CN106544080A - 船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油 - Google Patents

船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油 Download PDF

Info

Publication number
CN106544080A
CN106544080A CN201610927179.4A CN201610927179A CN106544080A CN 106544080 A CN106544080 A CN 106544080A CN 201610927179 A CN201610927179 A CN 201610927179A CN 106544080 A CN106544080 A CN 106544080A
Authority
CN
China
Prior art keywords
parts
marine cylinder
compound additive
cylinder oil
calcium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610927179.4A
Other languages
English (en)
Inventor
张宏萍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XINJIANG KUITUN NEW PETROCHEMICAL CO Ltd
Original Assignee
XINJIANG KUITUN NEW PETROCHEMICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XINJIANG KUITUN NEW PETROCHEMICAL CO Ltd filed Critical XINJIANG KUITUN NEW PETROCHEMICAL CO Ltd
Priority to CN201610927179.4A priority Critical patent/CN106544080A/zh
Publication of CN106544080A publication Critical patent/CN106544080A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/10—Amides of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • C10M2219/088—Neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/26—Waterproofing or water resistance
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明公开了一种船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油，其复合添加剂采用环烷酸盐为主剂，环烷酸盐与磺酸盐、硫化烷基酚盐和水杨酸盐相比，具有优异的抗水分水性、酸中和速度和扩散性，是生产船用气缸油的好原料，以环烷酸盐为主剂，同时辅以硫化烷基酚盐和磺酸盐，以发挥各添加剂的优势，产生协和效应，使复合添加剂具有良好的抗水分水性、扩散性、酸中和速度、抗磨性和清净性，复合添加剂所调制的70TBN船用气缸油在理化分析和模拟评定方面达到国外参比油的质量水平。

Description

船用气缸油复合添加剂及其生产方法及所调和成的船用气 缸油
技术领域
本发明属于石油化工领域，具体是一种船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油。
背景技术
船用气缸油按碱值可分为10TBN、40TBN、70TBN和100TBN几种型号，根据船舶所用燃料硫含量的不同而分别使用不同碱值的船用气缸油，以中和燃料燃烧后所产生的硫酸、亚硫酸等酸性产物，其中：10TBN船用气缸油主要用于燃料硫含量不大于1.5％的情况下使用；40TBN船用气缸油主要用于燃料硫含量不大于2.5％的情况下使用；70TBN船用气缸油主要用于燃料硫含量不大于3.5％的情况下使用；100TBN船用气缸油主要用于燃料硫含量不大于5.0％的情况下使用。处于环保和成本方面的考虑，国内外航运公司大多使用硫含量2.5％和3.5％的残渣重质燃料油，使用最多的是碱值为70TBN的船用气缸油。
上世纪80年代，我国10TBN、40TBN、70TBN和100TBN的船用气缸油主要依靠国外进口，船用气缸油复合剂产品在我国属空白，通过十几年的不懈努力，10TBN、40TBN和70TBN的船用气缸油产品分别在中国石油润滑油分公司、中国石化润滑油分公司研制成功并投入工业化生产，目前中国石油润滑油分公司可生产磺酸盐—硫化烷基酚盐—环烷酸盐配方体系的船用气缸油复合添加剂，商品牌号为：RHY3532、RHY3533。中国石化润滑油分公司船用气缸油复合添加剂生产是由中石化与Infinuem合资的上海海润添加剂有限公司生产，配方体系主要是：磺酸盐—水杨酸盐—硫化烷基酚盐。
国内无锡南方添加剂厂及个别地方小添加剂厂有用磺酸盐—硫化烷基酚盐添加剂配方体系生产船用气缸油复合添加剂的报道，但产、销量相对较小。
国外Lubrizol、Oronite、Afton和Infinuem等添加剂公司已有用磺酸盐或硫化烷基酚盐为主要添加剂配方体系，生产船用气缸油复合添加剂的产品，主要用于调制国外船用气缸油，但复合添加剂产品成本较高，尚未在国内市场大量推广应用。
国内外有用磺酸盐、硫化烷基酚盐为主要金属清净剂研制成功气缸油复合剂的报道和产品，但用环烷酸盐为主剂研制成功气缸油复合剂尚未见报道。
发明内容
本发明所要解决的技术问题是提供一种船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油，特别是一种用于调制70TBN船用气缸油的复合添加剂及其生产方法以及用该添加剂调和成的70TBN船用气缸油，该复合添加剂具有良好的抗水分水性、扩散性、酸中和速度、抗磨性和清净性，复合添加剂所调制的70TBN船用气缸油在理化分析和模拟评定方面达到国外参比油的质量水平。
本发明用于调制船用气缸油的复合添加剂为：按重量由300TBN环烷酸钙50-80份、硫化烷基酚钙5-40份、石油磺酸钙15-30份、丁二酰亚胺5-20份、二烷基二硫代磷酸锌5-15份、氨基甲酸锌1-10份、苯并三氮唑1-5份、烷基化二苯胺1-10份组成。
作为上述技术方案的进一步改进方案，所述的300TBN环烷酸钙的碱值为280-320mgKOH/g。
上述用于调制船用气缸油的复合添加剂的生产方法如下：将按比例所需要的300TBN环烷酸钙、硫化烷基酚钙、丁二酰亚胺、二烷基二硫代磷酸锌、氨基甲酸锌、苯并三氮唑依次加入不锈钢调合釜，搅拌升温，在80-90℃条件下搅拌6-8小时，待复合添加剂清澈透明即制得复合添加剂。
用上述复合添加剂调和成的70TBN船用气缸油，其特征在于：按重量百分比加入400SN基础油54-60份、KH 150BS基础油13-15份、复合添加剂25-32份均匀混合后即可得到70TBN船用气缸油。
与现有技术相比，本发明的复合添加剂采用环烷酸盐为主剂，环烷酸盐与磺酸盐、硫化烷基酚盐和水杨酸盐相比，具有优异的抗水分水性、酸中和速度和扩散性，是生产船用气缸油的好原料，以环烷酸盐为主剂，同时辅以硫化烷基酚盐和磺酸盐，以发挥各添加剂的优势，产生协和效应，使复合添加剂具有良好的抗水分水性、扩散性、酸中和速度、抗磨性和清净性，复合添加剂所调制的70TBN船用气缸油在理化分析和模拟评定方面达到国外参比油的质量水平。
具体实施方式
下面结合具体的实施例对本发明作进一步详细的说明。
实施例1：复合添加剂的重量百分配比为：300TBN环烷酸钙69.5份、硫化烷基酚钙13.9份、丁二酰亚胺10.4份、二烷基二硫代磷酸锌4.5份、氨基甲酸锌0.7份、苯并三氮唑1.0份，环烷酸钙的碱值为320mgKOH/g。
复合添加剂的生产方法：将上述比例的300TBN环烷酸钙、硫化烷基酚钙、丁二酰亚胺、二烷基二硫代磷酸锌、氨基甲酸锌、苯并三氮唑依次加入不锈钢调合釜中，搅拌升温至90℃，继续搅拌8小时，待复合添加剂清澈透明即可。
本实施例制得的船用气缸油复合添加剂主要质量指标如下：表1
表1
项目 质量指标 试验方法
外观 透明、无沉淀 目测
总碱值，mgKOH/g 不小于 250 SH/T0251
运动粘度(100℃)，mm2/s 不大于 160 GB/T265
机械杂质，％ 不大于 0.08 GB/T511
硫酸盐灰份，％ 不小于 28 GB/T2433
硫含量，％ 不小于 1.1 Q/LDJH-QC-02
钙含量，％ 不小于 8.0 SH/T0297
实施例2：复合添加剂的重量百分配比为：300TBN环烷酸钙73.2份、硫化烷基酚钙11.7份、丁二酰亚胺14.8份、二烷基二硫代磷酸锌8.1份、烷基化二苯胺3.6份，环烷酸钙的碱值为280mgKOH/g。
复合添加剂的生产方法：将上述比例的300TBN环烷酸钙、硫化烷基酚钙、丁二酰亚胺、二烷基二硫代磷酸锌、烷基化二苯胺依次加入不锈钢调合釜，搅拌升温至80℃，继续搅拌6小时，待复合添加剂清澈透明即可。
实施例3：复合添加剂的重量百分配比为：300TBN环烷酸钙63.2份、硫化烷基酚钙20.9份、丁二酰亚胺12.5份、二烷基二硫代磷酸锌7.5份、烷基化二苯胺4.3份，环烷酸钙的碱值为290mgKOH/g。
复合添加剂的生产方法：将上述比例的300TBN环烷酸钙、硫化烷基酚钙、丁二酰亚胺、二烷基二硫代磷酸锌、烷基化二苯胺依次加入不锈钢调合釜，搅拌升温至85℃，继续搅拌7小时，待复合添加剂清澈透明即可。
实施例4：复合添加剂的重量百分配比为：300TBN环烷酸钙66.3份、硫化烷基酚钙18.9份、丁二酰亚胺14.1份、二烷基二硫代磷酸锌6.7份，环烷酸钙的碱值为300mgKOH/g。
复合添加剂的生产方法：将上述比例的300TBN环烷酸钙、硫化烷基酚钙、丁二酰亚胺、二烷基二硫代磷酸锌依次加入不锈钢调合釜，搅拌升温至82℃，继续搅拌6.5小时，待复合添加剂清澈透明即可。
用实施例4配方工业化生产复合添加剂不同批次理化分析数据见表2。
表2不同批次工业化生产复合添加剂理化数据
表2中5个批次工业化生产的船用气缸油复合添加剂，全部符合添加剂质量指标要求，并且生产质量稳定
实施例5：复合添加剂的重量百分配比为：300TBN环烷酸钙52.6份、硫化烷基酚钙35.7份、丁二酰亚胺7.1份、二烷基二硫代磷酸锌5.8份，环烷酸钙的碱值为310mgKOH/g。
复合添加剂的生产方法：将上述比例的300TBN环烷酸钙、硫化烷基酚钙、丁二酰亚胺、二烷基二硫代磷酸锌依次加入不锈钢调合釜，搅拌升温至84℃，继续搅拌7.5小时，待复合添加剂清澈透明即可。
用复合添加剂调和成的70TBN船用气缸油的方法，按重量百分比加入400SN基础油60份、KH 150BS基础油15份、复合添加剂25均匀混合后即可得到70TBN船用气缸油。
以国外70TBN船用气缸油作为本发明调制的70TBN船用气缸油的参比油进行理化分析和模拟评定，本发明所用基础油理化性质见表3，调制的70TBN船用气缸油理化分析和模拟评定结果见表4。
表3基础油理化性质
表4调制的70TBN船用气缸油理化分析和模拟评定结果
理化分析数据表明，本发明复合添加剂所调制的70TBN船用气缸油与国外参比油相当。模拟评定结果表明，本发明复合添加剂所调制的70TBN船用气缸油，在酸中和速度、扩散性和抗磨损性方面优于国外参比油，在PDSC氧化和L-1A成焦板试验方面逊于国外参比油1而优于国外参比油2，用本发明复合添加剂所调制的70TBN船用气缸油，在理化分析和模拟评定方面达到了国外参比油质量水平。
以上所述的仅是本发明的优选实施方式，应当指出，对于本领域的普通技术人员来说，在不脱离本发明创造构思的前提下，还可以做出若干变化和改进，这些都属于本发明的保护范围。

Claims (5)

1.一种用于调制船用气缸油的复合添加剂，其特征在于：按重量由300TBN环烷酸钙50-80份、硫化烷基酚钙5-40份、石油磺酸钙15-30份、丁二酰亚胺5-20份、二烷基二硫代磷酸锌5-15份、氨基甲酸锌1-10份、苯并三氮唑1-5份、烷基化二苯胺1-10份组成。
2.根据权利要求1所述的用于调制船用气缸油的复合添加剂，其特征在于：所述的300TBN环烷酸钙的碱值为280-320mgKOH/g。
3.一种用于调制船用气缸油的复合添加剂的生产方法，其特征在于：按重量取300TBN环烷酸钙50-80份、硫化烷基酚钙5-40份、石油磺酸钙15-30份、丁二酰亚胺5-20份、二烷基二硫代磷酸锌5-15份、氨基甲酸锌1-10份、苯并三氮唑1-5份、烷基化二苯胺1-10份，
将上述的300TBN环烷酸钙、硫化烷基酚钙、丁二酰亚胺、二烷基二硫代磷酸锌、氨基甲酸锌、苯并三氮唑依次加入不锈钢调合釜，搅拌升温，在80-90℃条件下搅拌6-8小时，待混合物清澈透明即可。
4.根据权利要求1所述的用于调制船用气缸油的复合添加剂的生产方法，其特征在于：将所述的300TBN环烷酸钙的碱值调节为280-320mgKOH/g。
5.一种船用气缸油，其特征在于：按重量由400SN基础油54-60份、KH 150BS基础油13-15份和权利要求1-4任一项所述的用于调制船用气缸油的复合添加剂25-32份组成。
CN201610927179.4A 2016-10-31 2016-10-31 船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油 Pending CN106544080A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610927179.4A CN106544080A (zh) 2016-10-31 2016-10-31 船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610927179.4A CN106544080A (zh) 2016-10-31 2016-10-31 船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油

Publications (1)

Publication Number Publication Date
CN106544080A true CN106544080A (zh) 2017-03-29

Family

ID=58393604

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610927179.4A Pending CN106544080A (zh) 2016-10-31 2016-10-31 船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油

Country Status (1)

Country Link
CN (1) CN106544080A (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085114A (zh) * 2017-12-25 2018-05-29 洛阳名力科技开发有限公司 一种小型汽车用全合成机油
CN114644952A (zh) * 2022-03-28 2022-06-21 龙蟠润滑新材料（天津）有限公司 一种船用中速筒状活塞柴油机油组合物及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4375417A (en) * 1981-10-27 1983-03-01 Texaco Inc. Cylinder lubricating oil composition
CN1611590A (zh) * 2003-10-31 2005-05-04 中国石油化工股份有限公司 内燃机油及复合添加剂组合物
CN102676281A (zh) * 2011-03-10 2012-09-19 中国石油天然气股份有限公司 一种船用气缸润滑油组合物
CN103184092A (zh) * 2011-12-28 2013-07-03 中国石油天然气股份有限公司 一种70tbn船用气缸油的制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4375417A (en) * 1981-10-27 1983-03-01 Texaco Inc. Cylinder lubricating oil composition
CN1611590A (zh) * 2003-10-31 2005-05-04 中国石油化工股份有限公司 内燃机油及复合添加剂组合物
CN102676281A (zh) * 2011-03-10 2012-09-19 中国石油天然气股份有限公司 一种船用气缸润滑油组合物
CN103184092A (zh) * 2011-12-28 2013-07-03 中国石油天然气股份有限公司 一种70tbn船用气缸油的制备方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085114A (zh) * 2017-12-25 2018-05-29 洛阳名力科技开发有限公司 一种小型汽车用全合成机油
CN114644952A (zh) * 2022-03-28 2022-06-21 龙蟠润滑新材料（天津）有限公司 一种船用中速筒状活塞柴油机油组合物及其制备方法

Similar Documents

Publication Publication Date Title
JP2001262174A (ja) 脂肪油とモノ置換アルキレンジアミンの反応生成物からの油溶性モリブデン添加剤
CN101724499A (zh) 环保触变性防锈油及其生产方法
CN106544080A (zh) 船用气缸油复合添加剂及其生产方法及所调和成的船用气缸油
CN106032488B (zh) 润滑脂组合物及其制备方法
CN107312031A (zh) 一种二异辛基二硫代磷酸锌盐的制备方法
CN107312592A (zh) 柴油机油组合物
CN103627496B (zh) 一种复合环烷酸钙基润滑脂及其制备方法
CN106032486B (zh) 润滑脂组合物及其制备方法
CN110358612B (zh) 一种船用油复合剂、其制备方法及应用
CN102888263A (zh) 一种纳米级高碱度烷基水杨酸钙添加剂制备
CN104327906A (zh) 一种改善高温性能的复合磺酸钙基润滑脂的组合物及制备方法
CN101570712B (zh) 一种高碱值船用气缸润滑油
CN103987822A (zh) 后处理过的钼酰胺添加剂组合物和含有它的润滑油组合物的制备
CN106032483B (zh) 一种复合硫化烷基酚钙基润滑脂及其制备方法
CN106032485B (zh) 润滑脂组合物及其制备方法
CA2773647A1 (en) Preparation of a sulfurized molybdenum amide complex and additive compositions having low residual active sulfur
CN108865363A (zh) 润滑油组合物用于纯气体发动机润滑的用途
CN104449959A (zh) 一种高碱值复合钙基润滑脂及其制备方法
CN104450111B (zh) 一种复合磺酸钙‑环烷酸钙基润滑脂及其制备方法
CN104560276B (zh) 一种复合磺酸钙‑环烷酸钙锆基润滑脂及其制备方法
Wang et al. Synthesis of environmentally friendly calcium oleate detergent
CN104293449B (zh) 一种复合环烷酸钙基润滑脂及其制备方法
CN102977984B (zh) 液压支架乳化油及其制备方法
CN106032487B (zh) 润滑脂组合物及其制备方法
CN106147964A (zh) 一种高端润滑油

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170329