, depression are such as prevented and treated not in time, can cause to ruin garden in 2-3.Fall ill at the beginning of general 3 months, late April morbidity
Seriously, as the rising development of temperature slows down.The freeze injury of tree body and resistance have when the disease betides weather conditions then, survives the winter
Close.
At present the disease is mainly prevented and treated by chemical method, typically after fruit harvest or before entering the winter, sprays eradicant sterilization
Agent, root out the germ that hides.After the beginning of spring to rudiment, apply interior suction curative fungicide agent, suppress germ extension.After rudiment extremely
Thank to the florescence, it is to prevent and treat having for the disease to spray the mineral-type agricultural chemicals such as natural disposition bactericide, symptom management, Bordeaux mixture or lime sulfur that goes out
Effect medicament.Though chemical prevention medicament has kills the quick advantage of disease, persticide residue is big, and long-term consumption applied this kind of
The food of control agent can make human body produce chronic toxicity, especially the problems such as Delayed onset neurotoxic, to the existence ring of the mankind
Border constitutes a threat to;In addition, the extensive application of chemicals compromises the ecological agriculture, serious dirt is caused to soil and water resource
Dye, green, environmentally friendly, healthy and sustainable development the theory of serious non-compliance Modern times call.
The content of the invention
The purpose of the present invention be for solve Kiwi berry planting process in chemical pesticide abuse, cause soil and water resource tight
A kind of problem of heavily contaminated, there is provided Prospect on Kiwifruit Bacterial Canker herbal control agent and preparation method thereof.To realize the object of the invention institute
The technical scheme for using is:
A kind of Prospect on Kiwifruit Bacterial Canker herbal control agent, including the raw material of following parts by weight:Pomegranate 3-8 parts, leaves of Hawthorn 3-8
Part, garlic 2-7 parts, konjaku 1-5 parts, sealwort 1-4 parts, crow garlic 2-5 parts, lime 2-5 parts, root bark of Chinese wolf-berry 1-3 parts, tuber of dwarf lilyturf 2-3 part,
Lemon tablet 2-5 parts, betel nut 3-7 parts, semen litchi 3-7 parts, vine of multiflower knotweed 3-6 parts, water chestnut plant 3-7 parts, desmodium 3-6 parts, yncaria stem with hooks
1-4 parts, bark of official magnolia 1-3 part, teasel root 2-3 parts, rhizoma atractylodis 2-4 parts and bark of ash 3-5 parts.
Preferably, described herbal control agent also includes peach branch 2-6 parts.
Preferably, described herbal control agent also includes Poria cocos 2-5 parts.
Preferably, described pomegranate, leaves of Hawthorn, garlic, konjaku, sealwort, crow garlic, lime, the root bark of Chinese wolf-berry, the tuber of dwarf lilyturf, lemon
Piece, betel nut, semen litchi, the vine of multiflower knotweed, water chestnut plant, desmodium, yncaria stem with hooks, peach branch, Poria cocos, the bark of official magnolia, teasel root, rhizoma atractylodis and the bark of ash are equal
For the raw material being dried after drying.
Preferably, described raw material need to be crushed to particle diameter for 1-35mm through broken.
A kind of preparation method of Prospect on Kiwifruit Bacterial Canker herbal control agent, including it is Feedstock treating, extraction, spray drying, dry
Dry and packaging, concrete preparation process is as follows:
Feedstock treating:By pomegranate, leaves of Hawthorn, garlic, konjaku, sealwort, crow garlic, lime, the root bark of Chinese wolf-berry, the tuber of dwarf lilyturf, lemon tablet, Bin
It is 1-35mm that bulky, semen litchi, the vine of multiflower knotweed, water chestnut plant, desmodium, yncaria stem with hooks, the bark of official magnolia, teasel root, rhizoma atractylodis and the bark of ash are crushed to particle diameter,
Obtain mixture of Chinese herbal medicines;
Extract:Mixture of Chinese herbal medicines is added water to cook into material, the amount for adding water is 3-6 times of Traditional Chinese drug mixture, decocts to ripe rotten, decocts
The time is boiled for 3-7 hours, after decoction terminates, is filtered, filtrate concentration must concentrate filtrate, standby;
It is spray-dried:Concentration filtrate is sent in spray dryer, preparation forms extract powder;
It is dried:Extract powder is dried, temperature is 60-80 DEG C, and water content control obtains solid particle, solid below 5%
Sieve after particle cooling, obtain uniform solid particle;
Packaging:The solid particle of above-mentioned acquisition is loaded into air-locked aluminium foil bag, sealing preserve, i.e. finished product.
Preferably, the amount that described extraction adds water is 3-5 times of raw material, and decocting time is 4-6 hours.Described Kiwi berry
The using method of canker herbal control agent is that product is diluted into the 300-500 times of cauline leaf for being sprayed on Kiwi berry and root week
Enclose, effectively the generation of preventing and treating Prospect on Kiwifruit Bacterial Canker.
Beneficial effects of the present invention are:
1st, the raw material of control agent of the invention is the Nature material, and composition is nontoxic, and noresidue is nuisanceless, and the present invention is anti-
Control agent and process for producing same simple, it is easy to operate, low production cost is easy to use.
2nd, control agent of the invention can effectively prevent and treat the generation of Prospect on Kiwifruit Bacterial Canker, and one time killing rate reaches more than 90%,
And resistance is difficult, can persistently use, and some agricultural chemicals, even highly toxic pesticide, most Second Years, disease has just adapted to medicine
Property, double using just telling on.
3rd, not only killing rate is high for herbal control agent of the present invention, and efficacy stability, and the raw material after drug effect volatilization can also leaf
Leaven provides nutrient as plant, and its content of organic matter is more than 2 times of fertilizer, it is possible to increase Kiwi berry it is photosynthetic
Effect, to the mouthfeel of Kiwi berry the purpose of lifting is reached.The control agent also contains substantial amounts of C4 materials, reaches Kiwi berry after use
To the effect of volume increase.Therefore.Not only killing rate is high for herbal control agent of the present invention, and reduces Productive statistics, improves agriculture
The utilization rate of industry byproduct.
Specific embodiment
The present invention program is described in further detail with reference to embodiment, the description below is merely to explain this
It is bright, its content is not defined.
Embodiment 1
Feedstock treating:By pomegranate 3kg, leaves of Hawthorn 3kg, garlic 2kg, konjaku 1kg, sealwort 1kg, crow garlic 2kg, lime 2kg,
Bone skin 1kg, tuber of dwarf lilyturf 2kg, lemon tablet 2kg, betel nut 7kg, semen litchi 7kg, vine of multiflower knotweed 6kg, water chestnut plant 3kg, desmodium 3kg,
It is 1mm that yncaria stem with hooks 1kg, bark of official magnolia 1kg, teasel root 2kg, rhizoma atractylodis 2kg and bark of ash 3kg are crushed to particle diameter, obtains mixture of Chinese herbal medicines;
Extract:Mixture of Chinese herbal medicines is added water to cook into material, the amount for adding water is 162kg, decocted to ripe rotten, decocting time is 3 little
When, after decoction terminates, to filter, filtrate concentration must concentrate filtrate, standby;
It is spray-dried:Concentration filtrate is sent in spray dryer, preparation forms extract powder;
It is dried:Extract powder is dried, temperature is 60 DEG C, and water content control obtains solid particle, solid particle below 5%
Sieve after cooling, obtain uniform solid particle;
Packaging:The solid particle of above-mentioned acquisition is loaded into air-locked aluminium foil bag, sealing preserve, i.e. finished product.
Embodiment 2
Feedstock treating:By pomegranate 5kg, leaves of Hawthorn 4kg, garlic 6kg, konjaku 2kg, sealwort 3kg, crow garlic 4kg, lime 3kg,
Bone skin 2kg, tuber of dwarf lilyturf 2kg, lemon tablet 4kg, betel nut 3kg, semen litchi 5kg, vine of multiflower knotweed 4kg, water chestnut plant 5kg, desmodium 4kg,
It is 10mm that yncaria stem with hooks 3kg, peach branch 2kg, bark of official magnolia 2kg, teasel root 3kg, rhizoma atractylodis 3kg and bark of ash 4kg are crushed to particle diameter, obtains Chinese herbal medicine and mixes
Compound;
Extract:Mixture of Chinese herbal medicines is added water to cook into material, the amount for adding water is 292kg, decocted to ripe rotten, decocting time is 4 little
When, after decoction terminates, to filter, filtrate concentration must concentrate filtrate, standby;
It is spray-dried:Concentration filtrate is sent in spray dryer, preparation forms extract powder;
It is dried:Extract powder is dried, temperature is 65 DEG C, and water content control obtains solid particle, solid particle below 5%
Sieve after cooling, obtain uniform solid particle;
Packaging:The solid particle of above-mentioned acquisition is loaded into air-locked aluminium foil bag, sealing preserve, i.e. finished product.
Embodiment 3
Feedstock treating:By pomegranate 4kg, leaves of Hawthorn 7kg, garlic 5kg, konjaku 4kg, sealwort 2kg, crow garlic 4kg, lime 3kg,
Bone skin 3kg, tuber of dwarf lilyturf 2kg, lemon tablet 3kg, betel nut 6kg, semen litchi 5kg, vine of multiflower knotweed 4kg, water chestnut plant 6kg, desmodium 4kg,
It is 35mm that yncaria stem with hooks 3kg, peach branch 6kg, Poria cocos 2kg, bark of official magnolia 3kg, teasel root 2kg, rhizoma atractylodis 4kg and bark of ash 4kg are crushed to particle diameter, is obtained
Mixture of Chinese herbal medicines;
Extract:Mixture of Chinese herbal medicines is added water to cook into material, the amount for adding water is 430kg, decocted to ripe rotten, decocting time is 5 little
When, after decoction terminates, to filter, filtrate concentration must concentrate filtrate, standby;
It is spray-dried:Concentration filtrate is sent in spray dryer, preparation forms extract powder;
It is dried:Extract powder is dried, temperature is 70 DEG C, and water content control obtains solid particle, solid particle below 5%
Sieve after cooling, obtain uniform solid particle;
Packaging:The solid particle of above-mentioned acquisition is loaded into air-locked aluminium foil bag, sealing preserve, i.e. finished product.
Embodiment 4
Feedstock treating:By pomegranate 4kg, leaves of Hawthorn 6kg, garlic 6kg, konjaku 2kg, sealwort 4kg, crow garlic 3kg, lime 3kg,
Bone skin 3kg, tuber of dwarf lilyturf 2kg, lemon tablet 5kg, betel nut 6kg, semen litchi 3kg, vine of multiflower knotweed 4kg, water chestnut plant 5kg, desmodium 5kg,
It is 20mm that yncaria stem with hooks 4kg, peach branch 5kg, Poria cocos 5kg, bark of official magnolia 2kg, teasel root 2kg, rhizoma atractylodis 4kg and bark of ash 5kg are crushed to particle diameter, is obtained
Mixture of Chinese herbal medicines;
Extract:Mixture of Chinese herbal medicines is added water to cook into material, the amount for adding water is 392kg, decocted to ripe rotten, decocting time is 6 little
When, after decoction terminates, to filter, filtrate concentration must concentrate filtrate, standby;
It is spray-dried:Concentration filtrate is sent in spray dryer, preparation forms extract powder;
It is dried:Extract powder is dried, temperature is 75 DEG C, and water content control obtains solid particle, solid particle below 5%
Sieve after cooling, obtain uniform solid particle;
Packaging:The solid particle of above-mentioned acquisition is loaded into air-locked aluminium foil bag, sealing preserve, i.e. finished product.
Embodiment 5
Feedstock treating:By pomegranate 8kg, leaves of Hawthorn 8kg, garlic 7kg, konjaku 5kg, sealwort 4kg, crow garlic 5kg, lime 5kg,
Bone skin 3kg, tuber of dwarf lilyturf 3kg, lemon tablet 5kg, betel nut 3kg, semen litchi 3kg, vine of multiflower knotweed 3kg, water chestnut plant 7kg, desmodium 6kg,
It is 25mm that yncaria stem with hooks 4kg, Poria cocos 3kg, bark of official magnolia 3kg, teasel root 3kg, rhizoma atractylodis 4kg and bark of ash 5kg are crushed to particle diameter, obtains Chinese herbal medicine mixing
Thing;
Extract:Mixture of Chinese herbal medicines is added water to cook into material, the amount for adding water is 582kg, decocted to ripe rotten, decocting time is 7 little
When, after decoction terminates, to filter, filtrate concentration must concentrate filtrate, standby;
It is spray-dried:Concentration filtrate is sent in spray dryer, preparation forms extract powder;
It is dried:Extract powder is dried, temperature is 80 DEG C, and water content control obtains solid particle, solid particle below 5%
Sieve after cooling, obtain uniform solid particle;
Packaging:The solid particle of above-mentioned acquisition is loaded into air-locked aluminium foil bag, sealing preserve, i.e. finished product.
The above, the only specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, any
The change or replacement expected without creative work, all should be included within the scope of the present invention.Therefore, it is of the invention
The protection domain that protection domain should be limited by claims is defined.
Claims (7)
1. a kind of Prospect on Kiwifruit Bacterial Canker herbal control agent, it is characterised in that including the raw material of following parts by weight:Pomegranate 3-8
Part, leaves of Hawthorn 3-8 part, garlic 2-7 parts, konjaku 1-5 parts, sealwort 1-4 parts, crow garlic 2-5 parts, lime 2-5 parts, root bark of Chinese wolf-berry 1-3
Part, tuber of dwarf lilyturf 2-3 part, lemon tablet 2-5 parts, betel nut 3-7 parts, semen litchi 3-7 parts, vine of multiflower knotweed 3-6 parts, water chestnut plant 3-7 parts, money
Careless 3-6 parts, yncaria stem with hooks 1-4 parts, bark of official magnolia 1-3 part, teasel root 2-3 parts, rhizoma atractylodis 2-4 parts and bark of ash 3-5 parts.
2. Prospect on Kiwifruit Bacterial Canker herbal control agent according to claim 1, it is characterised in that described herbal control agent
Also include peach branch 2-6 parts.
3. Prospect on Kiwifruit Bacterial Canker herbal control agent according to claim 1 or claim 2, it is characterised in that described Chinese herbal medicine is prevented
Controlling agent also includes Poria cocos 2-5 parts.
4. the Prospect on Kiwifruit Bacterial Canker herbal control agent according to any one of claim 1-3, it is characterised in that described stone
Pomegranate, leaves of Hawthorn, garlic, konjaku, sealwort, crow garlic, lime, the root bark of Chinese wolf-berry, the tuber of dwarf lilyturf, lemon tablet, betel nut, semen litchi, the vine of multiflower knotweed, water chestnut
Shepherd's purse plant, desmodium, yncaria stem with hooks, peach branch, Poria cocos, the bark of official magnolia, teasel root, rhizoma atractylodis and the bark of ash are the raw material being dried after drying.
5. Prospect on Kiwifruit Bacterial Canker herbal control agent according to claim 4, it is characterised in that described raw material need to be through broken
It is broken, particle diameter is crushed to for 1-35mm.
6. the preparation method of Prospect on Kiwifruit Bacterial Canker herbal control agent according to claim 1, including Feedstock treating, extraction,
It is spray-dried, is dried and packs, it is characterised in that concrete preparation process is as follows:
Feedstock treating:By pomegranate, leaves of Hawthorn, garlic, konjaku, sealwort, crow garlic, lime, the root bark of Chinese wolf-berry, the tuber of dwarf lilyturf, lemon tablet, Bin
It is 1-35mm that bulky, semen litchi, the vine of multiflower knotweed, water chestnut plant, desmodium, yncaria stem with hooks, the bark of official magnolia, teasel root, rhizoma atractylodis and the bark of ash are crushed to particle diameter,
Obtain mixture of Chinese herbal medicines;
Extract:Mixture of Chinese herbal medicines is added water to cook into material, the amount for adding water is 3-6 times of Traditional Chinese drug mixture, decocts to ripe rotten, decocts
The time is boiled for 3-7 hours, after decoction terminates, is filtered, filtrate concentration must concentrate filtrate, standby;
It is spray-dried:Concentration filtrate is sent in spray dryer, preparation forms extract powder;
It is dried:Extract powder is dried, temperature is 60-80 DEG C, and water content control obtains solid particle, solid below 5%
Sieve after particle cooling, obtain uniform solid particle;
Packaging:The solid particle of above-mentioned acquisition is loaded into air-locked aluminium foil bag, sealing preserve, i.e. finished product.
7. the preparation method of Prospect on Kiwifruit Bacterial Canker herbal control agent according to claim 6, it is characterised in that described carries
The amount that adds water is taken for 3-5 times of raw material, decocting time is 4-6 hours.
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Cited By (2)
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CN109180304A (en) * | 2018-08-31 | 2019-01-11 | 广西南宁大地肥田农业科技有限公司 | A kind of prevention and treatment crop canker special plant nutrient and preparation method thereof |
CN109315447A (en) * | 2017-07-31 | 2019-02-12 | 安树义 | A kind of downy mildew of fruits and vegetables sterilization aqua and its production technology |
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CN105994451A (en) * | 2016-07-29 | 2016-10-12 | 广西素安生态农业有限公司 | Chinese herbal medicine control agent for common diseases of strawberries and preparation method thereof |
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CN102320894A (en) * | 2011-06-21 | 2012-01-18 | 吕金波 | The many mixture of a kind of biological pesticide |
CN104336109A (en) * | 2013-07-29 | 2015-02-11 | 青岛艾华隆生物科技有限公司 | High efficiency non-toxic pesticide |
CN105850449A (en) * | 2016-04-21 | 2016-08-17 | 固镇县传红家庭农场 | Method for planting high-yield disease-resistant tomatoes |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN109315447A (en) * | 2017-07-31 | 2019-02-12 | 安树义 | A kind of downy mildew of fruits and vegetables sterilization aqua and its production technology |
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Application publication date: 20170426 |