CN106520294A - 蓖麻基环境友好型切削液组合物 - Google Patents

蓖麻基环境友好型切削液组合物 Download PDF

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CN106520294A
CN106520294A CN201610962463.5A CN201610962463A CN106520294A CN 106520294 A CN106520294 A CN 106520294A CN 201610962463 A CN201610962463 A CN 201610962463A CN 106520294 A CN106520294 A CN 106520294A
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cutting fluid
friendly cutting
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黄福川
李康春
邓富康
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Guangxi University
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Abstract

本发明公开了蓖麻基环境友好型切削液组合物，采用质量比50％的三羧甲基丙烷油酸酯TMP318和50％的蓖麻基葵二酸二乙酯复合作为基础油，配合多种复合添加剂，包括：极压剂、抗磨剂、防锈剂、乳化剂、硬水稳定剂、抗菌防腐剂、PH稳定剂、偶合剂、抗氧剂、助乳化剂、消泡剂、去离子水、切屑沉降剂。本发明的组合物具有良好的冷却性、润滑性、承载能力、减摩减振性、清洗性和排屑作用、防锈性、抗氧防腐蚀性、消泡性、抗腐败性，低气味、无刺激性，有良好的抗微生物性，不易发臭、酸败，具有较长的使用寿命，残液易处理。

Description

蓖麻基环境友好型切削液组合物
技术领域
本发明蓖麻基环境友好型切削液组合物属于金属加工润滑剂领域。
背景技术
金属加工是工程学的一个分支，是通过成型、机械加工、焊接、铸造、热处理等过程来制造零件、机器和构件。金属加工润滑剂是指用于金属切削、磨削、冲压、轧制和拉拨等各种加工过程的润滑剂，主要包括金属切削润滑剂(包括磨削)、塑性加工润滑剂(包括冲压、轧制、拉拔)、热处理和防锈油脂等。随着先进机械设备越来越多，各种新型金属材料不断投入应用，金属加工工艺技术水平也得到提高，同时环境法规的要求日益苛刻，对金属加工润滑剂的质量要求越来越高，面临着一轮全新的全面技术升级换代。
由于各种金属加工工艺不同，润滑剂所发挥的作用不同，其技术要求也各不相同，大多数金属加工润滑剂都要求包含控制摩擦、减少磨损、控制热量和金属表面保护等基本性能；同时，近来安全环保和回收的要求不断提高。总之，在金属加工过程中，金属加工润滑剂不是孤立的因素，应该将其当成整个润滑计刬和系统工程的一部分，与工厂所有润滑剂和润滑装置组成一个完整的摩擦学体系，才能更好地实现金属材料的加工。金属切削润滑剂是金属加工润滑剂中用量最大、影响面最广的一类油品。金属切削加工存在着其特有的多样性、复杂性，国内各金属加工厂使用的润滑油也显多种多样。
切削液是金属加工工艺中重要的配套材料。它在金属加工过程中起到冷却、润滑、清洗和防锈的作用，并且可延长刀具的使用寿命，改善被加工件表面质量，提高生产效率，减少生产成本。随着科技的发展和人们环保意识的提高。使用后切削液的后处理的负面影响也日益引起了社会的重视。因此，新型的金属加工切削液的组分正受到新的环保法规的影响和改变。特别是否含有硫、磷、氯、硼、重金属亚硝酸盐以及芳烃类等有害物质的添加剂或组合受到了极大的限制。新研制的切削液适用加工高硬度、高温、耐磨合金钢及低热导率的镍、钛合金。
发明内容
本发明要解决的技术问题是提供一种蓖麻基环境友好型切削液组合物。
本发明采用如下技术方案解决上述技术问题：
蓖麻基环境友好型切削液组合物，采用质量比50％的三羧甲基丙烷油酸酯TMP318和50％的蓖麻基癸二酸二乙酯复合作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量
基础油 22～28％
极压剂 6～8％
抗磨剂 6～8％
防锈剂 2～3％
乳化剂 9～12％
硬水稳定剂 2.5～3％
抗菌防腐剂 1～2％
PH稳定剂 3.5～4％
偶合剂 2.5～3％
抗氧剂 0.2～0.5％
助乳化剂 3～4％
消泡剂 80～100ppm
去离子水 余量
切屑沉降剂 0.5～1％
以上各组分的质量百分比总和为100％。
极压剂是聚醚；抗磨剂是聚醚酯staradd 4310。。
防锈剂是质量比66.67％的羧酸铵star RP 3118和33.33％的烷基聚氧乙烯醚复合。
乳化剂是聚异丁烯琥珀酸酐PIBSA衍生物。
硬水稳定剂是脂肪醇聚氧乙烯醚羧酸。
抗菌防腐剂是质量比50％的三嗪starcide BK和50％的BIT starcide MW 200复合；PH稳定剂是聚醚胺。
偶合剂是2-烷基-1-烷醇。
抗氧剂是3.5-二叔丁基-4-羟基氧化肉桂酸烷基酯。
助乳化剂是醇醚羧酸Staradd HW 35。
消泡剂是3号复合抗泡剂T923；切屑沉降剂是starcool TOR。
本发明的显著优点在于：本发明的组合物具有良好的冷却性、润滑性、承载能力、减摩减振性、清洗性和排屑作用、防锈性、抗氧防腐蚀性、消泡性、抗腐败性，低气味、无刺激性，有良好的抗微生物性，不易发臭、酸败，具有较长的使用寿命，残液易处理。
具体实施方式
实施例1：
将下列各组分按质量百分比调和而成：
以上各组分的质量百分比总和为100％。
实施例2：
将下列质量百分比调和而成：
以上各组分的质量百分比总和为100％。
实施例3：
将下列质量百分比调和而成：
以上各组分的质量百分比总和为100％。
实施例3产品的主要技术指标
实施例2产品的主要技术指标
实施例1产品的主要技术指标

Claims (10)

1.蓖麻基环境友好型切削液组合物，其特征在于：采用质量比50％的三羧甲基丙烷油酸酯TMP318和50％的蓖麻基癸二酸二乙酯复合作为基础油，配合多种复合添加剂，其各自质量百分数的成分组成：
组分 质量百分比含量 基础油 22～28％ 极压剂 6～8％ 抗磨剂 6～8％ 防锈剂 2～3％ 乳化剂 9～12％ 硬水稳定剂 2.5～3％ 抗菌防腐剂 1～2％ PH稳定剂 3.5～4％ 偶合剂 2.5～3％ 抗氧剂 0.2～0.5％ 助乳化剂 3～4％ 消泡剂 80～100ppm 去离子水 余量 切屑沉降剂 0.5～1％
以上各组分的质量百分比总和为100％。
2.权利要求1所述的蓖麻基环境友好型切削液组合物，其特征在于极压剂是聚醚；抗磨剂是聚醚酯staradd 4310。
3.权利要求1所述的蓖麻基环境友好型切削液组合物，其特征在于防锈剂是质量比66.67％的羧酸铵star RP 3118和33.33％的烷基聚氧乙烯醚复合。
4.权利要求1所述的蓖麻基环境友好型切削液组合物，其特征在于乳化剂是聚异丁烯琥珀酸酐PIBSA衍生物。
5.权利要求1所述的蓖麻基环境友好型切削液组合物，其特征在于硬水稳定剂是脂肪醇聚氧乙烯醚羧酸。
6.权利要求1所述的蓖麻基环境友好型切削液组合物，其特征在于抗菌防腐剂是质量比50％的三嗪starcide BK和50％的BIT starcide MW 200复合；PH稳定剂是聚醚胺。
7.权利要求1所述的蓖麻基环境友好型切削液组合物，其特征在于偶合剂是2-烷基-1-烷醇。
8.权利要求1所述的蓖麻基环境友好型切削液组合物，其特征在于抗氧剂是3.5-二叔丁基-4-羟基氧化肉桂酸烷基酯。
9.权利要求1所述的蓖麻基环境友好型切削液组合物，其特征在于助乳化剂是醇醚羧酸Staradd HW 35。
10.权利要求1所述的蓖麻基环境友好型切削液组合物，其特征在于消泡剂是3号复合抗泡剂T923；切屑沉降剂是starcool TOR。
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