CN106520330A - Lubricant composition for power-spinning processing process for Hastelloy C-series alloys - Google Patents

Lubricant composition for power-spinning processing process for Hastelloy C-series alloys Download PDF

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CN106520330A
CN106520330A CN201610966090.9A CN201610966090A CN106520330A CN 106520330 A CN106520330 A CN 106520330A CN 201610966090 A CN201610966090 A CN 201610966090A CN 106520330 A CN106520330 A CN 106520330A
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kazakhstan
spinning processing
processing technique
lubricant compositions
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黄福川
唐弓斌
肖锋
张姗姗
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Guangxi University
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Guangxi University
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • C10M2207/2825Esters of (cyclo)aliphatic oolycarboxylic acids used as base material
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    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
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    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
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    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
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    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
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    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10M2229/04Siloxanes with specific structure
    • C10M2229/041Siloxanes with specific structure containing aliphatic substituents
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
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    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
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    • C10N2030/72Extended drain
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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    • C10N2040/244Metal working of specific metals

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  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a lubricant composition for a power-spinning processing process for Hastelloy C-series alloys. According to the lubricant composition, HVI90BS with a mass ratio being 50% and dioctyl sebacate with a mass ratio being 50% are compounded as composite base oil which is matched with various composite additives comprising an antioxidant, a metal deactivator, an oiliness agent, a friction improver, an extreme pressure agent, an anti-wear agent, an antirust agent, an anti-foaming agent, an oxygen and corrosion resisting agent, a filler and the like. The composition disclosed by the invention has the characteristics of having good cooling performance, lubricity, extreme-pressure wear-resistant carrying capacity, wettability, diffusivity, d cleaning property, anti-rust property, oxygen and corrosion resistance, anti-oxidation stability, anti-shearing stability, adhesion and high oil film strength, reducing surface scratches, improving processing efficiency and prolonging the service life of a mould.

Description

A kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions
Technical field
A kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions of the present invention belong to metal working lubricant Field.
Background technology
It is serial that Hastelloy (Hastelloyalloy) is broadly divided into B, C, G tri-, it be mainly used in iron-based Cr-Ni or The strong corrosive media occasion that Cr-Ni-Mo rustless steels, nonmetallic materials etc. cannot be used.Each trade mark has specific chemistry Composition, mechanical performance have his own strong points, it is impossible to which what characteristic Hastelloy of lumping together has.Hastelloy plate is applied to various Chemical industry containing oxidation and reductant.
Kazakhstan C series is mainly C-276 (00Cr16MO16W4)、C-4(00Cr16MO16)、C-22(00Cr22MO13W3)、C- 2000(00Cr20MO16) etc..By taking C-276 as an example, N:14.5~16.5, Cr:15~17, MO:4.0~7.0, Fe≤0.01, C≤ 0.08, Si≤2.5, CO≤ 1.0, Mn≤0.04, P≤0.03, S:3.0~4.5, W≤0.035.
Rotary pressure technology originates from ancient times pottery.He is that one kind combines forging, extruding, draw piece, bending, looping mill rolling, horizontal stroke Roll the few advanced technologies without machining with the process characteristic such as edging.Generally metal letter base, plate blank or prefabricated blank are used Tail top is held out against on spinning machine mould, drives plug and blank rotation by main shaft;Material is extruded by spinning wheel from blank side simultaneously On the core of rotation, material is made to produce the continuous plastic deformation of pointwise, so as to obtain the hollow rotary body of various shape of generatrix Part.According to the blank thickness situation of change during rotary pressing processing, spinning process is divided into conventional spinning and shear spinning two Plant, i.e. conventional spinning and shear spinning.
The referred to as general rotation of conventional spinning.During general rotation, the thickness of blank is held essentially constant, and shaping relies primarily on blank edge The contraction of circumference and along radial direction it is indeformable realizing with length.Which is mainly characterized by forming process, substantially can be seen Go out the change of blank external diameter.The basic mode of conventional spinning has:Draw spinning (drawing rotation), necking in spindown (contracting rotation) and expanding bulging Three kinds of (expanding rotation) etc..
Also known as flow turning, shear spinning is a kind of Near net shape grown up on the basis of conventional spinning to shear spinning Processing method, which is substantially added high pressure in blank using spinning roller, and rotary billet carries out local along shaping dies by external force Gradually spreading produce plastic deformation and it is thinning, so as to obtain high accuracy Thin-wall Revolving Part.
Tail top is adopted during spinning or blank is fixed on into mould otherwise, mould rotation, spinning roller are made feed motion, make hair Continuously pointwise is thinning and reclines mould and forms the part of required shape for base, and shear spinning relies primarily on subtracting for sotck thinkness The thin shaping to realize workpiece.
The content of the invention
It is a kind of good with good stability, lubricity, corrosion resistance that the technical problem to be solved in the present invention is to provide, The excellent Kazakhstan C series alloy shear spinning processing technique lubricant compositions of thermal oxidation stability.
The present invention solves above-mentioned technical problem by following technical solution:
A kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions, using the HVI90BS of mass ratio 50% Be complex as base oil with 50% di-n-octyl sebacate, coordinate various compound additives, its each mass percent into packet Into:
Component Mass percentage content
Base oil Surplus
Antioxidant 0.06%~0.6%
Metal deactivator 0.03%~0.3%
Oiliness improver 4%~8%
Friction improver 1%~2%
Extreme pressure agent 3%~5%
Antiwear additive 3%~5%
Antirust agent 0.05%~0.5%
Anti-foaming agent 10ppm~30ppm
Oxidation and corrosion inhibitor 0.5%~1.2%
Adhesive agent 2%~6%
Filler 2%~4%
The mass percent summation of above each component is 100%.
Antioxidant be mass ratio 50% 2,6- di-t-butyls mixed phenol with 50% it is right, to '-di-iso-octyldiphenylamine T538 is combined.Metal deactivator agent is that the thiadiazole of the thiadiazoles derivative T561 and 50% of mass ratio 50% is combined.
Oiliness improver is sulfuration cottonseed oil T404.Friction improver is sulfur molybdenum phosphate T461.
Extreme pressure agent is chlorinated paraffin T302.Antiwear additive is sulfide isobutene T321.
Antirust agent is that the petroleum sodium sulfonate of the BTA T706 and 50% of mass ratio 50% is combined;
Anti-foaming agent is methyl-silicone oil.Oxidation and corrosion inhibitor is sulfur phosphorus fourth octyl group zinc salt T202.
Adhesive agent is polyisobutylene T603D.Filler is paraffin wax fully refined 66.
A kind of remarkable advantage of Kazakhstan C series alloy shear spinning processing technique lubricant compositions of the present invention has good Cooling well, lubricity, extreme-pressure anti-wear load, wellability, diffusibility, cleaning, rust-preventing characteristic, antioxygen anti-corrosive properties, antioxygen Change stability, anti-shearing stability, adhesiveness, film strength is high, reduces galled spotss and cut, improves working (machining) efficiency, extends Die life.
Specific embodiment
Embodiment 1:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 2:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
Embodiment 3:
Following each component is pressed the mediation of row mass percent to form:
Above each component mass percentage content summation is 100%.
The typical physiochemical techniques index of 1 product of embodiment:
Project Quality index
Kinematic viscosity (40 DEG C)/mm2/s-1 226.5
Viscosity index (VI) 98
Flash-point (opening)/DEG C 277
Condensation point/DEG C -29
Coefficient of friction 0.055
Corrosivity (copper sheet, 100 DEG C, 3h)/level 1
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min 327
Resistance to emulsion (84 DEG C, 40-40-0)/min 11
Tetra-ball machine test/Pb/N 995
Sintering load/PD/N 6670
Terraced nurse agrees/N 283
FZG/ levels 13
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % 6.7
Mechanical admixture, % 0.003
Moisture, % Vestige
The typical physiochemical techniques index of 2 product of embodiment:
Project Quality index
Kinematic viscosity (40 DEG C)/mm2/s-1 229.3
Viscosity index (VI) 98
Flash-point (opening)/DEG C 276
Condensation point/DEG C -28
Coefficient of friction 0.055
Corrosivity (copper sheet, 100 DEG C, 3h)/level 1
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min 337
Resistance to emulsion (84 DEG C, 40-40-0)/min 12
Tetra-ball machine test/Pb/N 978
Sintering load/PD/N 6610
Terraced nurse agrees/N 284
FZG/ levels 13
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % 6.8
Mechanical admixture, % 0.003
Moisture, % Vestige
The typical physiochemical techniques index of 3 product of embodiment:
Project Quality index
Kinematic viscosity (40 DEG C)/mm2/s-1 228.7
Viscosity index (VI) 105
Flash-point (opening)/DEG C 266
Condensation point/DEG C -27
Coefficient of friction 0.057
Corrosivity (copper sheet, 100 DEG C, 3h)/level 1
Oxidation stability (rotary oxygen bomb, 150 DEG C)/min 333
Resistance to emulsion (84 DEG C, 40-40-0)/min 13
Tetra-ball machine test/Pb/N 970
Sintering load/PD/N 6560
Terraced nurse agrees/N 286
FZG/ levels 13
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % 7.1
Mechanical admixture, % 0.005
Moisture, % Vestige

Claims (10)

1. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions, it is characterised in that:Using mass ratio 50% The di-n-octyl sebacate of HVI90BS and 50% be complex as base oil, coordinate various compound additives, its respective mass percent Into being grouped into:
Component Mass percentage content Base oil Surplus Antioxidant 0.06%~0.6% Metal deactivator 0.03%~0.3% Oiliness improver 4%~8% Friction improver 1%~2% Extreme pressure agent 3%~5% Antiwear additive 3%~5% Antirust agent 0.05%~0.5% Anti-foaming agent 10ppm~30ppm Oxidation and corrosion inhibitor 0.5%~1.2% Adhesive agent 2%~6% Filler 2%~4%
The mass percent summation of above each component is 100%.
2. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions as claimed in claim 1, its feature exist In antioxidant be mass ratio 50% 2,6- di-t-butyls mixed phenol with 50% it is right, to '-di-iso-octyldiphenylamine T538 is multiple Close.
3. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions as claimed in claim 1, its feature exist In metal deactivator agent be mass ratio 50% thiadiazoles derivative T561 and 50% thiadiazole be combined.
4. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions as claimed in claim 1, its feature exist In oiliness improver be sulfuration cottonseed oil T404.
5. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions as claimed in claim 1, its feature exist In friction improver be sulfur molybdenum phosphate T461;Extreme pressure agent is chlorinated paraffin T302.
6. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions as claimed in claim 1, its feature exist In antiwear additive be sulfide isobutene T321.
7. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions as claimed in claim 1, its feature exist In antirust agent be mass ratio 50% BTA T706 and 50% petroleum sodium sulfonate be combined.
8. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions as claimed in claim 1, its feature exist In anti-foaming agent be methyl-silicone oil;Oxidation and corrosion inhibitor is sulfur phosphorus fourth octyl group zinc salt T202.
9. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions as claimed in claim 1, its feature exist In adhesive agent be polyisobutylene T603D.
10. a kind of Kazakhstan C series alloy shear spinning processing technique lubricant compositions as claimed in claim 1, its feature Be filler be paraffin wax fully refined 66.
CN201610966090.9A 2016-11-04 2016-11-04 Lubricant composition for power-spinning processing process for Hastelloy C-series alloys Withdrawn CN106520330A (en)

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