CN106565252A - 一种耐高温特种陶瓷及其制备方法 - Google Patents
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Abstract
本发明公开了一种耐高温特种陶瓷及其制备方法,包括以下重量份数的组分组成:锆英石20‑25份、二硼化锆18‑20份、酚醛树脂15‑20份、焦宝石12‑15份、紫砂泥10‑15份、钙长石10‑15份、水玻璃5‑10份、氧化铈2‑5份、纳米级氧化钼2‑5份、石墨烯2‑5份,去离子水适量。该耐高温特种陶瓷及其制备方法设计合理,采用先粉碎原料再球磨获得超细粉的工艺,保证了粉体的尺寸;加入酚醛树脂和纳米级氧化钼可以大大提高耐热温度,使得耐热温度超过4000℃;而具有高温耐热时间长,抗弯强度好的优点,大大增加了陶瓷的品质;而且制备工艺简单,降低了生产成本,能够满足使用需要,经济效益好。
Description
技术领域
本发明涉及一种陶瓷材料,具体是一种耐高温特种陶瓷及其制备方法。
背景技术
陶瓷按用途可以分为日用陶瓷、艺术陶瓷、工业陶瓷等。其中,工业陶瓷又分为建筑卫生陶瓷、化工陶瓷、电瓷、特种陶瓷等。特种陶瓷制品主要用于各种现代工业和尖端科学技术,例如航天航空、核工业、新能源、国防军工等领域,而且在各领域都急需大量的新材料,特种陶瓷由于具有优良的耐热性能,介电性能,耐磨性能,隔热性能,压电性能,透光性能受到各国的广泛重视。特种陶瓷材料有高铝氧质瓷、镁石质瓷、钛镁石质瓷、锆英石质瓷、锂质瓷、以及磁性瓷、金属陶瓷等多种类型。但是现有的特种陶瓷的耐热温度较低,生产工艺较复杂,增加了生产成本;而且产品的强度较低,不能满足使用要求。
发明内容
本发明的目的在于提供一种耐高温特种陶瓷及其制备方法,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案:
一种耐高温特种陶瓷,包括以下重量份数的组分组成:锆英石20-25份、二硼化锆18-20份、酚醛树脂15-20份、焦宝石12-15份、紫砂泥10-15份、钙长石10-15份、水玻璃5-10份、氧化铈2-5份、纳米级氧化钼2-5份、石墨烯2-5份,去离子水适量。
作为本发明进一步的方案:包括以下重量份数的组分组成:锆英石22份、二硼化锆19份、酚醛树脂17份、焦宝石13份、紫砂泥12份、钙长石12份、水玻璃7份、氧化铈3份、纳米级氧化钼4份、石墨烯5份,去离子水适量。
一种耐高温特种陶瓷的制备方法,具体步骤为:(1)将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀0.5-1h,烧蚀温度550-600℃;(2)将上步所得物放入粉碎机内进行粉碎,过70-80目筛,然后放入球磨机中,加入石墨烯,1500-2000rpm高速球磨0.5-1h,烘干,粉碎,得颗粒物Ⅰ;(3)将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.2-1.5h,烧蚀温度450-500℃;(4)将上步所得物放入粉碎机内进行粉碎,过80-90目筛,然后放入球磨机中,加入酚醛树脂,1500-2000rpm高速球磨0.5-1h,烘干,粉碎,得颗粒物Ⅱ;(5)将颗粒物Ⅰ和颗粒物Ⅱ放入球磨机中,加入纳米级氧化钼,6000-6500rpm高速球磨10-20min,得复合超细粉;(6)采用喷雾法向复合超细粉中加入适量去离子水,搅拌10-15min;(7)将上步所得物采用干压工艺进行胚体成型,压力为320-350MPa;(8)将上步所得物在常压高温1500-1800℃预烧3-4h,然后在2300-2500℃下烧结7.5-8.5h,即得成品。
作为本发明再进一步的方案:所述步骤(1)将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀0.6h,烧蚀温度580℃。
作为本发明再进一步的方案:所述步骤(2)将上步所得物放入粉碎机内进行粉碎,过80目筛,然后放入球磨机中,加入石墨烯,1600rpm高速球磨0.8h,烘干,粉碎,得颗粒物Ⅰ。
作为本发明再进一步的方案:所述步骤(3)将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.3h,烧蚀温度480℃。
作为本发明再进一步的方案:所述步骤(4)将上步所得物放入粉碎机内进行粉碎,过85目筛,然后放入球磨机中,加入酚醛树脂,1700rpm高速球磨0.7h,烘干,粉碎,得颗粒物Ⅱ。
作为本发明再进一步的方案:所述步骤(8)将上步所得物在常压高温1600℃预烧3.5h,然后在2400℃下烧结8h,即得成品。
与现有技术相比,本发明的有益效果是:
该耐高温特种陶瓷及其制备方法设计合理,采用先粉碎原料再球磨获得超细粉的工艺,保证了粉体的尺寸;加入酚醛树脂和纳米级氧化钼可以大大提高耐热温度,使得耐热温度超过4000℃;而具有高温耐热时间长,抗弯强度好的优点,大大增加了陶瓷的品质;而且制备工艺简单,降低了生产成本,能够满足使用需要,经济效益好。
具体实施方式
下面结合具体实施方式对本专利的技术方案作进一步详细地说明。
实施例1
称取锆英石20份、二硼化锆18份、酚醛树脂15份、焦宝石12份、紫砂泥10份、钙长石10份、水玻璃5份、氧化铈2份、纳米级氧化钼2份、石墨烯2份,去离子水适量,备用;将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀0.5h,烧蚀温度550℃;将上步所得物放入粉碎机内进行粉碎,过70目筛,然后放入球磨机中,加入石墨烯,1500rpm高速球磨0.5h,烘干,粉碎,得颗粒物Ⅰ;将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.2h,烧蚀温度450℃;将上步所得物放入粉碎机内进行粉碎,过80目筛,然后放入球磨机中,加入酚醛树脂,1500rpm高速球磨0.5h,烘干,粉碎,得颗粒物Ⅱ;将颗粒物Ⅰ和颗粒物Ⅱ放入球磨机中,加入纳米级氧化钼,6000rpm高速球磨10min,得复合超细粉;采用喷雾法向复合超细粉中加入适量去离子水,搅拌10min;将上步所得物采用干压工艺进行胚体成型,压力为320MPa;将上步所得物在常压高温1500℃预烧3h,然后在2300℃下烧结7.5h,即得成品。
实施例2
称取锆英石25份、二硼化锆20份、酚醛树脂20份、焦宝石15份、紫砂泥15份、钙长石15份、水玻璃10份、氧化铈5份、纳米级氧化钼5份、石墨烯5份,去离子水适量,备用;将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀1h,烧蚀温度600℃;将上步所得物放入粉碎机内进行粉碎,过80目筛,然后放入球磨机中,加入石墨烯,2000rpm高速球磨1h,烘干,粉碎,得颗粒物Ⅰ;将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.5h,烧蚀温度500℃;将上步所得物放入粉碎机内进行粉碎,过90目筛,然后放入球磨机中,加入酚醛树脂,2000rpm高速球磨1h,烘干,粉碎,得颗粒物Ⅱ;将颗粒物Ⅰ和颗粒物Ⅱ放入球磨机中,加入纳米级氧化钼,6500rpm高速球磨20min,得复合超细粉;采用喷雾法向复合超细粉中加入适量去离子水,搅拌15min;将上步所得物采用干压工艺进行胚体成型,压力为350MPa;将上步所得物在常压高温1800℃预烧4h,然后在2500℃下烧结8.5h,即得成品。
实施例3
称取锆英石22份、二硼化锆19份、酚醛树脂17份、焦宝石13份、紫砂泥12份、钙长石12份、水玻璃7份、氧化铈3份、纳米级氧化钼4份、石墨烯5份,去离子水适量,备用;将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀0.6h,烧蚀温度580℃;将上步所得物放入粉碎机内进行粉碎,过80目筛,然后放入球磨机中,加入石墨烯,1600rpm高速球磨0.8h,烘干,粉碎,得颗粒物Ⅰ;将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.3h,烧蚀温度480℃;将上步所得物放入粉碎机内进行粉碎,过85目筛,然后放入球磨机中,加入酚醛树脂,1700rpm高速球磨0.7h,烘干,粉碎,得颗粒物Ⅱ;将颗粒物Ⅰ和颗粒物Ⅱ放入球磨机中,加入纳米级氧化钼,6300rpm高速球磨15min,得复合超细粉;采用喷雾法向复合超细粉中加入适量去离子水,搅拌13min;将上步所得物采用干压工艺进行胚体成型,压力为340MPa;将上步所得物在常压高温1600℃预烧3.5h,然后在2400℃下烧结8h,即得成品。
对比例1
称取锆英石22份、二硼化锆19份、焦宝石13份、紫砂泥12份、钙长石12份、水玻璃7份、氧化铈3份、石墨烯5份,去离子水适量,备用;将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀0.6h,烧蚀温度580℃;将上步所得物放入粉碎机内进行粉碎,过80目筛,然后放入球磨机中,加入石墨烯,1600rpm高速球磨0.8h,烘干,粉碎,得颗粒物Ⅰ;将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.3h,烧蚀温度480℃;将上步所得物放入粉碎机内进行粉碎,过85目筛,然后放入球磨机中,在1700rpm高速球磨0.7h,烘干,粉碎,得颗粒物Ⅱ;将颗粒物Ⅰ和颗粒物Ⅱ放入球磨机中,在6300rpm高速球磨15min,得复合超细粉;采用喷雾法向复合超细粉中加入适量去离子水,搅拌13min;将上步所得物采用干压工艺进行胚体成型,压力为340MPa;将上步所得物在常压高温1600℃预烧3.5h,然后在2400℃下烧结8h,即得成品。
对比例2
称取锆英石22份、二硼化锆19份、焦宝石13份、紫砂泥12份、钙长石12份、水玻璃7份、氧化铈3份、纳米级氧化钼4份、石墨烯5份,去离子水适量,备用;将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀0.6h,烧蚀温度580℃;将上步所得物放入粉碎机内进行粉碎,过80目筛,然后放入球磨机中,加入石墨烯,1600rpm高速球磨0.8h,烘干,粉碎,得颗粒物Ⅰ;将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.3h,烧蚀温度480℃;将上步所得物放入粉碎机内进行粉碎,过85目筛,然后放入球磨机中,在1700rpm高速球磨0.7h,烘干,粉碎,得颗粒物Ⅱ;将颗粒物Ⅰ和颗粒物Ⅱ放入球磨机中,加入纳米级氧化钼,6300rpm高速球磨15min,得复合超细粉;采用喷雾法向复合超细粉中加入适量去离子水,搅拌13min;将上步所得物采用干压工艺进行胚体成型,压力为340MPa;将上步所得物在常压高温1600℃预烧3.5h,然后在2400℃下烧结8h,即得成品。
对比例3
称取锆英石22份、二硼化锆19份、酚醛树脂17份、焦宝石13份、紫砂泥12份、钙长石12份、水玻璃7份、氧化铈3份、石墨烯5份,去离子水适量,备用;将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀0.6h,烧蚀温度580℃;将上步所得物放入粉碎机内进行粉碎,过80目筛,然后放入球磨机中,加入石墨烯,1600rpm高速球磨0.8h,烘干,粉碎,得颗粒物Ⅰ;将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.3h,烧蚀温度480℃;将上步所得物放入粉碎机内进行粉碎,过85目筛,然后放入球磨机中,加入酚醛树脂,1700rpm高速球磨0.7h,烘干,粉碎,得颗粒物Ⅱ;将颗粒物Ⅰ和颗粒物Ⅱ放入球磨机中,在6300rpm高速球磨15min,得复合超细粉;采用喷雾法向复合超细粉中加入适量去离子水,搅拌13min;将上步所得物采用干压工艺进行胚体成型,压力为340MPa;将上步所得物在常压高温1600℃预烧3.5h,然后在2400℃下烧结8h,即得成品。
对实施例1-3和对比例1-3进行性能测试,性能测试结果如下表:
项目 | 高温耐热温度/℃ | 高温耐热时间/h | 抗弯强度/MPa | 韧性评价/KIC |
实施例1 | 3870 | 798 | 603 | 6 |
实施例2 | 3950 | 795 | 631 | 6 |
实施例3 | 4059 | 800 | 656 | 6 |
对比例1 | 1983 | 77 | 201 | 2 |
对比例2 | 2049 | 108 | 256 | 3 |
对比例3 | 2015 | 121 | 239 | 3 |
该耐高温特种陶瓷及其制备方法设计合理,采用先粉碎原料再球磨获得超细粉的工艺,保证了粉体的尺寸;加入酚醛树脂和纳米级氧化钼可以大大提高耐热温度,使得耐热温度超过4000℃;而具有高温耐热时间长,抗弯强度好的优点,大大增加了陶瓷的品质;而且制备工艺简单,降低了生产成本,能够满足使用需要,经济效益好。
上面对本专利的较佳实施方式作了详细说明,但是本专利并不限于上述实施方式,在本领域的普通技术人员所具备的知识范围内,还可以在不脱离本专利宗旨的前提下做出各种变化。
Claims (8)
1.一种耐高温特种陶瓷,其特征在于,包括以下重量份数的组分组成:锆英石20-25份、二硼化锆18-20份、酚醛树脂15-20份、焦宝石12-15份、紫砂泥10-15份、钙长石10-15份、水玻璃5-10份、氧化铈2-5份、纳米级氧化钼2-5份、石墨烯2-5份,去离子水适量。
2.根据权利要求1所述的耐高温特种陶瓷,其特征在于,包括以下重量份数的组分组成:锆英石22份、二硼化锆19份、酚醛树脂17份、焦宝石13份、紫砂泥12份、钙长石12份、水玻璃7份、氧化铈3份、纳米级氧化钼4份、石墨烯5份,去离子水适量。
3.一种如权利要求1-2任一所述的耐高温特种陶瓷的制备方法,其特征在于,具体步骤为:(1)将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀0.5-1h,烧蚀温度550-600℃;(2)将上步所得物放入粉碎机内进行粉碎,过70-80目筛,然后放入球磨机中,加入石墨烯,1500-2000rpm高速球磨0.5-1h,烘干,粉碎,得颗粒物Ⅰ;(3)将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.2-1.5h,烧蚀温度450-500℃;(4)将上步所得物放入粉碎机内进行粉碎,过80-90目筛,然后放入球磨机中,加入酚醛树脂,1500-2000rpm高速球磨0.5-1h,烘干,粉碎,得颗粒物Ⅱ;(5)将颗粒物Ⅰ和颗粒物Ⅱ放入球磨机中,加入纳米级氧化钼,6000-6500rpm高速球磨10-20min,得复合超细粉;(6)采用喷雾法向复合超细粉中加入适量去离子水,搅拌10-15min;(7)将上步所得物采用干压工艺进行胚体成型,压力为320-350MPa;(8)将上步所得物在常压高温1500-1800℃预烧3-4h,然后在2300-2500℃下烧结7.5-8.5h,即得成品。
4.一种如权利要求3所述的耐高温特种陶瓷的制备方法,其特征在于,所述步骤(1)将锆英石、焦宝石、钙长石放入煅烧炉中,烧蚀0.6h,烧蚀温度580℃。
5.一种如权利要求3所述的耐高温特种陶瓷的制备方法,其特征在于,所述步骤(2)将上步所得物放入粉碎机内进行粉碎,过80目筛,然后放入球磨机中,加入石墨烯,1600rpm高速球磨0.8h,烘干,粉碎,得颗粒物Ⅰ。
6.一种如权利要求3所述的耐高温特种陶瓷的制备方法,其特征在于,所述步骤(3)将二硼化锆、紫砂泥、水玻璃和氧化铈放入煅烧炉中,烧蚀1.3h,烧蚀温度480℃。
7.一种如权利要求3所述的耐高温特种陶瓷的制备方法,其特征在于,所述步骤(4)将上步所得物放入粉碎机内进行粉碎,过85目筛,然后放入球磨机中,加入酚醛树脂,1700rpm高速球磨0.7h,烘干,粉碎,得颗粒物Ⅱ。
8.一种如权利要求3所述的耐高温特种陶瓷的制备方法,其特征在于,所述步骤(8)将上步所得物在常压高温1600℃预烧3.5h,然后在2400℃下烧结8h,即得成品。
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