CN105862047A - Metal surface treating agent and preparation method thereof - Google Patents
Metal surface treating agent and preparation method thereof Download PDFInfo
- Publication number
- CN105862047A CN105862047A CN201610373030.6A CN201610373030A CN105862047A CN 105862047 A CN105862047 A CN 105862047A CN 201610373030 A CN201610373030 A CN 201610373030A CN 105862047 A CN105862047 A CN 105862047A
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- CN
- China
- Prior art keywords
- parts
- water
- metal conditioner
- acid
- mixture
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/46—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates
Abstract
The invention particularly relates to a metal surface treating agent and a preparation method thereof, belonging to the technical field of metal working. The metal surface treating agent comprises the following raw materials in parts by mass: 25-45 parts of phytic acid, 12-20 parts of water-based acrylic resin, 2-5 parts of titanium potassium oxalate, 3-8 parts of oxalic acid, 1-4 parts of sodium tartrate, 1-3 parts of JFC-2, 1-2.5 parts of nonylphenol polyethenoxy ether and 20-30 parts of water. The metal surface treating agent has favorable derusting and degreasing effects, and can form a protective film on the metal surface to protect the metal layer for a longer time.
Description
Technical field
The invention belongs to metal working technical area, be specifically related to a kind of metal conditioner and preparation side thereof
Method.
Background technology
Shape or equipment are due to the contact with moisture in long-term and air and air, the most oxidized shape in surface
Become rust stain, additionally process of metal working can be infected with the most unavoidably in greasy dirt, and plant maintenance repair procedures also
Can contact coal Water Oil Or Gas etc., these all can cause the burn into of shape and equipment aging, reduces and uses
In the life-span, therefore, shape or equipment are carried out.
Traditional cleaning way is mainly strong acid and cleans, but strong acid is to shape and the corrosivity of equipment itself
The most serious, and the cleaning performance of alkaline matter and surfactant is the best, holds time short, adds into
This.As the Chinese patent of Application No. 201410288453.9 discloses a kind of metal cleaner, although its tool
Having certain cleaning action, but after using, be the most again infected with greasy dirt, the cleaning frequency is shorter.
Therefore, it is desirable to provide a kind of cleaning performance is good, at the metal surface more thoroughly that degreases
Reason agent, and metal surface is also had certain protective action, maintain the clean conditions time long.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art to provide a kind of metal conditioner and preparation thereof
Method, this metal conditioner degreases effective, and forms protecting film in metal surface, more holds
Long guard metal layer.
The technical solution used in the present invention is as follows:
A kind of metal conditioner, the following raw material including according to mass fraction meter: phytic acid 25-45 part,
Water-borne acrylic resin 12-20 part, titanium potassium oxalate 2-5 part, oxalic acid 3-8 part, sodium tartrate 1-4 part,
JFC-2 1-3 part, NPE 1-2.5 part, water 20-30 part.
Above-described a kind of metal conditioner, the following raw material including according to mass fraction meter: phytic acid
35 parts, water-borne acrylic resin 16 parts, titanium potassium oxalate 4 parts, oxalic acid 5 parts, sodium tartrate 3 parts, JFC-2
2 parts, NPE 1.5 parts, 26 parts of water.
Above-described a kind of metal conditioner, the mass concentration of wherein said phytic acid is 0.5%-2%.
The preparation method of above-described a kind of metal conditioner, comprises the steps:
(1) first add water to, in reactor, be subsequently adding titanium potassium oxalate, sodium tartrate, JFC-2 and nonyl phenol
Polyoxyethylene ether, stirs 1-2h with 140-160r/min, obtains mixture A；
(2) in mixture A, add phytic acid and water-borne acrylic resin, continue stirring 1-2h, obtain mixture
B；
(3) adding oxalic acid in mixture B, regulation pH value is 3-5, stands 1h, to obtain final product after being sufficiently stirred for
Described a kind of metal conditioner.
Further, in described step (1) and (2), mixing speed is 150r/min.
Beneficial effects of the present invention: inventive formulation is reasonable, and the metal conditioner obtained degreases
Effective, and protecting film, more longlasting guard metal layer is formed in metal surface, it is better than traditional strong acid clear
Wash；Preparation method of the present invention is easy, low for equipment requirements, is suitable for large-scale production.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, but should not be construed as the limit to the present invention
System.In the present invention use raw material unless otherwise noted, all can by city available from.
Embodiment 1
A kind of metal conditioner, the following raw material including according to mass fraction meter: phytic acid 25 parts, aqueous
Acrylic resin 12 parts, titanium potassium oxalate 2 parts, oxalic acid 3 parts, sodium tartrate 1 part, JFC-2 1 part, nonyl
Base phenol polyethenoxy ether 1 part, 20 parts of water, the mass concentration of wherein said phytic acid is 0.5%.
The preparation method of above-described a kind of metal conditioner, comprises the steps:
(1) first add water to, in reactor, be subsequently adding titanium potassium oxalate, sodium tartrate, JFC-2 and nonyl phenol
Polyoxyethylene ether, stirs 1-2h with 140r/min, obtains mixture A；
(2) in mixture A, add phytic acid and water-borne acrylic resin, continue stirring 1-2h, obtain mixture
B；
(3) adding oxalic acid in mixture B, regulation pH value is 3-5, stands 1h, to obtain final product after being sufficiently stirred for
Described a kind of metal conditioner.
Embodiment 2
A kind of metal conditioner, the following raw material including according to mass fraction meter: phytic acid 30 parts, aqueous
Acrylic resin 15 parts, titanium potassium oxalate 3 parts, oxalic acid 4 parts, sodium tartrate 2 parts, JFC-2 1 part, nonyl
Base phenol polyethenoxy ether 1 part, 23 parts of water, the mass concentration of wherein said phytic acid is 0.5%.
The preparation method of above-described a kind of metal conditioner, comprises the steps:
(1) first add water to, in reactor, be subsequently adding titanium potassium oxalate, sodium tartrate, JFC-2 and nonyl phenol
Polyoxyethylene ether, stirs 1-2h with 145r/min, obtains mixture A；
(2) in mixture A, add phytic acid and water-borne acrylic resin, continue stirring 1-2h, obtain mixture
B；
(3) adding oxalic acid in mixture B, regulation pH value is 3-5, stands 1h, to obtain final product after being sufficiently stirred for
Described a kind of metal conditioner.
Embodiment 3
A kind of metal conditioner, the following raw material including according to mass fraction meter: phytic acid 35 parts, aqueous
Acrylic resin 16 parts, titanium potassium oxalate 4 parts, oxalic acid 5 parts, sodium tartrate 3 parts, JFC-2 2 parts, nonyl
Base phenol polyethenoxy ether 1.5 parts, 26 parts of water, the mass concentration of wherein said phytic acid is 1%.
The preparation method of above-described a kind of metal conditioner, comprises the steps:
(1) first add water to, in reactor, be subsequently adding titanium potassium oxalate, sodium tartrate, JFC-2 and nonyl phenol
Polyoxyethylene ether, stirs 1-2h with 150r/min, obtains mixture A；
(2) in mixture A, add phytic acid and water-borne acrylic resin, continue stirring 1-2h, obtain mixture
B；
(3) adding oxalic acid in mixture B, regulation pH value is 3-5, stands 1h, to obtain final product after being sufficiently stirred for
Described a kind of metal conditioner.
Embodiment 4
A kind of metal conditioner, the following raw material including according to mass fraction meter: phytic acid 40 parts, aqueous
Acrylic resin 18 parts, titanium potassium oxalate 5 parts, oxalic acid 6 parts, sodium tartrate 3 parts, JFC-2 3 parts, nonyl
Base phenol polyethenoxy ether 2 parts, 28 parts of water, the mass concentration of wherein said phytic acid is 1.5%.
The preparation method of above-described a kind of metal conditioner, comprises the steps:
(1) first add water to, in reactor, be subsequently adding titanium potassium oxalate, sodium tartrate, JFC-2 and nonyl phenol
Polyoxyethylene ether, stirs 1-2h with 155r/min, obtains mixture A；
(2) in mixture A, add phytic acid and water-borne acrylic resin, continue stirring 1-2h, obtain mixture
B；
(3) adding oxalic acid in mixture B, regulation pH value is 3-5, stands 1h, to obtain final product after being sufficiently stirred for
Described a kind of metal conditioner.
Embodiment 5
A kind of metal conditioner, the following raw material including according to mass fraction meter: phytic acid 45 parts, aqueous
Acrylic resin 20 parts, titanium potassium oxalate 5 parts, oxalic acid 8 parts, sodium tartrate 4 parts, JFC-2 3 parts, nonyl
Base phenol polyethenoxy ether 2.5 parts, 30 parts of water, the mass concentration of wherein said phytic acid is 2%.
The preparation method of above-described a kind of metal conditioner, comprises the steps:
(1) first add water to, in reactor, be subsequently adding titanium potassium oxalate, sodium tartrate, JFC-2 and nonyl phenol
Polyoxyethylene ether, stirs 1-2h with 160r/min, obtains mixture A；
(2) in mixture A, add phytic acid and water-borne acrylic resin, continue stirring 1-2h, obtain mixture
B；
(3) adding oxalic acid in mixture B, regulation pH value is 3-5, stands 1h, to obtain final product after being sufficiently stirred for
Described a kind of metal conditioner.
Performance test
The embodiment of the present invention 1～5 products obtained therefrom is carried out performance test, and wherein reference examples is Application No.
201410288453.9 Chinese patent disclosed in a kind of metal cleaner, result such as following table:
Table 1 properties of product test data
| Performance test | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Reference examples |
| Slow release rate | >=93% | >=94% | >=95% | >=95% | >=92% | >=90% |
| Cleaning speed | ＜ 1min | ＜ 1min | ＜ 1min | ＜ 1min | ＜ 1min | ＜ 40s |
| The oil-stain-preventing time | 29d | 30d | 30d | 29d | 28d | 25d |
| Antirust time | 24d | 24d | 25d | 25d | 23d | 20d |
As seen from the above table, products obtained therefrom of the present invention degreases effective, and forms protection in metal surface
Film, more longlasting guard metal layer, wherein embodiment 3 best results.
Claims (5)
1. a metal conditioner, it is characterised in that include the following raw material according to mass fraction meter:
Phytic acid 25-45 part, water-borne acrylic resin 12-20 part, titanium potassium oxalate 2-5 part, oxalic acid 3-8 part, wine
Stone acid sodium 1-4 part, JFC-2 1-3 part, NPE 1-2.5 part, water 20-30 part.
A kind of metal conditioner the most according to claim 1, it is characterised in that include according to matter
The following raw material of amount number meter: phytic acid 35 parts, water-borne acrylic resin 16 parts, titanium potassium oxalate 4 parts, grass
Acid 5 parts, sodium tartrate 3 parts, JFC-2 2 parts, NPE 1.5 parts, 26 parts of water.
A kind of metal conditioner the most according to claim 1 and 2, it is characterised in that described in plant
The mass concentration of acid is 0.5%-2%.
4. the preparation method of a kind of metal conditioner described in claim 1 or 2, it is characterised in that
Comprise the steps:
(1) first add water to, in reactor, be subsequently adding titanium potassium oxalate, sodium tartrate, JFC-2 and nonyl phenol
Polyoxyethylene ether, stirs 1-2h with 140-160r/min, obtains mixture A；
(2) in mixture A, add phytic acid and water-borne acrylic resin, continue stirring 1-2h, obtain mixture
B；
(3) adding oxalic acid in mixture B, regulation pH value is 3-5, stands 1h, to obtain final product after being sufficiently stirred for
Described a kind of metal conditioner.
The preparation method of a kind of metal conditioner the most according to claim 4, it is characterised in that
In described step (1) and (2), mixing speed is 150r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610373030.6A CN105862047A (en) | 2016-05-31 | 2016-05-31 | Metal surface treating agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610373030.6A CN105862047A (en) | 2016-05-31 | 2016-05-31 | Metal surface treating agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105862047A true CN105862047A (en) | 2016-08-17 |
Family
ID=56642759
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610373030.6A Pending CN105862047A (en) | 2016-05-31 | 2016-05-31 | Metal surface treating agent and preparation method thereof |
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| Country | Link |
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| CN (1) | CN105862047A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107177841A (en) * | 2017-07-12 | 2017-09-19 | 合肥轻风飏电气科技有限责任公司 | A kind of surface treatment method of farm machinery metallic stamping pieces |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006028233A1 (en) * | 2004-09-06 | 2006-03-16 | Furukawa Techno Material Co., Ltd. | Surfactant composition |
| CN103805977A (en) * | 2012-11-08 | 2014-05-21 | 上海丰野表面处理剂有限公司 | Chromium-free passivation liquid for treating tin-plated steel plate |
| CN104313608A (en) * | 2014-08-29 | 2015-01-28 | 平高集团有限公司 | Environment-friendly aluminum cleaning agent and preparation method thereof |
| CN105101948A (en) * | 2013-04-18 | 2015-11-25 | 宝洁公司 | Method for extracting biomarker for diagnosing pancreatic cancer, computing device therefor, biomarker for diagnosing pancreatic cancer and device for diagnosing pancreatic cancer including the same |
-
2016
- 2016-05-31 CN CN201610373030.6A patent/CN105862047A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006028233A1 (en) * | 2004-09-06 | 2006-03-16 | Furukawa Techno Material Co., Ltd. | Surfactant composition |
| CN103805977A (en) * | 2012-11-08 | 2014-05-21 | 上海丰野表面处理剂有限公司 | Chromium-free passivation liquid for treating tin-plated steel plate |
| CN105101948A (en) * | 2013-04-18 | 2015-11-25 | 宝洁公司 | Method for extracting biomarker for diagnosing pancreatic cancer, computing device therefor, biomarker for diagnosing pancreatic cancer and device for diagnosing pancreatic cancer including the same |
| CN104313608A (en) * | 2014-08-29 | 2015-01-28 | 平高集团有限公司 | Environment-friendly aluminum cleaning agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107177841A (en) * | 2017-07-12 | 2017-09-19 | 合肥轻风飏电气科技有限责任公司 | A kind of surface treatment method of farm machinery metallic stamping pieces |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160817 |
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| RJ01 | Rejection of invention patent application after publication |