CN106555204A - Metal cleaner and preparation method thereof - Google Patents
Metal cleaner and preparation method thereof Download PDFInfo
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- CN106555204A CN106555204A CN201510642139.0A CN201510642139A CN106555204A CN 106555204 A CN106555204 A CN 106555204A CN 201510642139 A CN201510642139 A CN 201510642139A CN 106555204 A CN106555204 A CN 106555204A
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- anion surfactant
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- defoamer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/032—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds
- C23G5/036—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing oxygen-containing compounds having also nitrogen
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
The present invention discloses a kind of metal cleaner, and which is made up of the raw material of following weight proportion：Sodium Polyacrylate 10-15 parts、Trifluoroethanol 4-6 parts、NPE 4-6 parts、Sodium citrate 4-6 parts、Tetra- sodium 2-4 parts of EDTA、Shitosan 2-4 parts、Dodecyl sodium sulfate 2-4 parts、Acetic acid 3-5 parts、Ethylene glycol 3-5 parts、Triethanolamine 3-5 parts、Di-o-tolyl-thiourea 3-5 parts、Sodium gluconate 3-5 parts、Carboxymethylcellulose calcium 3-5 parts、Enuatrol 3-5 parts、Sodium pyrophosphate 3-5 parts、Silica 3-5 parts、Nonionic surfactant 3-5 parts、Anion surfactant 2-4 parts、Defoamer 2-4 parts、Tertiary sodium phosphate 2-4 parts、Stabilizer 2-4 parts，Wherein described anion surfactant is selected from OPEO、High-carbon fatty alcohol polyoxyethylene ether、Polyoxyethylene carboxylate、One or more of sorbitan ester.The inorganic agent cleaning performance of the present invention is good.
Description
Technical field
The present invention relates to a kind of inorganic agent, relates more specifically to a kind of metal cleaner and preparation method thereof.
Background technology
Metal be it is a kind of with gloss, be rich in ductility, the material of the easy property such as conduction, heat conduction.It is in nature, big absolutely
Most metals are present with compound state, and a few metals such as gold, platinum, silver, bismuth are present with free state.Metalliferous mineral majority is oxidation
Thing and sulfide.Other existence forms have chloride, sulfate, carbonate and silicate.Metal is in processing, process and uses
During often there is different degrees of oxidation, corrosion etc., reduce the service life of metal material or hardware, therefore,
Need to process metal surface, increase its anti-oxidant, erosion-resisting ability, increase the service life.It is general using gold at present
Category cleaning agent is cleaned to metal surface, but metal cleaner in the market, mostly cleaning performance are bad, therefore, open
To send out a kind of new with low to environmental hazard, and with low cost, cleaning performance is excellent, to the less metal cleaner of metal attack,
Have become the problem of those skilled in the art's solution too impatient to wait.
The content of the invention
For the defect of prior art, the invention provides a kind of metal cleaner and preparation method thereof.
A kind of metal cleaner, which is made up of the raw material of following weight proportion：Sodium Polyacrylate 10-15 parts, trifluoroethanol 4-6
Part, NPE 4-6 parts, sodium citrate 4-6 parts, tetra- sodium 2-4 parts of EDTA, shitosan 2-4 parts, dodecane
Base sodium sulfonate 2-4 parts, acetic acid 3-5 parts, ethylene glycol 3-5 parts, triethanolamine 3-5 parts, di-o-tolyl-thiourea 3-5 parts, Portugal
Grape sodium saccharate 3-5 parts, carboxymethylcellulose calcium 3-5 parts, enuatrol 3-5 parts, sodium pyrophosphate 3-5 parts, silica 3-5 parts,
It is nonionic surfactant 3-5 parts, anion surfactant 2-4 parts, defoamer 2-4 parts, tertiary sodium phosphate 2-4 parts, steady
Determine agent 2-4 parts, wherein the anion surfactant selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether,
One or more of polyoxyethylene carboxylate, sorbitan ester.
A kind of preparation method of metal cleaner, comprises the steps：
S100：Anion surfactant processed, by OPEO, high-carbon fatty alcohol polyoxyethylene ether, fatty acid polyglycol
One or more of oxygen vinyl acetate, sorbitan ester, adds 30% deionized water to be sufficiently mixed and stirs 10-15min, then after
30 DEG C -32 DEG C are heated to, 10-15min is sufficiently stirred for；
S200：Sodium Polyacrylate, trifluoroethanol, NPE, sodium citrate, the mixing of tetra- sodium of EDTA are taken, anti-
Answer in kettle with 1000 revs/min of speed dispersed with stirring, add shitosan；
S300：Take dodecyl sodium sulfate, acetic acid, ethylene glycol, triethanolamine, di-o-tolyl-thiourea, sodium gluconate, carboxylic
Methylcellulose, enuatrol, sodium pyrophosphate, silica, add 70% part of deionized water of mixture, stir, stirring
Mix down and be heated to 45 DEG C, be incubated 40min；
S400：Solution obtained in step S100-S400 is mixed, add nonionic surfactant, defoamer, tertiary sodium phosphate,
And stabilizer, 25min is stirred, is added acid-base modifier that pH value is adjusted to 6-7, is stirred.
The invention has the beneficial effects as follows：The rust remover in raw material in the present invention can effectively remove the dirt of metal surface, detergency
By force, cleaning performance is good, various oils easily can be eluted out from various absorbent bodies, not phosphorous, without organic molten
Agent, prevents oxidation, the corrosion of metal, keeps metal surface light, and the raffinate after cleaning will not be to ecological environment；
Using NPE can increase the compatibility of each material, each material is dispersed in water well, the oil in raw material
Sour sodium, sodium pyrophosphate can effectively remove spot, metal parts corrosion-free, noresidue Jing after present invention cleaning；Environmental protection of the invention, safety
Good, the nontoxic non-corrosiveness of property, free from environmental pollution, safety and stability.
Specific embodiment
Embodiment 1
A kind of metal cleaner, which is made up of the raw material of following weight proportion：20 parts of Sodium Polyacrylate, 2 parts of trifluoroethanol,
2 parts of NPE, 2 parts of sodium citrate, 6 parts of tetra- sodium of EDTA, 6 parts of shitosan, 6 parts of dodecyl sodium sulfate,
3 parts of acetic acid, 3 parts of ethylene glycol, 3 parts of triethanolamine, 3 parts of di-o-tolyl-thiourea, 3 parts of sodium gluconate, carboxymethyl cellulose
5 parts of element, 5 parts of enuatrol, 5 parts of sodium pyrophosphate, 5 parts of silica, 5 parts of nonionic surfactant, anionic surface
4 parts of activating agent, 4 parts of defoamer, 4 parts of tertiary sodium phosphate, 4 parts of stabilizer.Wherein nonionic surfactant elects aliphatic acid as
Alkanolamide；The anion surfactant is selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether, aliphatic acid
One or more of polyoxyethylene ester, sorbitan ester；The defoamer is selected from NPE or polyvinylether；
The stabilizer is sub- selected from phosphorous acid hexichol one last of the ten Heavenly stems ester, one benzene didecyl of phosphorous acid, butyl epoxy stearate, monooctyl ester ethylenediamine tetraacetic
One or more of methylphosphonic acid sodium.
Embodiment 2
A kind of metal cleaner, which is made up of the raw material of following weight proportion：15 parts of Sodium Polyacrylate, 6 parts of trifluoroethanol,
6 parts of NPE, 6 parts of sodium citrate, 2 parts of tetra- sodium of EDTA, 2 parts of shitosan, 2 parts of dodecyl sodium sulfate,
5 parts of acetic acid, 5 parts of ethylene glycol, 5 parts of triethanolamine, 5 parts of di-o-tolyl-thiourea, 5 parts of sodium gluconate, carboxymethyl cellulose
3 parts of element, 3 parts of enuatrol, 3 parts of sodium pyrophosphate, 3 parts of silica, 3 parts of nonionic surfactant, anionic surface
6 parts of activating agent, 6 parts of defoamer, 5 parts of tertiary sodium phosphate, 4 parts of stabilizer.Wherein nonionic surfactant elects aliphatic acid as
Alkanolamide；The anion surfactant is selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether, aliphatic acid
One or more of polyoxyethylene ester, sorbitan ester；The defoamer is selected from NPE or polyvinylether；
The stabilizer is sub- selected from phosphorous acid hexichol one last of the ten Heavenly stems ester, one benzene didecyl of phosphorous acid, butyl epoxy stearate, monooctyl ester ethylenediamine tetraacetic
One or more of methylphosphonic acid sodium.
Embodiment 3
A kind of metal cleaner, which is made up of the raw material of following weight proportion：25 parts of Sodium Polyacrylate, 4 parts of trifluoroethanol,
4 parts of NPE, 4 parts of sodium citrate, 4 parts of tetra- sodium of EDTA, 4 parts of shitosan, 4 parts of dodecyl sodium sulfate,
4 parts of acetic acid, 4 parts of ethylene glycol, 4 parts of triethanolamine, 4 parts of di-o-tolyl-thiourea, 4 parts of sodium gluconate, carboxymethyl cellulose
4 parts of element, 4 parts of enuatrol, 4 parts of sodium pyrophosphate, 4 parts of silica, 4 parts of nonionic surfactant, anionic surface
3 parts of activating agent, 3 parts of defoamer, 3 parts of tertiary sodium phosphate, 2 parts of stabilizer.Wherein nonionic surfactant elects aliphatic acid as
Alkanolamide；The anion surfactant is selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether, aliphatic acid
One or more of polyoxyethylene ester, sorbitan ester；The defoamer is selected from NPE or polyvinylether；
The stabilizer is sub- selected from phosphorous acid hexichol one last of the ten Heavenly stems ester, one benzene didecyl of phosphorous acid, butyl epoxy stearate, monooctyl ester ethylenediamine tetraacetic
One or more of methylphosphonic acid sodium.
Embodiment 4
A kind of metal cleaner, which is made up of the raw material of following weight proportion：10 parts of Sodium Polyacrylate, 2 parts of trifluoroethanol,
2 parts of NPE, 2 parts of sodium citrate, 8 parts of tetra- sodium of EDTA, 8 parts of shitosan, 8 parts of dodecyl sodium sulfate,
3 parts of acetic acid, 3 parts of ethylene glycol, 3 parts of triethanolamine, 3 parts of di-o-tolyl-thiourea, 3 parts of sodium gluconate, carboxymethyl cellulose
8 parts of element, 8 parts of enuatrol, 5 parts of sodium pyrophosphate, 5 parts of silica, 5 parts of nonionic surfactant, anionic surface
4 parts of activating agent, 4 parts of defoamer, 4 parts of tertiary sodium phosphate, 4 parts of stabilizer.Wherein nonionic surfactant elects aliphatic acid as
Alkanolamide：The anion surfactant is selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether, aliphatic acid
One or more of polyoxyethylene ester, sorbitan ester；The defoamer is selected from NPE or polyvinylether；
The stabilizer is sub- selected from phosphorous acid hexichol one last of the ten Heavenly stems ester, one benzene didecyl of phosphorous acid, butyl epoxy stearate, monooctyl ester ethylenediamine tetraacetic
One or more of methylphosphonic acid sodium.
Embodiment 5
A kind of metal cleaner, which is made up of the raw material of following weight proportion：30 parts of Sodium Polyacrylate, 2 parts of trifluoroethanol,
2 parts of NPE, 2 parts of sodium citrate, 4 parts of tetra- sodium of EDTA, 4 parts of shitosan, 4 parts of dodecyl sodium sulfate,
3 parts of acetic acid, 3 parts of ethylene glycol, 3 parts of triethanolamine, di-o-tolyl-thiourea 3, sodium gluconate 3, carboxymethylcellulose calcium 5,
Enuatrol 5, sodium pyrophosphate 3,3 parts of silica, 5 parts of nonionic surfactant, 4 parts of anion surfactant, disappear
4 parts of infusion, 4 parts of tertiary sodium phosphate, 4 parts of stabilizer.Wherein nonionic surfactant elects fatty acid alkanol amides as；It is described
Anion surfactant is selected from OPEO, high-carbon fatty alcohol polyoxyethylene ether, polyoxyethylene carboxylate, mistake
One or more of water sorbitol ester；The defoamer is selected from NPE or polyvinylether；The stabilizer is selected from
Phosphorous acid hexichol one last of the ten Heavenly stems ester, one benzene didecyl of phosphorous acid, butyl epoxy stearate, the one of monooctyl ester sodium ethylenediamine tetramethylenephosphonate
Plant or various.
Preparation method：
A kind of preparation method of metal cleaner, comprises the steps：
S100：Anion surfactant processed, by OPEO, high-carbon fatty alcohol polyoxyethylene ether, fatty acid polyglycol
One or more of oxygen vinyl acetate, sorbitan ester, adds 30% deionized water to be sufficiently mixed and stirs 10-15min, then after
30 DEG C -32 DEG C are heated to, 10-15min is sufficiently stirred for；
S200：Sodium Polyacrylate, trifluoroethanol, NPE, sodium citrate, the mixing of tetra- sodium of EDTA are taken, anti-
Answer in kettle with 1000 revs/min of speed dispersed with stirring, add shitosan；
S300：Take dodecyl sodium sulfate, acetic acid, ethylene glycol, triethanolamine, di-o-tolyl-thiourea, sodium gluconate, carboxylic
Methylcellulose, enuatrol, sodium pyrophosphate, silica, add 70% part of deionized water of mixture, stir, stirring
Mix down and be heated to 45 DEG C, be incubated 40min；
S400：Solution obtained in step S100-S400 is mixed, add nonionic surfactant, defoamer, tertiary sodium phosphate,
And stabilizer, 25min is stirred, is added acid-base modifier that pH value is adjusted to 6-7, is stirred.
Elaborate many details in order to fully understand the present invention in the above description.But above description is only the present invention
Preferred embodiment, the present invention can be to be much different from alternate manner described here implementing, therefore the present invention is not received
The restriction being embodied as disclosed above.Any those skilled in the art are without departing from technical solution of the present invention scope feelings simultaneously
Under condition, many possible variations and modification are made to technical solution of the present invention using the methods and techniques content of the disclosure above all,
Or it is revised as the Equivalent embodiments of equivalent variations.Every content without departing from technical solution of the present invention, according to the technology reality of the present invention
Verify any simple modification made for any of the above embodiments, equivalent variations and modification, still fall within the model of technical solution of the present invention protection
In enclosing.
Claims (2)
1. a kind of metal cleaner, it is characterised in which is made up of the raw material of following weight proportion：Sodium Polyacrylate 10-15
Part, trifluoroethanol 4-6 parts, NPE 4-6 parts, sodium citrate 4-6 parts, tetra- sodium 2-4 parts of EDTA, shell gather
Sugared 2-4 parts, dodecyl sodium sulfate 2-4 parts, acetic acid 3-5 parts, ethylene glycol 3-5 parts, triethanolamine 3-5 parts, two adjacent first
Benzene thiocarbamide 3-5 parts, sodium gluconate 3-5 parts, carboxymethylcellulose calcium 3-5 parts, enuatrol 3-5 parts, sodium pyrophosphate 3-5 parts,
Silica 3-5 parts, nonionic surfactant 3-5 parts, anion surfactant 2-4 parts, defoamer 2-4 parts, phosphorus
Sour trisodium 2-4 part, stabilizer 2-4 parts, wherein the anion surfactant is selected from OPEO, high-carbon fat
Fat alcohol APEO, polyoxyethylene carboxylate, one or more of sorbitan ester.
2. the preparation method of the metal cleaner described in a kind of claim 1, it is characterised in that comprise the steps：
S100：Anion surfactant processed, by OPEO, high-carbon fatty alcohol polyoxyethylene ether, fatty acid polyglycol
One or more of oxygen vinyl acetate, sorbitan ester, adds 30% deionized water to be sufficiently mixed and stirs 10-15min, then after
30 DEG C -32 DEG C are heated to, 10-15min is sufficiently stirred for；
S200：Sodium Polyacrylate, trifluoroethanol, NPE, sodium citrate, the mixing of tetra- sodium of EDTA are taken, anti-
Answer in kettle with 1000 revs/min of speed dispersed with stirring, add shitosan；
S300：Take dodecyl sodium sulfate, acetic acid, ethylene glycol, triethanolamine, di-o-tolyl-thiourea, sodium gluconate, carboxylic
Methylcellulose, enuatrol, sodium pyrophosphate, silica, add 70% part of deionized water of mixture, stir, stirring
Mix down and be heated to 45 DEG C, be incubated 40min；
S400：Solution obtained in step S100-S400 is mixed, add nonionic surfactant, defoamer, tertiary sodium phosphate,
And stabilizer, 25min is stirred, is added acid-base modifier that pH value is adjusted to 6-7, is stirred.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510642139.0A CN106555204A (en) | 2015-09-30 | 2015-09-30 | Metal cleaner and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510642139.0A CN106555204A (en) | 2015-09-30 | 2015-09-30 | Metal cleaner and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106555204A true CN106555204A (en) | 2017-04-05 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510642139.0A Pending CN106555204A (en) | 2015-09-30 | 2015-09-30 | Metal cleaner and preparation method thereof |
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| CN (1) | CN106555204A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107723122A (en) * | 2017-11-07 | 2018-02-23 | 邵莹 | A kind of filter filter element cleaning agent |
| CN113061897A (en) * | 2021-03-08 | 2021-07-02 | 柳州贝丽嘉涂料有限公司 | Boiling-free water-based cleaning agent with heavy dirt on metal surface and preparation method thereof |
| CN113862683A (en) * | 2021-11-01 | 2021-12-31 | 长沙永安新材料有限公司 | Cleaning agent and cleaning process for stainless steel polishing wax |
-
2015
- 2015-09-30 CN CN201510642139.0A patent/CN106555204A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107723122A (en) * | 2017-11-07 | 2018-02-23 | 邵莹 | A kind of filter filter element cleaning agent |
| CN113061897A (en) * | 2021-03-08 | 2021-07-02 | 柳州贝丽嘉涂料有限公司 | Boiling-free water-based cleaning agent with heavy dirt on metal surface and preparation method thereof |
| CN113862683A (en) * | 2021-11-01 | 2021-12-31 | 长沙永安新材料有限公司 | Cleaning agent and cleaning process for stainless steel polishing wax |
| CN113862683B (en) * | 2021-11-01 | 2024-02-09 | 长沙永安新材料有限公司 | Cleaning agent and cleaning process for stainless steel polishing wax |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170405 |
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| WD01 | Invention patent application deemed withdrawn after publication |