CN106567276A - Roll paper for smoking articles - Google Patents
Roll paper for smoking articles Download PDFInfo
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- CN106567276A CN106567276A CN201610802278.XA CN201610802278A CN106567276A CN 106567276 A CN106567276 A CN 106567276A CN 201610802278 A CN201610802278 A CN 201610802278A CN 106567276 A CN106567276 A CN 106567276A
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- Prior art keywords
- mass
- paper
- smoking article
- calcium carbonate
- pulp
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
- A24D1/022—Papers for roll-your-own cigarettes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
A technical problem to be solved by the present invention is to provide a roll for a smoking article for reducing the amount of ash produced by the burning of cigarettes from the cigarette. Specifically, the paper contains, for example, pulp, calcium carbonate, D50 median particle diameter obtained by laser diffraction scattering, 1.8 Mu m or more and 5.5 Mu m or less, and a combustion modifier, the content of calcium carbonate is 35% by mass or more and less than 50% by mass, and the content of the combustion modifier is 0.6% by mass or more and 4.0% by mass or less.
Description
Technical field
The present invention relates to the smoking article volume that the ash produced by the burning of medicated cigarette when reducing smoking disperses from medicated cigarette, comes off
Paper.
Background technology
Medicated cigarette is the article that tobacco shred etc. is wrapped up with smoking article coil paper.Generally, the smoking article coil paper by with
Under be fabricated by, add in the non-wood pulp of wood pulp, Caulis et Folium Lini etc. for making Calcium Carbonate etc. that opacity improves
Then filler carries out copy paper, and then is coated with and adjusts for the burning for adjusting the alkali metal salt of combustible organic acid, mineral acid etc.
Agent.
When the smoking article coil paper of so manufacture can control smoking according to the burning velocity of coil paper, a piece cigarette to burning end is
Puff count only, and control tar content, nicotine content.The tobacco ash produced during smoking is easily peeled off and is dispersed, and not only damages fragrant
The outward appearance of cigarette, also pollutes Environmental Tobacco Smoke in Non-industrial Area of China sometimes.
Disperse to reduce tobacco ash, carried out some motions.For example, Patent Document 1 discloses by volume
The median particle diameter for adding below more than 25 mass %, 35 mass % in paper is 0.2～0.4 μm of Calcium Carbonate, makes grey cohesion, prevents
The method that ash is excessively peeled off from medicated cigarette.Patent Document 2 discloses the metal to as combustionregulator addition sodium hydroxide
Hydroxide, the method for improving by the pH of aqueous solution is adjusted to 6.5～7 coherency of ash.It is public in patent documentation 3
Alkali metal carbonic acid (hydrogen) salt by adding sodium bicarbonate etc. in the filler of the alkaline earth metal carbonate of Calcium Carbonate etc. is opened
Method to improve grey characteristic.
Additionally, the Calcium Carbonate by coordinating given shape with specified quantitative in cigarette wrapping paper in patent documentation 4, has been recorded, from
And make the method that visible amount of sidestream and the CO content in mainstream smoke are reduced.
Prior art literature
Patent documentation
Patent documentation 1：No. 4237282 publications of Japanese Patent No.
Patent documentation 2：No. 3953725 publications of Japanese Patent No.
Patent documentation 3：Japanese Unexamined Patent Publication 2004-137613 publications
Patent documentation 4：No. 5716087 publications of Japanese Patent No.
The content of the invention
For the method for patent documentation 1, the Calcium Carbonate in microgranule footpath is stayed in difficult in paper, the companion in actual coil paper manufacture
With larger difficulty.For the method for patent documentation 2, due to compromising significantly smoking mouthfeel, therefore it is unsuitable for practicality.For
Method described in patent documentation 3, for becoming required to the new operation that filler implements pre-treatment in advance.
For the method for patent documentation 4, filler is more, in the case where the air permeability required for cigarette wrapping paper is maintained, nothing
Method obtains the mechanical strength required for common high-speed cigarette machine, and the volume production of medicated cigarette is difficult.
As carbon monoxide is produced by imperfect combustion, therefore by improving air permeability, its generation is prevented from.If however, thoroughly
Manner is uprised, then the interfibrous gap of paper becomes many, intensity decreases, therefore operability mechanically is reduced.
Therefore, technical task to be solved by this invention is to provide
Ash disperses from medicated cigarette, comes off, and with can volume production mechanical strength, and with the high air permeability that reduce can carbon monoxide
Smoking article coil paper.
1. a kind of smoking article coil paper, it is characterised in that contain：Paper pulp；Calcium Carbonate, is obtained by laser diffraction and scattering method
D50 median particle diameters be less than more than 1.8 μm 5.5 μm；And combustionregulator,
The content of the Calcium Carbonate is for, more than 35 mass %, less than 50 mass %, the content of the combustionregulator is 0.6 matter
Below amount 4.0 mass % of more than %.
2. the smoking article coil paper according to 1., it is characterised in that the content of the Calcium Carbonate is 13.5g/m2More than
25.0g/m2Below.
3. the smoking article coil paper according to 1. or 2., it is characterised in that the base weight of the smoking article coil paper is
30g/m2Above 50g/m2Below.
4. the smoking article coil paper according to any one in 1.～3., it is characterised in that the gross mass of the paper pulp
More than 26 mass % it is wood pulp.
5. the smoking article coil paper according to any one in 1.～4., it is characterised in that the combustionregulator is alkali
Metal citrate.
6. the smoking article coil paper according to any one in 1.～5., it is characterised in that air permeability is more than 8cu 55cu
Below.
7. a kind of smoking article coil paper, it is characterised in that contain：Paper pulp；Calcium Carbonate, is obtained by laser diffraction and scattering method
D50 median particle diameters are less than more than 1.8 μm 5.5 μm；Combustionregulator；And Oxytarch,
The content of the Calcium Carbonate is for, more than 35 mass %, less than 50 mass %, the content of the combustionregulator is 0.6 matter
Below amount 4.0 mass % of more than %, the content of the Oxytarch is 0.2g/m2Above 0.9g/m2Below.
8. the smoking article coil paper according to 7., it is characterised in that air permeability is more than 36cu below 56cu.
9. the smoking article coil paper according to 7. or 8., it is characterised in that the content of the Calcium Carbonate is 13.5g/m2With
Upper 25.0g/m2Below.
10. the smoking article coil paper according to any one in 7.～9., it is characterised in that the smoking article coil paper
Base weight be 30g/m2Above 50g/m2Below.
The 11. smoking article coil papers according to any one in 7.～10., it is characterised in that the gross mass of the paper pulp
26 mass % more than be wood pulp.
The 12. smoking article coil papers according to any one in 7.～11., it is characterised in that the combustionregulator is
Alkali-metal citrate.
13. a kind of medicated cigarettes, it is characterised in that wrap up cigarette with coil paper comprising the smoking article by described in any one in 1.～12.
Cigarette obtained from silk and the filter plug being connected to by tipping paper in one end of the cigarette on coaxially.
The smoking article coil paper of the present invention burn in smoking produced ash, is less prone to crack, and is difficult from combustion
Medicated cigarette in burning is dispersed, is come off.As ash is difficult to disperse, comes off, therefore the handss of smoker, clothes are difficult to be made dirty by ash.Due to
Ash is difficult to disperse, comes off, therefore Environmental Tobacco Smoke in Non-industrial Area of China is difficult pollution, easily cleans in addition.
Additionally, the smoking article coil paper of the present invention does not damage smoking mouthfeel, the local flavor and fragrance of Nicotiana tabacum L. can be enjoyed, together
When can reduce the CO content of suction.
Meanwhile, the smoking article coil paper of present invention intensity required when there is cigarette manufacture and treatability.The suction of the present invention
Cigarette article coil paper is used directly for common volume production equipment, being capable of the substantial amounts of medicated cigarette of high-speed production.
Description of the drawings
Fig. 1 is the photo after the cigarette combustion of embodiment 1.
Fig. 2 is the photo after the cigarette combustion of embodiment 3.
Fig. 3 is the photo after the cigarette combustion of comparative example 1.
Fig. 4 is the photo after the cigarette combustion of comparative example 2.
Specific embodiment
Hereinafter, the present invention will be described in detail.The smoking article of the present invention is with coil paper (below, sometimes referred to as coil paper)
Feature be, containing more than 35 mass %, less than the D50 intermediate values obtained by laser diffraction and scattering method of 50 mass % in coil paper
Particle diameter is less than more than 1.8 μm 5.5 μm of Calcium Carbonate, containing the combustionregulator below more than 0.6 mass % 4.0 mass %.
<Paper pulp>
The smoking article coil paper of the present invention, can in addition to the wood pulp copy paper using coniferous tree paper pulp, broad leaf tree paper pulp etc.
The non-wood of smoking article coil paper is generally used in mix flax paper pulp, hemp paper-pulp, Folium Agaves Sisalanae paper pulp, Spanish grass (Esparto) paper pulp etc.
Material paper pulp is manufacturing.As the species of paper pulp, can use by sulfate process, acid neutrality alkali sulfite process, alkaline process
The chemical pulp for obtaining, ground wood pulp, chemigroundwood pulp, thermomechanical pulp etc..
Additionally, for used as the smoking article coil paper based on the non-wood pulp of Caulis et Folium Lini etc., worry contains one in a large number
During the Calcium Carbonate of the quantitative above, the intensity of coil paper is substantially reduced, and Medicated cigarette adaptive is compromised.In order to fill up intensity decreases, it is necessary to enter
The beating of row paper pulp, however, as the phloem fiber of non-timber generally has easily beating property, Jing beating causes the air permeability of coil paper big
It is big to reduce, therefore the low coil paper of breathability can only be accessed.In order to ensure coil paper air permeability while fill up intensity decreases, it is excellent
Choosing makes the wood pulp of difficult beating property become more than 26 mass %.
<White filler>
The burning of medicated cigarette starts burning from the coil paper of periphery first, and then internal tobacco shred is thermally decomposed and become charcoal
And smoulder.Coil paper burns after forming ash, causes and thermally decompose and volume is reduced inside medicated cigarette.Now, if coming from the ash of coil paper
Layer is thin, then Jing does not live change in volume, and crack occurs, if which is excessively carried out, the grey piece of the coil paper produced by crack is taken off from medicated cigarette
Fall.By white filler contained in the paper of increase smoking article coil paper, make the ash layering from coil paper thickening, can reduce and be somebody's turn to do
The crack of ash.The amount of white filler relative to smoking article coil paper gross mass be 35 mass % more than, less than 50 mass %.
When the amount of white filler is less than 35 mass %, ash layering is thinning, is also easy to produce crack, comes off.The amount of white filler is 50 mass %
During the above, the intensity decreases of coil paper become fragile when processing with cigarette machine.
As white filler, can be commonly used using smoking article coil papers such as Calcium Carbonate, titanium dioxide, Kaolin
White filler, preferably uses Calcium Carbonate from smoking mouthfeel grade.The crystal habit of Calcium Carbonate is not particularly limited, but by laser
The D50 median particle diameters that diffraction scattering method is obtained are less than more than 1.8 μm 5.5 μm.When D50 median particle diameters are less than 1.8 μm, astringent taste,
Pungent etc. increases, and damages the smoking mouthfeel of medicated cigarette.When D50 median particle diameters are more than 5.5 μm, ash becomes to be difficult to condense, even if ash
Layer is thickening, also becomes prone to crack, comes off.
13.5g/m is preferably per the amount of the white filler of 1 square metre of smoking article coil paper2Above 25.0g/m2Below.In vain
The amount of color filler is less than 13.5g/m2When ash layering it is thinning, it is easy to produce crack, come off.The amount of white filler is more than 25.0g/m2
When, become too much again as smoking article coil paper base.And, the base weight of smoking article coil paper is generally in 30g/m2Above 50g/
m2Following scope.
<Combustionregulator>
The combustionregulator that the smoking article coil paper of the present invention generally be able to can be used using smoking article coil paper.Can for example add
Adding citric acid sodium, potassium citrate, sodium tartrate, Soluble tartar., potassium sodium tartrate (Rochelle salt), their mixture etc.
The alkali metal salt of carboxylic acid, or the phosphatic alkaline phosphate comprising potassium phosphate, ammonium phosphate etc..
The content of combustionregulator is more than 0.6 mass % below 4.0 mass %, more than preferably 1.1 mass % 2.9 mass % with
Under.When the content of combustionregulator is less than 0.6 mass %, even if the white filler ash for having abundance in paper does not also condense, dustability
It is not enhanced.Additionally, when combustionregulator is more than 4.0 mass %, bitterness becomes weight and the smoking mouthfeel of medicated cigarette is compromised.Although not
The impact that combustionregulator is brought to the ash of smoking article coil paper is thrown a flood of light on, but is inferred when the carbonization that there is appropriate amount in ash
During residual component, the white filler particle set each other in ash is made, improve the coherency of ash.
<Starch>
A large amount of fillers containing Calcium Carbonate etc. in smoking article coil paper, in the case where high-air-permeability is maintained, intensity is significantly
Reduce, it is impossible to obtain the mechanical adaptive required for Medicated cigarette.Although for this purpose, exist the difficult beating property of mixing wood pulp so that it is guaranteed that
High-air-permeability, while the method for improving mechanical strength, but still be not enough to obtain common as PROTOS (Hauni company systems)
Intensity necessary to high-speed cigarette machine.In order to be processed with high-speed cigarette machine, expectation stretches energy by defined in JIS P8113
Absorbtivity is 6.5J/m2More than.
Here, the known mechanical strength that can improve paper by paper power reinforcing agent.However, due to using paper power reinforcing agent
When, the interfibrous gap of paper is filled to reduce so as to air permeability, therefore oxygen when burning is not enough and become imperfect combustion,
The yield of the harmful substance of carbon monoxide, benzene etc. is caused to increase.Additionally, for the paper power reinforcing agent of smoking article coil paper,
The medicine that can be used from the point of safety, smoking mouthfeel is restricted.The present inventors have studied various paper power reinforcing agents,
As a result find to contain 0.2g/m2Above 0.9g/m2Below during various starch, air permeability and mechanical strength improve.By using few
It is new opinion unknown so far that amount improves air permeability as the various starch of paper power reinforcing agent.Smoking article coil paper
Preferred more than the 36cu of air permeability, more preferably more than 40cu, further preferred more than 44cu, most preferably more than 48cu.Contain
0.2g/m2Above 0.9g/m2The upper limit of air permeability during following starch is 56cu or so.
In addition, although the addition of starch causes the smoking mouthfeel of smoking article coil paper to reduce, but the degeneration of starch cause it is right
The impact of smoking mouthfeel has differences.In various modified starches, impact of the Oxytarch to smoking mouthfeel is little.Further, oxidation is formed sediment
In powder, from the point of smoking mouthfeel, the Oxytarch for coming from Semen Maydiss is preferably used.
<Copy paper>
As the paper machine of manufacture coil paper, gage paper machine, cylinder paper machine, short net formula paper machine, folder can be arbitrarily used
Net formula paper machine etc..Additionally, copy paper is carried out in the arbitrary mode of neutral papermaking, alkaline copy paper.Additionally, can add as needed
Aluminum sulfate, the yield rate Improve agent of various anionic property, cationic, nonionic or both sexes, drainability Improve agent, paper power
The copy paper of reinforcing agent etc. adds auxiliary agent with interior.Further, dyestuff, pH adjusting agent, defoamer, pitch trouble control can be added as needed
The paper additive processed of agent, agent of sizing mixing etc..
Embodiment
Hereinafter, according to embodiment, the present invention will be described, but the present invention is not only defined in following examples.
(embodiment 1)
By wood pulp (coniferous tree paper pulp：100 mass %) it is beaten to freeness：56 ° of SR, add relative to the total of wood pulp
Quality is Calcium Carbonate (white lapicide's industry company system, PCX-850, the shape of particle of 65～75 mass %：Spindle, mean diameter 1：
5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation)), and then add relative to timber
The gross mass of paper pulp is that (E.I.Du Pont Company's system, MEYPROID is 6700) and then modulation is former for the paper power reinforcing agent guar gum of 1.0 mass %
Slip material.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, sodium citrate is then coated with
(Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, citric acid
Tripotassium monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：37.0g/m2, calcium carbonate content：
13.5g/m2, ash：36.5%, combustionregulator amount：2.2 mass %, air permeability：9.2cu.
(embodiment 2)
By wood pulp (coniferous tree paper pulp：100 mass %) it is beaten to freeness：56 ° of SR, add relative to the total of wood pulp
Quality is Calcium Carbonate (white lapicide's industry company system, PCX-850, the shape of particle of 75～85 mass %：Spindle, mean diameter 1：
5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation)), and then add relative to timber
The gross mass of paper pulp is that (E.I.Du Pont Company's system, MEYPROID is 6700) and then modulation is former for the paper power reinforcing agent guar gum of 1.0 mass %
Slip material.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, sodium citrate is then coated with
(Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, citric acid
Tripotassium monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：41.3g/m2, calcium carbonate content：
16.0g/m2, ash：38.7%, combustionregulator amount：2.0 mass %, air permeability：8.4cu.
(embodiment 3)
By wood pulp (coniferous tree paper pulp：100 mass %) it is beaten to freeness：74 ° of SR, add relative to the total of wood pulp
Quality is Calcium Carbonate (white lapicide's industry company system, PCX-850, the shape of particle of 95～100 mass %：Spindle, mean diameter 1：
5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation)) and then brewable material slurry.With
Gage paper machine carries out copy paper to the raw material slurry and forms base paper, is then coated with sodium citrate (Jungbunzlauer companies
System, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, potassium citrate monohydrate) 95/
5 mixed liquors, obtain following smoking article coil paper：Base weight：47.0g/m2, calcium carbonate content：23.2g/m2, ash：
49.4%, combustionregulator amount：0.7 mass %, air permeability：12.3cu.
(embodiment 4)
Will be relative to wood pulp (coniferous tree paper pulp：100 mass %) gross mass be mixed with the flax paper pulp of 66 mass %
Raw material pulping is to freeness：30 ° of SR, add and relative to the gross mass of the mixed material of wood pulp/flax paper pulp (60/40) are
Calcium Carbonate (white lapicide's industry company system, PCX-850, the shape of particle of 65～75 mass %：Spindle, mean diameter 1：5.0μm
(laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation)), so add relative to wood pulp/
The gross mass of the mixed material of flax paper pulp (60/40) be 0.7 mass % paper power reinforcing agent guar gum (E.I.Du Pont Company's system,
6700) and then brewable material slurry MEYPROID.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed,
Then sodium citrate (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate are coated with
95/5 mixed liquor of (Jungbunzlauer company systems, potassium citrate monohydrate), obtains following smoking article volume
Paper：Base weight：37.4g/m2, calcium carbonate content：13.8g/m2, ash：36.9%, combustionregulator amount：0.7 mass %, breathes freely
Degree：38.1cu.
(embodiment 5)
By wood pulp (coniferous tree paper pulp：100 mass %) it is beaten to freeness：53 ° of SR, add relative to the total of wood pulp
Quality is Calcium Carbonate (white lapicide's industry company system, PCX-850, the shape of particle of 95～100 mass %：Spindle, mean diameter 1：
5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation)), and then add relative to timber
The gross mass of paper pulp is that (E.I.Du Pont Company's system, MEYPROID is 6700) and then modulation is former for the paper power reinforcing agent guar gum of 0.7 mass %
Slip material.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, potassium citrate is then coated with
(Jungbunzlauer company systems, potassium citrate monohydrate) solution, obtains following smoking article coil paper：Base weight：
45.5g/m2, calcium carbonate content：18.2g/m2, ash：40.0%, combustionregulator amount：2.9 mass %, air permeability：36.1cu.
(embodiment 6)
Will be relative to wood pulp (coniferous tree paper pulp：100 mass %) gross mass be mixed with the flax paper pulp of 200 mass %
Mixed material is beaten to freeness：68 ° of SR, add total matter of the mixed material relative to wood pulp/flax paper pulp (33/67)
Measure Calcium Carbonate (white lapicide's industry company system, PCX-850, the shape of particle for 95～100 mass %：Spindle, mean diameter 1：
5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation)), and then add relative to timber
The gross mass of the mixed material of paper pulp/flax paper pulp (33/67) is the paper power reinforcing agent guar gum (E.I.Du Pont Company of 0.7 mass %
6700) and then brewable material slurry system, MEYPROID.Copy paper is carried out to the raw material slurry with gage paper machine and base is formed
Paper, is then coated with the solution of sodium citrate (Jungbunzlauer company systems, citrate trisodium dihydrate), obtains following
Smoking article coil paper：Base weight：47.7g/m2, calcium carbonate content：20.0g/m2, ash：42.0%, combustionregulator amount：2.9
Quality %, air permeability：27.4cu.
(embodiment 7)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
The solution of sodium (Jungbunzlauer company systems, citrate trisodium dihydrate), obtains following smoking article coil paper：Base
Weight：40.1g/m2, calcium carbonate content：17.3g/m2, ash：43.1%, combustionregulator amount：2.1 mass %, air permeability：
47.8cu。
(comparative example 1)
Using generally commercially available smoking article coil paper, the smoking article coil paper is wood pulp：100 mass % (coniferous trees
Paper pulp：15 mass %, broad leaf tree paper pulp：85 mass %), base weight：30.4g/m2, calcium carbonate content：9.6g/m2, ash：
31.6%, combustionregulator amount (potassium citrate：100 mass %)：1.0 mass %, air permeability：64.0cu.
(comparative example 2)
Flax paper pulp is beaten to freeness：80 ° of SR, add relative to flax paper pulp gross mass be 45～55 mass % carbon
Sour calcium (white lapicide's industry company system, PCX-850, shape of particle：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method),
Mean diameter 2：2.6 μm (X-ray transmission formula sedimentation)) and then brewable material slurry.The raw material is starched with gage paper machine
Material carries out copy paper and forms base paper, is then coated with sodium citrate (Jungbunzlauer company systems, citrate trisodium dihydrate)
And 95/5 mixed liquor of potassium citrate (Jungbunzlauer company systems, potassium citrate monohydrate), obtain following smoking
Article coil paper：Base weight：23.5g/m2, calcium carbonate content：6.7g/m2, ash：28.5%, combustionregulator amount：0.8 matter
Amount %, air permeability：10.8cu.
(comparative example 3)
By wood pulp (coniferous tree paper pulp：100 mass %) it is beaten to freeness：74 ° of SR, add relative to the total of wood pulp
Quality is Calcium Carbonate (white lapicide's industry company system, PCX-850, the shape of particle of 95～100 mass %：Spindle, mean diameter 1：
5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation)) and then brewable material slurry.With
The raw material slurry is carried out copy paper by gage paper machine, obtains following smoking article coil paper：Base weight：45.0g/m2, carbonic acid
Calcium content：18.0g/m2, ash：40.0%, combustionregulator amount：0 mass %, air permeability：21.3cu.
(comparative example 4)
By wood pulp (coniferous tree paper pulp：15 mass %, broad leaf tree paper pulp：85 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：42.3g/m2, Calcium Carbonate contains
Amount：18.0g/m2, ash：42.6%, combustionregulator amount：0.3 mass %, air permeability：46.8cu.
(comparative example 5)
By wood pulp (coniferous tree paper pulp：100 mass %) it is beaten to freeness：74 ° of SR, add relative to the total of wood pulp
Quality is Calcium Carbonate (white lapicide's industry company system, PCX-850, the shape of particle of 95～100 mass %：Spindle, mean diameter 1：
5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation)) and then brewable material slurry.With
Gage paper machine carries out copy paper to the raw material slurry and forms base paper, is then coated with sodium citrate (Jungbunzlauer companies
System, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, potassium citrate monohydrate) 95/
5 mixed liquors, obtain following smoking article coil paper：Base weight：47.0g/m2, calcium carbonate content：18.0g/m2, ash：
38.3%, combustionregulator amount：5.0 mass %, air permeability：22.0cu.
(embodiment 8)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：42.7g/m2, Calcium Carbonate contains
Amount：17.9g/m2, ash：41.9%, combustionregulator amount：2.1 mass %, air permeability：47.4cu.
(embodiment 9)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus be that (white lapicide's industry company system, PCX-850 change I, grain for the Calcium Carbonate of 95～100 mass % relative to the gross mass of wood pulp
Sub- shape：Spindle, mean diameter 1：5.5 μm (laser diffraction and scattering method), mean diameter 2：2.8 μm (X-ray transmission formula is settled
Method)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, lemon is then coated with
Lemon acid sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems,
Potassium citrate monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：42.5g/m2, Calcium Carbonate
Content：18.1g/m2, ash：42.6%, combustionregulator amount：2.1 mass %, air permeability：46.6cu.
(embodiment 10)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (Specialty Minerals company systems,
ALBACAE 5970, shape of particle：Scalenohedron shape, mean diameter 1：3.9 μm (laser diffraction and scattering method), mean diameter 2：
1.9 μm (X-ray transmission formula sedimentation)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine
And base paper is formed, then it is coated with sodium citrate (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate
95/5 mixed liquor of (Jungbunzlauer company systems, potassium citrate monohydrate), obtains following smoking article volume
Paper：Base weight：41.1g/m2, calcium carbonate content：17.8g/m2, ash：43.3%, combustionregulator amount：2.1 mass %, breathe freely
Degree：47.8cu.
(embodiment 11)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 100～115 mass % Calcium Carbonate (Ao Duomo industrial groups system, TP121-6S, grain
Sub- shape：Spindle, mean diameter 1：2.4 μm (laser diffraction and scattering method), mean diameter 2：1.2 μm (X-ray transmission formula is settled
Method)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, lemon is then coated with
Lemon acid sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems,
Potassium citrate monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：42.4g/m2, Calcium Carbonate
Content：18.0g/m2, ash：42.5%, combustionregulator amount：2.0 mass %, air permeability：45.6cu.
(embodiment 12)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 100～115 mass % Calcium Carbonate (white lapicide's industry company system, KK-21, particle shape
Shape：Cube, mean diameter 1：1.8 μm (laser diffraction and scattering method), mean diameter 2：0.8 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：41.9g/m2, Calcium Carbonate contains
Amount：17.9g/m2, ash：42.7%, combustionregulator amount：2.0 mass %, air permeability：44.9cu.
(embodiment 13)
Will be relative to wood pulp (coniferous tree paper pulp：66 mass %, broad leaf tree paper pulp：34 mass %) gross mass be mixed with
The mixed material of the flax paper pulp of 100 mass % is beaten to freeness：56 ° of SR, add relative to wood pulp/flax paper pulp
(50/50) gross mass of mixed material is Calcium Carbonate (white lapicide's industry company system, PCX-850, the particle of 95～100 mass %
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula is settled
Method)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, lemon is then coated with
Lemon acid sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems,
Potassium citrate monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：41.6g/m2, Calcium Carbonate
Content：17.8g/m2, ash：42.8%, combustionregulator amount：2.0 mass %, air permeability：48.6cu.
(embodiment 14)
Will be relative to wood pulp (coniferous tree paper pulp：65 mass %, broad leaf tree paper pulp：35 mass %) gross mass be mixed with
The mixed material of the flax paper pulp of 285 mass % is beaten to freeness：56 ° of SR, add relative to wood pulp/flax paper pulp
(26/74) gross mass of mixed material is Calcium Carbonate (white lapicide's industry company system, PCX-850, the particle of 95～100 mass %
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula is settled
Method)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, lemon is then coated with
Lemon acid sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems,
Potassium citrate monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：42.3g/m2, Calcium Carbonate
Content：18.3g/m2, ash：43.3%, combustionregulator amount：2.1 mass %, air permeability：40.1cu.
(embodiment 15)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：66 ° of SR, add
Plus relative to wood pulp gross mass be 120～140 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula is settled
Method)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, lemon is then coated with
Lemon acid sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems,
Potassium citrate monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：30.3g/m2, Calcium Carbonate
Content：13.5g/m2, ash：44.6%, combustionregulator amount：2.1 mass %, air permeability：26.5cu.
(embodiment 16)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：42.3g/m2, Calcium Carbonate contains
Amount：18.0g/m2, ash：42.6%, combustionregulator amount：0.6 mass %, air permeability：46.8cu.
(embodiment 17)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：42.1g/m2, Calcium Carbonate contains
Amount：17.9g/m2, ash：42.5%, combustionregulator amount：3.0 mass %, air permeability：47.0cu.
(embodiment 18)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：42.0g/m2, Calcium Carbonate contains
Amount：18.1g/m2, ash：43.1%, combustionregulator amount：4.0 mass %, air permeability：45.9cu.
(comparative example 6)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus be that (white lapicide's industry company system, PCX-850 change II, grain for the Calcium Carbonate of 95～100 mass % relative to the gross mass of wood pulp
Sub- shape：Spindle, mean diameter 1：8.0 μm (laser diffraction and scattering method), mean diameter 2：4.2 μm (X-ray transmission formula is settled
Method)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, lemon is then coated with
Lemon acid sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems,
Potassium citrate monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：42.1g/m2, Calcium Carbonate
Content：18.2g/m2, ash：43.2%, combustionregulator amount：2.0 mass %, air permeability：49.3cu.
(comparative example 7)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：66 ° of SR, add
Plus relative to wood pulp gross mass be 120～140 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula is settled
Method)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, lemon is then coated with
Lemon acid sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems,
Potassium citrate monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：30.3g/m2, Calcium Carbonate
Content：18.0g/m2, ash：59.4%, combustionregulator amount：2.1 mass %, air permeability：38.5cu.
(comparative example 8)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：80 ° of SR, add
Plus relative to wood pulp gross mass be 120～140 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula is settled
Method)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, lemon is then coated with
Lemon acid sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems,
Potassium citrate monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：25.8g/m2, Calcium Carbonate
Content：18.0g/m2, ash：69.8%, combustionregulator amount：2.1 mass %, air permeability：10.5cu.
(comparative example 9)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：80 ° of SR, add
Plus relative to wood pulp gross mass be 120～140 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula is settled
Method)) and then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, lemon is then coated with
Lemon acid sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems,
Potassium citrate monohydrate) 95/5 mixed liquor, obtain following smoking article coil paper：Base weight：25.9g/m2, Calcium Carbonate
Content：13.5g/m2, ash：52.1%, combustionregulator amount：2.1 mass %, air permeability：9.7cu.
(embodiment 19)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 and Oxytarch (Japanese corn starch company system, SK100, raw material：Semen Maydiss) mixed liquor,
Obtain following smoking article coil paper：Base weight：41.3g/m2, calcium carbonate content：17.7g/m2, ash：42.9%, burning is adjusted
Section dosage：2.1 mass %, air permeability：54.8cu, content of starch：0.2g/m2。
(embodiment 20)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 and Oxytarch (Japanese corn starch company system, SK100, raw material：Semen Maydiss) mixed liquor,
Obtain following smoking article coil paper：Base weight：41.2g/m2, calcium carbonate content：17.6g/m2, ash：42.7%, burning is adjusted
Section dosage：2.1 mass %, air permeability：54.7cu, content of starch：0.4g/m2。
(embodiment 21)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 and Oxytarch (Japanese corn starch company system, SK100, raw material：Semen Maydiss) mixed liquor,
Obtain following smoking article coil paper：Base weight：41.7g/m2, calcium carbonate content：17.5g/m2, ash：41.9%, burning is adjusted
Section dosage：2.1 mass %, air permeability：55.1cu, content of starch：0.8g/m2。
(embodiment 22)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 and Oxytarch (Japanese corn starch company system, SK100, raw material：Semen Maydiss) mixed liquor,
Obtain following smoking article coil paper：Base weight：41.0g/m2, calcium carbonate content：17.7g/m2, ash：43.2%, burning is adjusted
Section dosage：2.1 mass %, air permeability：53.2cu, content of starch：0.9g/m2。
(comparative example 10)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 and Oxytarch (Japanese corn starch company system, SK100, raw material：Semen Maydiss) mixed liquor,
Obtain following smoking article coil paper：Base weight：41.3g/m2, calcium carbonate content：17.7g/m2, ash：42.9%, burning is adjusted
Section dosage：2.1 mass %, air permeability：46.2cu, content of starch：1.0g/m2。
(comparative example 11)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 and etherification starch (Song Gu chemical industrial companies system, SolfarexA55, raw material：Rhizoma Solani tuber osi)
Mixed liquor, obtains following smoking article coil paper：Base weight：41.3g/m2, calcium carbonate content：17.6g/m2, ash：42.6%,
Combustionregulator amount：2.1 mass %, air permeability：55.2cu, content of starch：0.8g/m2。
(comparative example 12)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 and carbamide organic phosphate starch (japanese food process company system, MS#4600, raw material：Semen Maydiss)
Mixed liquor, obtain following smoking article coil paper：Base weight：41.1g/m2, calcium carbonate content：17.7g/m2, ash：
43.1%, combustionregulator amount：2.1 mass %, air permeability：54.2cu, content of starch：0.8g/m2。
(comparative example 13)
By wood pulp (coniferous tree paper pulp：74 mass %, broad leaf tree paper pulp：26 mass %) it is beaten to freeness：56 ° of SR, add
Plus relative to wood pulp gross mass be 95～100 mass % Calcium Carbonate (white lapicide's industry company system, PCX-850, particle shape
Shape：Spindle, mean diameter 1：5.0 μm (laser diffraction and scattering method), mean diameter 2：2.6 μm (X-ray transmission formula sedimentation))
Then brewable material slurry.Copy paper is carried out to the raw material slurry with gage paper machine and base paper is formed, citric acid is then coated with
Sodium (Jungbunzlauer company systems, citrate trisodium dihydrate) and potassium citrate (Jungbunzlauer company systems, Fructus Citri Limoniae
Sour tripotassium monohydrate) 95/5 and amphoterisation starch (National starch and chemical company systems,
CATE3210, raw material：Maninot esculenta crantz.) mixed liquor, obtain following smoking article coil paper：Base weight：41.2g/m2, Calcium Carbonate contains
Amount：17.5g/m2, ash：42.5%, combustionregulator amount：2.1 mass %, air permeability：55.2cu, content of starch：0.8g/m2。
<Evaluate>
(paper pulp freeness)
The filter of the paper pulp raw material used by each example is determined according to the SchopperRiegler methods of defined in JIS P8121-1
Water degree.
(according to measure of the laser diffraction and scattering method to the mean diameter 1 of Calcium Carbonate)
5ml is put in 500ml sodium hexameta phosphate 10ppm aqueous solutions to adjust to the calcium carbonate serosity of 20wt%, one minute is carried out
Strong mixing, make calcium carbonate particle dispersion and as sample.The sample is put into into laser diffraction formula particle size distribution machine in right amount
In (Shimadzu Seisakusho Ltd.'s company system, SALD-300V), adjust in a looping fashion concentration cause diffraction/light scatter intensity become 750 ±
After 250, it is to determine particle size distribution under 0.00-1.60i in refractive index.Weighted average grain is made according to the measurement result of particle size distribution
The cumulative distribution table in footpath, tries to achieve D50 intermediate values and is mean diameter 1.
(according to measure of the X-ray transmission formula sedimentation to the mean diameter 2 of Calcium Carbonate)
5ml is put in 500ml sodium hexameta phosphate 10ppm aqueous solutions to adjust to the calcium carbonate serosity of 20wt%, one minute is carried out
Strong mixing, after disperseing calcium carbonate particle, by X-ray transmission formula particle size distribution machine (Mike's Mo Ruitike company systems, Sedi
5100) Graph determines particle size distribution.The cumulative distribution table of weight mean particle size is made according to the result, D50 intermediate values is tried to achieve i.e.
For mean diameter 2.
(BET specific surface area of Calcium Carbonate)
Using specific area measuring device (Shimadzu Seisakusho Ltd.'s company system, Flow Sorb II2300), according to nitrogen adsorption method (JIS
8830) Z determines the BET specific surface area that surface covers calcium carbonate particle.
(base weight)
The base weight of the smoking article coil paper by obtained by each example is determined according to the method for JIS P8124 defineds.
(calcium carbonate content)
The calcium carbonate content of the smoking article coil paper by obtained by each example is tried to achieve by the product of base weight and ash.
(ash)
The ash of the smoking article coil paper by obtained by each example is represented with the ash amount at determined according to JIS P8252 525 DEG C
Point.
(stretching property of tensile strength stretching energy absorbtivity)
Using Kumagai Riki Kogyo cross tensile test machine, on the basis of the method (only longitudinal) of JIS P8113 defineds
The stretching property of tensile strength for determining the longitudinal direction of the smoking article coil paper by obtained by each example stretches energy absorbtivity.
(air permeability)
Using Borg World company systems：Permeability Tester A20, determine according to the method for ISO2965 defineds
The air permeability of the smoking article coil paper by obtained by each example.
(combustionregulator amount)
The content of the combustionregulator of smoking article coil paper by obtained by each example is tried to achieve as following method.
The each samples of 250mg are extracted by 40ml NaOH solutions (0.02N), by capillary electrophoresis (great mound electronics corporation system,
Agilent 7100, using organic acid chromatographic column：75 μ × 805mm, voltage：25kV, detection：UV) determine in its extracting solution
Organic acid concentration.
According to the product of the molecular weight of organic acid concentration and anhydrous citric acid by said determination, by the quality of the organic acid being extracted
Calculate as anhydrous citric acid, try to achieve the ratio of the anhydrous citric acid quality of quality relative to sample, as combustionregulator amount.
(content of starch)
Coating fluid is multiplied by with the coating fluid pickup of paper by each by the content of the starch of the smoking article coil paper obtained by each example
In starch concentration and try to achieve.
(Medicated cigarette)
Using the smoking article coil paper by obtained by each example, circumference is manufactured by cigarette machine (Hauni company systems, PROTOS)：
17mm, volume length：56mm, tobacco shred loading：0.27～0.33g and circumference：25mm, volume length：56mm, tobacco shred loading：0.52～
The filter-tipped medicated cigarette of 0.55g.
(the dustability evaluation of ash)
At 22 DEG C, under the atmosphere of 60%RH, the medicated cigarette of trial-production is made to burn under static condition, the shape of the ash observed after cigarette combustion
State, the crack of ash, few medicated cigarette that comes off are denoted as zero, and the crack of ash, many medicated cigarettes that come off are denoted as ×.
Using by embodiment 1,3 and comparative example 1, the photo after the burning of the medicated cigarette of the smoking article coil paper obtained by 2 shows respectively
In Fig. 1～4.
(smoking mouthfeel)
The medicated cigarette of trial-production is inhaled, is contrasted with the smoking mouthfeel of the existing product Nicotiana tabacum L. of comparative example 1, is integrally divided into 5 levels and is commented
Valency.It is carried out as follows evaluation：3 are denoted as with the medicated cigarette of 1 equal smoking mouthfeel above of comparative example, the medicated cigarette of smoking taste bad
2 are denoted as, astringent taste etc. further occur and the medicated cigarette of smoking taste bad is denoted as 1, the perfume (or spice) that smoking mouthfeel is lifted compared with comparative example 1
Cigarette is denoted as 4, and local flavor of Nicotiana tabacum L. etc. further increases and the medicated cigarette of smoking mouthfeel lifting is denoted as 5.
Table 1
Table 2
Table 3
Claims (13)
1. a kind of smoking article coil paper, it is characterised in that
Contain：Paper pulp；Calcium Carbonate, the D50 median particle diameters obtained by laser diffraction and scattering method are less than more than 1.8 μm 5.5 μm；With
Combustionregulator,
The content of the Calcium Carbonate is for, more than 35 mass %, less than 50 mass %, the content of the combustionregulator is 0.6 matter
Below amount 4.0 mass % of more than %.
2. smoking article coil paper according to claim 1, it is characterised in that the content of the Calcium Carbonate is 13.5g/m2
Above 25.0g/m2Below.
3. smoking article coil paper according to claim 1 and 2, it is characterised in that the base of the smoking article coil paper
Weight is 30g/m2Above 50g/m2Below.
4. the smoking article coil paper according to any one in claims 1 to 3, it is characterised in that the paper pulp it is total
More than 26 mass % of quality it is wood pulp.
5. the smoking article coil paper according to any one in Claims 1 to 4, it is characterised in that the burning is adjusted
Agent is alkali-metal citrate.
6. the smoking article coil paper according to any one in Claims 1 to 5, it is characterised in that air permeability be 8cu with
Upper below 55cu.
7. a kind of smoking article coil paper, it is characterised in that contain：Paper pulp；Calcium Carbonate, is obtained by laser diffraction and scattering method
D50 median particle diameters are less than more than 1.8 μm 5.5 μm；Combustionregulator；And Oxytarch,
The content of the Calcium Carbonate is for, more than 35 mass %, less than 50 mass %, the content of the combustionregulator is 0.6 matter
Below amount 4.0 mass % of more than %, the content of the Oxytarch is 0.2g/m2Above 0.9g/m2Below.
8. smoking article coil paper according to claim 7, it is characterised in that air permeability is more than 36cu below 56cu.
9. the smoking article coil paper according to claim 7 or 8, it is characterised in that the content of the Calcium Carbonate is
13.5g/m2Above 25.0g/m2Below.
10. the smoking article coil paper according to any one in claim 7～9, it is characterised in that the smoking article
It is 30g/m with the base weight of coil paper2Above 50g/m2Below.
The 11. smoking article coil papers according to any one in claim 7～10, it is characterised in that the paper pulp
More than 26 mass % of gross mass it is wood pulp.
The 12. smoking article coil papers according to any one in claim 7～11, it is characterised in that the burning is adjusted
Section agent is alkali-metal citrate.
13. a kind of medicated cigarettes, it is characterised in that comprising the smoking article coil paper by described in any one in claim 1～12
Cigarette obtained from parcel tobacco shred and the filter plug being connected to by tipping paper in one end of the cigarette on coaxially.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015-200386 | 2015-10-08 | ||
| JP2015200386 | 2015-10-08 | ||
| JP2015-244508 | 2015-12-15 | ||
| JP2015244508A JP5997356B1 (en) | 2015-10-08 | 2015-12-15 | Wrapping paper for smoking articles |
| JP2016-114958 | 2016-06-09 | ||
| JP2016114958A JP2017218699A (en) | 2016-06-09 | 2016-06-09 | Roll paper for smoking article |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106567276A true CN106567276A (en) | 2017-04-19 |
Family
ID=58531655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610802278.XA Pending CN106567276A (en) | 2015-10-08 | 2016-09-05 | Roll paper for smoking articles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106567276A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108951269A (en) * | 2018-07-05 | 2018-12-07 | 常州思宇知识产权运营有限公司 | A kind of preparation method of cigarette tipping paper |
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| CN103074803A (en) * | 2011-10-25 | 2013-05-01 | 王子控股株式会社 | Matt coated paper for printing |
| CN104428466A (en) * | 2012-07-09 | 2015-03-18 | 德尔福特集团有限公司 | Cigarette paper with improved air-permeability |
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