CN104313608B - Environment-friendly aluminum cleaning agent and preparation method thereof - Google Patents
Environment-friendly aluminum cleaning agent and preparation method thereof Download PDFInfo
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- CN104313608B CN104313608B CN201410438356.3A CN201410438356A CN104313608B CN 104313608 B CN104313608 B CN 104313608B CN 201410438356 A CN201410438356 A CN 201410438356A CN 104313608 B CN104313608 B CN 104313608B
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 103
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 103
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000002253 acid Substances 0.000 claims abstract description 34
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 22
- 150000007524 organic acids Chemical class 0.000 claims abstract description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 69
- 239000000463 material Substances 0.000 claims description 44
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 22
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 16
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 14
- -1 polyoxyethylene Polymers 0.000 claims description 14
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical group CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 13
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 13
- 239000012467 final product Substances 0.000 claims description 11
- 239000001117 sulphuric acid Substances 0.000 claims description 11
- 235000011149 sulphuric acid Nutrition 0.000 claims description 11
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 10
- 239000011707 mineral Substances 0.000 claims description 10
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 9
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 8
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- 239000002738 chelating agent Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 8
- 239000004310 lactic acid Substances 0.000 claims description 8
- 235000014655 lactic acid Nutrition 0.000 claims description 8
- 230000000149 penetrating effect Effects 0.000 claims description 8
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 claims description 7
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 claims description 7
- 229960003237 betaine Drugs 0.000 claims description 7
- 239000000467 phytic acid Substances 0.000 claims description 7
- 229940068041 phytic acid Drugs 0.000 claims description 7
- 235000002949 phytic acid Nutrition 0.000 claims description 7
- 239000001509 sodium citrate Substances 0.000 claims description 7
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical group [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 7
- 229940038773 trisodium citrate Drugs 0.000 claims description 7
- 239000002280 amphoteric surfactant Substances 0.000 claims description 6
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 5
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 229960000583 acetic acid Drugs 0.000 claims description 4
- 239000012362 glacial acetic acid Substances 0.000 claims description 4
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims description 3
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 235000017858 Laurus nobilis Nutrition 0.000 claims 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims 1
- 244000125380 Terminalia tomentosa Species 0.000 claims 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 claims 1
- 229960002050 hydrofluoric acid Drugs 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 claims 1
- 239000011975 tartaric acid Substances 0.000 claims 1
- 235000002906 tartaric acid Nutrition 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 21
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract description 2
- 230000002378 acidificating effect Effects 0.000 abstract description 2
- 229910017604 nitric acid Inorganic materials 0.000 abstract description 2
- 235000005985 organic acids Nutrition 0.000 abstract 3
- 150000007513 acids Chemical class 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000008139 complexing agent Substances 0.000 abstract 1
- 150000007522 mineralic acids Chemical class 0.000 abstract 1
- 239000002357 osmotic agent Substances 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 description 34
- 239000012153 distilled water Substances 0.000 description 28
- 238000000034 method Methods 0.000 description 15
- 238000011010 flushing procedure Methods 0.000 description 11
- 238000009826 distribution Methods 0.000 description 8
- VZOPRCCTKLAGPN-ZFJVMAEJSA-L potassium;sodium;(2r,3r)-2,3-dihydroxybutanedioate;tetrahydrate Chemical compound O.O.O.O.[Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O VZOPRCCTKLAGPN-ZFJVMAEJSA-L 0.000 description 7
- 229940074446 sodium potassium tartrate tetrahydrate Drugs 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- NCBISIFFSNXYQJ-UHFFFAOYSA-N 1-dodecyl-4,5-dihydroimidazole Chemical compound CCCCCCCCCCCCN1CCN=C1 NCBISIFFSNXYQJ-UHFFFAOYSA-N 0.000 description 5
- 229910000838 Al alloy Inorganic materials 0.000 description 4
- 230000003628 erosive effect Effects 0.000 description 4
- 230000002411 adverse Effects 0.000 description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/12—Light metals
- C23G1/125—Light metals aluminium
Abstract
The invention discloses an environment-friendly aluminum cleaning agent and a preparation method thereof. The cleaning agent is composed of the following components in percentage by weight: 20% to 25% of inorganic acid, 10% to 20% of organic acid, 10% to 18% of surfactant, 8% to 15% of osmotic agent, 6% to 18% of emulsifier, 2% to 8% of antifoaming agent, 5% to 8% of complexing agent, and 25% to 30% of water. In the provided cleaning agent, the using amount of hydrochloric acid, sulfuric acid, and nitric acid is reduced, the aluminum parts are washed by medium-strong acids and organic acids, and the cleaning agent has a very good oil stain and rust removing ability. The cleaning agent is acidic, the pH value of the cleaning agent is 2.1 to 5.6, and the cleaning agent can well remove the oxide scale on the aluminum surface. Because the acidity of the organic acids is weak, the over-corrosion on work tools and acid volatilization, which can harm the workers' health, are effectively avoided, and the cleaning effect is not influenced at the same time. Moreover the adopted organic acids are easy to decompose, and thus the cleaning agent is environment-friendly.
Description
Technical field
The invention belongs to aluminium cleaning technique field, and in particular to a kind of environment-friendly type aluminum material cleaning agent, also relates to one
Plant the preparation method of environment-friendly type aluminum material cleaning agent.
Background technology
Aluminium alloy is due to having that density is little, specific strength is high, good heat conductivity, be easy to the many merits such as processing and forming, in material
Material engineering aspect is widely used.During the use of aluminium alloy, different use environments is for example alkaline, acid, neutral
Solution and marine environment etc. all can cause the corrosion of aluminium alloy；And conventional anti-corrosive treatment method has surface spraying paint, powder
End spraying, anodic oxidation and differential arc oxidation etc..State in realization anti-corrosion treatment, coating film layer before be intended to aluminium workpiece surface
It is carried out processing, the quality of cleaning quality directly affects performance and the quality of subsequent film.In prior art, all have both at home and abroad
The patent of aluminum component abluent aspect and article, common for alkaline cleaner, and acidic cleaner is mainly based on industrial three acid.Often
Substantial amounts of industrial three acid that rule abluent contains, such as sulphuric acid, nitric acid and hydrochloric acid, in use because the volatilization etc. of acid solution is right
The healthy and safe of operator produces a very large impact；And easily cause the excessive erosion of workpiece when cleaning workpiece, thus making
Become great economic loss.
Society now, people are to the healthy and safe of itself and more and more stronger to the protective awareness of environment, conventional surface
Abluent contains factor harmful and that environment is adversely affected so that its application is subject to certain restrictions due to it,
Therefore, study a kind of aluminum cleaning agent of novel environment friendly to have great importance.
Content of the invention
It is an object of the invention to provide a kind of environment-friendly type aluminum material cleaning agent, solve industrial three strong acid in existing aluminum material cleaning agent
Too high levels, threaten operator safety and the problem easily causing workpiece excessive erosion.
Second object of the present invention is to provide a kind of preparation method of environment-friendly type aluminum material cleaning agent.
In order to realize object above, the technical solution adopted in the present invention is：A kind of environment-friendly type aluminum material cleaning agent, by following
The group of mass percent is grouped into：Mineral acid 20%～25%, organic acid 10%～20%, surfactant 10%～18%,
Penetrating agent 8%～15%, emulsifying agent 6%～18%, defoamer 2～8%, chelating agent 5%～8%, water 25%～30%.
Described aluminium includes aluminum, aluminium alloy and other alumina-base materials.
Described mineral acid is phosphoric acid, hydrochloric acid, sulphuric acid, any one or more in Fluohydric acid..
Described mineral acid is hydrochloric acid, sulphuric acid, any one or two kinds of mixture with phosphoric acid in Fluohydric acid..
Mass concentration >=85% of described phosphoric acid.The mass concentration of described hydrochloric acid is 36%～38%.The matter of described sulphuric acid
Amount concentration is 95%～98%.Mass concentration >=40% of described Fluohydric acid..
Described organic acid is lactic acid, succinic acid, phytic acid, any one or more in glacial acetic acid.
Described surfactant is NPE, OPEO, succinate sodium salt, lauryl
Any one or more in imidazolinium betaine amphoteric surfactant.
Described succinate sodium salt is fatty alcohol-polyoxyethylene ether sulfosuccinate disodium salt (AESS).
Described penetrating agent is fatty alcohol-polyoxyethylene ether, butyl glycol ether, any one or more in propandiol butyl ether.
Described emulsifying agent is alkylphenol polyoxyethylene.
Described defoamer is butyl ether.
Described chelating agent is trisodium citrate, sodium potassium tartrate tetrahydrate, any in disodiumedetate (EDTA-2Na)
One or more.
A kind of preparation method of above-mentioned environment-friendly type aluminum material cleaning agent, comprises the following steps：
1) take mineral acid, after dilute with water, add organic acid, stir, obtain mixture A；
2) take surfactant, penetrating agent, emulsifying agent, defoamer mix homogeneously, obtain mixture B；
3) mixture B is added in mixture A, stir, add chelating agent, and add the remaining water of formula ratio, mix
After closing uniformly, obtain final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 3～5min at normal temperatures.Aluminum component after cleaning after distilled water flushing, gained aluminium workpiece surface study of water film distribution
Uniformly, no greasy residues, and aluminium workpiece surface color is aluminium true qualities.
The environment-friendly type aluminum material cleaning agent of the present invention, using mineral acid, organic acid, surfactant, penetrating agent, emulsifying agent,
Defoamer, chelating agent and water are compounded, and using more organic acid and organic surface active agent, decrease the use of industrial three acid
Amount, is carried out to aluminum component using middle strong acid and organic acid, has good degreasing and rust cleaning ability；Gained abluent is in acid
Property, pH value is 2.1～5.6, can remove the oxide skin of aluminium workpiece surface well；The organic acid acidity being adopted is weaker, is ensureing
On the basis of cleaning performance, effectively avoid the impact that workers ' health is produced safely of volatilizing of workpiece excessive erosion and acid,
One line operator's personal safety health is protected, it is preferably minimized to the adverse effect of environment simultaneously；Due to adopting
Organic acid is degradable, and this abluent is environmentally friendly abluent, and environmental conservation is played a positive role.
Mineral acid, organic acid are first mixed to obtain mixture A by the preparation method of the environment-friendly type aluminum material cleaning agent of the present invention, will
Surfactant, penetrating agent, emulsifying agent, defoamer mix to obtain mixture B, then by mixture B add mixture B in, finally plus
Enter chelating agent and water, the method makes each component fully dissolve and mixes, avoid the concentration ladder leading to because of mixing to greatest extent
Degree and precipitation, gained abluent is in acidity, and pH value is 2.1～5.6, can remove the oxide skin of aluminium workpiece surface well, have good
Good degreasing and rust cleaning ability；On the basis of ensureing cleaning performance, effectively avoid waving of workpiece excessive erosion and acid
Send out the impact that workers ' health is produced safely so that line operator's personal safety health is protected, simultaneously by it to ring
The adverse effect in border is preferably minimized；The method process is simple, easy to operate, low cost, it is easy to automatically control, is suitable for extensive work
Industry metaplasia is produced.
Specific embodiment
With reference to specific embodiment, the present invention is further illustrated.
Embodiment 1
The environment-friendly type aluminum material cleaning agent of the present embodiment, is grouped into by the group of following mass percent：
The preparation method of the environment-friendly type aluminum material cleaning agent of the present embodiment, comprises the following steps：
1) take phosphoric acid to mix with Fluohydric acid., after being diluted uniformly with distilled water, add phytic acid and lactic acid, stir,
Obtain mixture A；
2) NPE of formula ratio, lauryl imidazolinium betaine amphoteric surfactant, propylene glycol are taken
Butyl ether, alkylphenol polyoxyethylene OP-10, butyl ether mix homogeneously, obtain mixture B；
3) mixture B is added in mixture A, be stirring evenly and then adding into trisodium citrate, the EDTA-2Na of formula ratio, and
Add the remaining distilled water of formula ratio, after mix homogeneously, obtain final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 3min at normal temperatures., after distilled water flushing, gained aluminium workpiece surface study of water film distribution is equal for aluminum component after cleaning
Even, no greasy residues, and aluminium workpiece surface color is aluminium true qualities.
Embodiment 2
The environment-friendly type aluminum material cleaning agent of the present embodiment, is grouped into by the group of following mass percent：
The preparation method of the environment-friendly type aluminum material cleaning agent of the present embodiment, comprises the following steps：
1) take phosphoric acid and mixed in hydrochloric acid, after being diluted uniformly with distilled water, add succinic acid, stir, obtain mixing
Thing A；
2) OPEO of formula ratio, butyl glycol ether, propandiol butyl ether, alkylphenol polyoxyethylene are taken
OP-10, butyl ether mix homogeneously, obtain mixture B；
3) mixture B is added in mixture A, be stirring evenly and then adding into the sodium potassium tartrate tetrahydrate of formula ratio, and add formula
Measure remaining distilled water, after mix homogeneously, obtain final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 4min at normal temperatures., after distilled water flushing, gained aluminium workpiece surface study of water film distribution is equal for aluminum component after cleaning
Even, no greasy residues, and aluminium workpiece surface color is aluminium true qualities.
Embodiment 3
The environment-friendly type aluminum material cleaning agent of the present embodiment, is grouped into by the group of following mass percent：
The preparation method of the environment-friendly type aluminum material cleaning agent of the present embodiment, comprises the following steps：
1) take phosphoric acid to mix with sulphuric acid, after being diluted uniformly with distilled water, add glacial acetic acid, stir, obtain mixing
Thing A；
2) the lauryl imidazolinium betaine amphoteric surfactant of formula ratio, fatty alcohol-polyoxyethylene ether AEO-9, alkane are taken
Base phenol polyethenoxy ether OP-10, butyl ether mix homogeneously, obtain mixture B；
3) mixture B is added in mixture A, be stirring evenly and then adding into the EDTA-2Na of formula ratio, and add formula ratio
Remaining distilled water, after mix homogeneously, obtains final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 5min at normal temperatures., after distilled water flushing, gained aluminium workpiece surface study of water film distribution is equal for aluminum component after cleaning
Even, no greasy residues, and aluminium workpiece surface color is aluminium true qualities.
Embodiment 4
The environment-friendly type aluminum material cleaning agent of the present embodiment, is grouped into by the group of following mass percent：
The preparation method of the environment-friendly type aluminum material cleaning agent of the present embodiment, comprises the following steps：
1) take phosphoric acid and sulphuric acid, mixed in hydrochloric acid, after being diluted uniformly with distilled water, add lactic acid, succinic acid, ice second
Acid, stirs, and obtains mixture A；
2) the fatty alcohol-polyoxyethylene ether sulfosuccinate disodium salt of formula ratio, butyl glycol ether, alkyl phenol polyoxy are taken
Vinyl Ether OP-10, butyl ether mix homogeneously, obtain mixture B；
3) mixture B is added in mixture A, be stirring evenly and then adding into the trisodium citrate of formula ratio, and add formula
Measure remaining distilled water, after mix homogeneously, obtain final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 3min at normal temperatures., after distilled water flushing, gained aluminium workpiece surface study of water film distribution is equal for aluminum component after cleaning
Even, no greasy residues, and aluminium workpiece surface color is aluminium true qualities.
Embodiment 5
The environment-friendly type aluminum material cleaning agent of the present embodiment, is grouped into by the group of following mass percent：
The preparation method of the environment-friendly type aluminum material cleaning agent of the present embodiment, comprises the following steps：
1) take phosphoric acid to mix with sulphuric acid, Fluohydric acid., after being diluted uniformly with distilled water, add lactic acid, stir, obtain
Mixture A；
2) NPE of formula ratio, OPEO, lauryl imidazolinium betaine both sexes are taken
Surfactant, butyl glycol ether, alkylphenol polyoxyethylene OP-10, butyl ether mix homogeneously, obtain mixture B；
3) mixture B is added in mixture A, be stirring evenly and then adding into the trisodium citrate of formula ratio, sodium potassium tartrate tetrahydrate,
EDTA-2Na, and add the remaining distilled water of formula ratio, after mix homogeneously, obtain final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 4min at normal temperatures., after distilled water flushing, gained aluminium workpiece surface study of water film distribution is equal for aluminum component after cleaning
Even, no greasy residues, and aluminium workpiece surface color is aluminium true qualities.
Embodiment 6
The environment-friendly type aluminum material cleaning agent of the present embodiment, is grouped into by the group of following mass percent：
The preparation method of the environment-friendly type aluminum material cleaning agent of the present embodiment, comprises the following steps：
1) take phosphoric acid to mix with hydrochloric acid, Fluohydric acid., after being diluted uniformly with distilled water, add phytic acid, lactic acid, fourth two
Acid, glacial acetic acid, stir, obtain mixture A；
2) OPEO of formula ratio, fatty alcohol-polyoxyethylene ether AEO-9, butyl glycol ether, propylene glycol are taken
Butyl ether, alkylphenol polyoxyethylene OP-10, butyl ether mix homogeneously, obtain mixture B；
3) mixture B is added in mixture A, be stirring evenly and then adding into the sodium potassium tartrate tetrahydrate of formula ratio, and add formula
Measure remaining distilled water, after mix homogeneously, obtain final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 5min at normal temperatures., after distilled water flushing, gained aluminium workpiece surface study of water film distribution is equal for aluminum component after cleaning
Even, no greasy residues, and aluminium workpiece surface color is aluminium true qualities.
Embodiment 7
The environment-friendly type aluminum material cleaning agent of the present embodiment, is grouped into by the group of following mass percent：
The preparation method of the environment-friendly type aluminum material cleaning agent of the present embodiment, comprises the following steps：
1) take phosphoric acid to mix with Fluohydric acid., after being diluted uniformly with distilled water, add phytic acid, stir, obtain mixing
Thing A；
2) NPE of formula ratio, OPEO, fatty alcohol-polyoxyethylene ether sulfo group amber are taken
Amber acid esters disodium salt, lauryl imidazolinium betaine amphoteric surfactant, butyl glycol ether, alkylphenol polyoxyethylene OP-
10th, butyl ether mix homogeneously, obtains mixture B；
3) mixture B is added in mixture A, be stirring evenly and then adding into the sodium potassium tartrate tetrahydrate of formula ratio, and add formula
Measure remaining distilled water, after mix homogeneously, obtain final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 3min at normal temperatures., after distilled water flushing, gained aluminium workpiece surface study of water film distribution is equal for aluminum component after cleaning
Even, no greasy residues, and aluminium workpiece surface color is aluminium true qualities.
Embodiment 8
The environment-friendly type aluminum material cleaning agent of the present embodiment, is grouped into by the group of following mass percent：
The preparation method of the environment-friendly type aluminum material cleaning agent of the present embodiment, comprises the following steps：
1) take phosphoric acid to mix with Fluohydric acid., sulphuric acid, after being diluted uniformly with distilled water, add phytic acid, lactic acid, stirring is all
Even, obtain mixture A；
2) NPE of formula ratio, OPEO, fatty alcohol-polyoxyethylene ether sulfo group amber are taken
Amber acid esters disodium salt, propandiol butyl ether, alkylphenol polyoxyethylene OP-10, butyl ether mix homogeneously, obtain mixture B；
3) mixture B is added in mixture A, is stirring evenly and then adding into sodium potassium tartrate tetrahydrate, the trisodium citrate of formula ratio,
And add the remaining distilled water of formula ratio, after mix homogeneously, obtain final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 3min at normal temperatures., after distilled water flushing, aluminium workpiece surface index is as shown in table 1 below for aluminum component after cleaning.
Table 1 adopts aluminium workpiece surface testing result after the cleaning of embodiment 8 gained abluent
Embodiment 9
The environment-friendly type aluminum material cleaning agent of the present embodiment, is grouped into by the group of following mass percent：
The preparation method of the environment-friendly type aluminum material cleaning agent of the present embodiment, comprises the following steps：
1) take phosphoric acid and Fluohydric acid., sulphuric acid, mixed in hydrochloric acid, after dilute uniformly with distilled water, addition phytic acid, lactic acid,
Succinic acid, stirs, and obtains mixture A；
2) NPE of formula ratio, OPEO, fatty alcohol-polyoxyethylene ether sulfo group amber are taken
Amber acid esters disodium salt, lauryl imidazolinium betaine amphoteric surfactant, butyl glycol ether, propandiol butyl ether, alkyl phenol gather
Oxygen vinyl Ether OP-10, butyl ether mix homogeneously, obtain mixture B；
3) mixture B is added in mixture A, be stirring evenly and then adding into the sodium potassium tartrate tetrahydrate of formula ratio, trisodium citrate,
Disodium EDTA (EDTA-2Na), and add the remaining distilled water of formula ratio, after mix homogeneously, obtain final product.
The using method of the environment-friendly type aluminum material cleaning agent of the present embodiment, is that aluminum component to be cleaned is impregnated into gained abluent
In, and soak 5min at normal temperatures., after distilled water flushing, aluminium workpiece surface index is as shown in table 2 below for aluminum component after cleaning.
Table 2 adopts aluminium workpiece surface testing result after the cleaning of embodiment 9 gained abluent
| Test event | Performance |
| Aluminium workpiece surface | Glossy, in matrix true qualities, surface moisture film is continuously uninterrupted, no greasy residues |
| Cleaning speed | Aluminum component can get clean surface using giant once flushing after soaking |
Claims (3)
1. a kind of environment-friendly type aluminum material cleaning agent it is characterised in that：It is grouped into by the group of following mass percent：Mineral acid 20%～
25%th, organic acid 10%～20%, surfactant 10%～18%, penetrating agent 8%～15%, emulsifying agent 6%～18%, defoamer 2～
8%th, chelating agent 5%～8%, water 25%～30%；Wherein, described organic acid be lactic acid, succinic acid, phytic acid, any one in glacial acetic acid
Plant or multiple；Described surfactant is NPE, OPEO, succinate sodium salt, Laurel
Any one or more in base imidazolinium betaine amphoteric surfactant；Described chelating agent is trisodium citrate, tartaric acid
Any one or more in potassium sodium, disodiumedetate；Described mineral acid is phosphoric acid, hydrochloric acid, sulphuric acid, in Fluohydric acid.
Any one or more；Described penetrating agent is fatty alcohol-polyoxyethylene ether, butyl glycol ether, any one in propandiol butyl ether
Or it is multiple；Described emulsifying agent is alkylphenol polyoxyethylene；Described defoamer is butyl ether.
2. environment-friendly type aluminum material cleaning agent according to claim 1 it is characterised in that：Described mineral acid is hydrochloric acid, sulphuric acid, hydrogen
Any one in fluoric acid or two kinds of mixture with phosphoric acid.
3. a kind of preparation method of the environment-friendly type aluminum material cleaning agent as described in claim 1 it is characterised in that：Including following step
Suddenly：
1）Take mineral acid, after dilute with water, add organic acid, stir, obtain mixture A；
2）Take surfactant, penetrating agent, emulsifying agent, defoamer mix homogeneously, obtain mixture B；
3）Mixture B is added in mixture A, stirs, add chelating agent, and add the remaining water of formula ratio, mixing
After uniformly, obtain final product.
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Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040242449A1 (en) * | 2003-06-02 | 2004-12-02 | Joshi Nayan H. | Nitric acid and chromic acid-free compositions and process for cleaning aluminum and aluminum alloy surfaces |
| CN102296301B (en) * | 2011-08-31 | 2013-02-13 | 蚌埠市钰诚五金工贸有限公司 | Environment-friendly comprehensive pretreatment agent |
| CN102296302A (en) * | 2011-08-31 | 2011-12-28 | 蚌埠市钰诚五金工贸有限公司 | High-efficiency environment-friendly pretreatment agent |
| CN103668245A (en) * | 2013-12-27 | 2014-03-26 | 马振铨 | Efficient and environment-friendly oil-removing, rust-removing and descaling agent and preparation method thereof |
| CN103849882B (en) * | 2014-03-13 | 2016-03-09 | 江苏省轻工业科学研究设计院有限公司 | A kind of electric bicycle controller aluminum hull treatment agent and preparation method thereof |
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