CN106520346A - Lubricant composite for permalloy power spinning processing technology - Google Patents

Lubricant composite for permalloy power spinning processing technology Download PDF

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Publication number
CN106520346A
CN106520346A CN201610966175.7A CN201610966175A CN106520346A CN 106520346 A CN106520346 A CN 106520346A CN 201610966175 A CN201610966175 A CN 201610966175A CN 106520346 A CN106520346 A CN 106520346A
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China
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agent
permalloy
spinning processing
processing technique
lubricant compositions
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黄福川
邓富康
李康春
唐弓斌
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Guangxi University
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Guangxi University
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Priority to CN201610966175.7A priority Critical patent/CN106520346A/en
Publication of CN106520346A publication Critical patent/CN106520346A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/2805—Esters used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/09—Heterocyclic compounds containing no sulfur, selenium or tellurium compounds in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention discloses a lubricant composite for a permalloy power spinning processing technology. According to the lubricant composite, an HMI120BS with the mass ratio of 50% and an ester oil Radialube7368 with the mass ratio of 50% are compounded to serve as a base oil, and a variety of composite additives are added. The composite additives comprise an antioxidant, a metal deactivator, an oiliness agent, a friction modifier, an extreme pressure agent, an antiwear agent, an oxidation and corrosion inhibitor, an anti-foaming agent, an antirust agent, a filling agent and the like. The composite is good in cooling property, lubricating property, diffusion property, antirust property, oxidation resistance and corrosion resistance and adhesive property, and reduces surface scrapes and scratches.

Description

A kind of permalloy shear spinning processing technique lubricant compositions
Technical field
A kind of permalloy shear spinning processing technique lubricant compositions of the present invention belong to metal working lubricant field.
Background technology
Permalloy refers to iron-nickel alloy, the wide range of its nickel content, between 35%-90%.The maximum of permalloy Feature is with very high low-intensity magnetic field permeability.Their saturation induction density is typically between 0.6--1.0T.Permalloy It is a kind of iron-nickel alloy for having higher pcrmeability under compared with low-intensity magnetic field, dilval of the nickel content more than 30%, in room temperature Shi Douwei single-phase face-centered cubic (γ) structure, but the phase structure near 30%Ni is very unstable, therefore the ferrum nickel of practicality Magnetically soft alloy, nickel content is all more than 36%.Iron-nickel alloy near nickeliferous 75% (atomic fraction), the meeting in this single-phase alloy Generation Ni3Fe long-range orders change, at this moment the lattice constant and physical property of alloy, and such as resistivity and magnetic etc. can all occur to become Change.Therefore, impact of the ordering transition to performance is considered.Generally in Ni3The additional elements such as a small amount of Mo or Cu are added in Fe alloys, To suppress the generation of long-range order.
Rotary pressure technology originates from ancient times pottery, is that one kind combines forging, extruding, draw piece, bending, looping mill rolling, transverse rolling With few advanced technologies without machining of the process characteristic such as edging.Generally by metal letter base, plate blank or prefabricated blank tail Hold out against on spinning machine mould, plug and blank rotation are driven by main shaft；Material is squeezed in by spinning wheel from blank side simultaneously On the core of rotation, material is made to produce the continuous plastic deformation of pointwise, so as to obtain the hollow rotary body zero of various shape of generatrix Part.According to the blank thickness situation of change during rotary pressing processing, spinning process is divided into two kinds of conventional spinning and shear spinning, That is conventional spinning and shear spinning.
Also known as flow turning, shear spinning is a kind of Near net shape grown up on the basis of conventional spinning to shear spinning Processing method, which is substantially added high pressure in blank using spinning roller, and rotary billet carries out local along shaping dies by external force Gradually spreading produce plastic deformation and it is thinning, so as to obtain high accuracy Thin-wall Revolving Part.Tail top or other is adopted during spinning Blank is fixed on mould by mode, and feed motion is made in mould rotation, spinning roller, make blank continuously pointwise it is thinning and recline mould and The part of shape required for being formed.
Shear spinning technique rely primarily on sotck thinkness it is thinning come realize shape, blank external diameter is held essentially constant. Generally when shear spinning is carried out, the pressure that spinning roller is added on blank is more much bigger than during conventional spinning, the deformation ratio of blank It is much bigger during conventional spinning, also differ widely when the deformation and conventional spinning of blank.During conventional spinning, blank is thick Degree change is little, but diameter change is very big from large to small or changes from small to big.And in strong spinning process, blank diameter is basic Keep constant, but thickness change is very thinning by thickness greatly.Therefore shear spinning is also called flow turning.From process analysis Think：Shear spinning belongs to axial extension, deformed area material be in two to or three-dimensional stress state, thus higher deformation can be produced Degree.According to the difference of the type and flow of metal mechanism of spinning part, shear spinning can be divided into Tapered Cup shear spinning and cut Cut two kinds of spinning and power spinning of tube workpiece extrusion Qiang Xuan etc..Shear spinning is used for being spun into for the bodies such as various, cone The process technology of shell body, is the method and technique of a kind of comparative maturity, is also boiling hot plate method.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of with good cooling, lubricity, diffusibility, antirust Property, antioxygen anti-corrosive properties, adhesiveness and reduce galled spotss permalloy shear spinning processing technique lubricant compositions.
The present invention solves above-mentioned technical problem by following technical solution：
A kind of permalloy shear spinning processing technique lubricant compositions, using mass ratio 50% HMI120BS and Oil based on 50% Esters oil Radialube7368 is compound, coordinate various compound additives, its respective mass percent Into being grouped into：
Component Mass percentage content
Base oil Surplus
Antioxidant 0.05%～0.2%
Metal deactivator 0.03%～0.1%
Oiliness improver 3.0%～8.0%
Friction improver 0.5%～2.0%
Extreme pressure agent 3.0%～5.0%
Antiwear additive 4.0%～6.0%
Oxidation and corrosion inhibitor 0.8%～1.2%
Anti-foaming agent 10～30ppm
Antirust agent 0.03%～0.1%
Filler 1.0%～4.0%
The mass percent summation of above each component is 100%.
Antioxidant be dinonyldiphenylamine T558 of mass ratio 50% and 50% 2,6- di-t-butyl mixed phenols T502 it is multiple Close；
Metal deactivator is 2- sulfenyl benzimidazoles.Oiliness improver is sulfurized lard.Friction improver is sulfur molybdenum phosphate T461.
Extreme pressure agent is chlorinated paraffin T301.Antiwear additive is sulfide isobutene T321.Oxidation and corrosion inhibitor is sulfur phosphorus double-basis alkalescence Zinc salt T203.
Anti-foaming agent is methyl-silicone oil.Antirust agent is that the lanoline of the BTA T706 and 50% of mass ratio 50% is multiple Close；Filler is liquid paraffin.
The remarkable advantage of the present invention：The present composition have good cooling, lubricity (extreme-pressure anti-wear load), Diffusibility, rust-preventing characteristic, antioxygen anti-corrosive properties, adhesiveness and galled spotss can be reduced.
Specific embodiment
Embodiment 1：
Following each component is pressed the mediation of row mass percent to form：
Above each component mass percentage content summation is 100%.
Embodiment 2：
Following each component is pressed the mediation of row mass percent to form：
Above each component mass percentage content summation is 100%.
Embodiment 3：
Following each component is pressed the mediation of row mass percent to form：
Above each component mass percentage content summation is 100%.
The key technical indexes of 1 product of embodiment：
Project Actual measurement index
40 DEG C of kinematic viscosity/(mm2S-1) 315
Flash-point (opening)/DEG C 272
Condensation point/DEG C -18
Viscosity Index 122
Coefficient of friction 0.091
Oxidation stability (rotary bomb oxidation test, 150 DEG C)/min 318
Resistance to emulsion, 84 DEG C of (40-40-0) min 13
Tetra-ball machine test Pb/N 965
Sintering load PD/N 6750
Terraced nurse agrees/N 295
FZG/ levels 13
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % 16
The key technical indexes of 2 product of embodiment：
Project Actual measurement index
40 DEG C of kinematic viscosity/(mm2S-1) 331
Flash-point (opening)/DEG C 281
Condensation point/DEG C -21
Viscosity Index 126
Coefficient of friction 0.081
Oxidation stability (rotary bomb oxidation test, 150 DEG C)/min 302
Resistance to emulsion, 84 DEG C of (40-40-0) min 13
Tetra-ball machine test Pb/N 955
Sintering load PD/N 6530
Terraced nurse agrees/N 288
FZG/ levels 13
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % 13
The key technical indexes of 3 product of embodiment：
Project Actual measurement index
40 DEG C of kinematic viscosity/(mm2S-1) 328
Flash-point (opening)/DEG C 276
Condensation point/DEG C -19
Viscosity Index 118
Coefficient of friction 0.083
Oxidation stability (rotary bomb oxidation test, 150 DEG C)/min 330
Resistance to emulsion, 84 DEG C of (40-40-0) min 14
Tetra-ball machine test Pb/N 978
Sintering load PD/N 6810
Terraced nurse agrees/N 311
FZG/ levels 13
Evaporation loss (Noack methods, 250 DEG C, 1h) (m), % 15

Claims (6)

1. a kind of permalloy shear spinning processing technique lubricant compositions, it is characterised in that：Using mass ratio 50% Oil based on the Esters oil Radialube7368 of HMI120BS and 50% is compound, coordinates various compound additives, its respective matter Amount percent into being grouped into：
Component Mass percentage content Base oil Surplus Antioxidant 0.05%～0.2% Metal deactivator 0.03%～0.1% Oiliness improver 3.0%～8.0% Friction improver 0.5%～2.0% Extreme pressure agent 3.0%～5.0% Antiwear additive 4.0%～6.0% Oxidation and corrosion inhibitor 0.8%～1.2% Anti-foaming agent 10～30ppm Antirust agent 0.03%～0.1% Filler 1.0%～4.0%
The mass percent summation of above each component is 100%.
2. a kind of permalloy shear spinning processing technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Oxygen agent be dinonyldiphenylamine T558 of mass ratio 50% and 50% 2,6- di-t-butyl mixed phenols T502 be combined；Metal deactivating Agent is 2- sulfenyl benzimidazoles.
3. a kind of permalloy shear spinning processing technique lubricant compositions as claimed in claim 1, it is characterised in that oil Property agent is sulfurized lard；Friction improver is sulfur molybdenum phosphate T461.
4. a kind of permalloy shear spinning processing technique lubricant compositions as claimed in claim 1, it is characterised in that pole Pressure agent is chlorinated paraffin T301；Antiwear additive is sulfide isobutene T321.
5. a kind of permalloy shear spinning processing technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Oxygen anti-corrosion additive is sulfur phosphorus double-basis basic zinc salt T203；Anti-foaming agent is methyl-silicone oil.
6. a kind of permalloy shear spinning processing technique lubricant compositions as claimed in claim 1, it is characterised in that anti- Rust agent is that the lanoline of the BTA T706 and 50% of mass ratio 50% is combined；Filler is liquid paraffin.
CN201610966175.7A 2016-11-04 2016-11-04 Lubricant composite for permalloy power spinning processing technology Withdrawn CN106520346A (en)

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Application publication date: 20170322