CN106555193A - Metal conditioner and preparation method thereof - Google Patents
Metal conditioner and preparation method thereof Download PDFInfo
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- CN106555193A CN106555193A CN201510622889.1A CN201510622889A CN106555193A CN 106555193 A CN106555193 A CN 106555193A CN 201510622889 A CN201510622889 A CN 201510622889A CN 106555193 A CN106555193 A CN 106555193A
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- sodium
- npe
- defoamer
- stabilizer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
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Abstract
The present invention discloses a kind of metal conditioner, is made up of the raw material of following weight proportion：Sodium polyacrylate 15-20 parts, trifluoroethanol 2-4 parts, NPE 2-4 parts, sodium citrate 2-4 parts, tetra- sodium 4-6 parts of EDTA, shitosan 4-6 parts, dodecyl sodium sulfate 4-6 parts, acetic acid 3-5 parts, ethylene glycol 3-5 parts, triethanolamine 3-5 parts, di-o-tolyl-thiourea 3-5 parts, sodium gluconate 3-5 parts, carboxymethyl cellulose 3-5 parts, enuatrol 3-5 parts, sodium pyrophosphate 3-5 parts, silicon dioxide 3-5 parts, nonionic surfactant 3-5 parts, 4 parts of anion surfactant, 4 parts of defoamer, 4 parts of tertiary sodium phosphate, 4 parts of stabilizer, wherein described defoamer is selected from NPE or polyvinylether.The inorganic agent cleaning performance of the present invention is good.
Description
Technical field
The present invention relates to a kind of inorganic agent, relates more specifically to a kind of metal conditioner and preparation method thereof.
Background technology
Metal be it is a kind of with gloss, be rich in ductility, the material of the easy property such as conduction, heat conduction.It is in nature, big absolutely
Most metals are present with compound state, and a few metals such as gold, platinum, silver, bismuth are present with free state.Metalliferous mineral majority is oxidation
Thing and sulfide.Other existence forms have chloride, sulfate, carbonate and silicate.Metal is in processing, process and uses
During often there is different degrees of oxidation, corrosion etc., reduce the service life of metal material or hardware, therefore,
Need to process metal surface, increase its antioxidation, erosion-resisting ability, increase the service life.It is general using gold at present
Category abluent is cleaned to metal surface, but metal cleaner in the market, mostly cleaning performance are bad, therefore, open
To send out a kind of new with low to environmental hazard, and with low cost, cleaning performance is excellent, to the less metal cleaner of metal attack,
Have become the problem of those skilled in the art's solution too impatient to wait.
The content of the invention
For the defect of prior art, the invention provides a kind of metal conditioner and preparation method thereof.
A kind of metal conditioner, which is made up of the raw material of following weight proportion：Sodium polyacrylate 15-20 parts, trifluoro second
Alcohol 2-4 parts, NPE 2-4 parts, sodium citrate 2-4 parts, tetra- sodium 4-6 parts of EDTA, shitosan 4-6 parts,
Dodecyl sodium sulfate 4-6 parts, acetic acid 3-5 parts, ethylene glycol 3-5 parts, triethanolamine 3-5 parts, di-o-tolyl-thiourea 3-5
Part, sodium gluconate 3-5 parts, carboxymethyl cellulose 3-5 parts, enuatrol 3-5 parts, sodium pyrophosphate 3-5 parts, silicon dioxide
3-5 parts, nonionic surfactant 3-5 parts, 4 parts of anion surfactant, 4 parts of defoamer, 4 parts of tertiary sodium phosphate,
4 parts of stabilizer, wherein the defoamer is selected from NPE or polyvinylether.
A kind of preparation method of metal conditioner, comprises the steps：
S100：Anion surfactant processed, by OPEO, high-carbon fatty alcohol polyoxyethylene ether, fatty acid polyglycol
One or more of oxygen vinyl acetate, sorbitan ester, adds 30% deionized water to be sufficiently mixed and stirs 10-15min, then after
30 DEG C -32 DEG C are heated to, 10-15min is sufficiently stirred for；
S200：Sodium polyacrylate, trifluoroethanol, NPE, sodium citrate, the mixing of tetra- sodium of EDTA are taken, anti-
Answer in kettle with 1000 revs/min of speed dispersed with stirring, add shitosan；
S300：Take dodecyl sodium sulfate, acetic acid, ethylene glycol, triethanolamine, di-o-tolyl-thiourea, sodium gluconate, carboxylic
Methylcellulose, enuatrol, sodium pyrophosphate, silicon dioxide, add 70% part of deionized water of mixture, stir, stirring
Mix down and be heated to 45 DEG C, be incubated 40min；
S400：Solution obtained in step S100-S400 is mixed, add nonionic surfactant, defoamer, tertiary sodium phosphate,
And stabilizer, 25min is stirred, is added acid-base modifier that pH value is adjusted to 6-7, is stirred.
The invention has the beneficial effects as follows：The rust remover in raw material in the present invention can effectively remove the dirt of metal surface, detergency
By force, cleaning performance is good, various oils easily can be eluted out from various absorbent bodies, not phosphorous, without organic molten
Agent, prevents oxidation, the corrosion of metal, keeps metal surface light, and the residual liquid after cleaning will not be to ecological environment；
Using NPE can increase the compatibility of each material, each material is dispersed in water well, the oil in raw material
Sour sodium, sodium pyrophosphate can effectively remove speckle, metal parts corrosion-free, noresidue Jing after present invention cleaning；Environmental protection of the invention, safety
Good, the nontoxic non-corrosiveness of property, free from environmental pollution, safety and stability.
Specific embodiment
Embodiment 1
A kind of metal conditioner, which is made up of the raw material of following weight proportion：20 parts of sodium polyacrylate, trifluoroethanol 2
Part, 2 parts of NPE, 2 parts of sodium citrate, 6 parts of tetra- sodium of EDTA, 6 parts of shitosan, dodecyl sodium sulfate
6 parts, 3 parts of acetic acid, 3 parts of ethylene glycol, 3 parts of triethanolamine, 3 parts of di-o-tolyl-thiourea, 3 parts of sodium gluconate, carboxylic first
5 parts of base cellulose, 5 parts of enuatrol, 5 parts of sodium pyrophosphate, 5 parts of silicon dioxide, 5 parts of nonionic surfactant, it is cloudy from
4 parts of sub- surfactant, 4 parts of defoamer, 4 parts of tertiary sodium phosphate, 4 parts of stabilizer.Wherein nonionic surfactant is elected as
Fatty acid alkanol amides；The anion surfactant selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether,
One or more of polyoxyethylene carboxylate, sorbitan ester；The defoamer is selected from NPE or poly- second
Alkene ether；The stabilizer is selected from phosphorous acid hexichol one last of the ten Heavenly stems ester, one benzene didecyl of phosphorous acid, butyl epoxy stearate, monooctyl ester second two
One or more of amine tetramethylene phosphonic acid sodium.
Embodiment 2
A kind of metal conditioner, which is made up of the raw material of following weight proportion：15 parts of sodium polyacrylate, trifluoroethanol 6
Part, 6 parts of NPE, 6 parts of sodium citrate, 2 parts of tetra- sodium of EDTA, 2 parts of shitosan, dodecyl sodium sulfate
2 parts, 5 parts of acetic acid, 5 parts of ethylene glycol, 5 parts of triethanolamine, 5 parts of di-o-tolyl-thiourea, 5 parts of sodium gluconate, carboxylic first
3 parts of base cellulose, 3 parts of enuatrol, 3 parts of sodium pyrophosphate, 3 parts of silicon dioxide, 3 parts of nonionic surfactant, it is cloudy from
6 parts of sub- surfactant, 6 parts of defoamer, 5 parts of tertiary sodium phosphate, 4 parts of stabilizer.Wherein nonionic surfactant is elected as
Fatty acid alkanol amides；The anion surfactant selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether,
One or more of polyoxyethylene carboxylate, sorbitan ester；The defoamer is selected from NPE or poly- second
Alkene ether；The stabilizer is selected from phosphorous acid hexichol one last of the ten Heavenly stems ester, one benzene didecyl of phosphorous acid, butyl epoxy stearate, monooctyl ester second two
One or more of amine tetramethylene phosphonic acid sodium.
Embodiment 3
A kind of metal conditioner, which is made up of the raw material of following weight proportion：25 parts of sodium polyacrylate, trifluoroethanol 4
Part, 4 parts of NPE, 4 parts of sodium citrate, 4 parts of tetra- sodium of EDTA, 4 parts of shitosan, dodecyl sodium sulfate
4 parts, 4 parts of acetic acid, 4 parts of ethylene glycol, 4 parts of triethanolamine, 4 parts of di-o-tolyl-thiourea, 4 parts of sodium gluconate, carboxylic first
4 parts of base cellulose, 4 parts of enuatrol, 4 parts of sodium pyrophosphate, 4 parts of silicon dioxide, 4 parts of nonionic surfactant, it is cloudy from
3 parts of sub- surfactant, 3 parts of defoamer, 3 parts of tertiary sodium phosphate, 2 parts of stabilizer.Wherein nonionic surfactant is elected as
Fatty acid alkanol amides；The anion surfactant selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether,
One or more of polyoxyethylene carboxylate, sorbitan ester；The defoamer is selected from NPE or poly- second
Alkene ether；The stabilizer is selected from phosphorous acid hexichol one last of the ten Heavenly stems ester, one benzene didecyl of phosphorous acid, butyl epoxy stearate, monooctyl ester second two
One or more of amine tetramethylene phosphonic acid sodium.
Embodiment 4
A kind of metal conditioner, which is made up of the raw material of following weight proportion：10 parts of sodium polyacrylate, trifluoroethanol 2
Part, 2 parts of NPE, 2 parts of sodium citrate, 8 parts of tetra- sodium of EDTA, 8 parts of shitosan, dodecyl sodium sulfate
8 parts, 3 parts of acetic acid, 3 parts of ethylene glycol, 3 parts of triethanolamine, 3 parts of di-o-tolyl-thiourea, 3 parts of sodium gluconate, carboxylic first
8 parts of base cellulose, 8 parts of enuatrol, 5 parts of sodium pyrophosphate, 5 parts of silicon dioxide, 5 parts of nonionic surfactant, it is cloudy from
4 parts of sub- surfactant, 4 parts of defoamer, 4 parts of tertiary sodium phosphate, 4 parts of stabilizer.Wherein nonionic surfactant is elected as
Fatty acid alkanol amides；The anion surfactant selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether,
One or more of polyoxyethylene carboxylate, sorbitan ester；The defoamer is selected from NPE or poly- second
Alkene ether；The stabilizer is selected from phosphorous acid hexichol one last of the ten Heavenly stems ester, one benzene didecyl of phosphorous acid, butyl epoxy stearate, monooctyl ester second two
One or more of amine tetramethylene phosphonic acid sodium.
Embodiment 5
A kind of metal conditioner, which is made up of the raw material of following weight proportion：30 parts of sodium polyacrylate, trifluoroethanol 2
Part, 2 parts of NPE, 2 parts of sodium citrate, 4 parts of tetra- sodium of EDTA, 4 parts of shitosan, dodecyl sodium sulfate
4 parts, 3 parts of acetic acid, 3 parts of ethylene glycol, 3 parts of triethanolamine, di-o-tolyl-thiourea 3, sodium gluconate 3, carboxymethyl cellulose
Element 5, enuatrol 5, sodium pyrophosphate 3,3 parts of silicon dioxide, 5 parts of nonionic surfactant, anion surfactant 4
Part, 4 parts of defoamer, 4 parts of tertiary sodium phosphate, 4 parts of stabilizer.Wherein nonionic surfactant elects fatty acid alkanol amides as；
The anion surfactant selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate,
One or more of sorbitan ester；The defoamer is selected from NPE or polyvinylether；The stabilizer choosing
From phosphorous acid hexichol one last of the ten Heavenly stems ester, phosphorous acid one benzene didecyl, butyl epoxy stearate, monooctyl ester sodium ethylenediamine tetramethylenephosphonate
One or more.
Preparation method：
A kind of preparation method of metal conditioner, comprises the steps：
S100：Anion surfactant processed, by OPEO, high-carbon fatty alcohol polyoxyethylene ether, fatty acid polyglycol
One or more of oxygen vinyl acetate, sorbitan ester, adds 30% deionized water to be sufficiently mixed and stirs 10-15min, then after
30 DEG C -32 DEG C are heated to, 10-15min is sufficiently stirred for；
S200：Sodium polyacrylate, trifluoroethanol, NPE, sodium citrate, the mixing of tetra- sodium of EDTA are taken, anti-
Answer in kettle with 1000 revs/min of speed dispersed with stirring, add shitosan；
S300：Take dodecyl sodium sulfate, acetic acid, ethylene glycol, triethanolamine, di-o-tolyl-thiourea, sodium gluconate, carboxylic
Methylcellulose, enuatrol, sodium pyrophosphate, silicon dioxide, add 70% part of deionized water of mixture, stir, stirring
Mix down and be heated to 45 DEG C, be incubated 40min；
S400：Solution obtained in step S100-S400 is mixed, add nonionic surfactant, defoamer, tertiary sodium phosphate,
And stabilizer, 25min is stirred, is added acid-base modifier that pH value is adjusted to 6-7, is stirred.
Elaborate many details in order to fully understand the present invention in the above description.But above description is only the present invention
Preferred embodiment, the present invention can be to be much different from alternate manner described here implementing, therefore the present invention is not received
The restriction being embodied as disclosed above.Any those skilled in the art are without departing from technical solution of the present invention scope feelings simultaneously
Under condition, many possible variations and modification are made to technical solution of the present invention using the methods and techniques content of the disclosure above all,
Or it is revised as the Equivalent embodiments of equivalent variations.Every content without departing from technical solution of the present invention, according to the technology reality of the present invention
Verify any simple modification made for any of the above embodiments, equivalent variations and modification, still fall within the model of technical solution of the present invention protection
In enclosing.
Claims (2)
1. a kind of metal conditioner, it is characterised in which is made up of the raw material of following weight proportion：Sodium polyacrylate 15-20
Part, trifluoroethanol 2-4 parts, NPE 2-4 parts, sodium citrate 2-4 parts, tetra- sodium 4-6 parts of EDTA, shell gather
Sugared 4-6 parts, dodecyl sodium sulfate 4-6 parts, acetic acid 3-5 parts, ethylene glycol 3-5 parts, triethanolamine 3-5 parts, two adjacent first
Benzene thiourea 3-5 parts, sodium gluconate 3-5 parts, carboxymethyl cellulose 3-5 parts, enuatrol 3-5 parts, sodium pyrophosphate 3-5 parts,
Silicon dioxide 3-5 parts, nonionic surfactant 3-5 parts, 4 parts of anion surfactant, 4 parts of defoamer, tricresyl phosphate
4 parts of sodium, 4 parts of stabilizer, wherein the defoamer is selected from NPE or polyvinylether.
2. the preparation method of the metal conditioner described in a kind of claim 1, it is characterised in that comprise the steps：
S100：Anion surfactant processed, by OPEO, high-carbon fatty alcohol polyoxyethylene ether, fatty acid polyglycol
One or more of oxygen vinyl acetate, sorbitan ester, adds 30% deionized water to be sufficiently mixed and stirs 10-15min, then after
30 DEG C -32 DEG C are heated to, 10-15min is sufficiently stirred for；
S200：Sodium polyacrylate, trifluoroethanol, NPE, sodium citrate, the mixing of tetra- sodium of EDTA are taken, anti-
Answer in kettle with 1000 revs/min of speed dispersed with stirring, add shitosan；
S300：Take dodecyl sodium sulfate, acetic acid, ethylene glycol, triethanolamine, di-o-tolyl-thiourea, sodium gluconate, carboxylic
Methylcellulose, enuatrol, sodium pyrophosphate, silicon dioxide, add 70% part of deionized water of mixture, stir, stirring
Mix down and be heated to 45 DEG C, be incubated 40min；
S400：Solution obtained in step S100-S400 is mixed, add nonionic surfactant, defoamer, tertiary sodium phosphate,
And stabilizer, 25min is stirred, is added acid-base modifier that pH value is adjusted to 6-7, is stirred.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510622889.1A CN106555193A (en) | 2015-09-28 | 2015-09-28 | Metal conditioner and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510622889.1A CN106555193A (en) | 2015-09-28 | 2015-09-28 | Metal conditioner and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106555193A true CN106555193A (en) | 2017-04-05 |
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| CN201510622889.1A Pending CN106555193A (en) | 2015-09-28 | 2015-09-28 | Metal conditioner and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108085671A (en) * | 2017-12-27 | 2018-05-29 | 洛阳神佳窑业有限公司 | Novel colored metal conditioner |
| CN108149260A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | A kind of surface conditioning agent for non-ferrous metal |
| CN108149265A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | For the surface conditioning agent of non-ferrous metal |
| CN108149259A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | A kind of surface conditioning agent used for non-ferrous metal |
-
2015
- 2015-09-28 CN CN201510622889.1A patent/CN106555193A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108085671A (en) * | 2017-12-27 | 2018-05-29 | 洛阳神佳窑业有限公司 | Novel colored metal conditioner |
| CN108149260A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | A kind of surface conditioning agent for non-ferrous metal |
| CN108149265A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | For the surface conditioning agent of non-ferrous metal |
| CN108149259A (en) * | 2017-12-27 | 2018-06-12 | 洛阳神佳窑业有限公司 | A kind of surface conditioning agent used for non-ferrous metal |
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Application publication date: 20170405 |