CN110042700A - Food-grade tipping paper - Google Patents
Food-grade tipping paper Download PDFInfo
- Publication number
- CN110042700A CN110042700A CN201910324796.9A CN201910324796A CN110042700A CN 110042700 A CN110042700 A CN 110042700A CN 201910324796 A CN201910324796 A CN 201910324796A CN 110042700 A CN110042700 A CN 110042700A
- Authority
- CN
- China
- Prior art keywords
- parts
- food
- grade
- titanium dioxide
- tipping paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
- D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
- D21H17/45—Nitrogen-containing groups
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
Abstract
The invention belongs to field of packaging material, more particularly to a kind of food-grade tipping paper, each component including following parts by weight: 40-60 parts of softwood pulp, 60-80 parts of hardwood pulp, 5-8 parts of cationic polyacrylamide, 15-20 parts of hydroxypropul starch, 1-3 parts of sodium metasilicate, 1-3 parts of gelatin, 3-5 parts of polyethylene glycol, 3-8 parts of modified food grade nano-titanium dioxide, 2-5 parts of silver-series antibacterial agent, 10-15 parts of deionized water.The present invention adds antibacterial agent using food grade materials as raw material to realize antibacterial effect, meanwhile, the effect of added modified food grade nano-titanium dioxide and antibacterial agent performance Synergistic antimicrobial；There is beta-cyclodextrin structure, which can effectively adsorb the tar in flue gas, play the role of tar reduction in the modified food grade nano-titanium dioxide of addition；It will first be added in slurry after modified food grade nano-titanium dioxide and silver nitrate in water hybrid reaction, the dissolved silver ion of silver nitrate enters in the hole configurations of cyclodextrin, slow releasing function can be played, to realize long-term antibacterial.
Description
Technical field
The invention belongs to field of packaging material, and in particular to a kind of food-grade tipping paper.
Background technique
With the improvement of living standards, people are also higher and higher for the attention degree of health.Tipping paper conduct will filter
The dedicated paper that mouth and Cigarette cigarette are got up, belongs to the important materials of production of cigarettes, be consumer in smoking directly and mouth
Lipped joint touching position, the factors such as physical characteristic, sanitary index of tipping paper not only can to the quality of cigarette product generate directly or
Indirectly influence, safety and wholesomeness also directly affect the health of smoker.
Since tipping paper is the position in direct paper roll cigarette with lip contact, sanitary standard can be reached, whether had
Fungistatic effect and whether can enduringly to play bacteriostasis all be food-grade tipping paper key factor in need of consideration.This
Outside, consider that burnt effect is also a key factor in need of consideration by tipping paper for health.
Summary of the invention
To solve the above-mentioned problems, the invention discloses a kind of food-grade tipping papers, using food grade materials, and by adding
Add modified food grade nano-titanium dioxide and antibacterial agent that tipping paper is made to reach food-grade requirement, has long-term antibacterial effect, and have
There is tar reduction effect.
To achieve the goals above, the present invention adopts the following technical scheme:
A kind of food-grade tipping paper, each component including following parts by weight:
40-60 parts of softwood pulp
60-80 parts of hardwood pulp
5-8 parts of cationic polyacrylamide
15-20 parts of hydroxypropul starch
1-3 parts of sodium metasilicate
1-3 parts of gelatin
3-5 parts of polyethylene glycol
3-8 parts of modified food grade nano-titanium dioxide
2-5 parts of antibacterial agent
10-15 parts of deionized water.
Preferably, the structural formula of above-mentioned modified food grade nano-titanium dioxide are as follows:
The modified food grade nano-titanium dioxide the preparation method comprises the following steps: by mass ratio be 1:1-5 food-grade nanometer two
Titanium oxide and beta-cyclodextrin are dispersed in water, and being added and accounting for food-grade nano-titanium dioxide mass percent is the anhydrous of 2-3%
HCl is heated to 60-70 DEG C, stirs 6-8h, is filtered, washed, dries to get modified food grade nano-titanium dioxide, reactional equation
Formula are as follows:
Preferably, above-mentioned antibacterial agent is silver nitrate.
Preferably, above-mentioned food-grade tipping paper, is prepared by following steps:
(1) beater is added in softwood pulp and hardwood pulp, is beaten, obtain slurry；
(2) in deionized water by the dispersion of modified food grade nano-titanium dioxide, then nitre is added in sonic oscillation 20min
Sour silver, is stirred to react 1-2h at 90 DEG C, obtains mixed liquor；
(3) mixed liquor of step (2) is added in the slurry of step (1), is uniformly mixed, obtains mixed slurry；
(4) cationic polyacrylamide, hydroxypropul starch, sodium metasilicate, gelatin and polyethylene glycol are sequentially added into mixing
It in slurry, is uniformly mixed, obtains paper pulp；
(5) paper pulp is suppressed on nipper through wet end and press section drainage and formation, and is punched.
Preferably, beating consistency control is in 3.5-4.5% in above-mentioned pulping process.
Preferably, beating degree control is in 65-75 ° of SR in above-mentioned pulping process.
The present invention is with following the utility model has the advantages that (1) present invention using food grade materials as raw material, adds antibacterial agent to provide
Antibacterial effect, meanwhile, the effect of added modified food grade nano-titanium dioxide and antibacterial agent performance Synergistic antimicrobial facilitates
Guarantee the antibacterial effect of tipping paper；
(2) there is beta-cyclodextrin structure in the modified food grade nano-titanium dioxide that the present invention adds, which can have
Tar in effect absorption flue gas, plays the role of significant tar reduction；
(3) present invention first will add slurry after modified food grade nano-titanium dioxide and silver nitrate in water hybrid reaction
In, the dissolved silver ion of silver nitrate enters in the hole configurations of cyclodextrin, slow releasing function can be played, to realize permanent anti-
Bacterium.
Specific embodiment
Presently in connection with embodiment, the present invention is described in further detail.
Food-grade tipping paper, it is characterised in that: be prepared by following steps:
(1) beater is added in softwood pulp and hardwood pulp, is beaten, obtain slurry；
(2) in deionized water by the dispersion of modified food grade nano-titanium dioxide, then nitre is added in sonic oscillation 20min
Sour silver, is stirred to react 1-2h at 90 DEG C, obtains mixed liquor；
(3) mixed liquor of step (2) is added in the slurry of step (1), is uniformly mixed, obtains mixed slurry；
(4) cationic polyacrylamide, hydroxypropul starch, sodium metasilicate, gelatin and polyethylene glycol are sequentially added into mixing
It in slurry, is uniformly mixed, obtains paper pulp；
(5) paper pulp is suppressed on nipper through wet end and press section drainage and formation, and is punched.
Wherein, beating consistency is controlled in 3.5-4.5% in pulping process；Beating degree control is at 65-75 ° in pulping process
SR。
See Table 1 for details for each component and its parts by weight of embodiment 1-4 and comparative example 1-5.
Table 1
Comparative example 6 is substantially the same manner as Example 1, the difference is that, the reaction of step (2) is not carried out, but will be modified
It is directly added into slurry after food-grade nano-titanium dioxide, silver nitrate and water mixing.
Tipping paper prepared by above-described embodiment 1-4 and comparative example 1-6 is tested for the property, test result is shown in Table 2.
Table 2
Wherein, the test method of tar adsorbance is that the tipping paper prepared by embodiment 1-4 and comparative example 1-6 exists
Same board, with pipe tobacco in the case where paper roll cigarette is made, will be inserted into after the combustion of paper roll smoke point intratracheal, and pass through air-introduced machine air draught and (keep
Identical air draught speed), after cigarette all burnt, tipping paper is torn, detects the tar content on tipping paper.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention
Property range is not limited to the contents of the specification, it is necessary to which the technical scope thereof is determined according to the scope of the claim.
Claims (6)
1. a kind of food-grade tipping paper, it is characterised in that: each component including following parts by weight:
40-60 parts of softwood pulp
60-80 parts of hardwood pulp
5-8 parts of cationic polyacrylamide
15-20 parts of hydroxypropul starch
1-3 parts of sodium metasilicate
1-3 parts of gelatin
3-5 parts of polyethylene glycol
3-8 parts of modified food grade nano-titanium dioxide
2-5 parts of silver-series antibacterial agent
10-15 parts of deionized water.
2. food-grade tipping paper as described in claim 1, it is characterised in that: the knot of the modified food grade nano-titanium dioxide
Structure formula are as follows:
3. food-grade tipping paper as described in claim 1, it is characterised in that: the antibacterial agent is silver nitrate.
4. food-grade tipping paper as claimed in claim 3, it is characterised in that: be prepared by following steps:
(1) beater is added in softwood pulp and hardwood pulp, is beaten, obtain slurry；
(2) in deionized water by the dispersion of modified food grade nano-titanium dioxide, then silver nitrate is added in sonic oscillation 20min,
It is stirred to react 1-2h at 90 DEG C, obtains mixed liquor；
(3) mixed liquor of step (2) is added in the slurry of step (1), is uniformly mixed, obtains mixed slurry；
(4) cationic polyacrylamide, hydroxypropul starch, sodium metasilicate, gelatin and polyethylene glycol are sequentially added into mixed slurry
In, it is uniformly mixed, obtains paper pulp；
(5) paper pulp is suppressed on nipper through wet end and press section drainage and formation, and is punched.
5. food-grade tipping paper as claimed in claim 4, it is characterised in that: beating consistency control exists in the pulping process
3.5-4.5%.
6. food-grade tipping paper as claimed in claim 4, it is characterised in that: beating degree control is in 65- in the pulping process
75°SR。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910324796.9A CN110042700A (en) | 2019-04-22 | 2019-04-22 | Food-grade tipping paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910324796.9A CN110042700A (en) | 2019-04-22 | 2019-04-22 | Food-grade tipping paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110042700A true CN110042700A (en) | 2019-07-23 |
Family
ID=67278382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910324796.9A Pending CN110042700A (en) | 2019-04-22 | 2019-04-22 | Food-grade tipping paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110042700A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113308943A (en) * | 2021-05-10 | 2021-08-27 | 江苏众立生包装科技有限公司 | Antibacterial tipping paper |
| CN113529482A (en) * | 2021-06-16 | 2021-10-22 | 河南中烟工业有限责任公司 | Preparation method of antibacterial tipping paper |
| CN113802412A (en) * | 2021-08-19 | 2021-12-17 | 江苏众立生包装科技有限公司 | Anti-wrinkle and anti-wet tipping paper |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1286052A (en) * | 1998-11-18 | 2001-03-07 | 史超 | Easily ignited fragrant cigarettes containing tar reduced selectively and its production method |
| CN103290721A (en) * | 2013-05-21 | 2013-09-11 | 牡丹江恒丰纸业股份有限公司 | Production method of tipping base paper for flame-retardant cigarettes |
| CN107190578A (en) * | 2016-03-15 | 2017-09-22 | 江苏金恒新型包装材料有限公司 | A kind of cork paper and preparation method thereof |
| CN108193547A (en) * | 2017-12-01 | 2018-06-22 | 蒋春霞 | A kind of preparation method of antibacterial hydrophobic type cork paper |
-
2019
- 2019-04-22 CN CN201910324796.9A patent/CN110042700A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1286052A (en) * | 1998-11-18 | 2001-03-07 | 史超 | Easily ignited fragrant cigarettes containing tar reduced selectively and its production method |
| CN103290721A (en) * | 2013-05-21 | 2013-09-11 | 牡丹江恒丰纸业股份有限公司 | Production method of tipping base paper for flame-retardant cigarettes |
| CN107190578A (en) * | 2016-03-15 | 2017-09-22 | 江苏金恒新型包装材料有限公司 | A kind of cork paper and preparation method thereof |
| CN108193547A (en) * | 2017-12-01 | 2018-06-22 | 蒋春霞 | A kind of preparation method of antibacterial hydrophobic type cork paper |
Non-Patent Citations (1)
| Title |
|---|
| 叶霖等: "《环糊精自组装 一种新型超分子材料的制备与应用》", 30 November 2013 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113308943A (en) * | 2021-05-10 | 2021-08-27 | 江苏众立生包装科技有限公司 | Antibacterial tipping paper |
| CN113529482A (en) * | 2021-06-16 | 2021-10-22 | 河南中烟工业有限责任公司 | Preparation method of antibacterial tipping paper |
| CN113802412A (en) * | 2021-08-19 | 2021-12-17 | 江苏众立生包装科技有限公司 | Anti-wrinkle and anti-wet tipping paper |
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Application publication date: 20190723 |