CN106518328A - Organic fertilizer production method - Google Patents
Organic fertilizer production method Download PDFInfo
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- CN106518328A CN106518328A CN201610924592.5A CN201610924592A CN106518328A CN 106518328 A CN106518328 A CN 106518328A CN 201610924592 A CN201610924592 A CN 201610924592A CN 106518328 A CN106518328 A CN 106518328A
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- organic substance
- microorganism
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biotechnology (AREA)
- Pest Control & Pesticides (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to an organic fertilizer production method. The method comprises the following steps: adding macroelements, medium elements, trace elements and an auxiliary material according to a certain mass ratio, adding the materials in an organic matter without antibiotic, uniformly mixing the materials, granulating the materials, drying the materials, and screening the materials to obtain the organic fertilizer. Through cooperation of a photocatalyst and microbe, the purposes of short stacking and decomposing time as well as good removal effect of antibiotic can be achieved.
Description
Technical field
The present invention relates to a kind of production method of fertilizer.
Background technology
Organic fertilizer with feces of livestock and poultry as primary raw material becomes the important sources of farmland antibiotic pollution.In current poultry
In animal husbandry, antibiotic has become the fertilizers such as the chicken manure that the necessary means of cultivation, particularly people commonly use, pig manure, containing compared with
A high proportion of antibiotic.The result of study that Guangzhou Geochemistry Inst., Chinese Academy of Sciences announces for 2015 shows, in 2013
The total usage amount of state's antibiotic reaches about 16.2 ten thousand tons, and wherein 48% is used for medical-therapeutic treatment of human body system, in addition up to 52% antibiosis
It is plain then be used directly to the fields such as animal husbandry and fishery cultivation.Raiser feeds big in order to prevent the sick infection of poultry, often
The antibiotic of dosage, and these antibiotic major parts are not all absorbed, about 60%～90% with active compound and metabolite
Form with fowl and animal excrement discharge.And these feces are often applied directly over field or make into fertilizer otherwise and apply
Field is used, these antibiotic parts are likely to be absorbed by plants, it is final to be absorbed by the body again, and another part is enriched in
In soil, subsoil water etc. is polluted.
Not yet there is the method to remove the antibiotic in fertilizer of the feces of livestock and poultry as raw material at present.
The content of the invention
The technical problem to be solved is to provide a kind of production method of fertilizer, and the present invention is in Organic substance
Addition photocatalyst agent and microorganism, by stacking, contained antibiotic in organics removal.
In order to solve above-mentioned technical problem, the present invention is employed the following technical solutions：
A kind of production method of fertilizer, it is characterised in that follow the steps below：
A great number of elements, moderate-element, trace element and adjuvant are added separately in the Organic substance for remove antibiotic, in a large number
The mass ratio of element, moderate-element, trace element, adjuvant and the Organic substance for removing antibiotic is 1～15:0～20:0～20:0
～55:40～99, mix homogeneously, by pelletize, drying, screening and after the assay was approved, obtain final product fertilizer；
The a great number of elements is carbamide, ammonium sulfate, MAP, APP, PA 800K, potassium sulfate, potassium nitrate, phosphorus
One kind or arbitrary proportion in acid dihydride potassium, ammonium chloride, ammonium nitrate phosphorus, calcium superphosphate and potassium chloride it is two or more；
The moderate-element is magnesium sulfate, ethylenediamine tetraacetic acid disodium magnesium salt, magnesium acetate, calcium acetate, ethylenediaminetetraacetic acid two
One kind or arbitrary proportion in sodium calcium, magnesium nitrate and calcium nitrate it is two or more；
The trace element is copper sulfate, disodiumedetate copper, zinc sulfate, ethylenediamine tetraacetic acid disodium zinc salt, sulfur
In sour manganese, disodiumedetate manganese, ferrous sulfate, disodiumedetate ferrous iron, boric acid, ammonium molybdate and sodium molybdate
A kind of or arbitrary proportion it is two or more；
The adjuvant be bentonite, Pulvis Talci, Kaolin, attapulgite, dimethyl sulfoxide, Polysorbate, potassium humate,
Sorbitol, potassium fulvate, sodium alginate, fish protein, amine fresh fat, molasses fermented liquid, bacillus cereuss, yeast, trichoderma, paddy ammonia
One kind or arbitrary proportion in sour sodium and poly-aspartic-acid potassium it is two or more；
The Organic substance for removing antibiotic is followed the steps below：
By nitrogenous fertilizer, photocatalyst agent and microorganism according to certain mass than being added in Organic substance to be fermented, nitrogenous fertilizer, light
The mass ratio of catalyzer contact agent, microorganism and Organic substance is 0～150:0～20:0.1～20:1000, the moisture of compost is kept during stacking
Between 40%～70%, and it is spaced 2～48h and stirs once, at a temperature of 5～35 DEG C, stacks 5～90 days, it is qualified after testing,
Obtain final product the Organic substance for removing antibiotic；
The nitrogenous fertilizer is the two or more of the one kind in carbamide, ammonium chloride, ammonium sulfate and MAP or arbitrary proportion；
The photocatalyst agent is the one kind in nano titanium oxide, nano zine oxide, nano-sized iron oxide and nano-zinc sulfide
Or arbitrary proportion is two or more；
The microorganism is bacillus cereuss, lactic acid bacteria, yeast, nitrogen-fixing bacteria, root nodule bacteria, muscardine, trichoderma and original inhabitants
One kind or arbitrary proportion in microorganism it is two or more；
The Organic substance is crop straw, mushroom residue, humic acidss, furfural dregs, weeds, Testa Tritici, sawdust, bean cake, leaveves, mud
One kind or arbitrary proportion in charcoal and people and animals' fecaluria it is two or more；
The preparation method of the indigenous microorganism is：
Water content is put in gas-permeable container in 40%～65% culture medium, the 30% of fiduciary point gas-permeable container volume is cultivated
～60%, lid rice paper tighten on gas-permeable container, gas-permeable container is embedded in the fallen leaves of the woods, the temperature during burying is 10 DEG C
～35 DEG C, to white colony is formed, the culture medium with white colony is put in gas impermeable container and adds brown sugar to mix, band
There are the culture medium of white colony and the mass ratio of brown sugar to be 100:30～60, cover rice paper and tighten, be positioned over 15～35 DEG C of rings
5～35 days in border, that is, obtain indigenous microorganism stock solution；Indigenous microorganism stock solution after drying, obtains indigenous microorganism original powder；
During the culture medium is rice, steamed bread, the branch crushed, bark, leaveves, Pericarppium arachidis hypogaeae, wheat straw, Testa oryzae and bean cake
A kind of or arbitrary proportion it is two or more.
The culture medium is the rice that water content is 60%；The 40% of culture fiduciary point gas-permeable container volume；With white bacterium
The culture medium for falling and the mass ratio of brown sugar are 100:45.
In the preparation of indigenous microorganism, the nitrogenous fertilizer is ammonium sulfate；The photocatalyst agent is nano titanium oxide and nanometer
Zinc Oxide is according to mass ratio 1:3 compositionss；Microorganism is yeast and indigenous microorganism according to mass ratio 1:4 compositionss,
The yeast is yeast；The Organic substance is chicken manure and furfural dregs according to 5:1 compositionss；Nitrogenous fertilizer, photocatalyst agent, microorganism
Mass ratio with Organic substance is 50:1:2:1000；Stirred once every 8 hours.
Invention is with following Advantageous Effects：
1st, indigenous microorganism and saccharomycetic compositionss of the microorganism using the woods in the present invention, wherein indigenous microorganism tool
There are extremely powerful vitality and capacity of decomposition, adapt to the change of external environment.
2nd, the present invention adopts photocatalyst agent and microorganism to decompose jointly, and becoming thoroughly decomposed with stacking, the time is short, and removal antibiotic is imitated
Really good the characteristics of.
3rd, the present invention adopts nano titanium oxide and nano zine oxide for photocatalyst agent, and titanium and zinc are also used as beneficial unit
Element carries out nutritional supplementation to crop.
4th, the fertilizer of present invention production, antibiotic content are low, meet national standard requirement.
Specific embodiment
The present invention is further illustrated with reference to instantiation.
Embodiment 1
A great number of elements, moderate-element, trace element and adjuvant are removed into having for antibiotic according to certain mass than being added to
In machine thing, the mass ratio of a great number of elements, moderate-element, trace element, adjuvant and the Organic substance for removing antibiotic is 5:3:2:20:
70, mix homogeneously, by pelletize, drying, screening and after the assay was approved, obtain final product fertilizer.
The Organic substance for removing antibiotic is followed the steps below：
By nitrogenous fertilizer, photocatalyst agent and microorganism according to certain mass than being added in Organic substance to be fermented, nitrogenous fertilizer, light
The mass ratio of catalyzer contact agent, microorganism and Organic substance is 50:1:2:1000；Keeping moisture 55%～60%, turning over every 8 hours
It is dynamic once, in 25～32 DEG C of environment of temperature, to stack 22 days, it is qualified after testing after, obtain final product the Organic substance for removing antibiotic.
Embodiment 2
A great number of elements, moderate-element, trace element and adjuvant are removed into having for antibiotic according to certain mass than being added to
In machine thing, the mass ratio of a great number of elements, moderate-element, trace element, adjuvant and the Organic substance for removing antibiotic is 7:3:2:3:
85, mix homogeneously, by pelletize, drying, screening and after the assay was approved, obtain final product fertilizer.
The Organic substance for removing antibiotic is followed the steps below：
By nitrogenous fertilizer, photocatalyst agent and microorganism according to certain mass than being added in Organic substance to be fermented, nitrogenous fertilizer, light
The mass ratio of catalyzer contact agent, microorganism and Organic substance is 50:1:2:1000；Keeping moisture 55%～60%, turning over every 8 hours
It is dynamic once, in 25～32 DEG C of environment of temperature, to stack 22 days, it is qualified after testing after, obtain final product the Organic substance for removing antibiotic.
Embodiment 3
A great number of elements, moderate-element, trace element and adjuvant are removed into having for antibiotic according to certain mass than being added to
In machine thing, the mass ratio of a great number of elements, moderate-element, trace element, adjuvant and the Organic substance for removing antibiotic is 4:3:3:15:
75, mix homogeneously, by pelletize, drying, screening and after the assay was approved, obtain final product fertilizer.
The Organic substance for removing antibiotic is followed the steps below：
By microorganism according to certain mass than being added in Organic substance to be fermented, the mass ratio of microorganism and Organic substance
For 3:1000；Keep moisture 55%～60%, stirring once every 8 hours, in 25～32 DEG C of environment of temperature, stack 22
My god, it is qualified after testing after, obtain final product the Organic substance for removing antibiotic.
Embodiment 4
A great number of elements, moderate-element, trace element and adjuvant are removed into having for antibiotic according to certain mass than being added to
In machine thing, the mass ratio of a great number of elements, moderate-element, trace element, adjuvant and the Organic substance for removing antibiotic is 7:93, mixing
Uniformly, by pelletize, drying, screening and after the assay was approved, obtain final product fertilizer.
The Organic substance for removing antibiotic is followed the steps below：
By nitrogenous fertilizer, photocatalyst agent and microorganism according to certain mass than being added in Organic substance to be fermented, nitrogenous fertilizer, light
The mass ratio of catalyzer contact agent, microorganism and Organic substance is 50:1:2:1000；Keeping moisture 55%～60%, turning over every 8 hours
It is dynamic once, in 25～32 DEG C of environment of temperature, to stack 22 days, it is qualified after testing after, obtain final product the Organic substance for removing antibiotic.
The preparation method of wherein indigenous microorganism is：
The rice of water content 60% is put in gas-permeable container, rice accounts for the 40% of gas-permeable container volume, breathes freely and hold
Lid rice paper tighten on device, gas-permeable container is embedded in the fallen leaves of the woods, the temperature during burying is 28 DEG C, to forming white bacterium
Fall, the rice with white colony is put in gas impermeable container and adds brown sugar to mix, the rice with white colony
Mass ratio with brown sugar is 100:45, cover rice paper and tighten, be positioned over 7 days in 18～25 DEG C of environment, that is, obtain indigenous micro- life
Thing stock solution；Indigenous microorganism stock solution after drying, obtains indigenous microorganism original powder；
A great number of elements described in embodiment 1 to 4 is carbamide；The moderate-element is magnesium sulfate；The trace element is sulfur
Sour zinc；The adjuvant is bentonite；The nitrogenous fertilizer is ammonium sulfate；The photocatalyst agent is nano titanium oxide and nano zine oxide
According to mass ratio 1:3 compositionss；The microorganism is yeast and indigenous microorganism according to mass ratio 1:4 compositionss；It is described
Organic substance is chicken manure and furfural dregs according to 5:1 compositionss.
Beneficial effects of the present invention are further illustrated with reference to experimental data：
1st, test material to be tested
1 materials and methods：
1.1 test site：Yantai development zone.
1.2 experiment detections：Using oxytetracycline, tetracycline, chlortetracycline and strength in high performance liquid chromatography detection fertilizer
The content of mycin.
1.3 material to be tested：For common fertilizer 1 (when removing the Organic substance of antibiotic and making, except do not add microorganism and
Outside photocatalyst agent, other manufacture methods are consistent with embodiment 1), common fertilizer 2 (when removing the Organic substance of antibiotic and making, removes
Do not add outside photocatalyst agent, other manufacture methods are consistent with embodiment 1) and embodiment 1 do detection and compare.
This experiment is consistent with other management in addition to difference are processed except experiment.
2 results and analysis
For common fertilizer 1 (when removing the Organic substance of antibiotic and making, in addition to microorganism and photocatalyst agent is not added,
Other manufacture methods are consistent with embodiment 1), common fertilizer 2 (when removing the Organic substance of antibiotic and making, touched except light is not added
Outside mediator, other manufacture methods are consistent with embodiment 1) and embodiment 1, oxytetracycline, tetracycline, chlortetracycline and strength is detected respectively
Mycin, testing result are shown in Table 1.
The testing result of oxytetracycline, tetracycline, chlortetracycline and doxycycline in 1 each process of table
| Oxytetracycline (mg/kg) | Tetracycline (mg/kg) | Chlortetracycline (mg/kg) | Doxycycline (mg/kg) | |
| Common fertilizer 1 | 0.05 | 0.06 | 0.09 | 0.04 |
| Common fertilizer 2 | 0.03 | 0.04 | 0.06 | 0.02 |
| Embodiment 1 | 0 | 0 | 0.01 | 0 |
As can be seen from Table 1 the embodiment of the present invention 1 under equal conditions, remove antibiotic in terms of best results.
Claims (4)
1. a kind of production method of fertilizer, it is characterised in that follow the steps below：
A great number of elements, moderate-element, trace element and adjuvant are added separately in the Organic substance for remove antibiotic, great Liang Yuan
The mass ratio of element, moderate-element, trace element, adjuvant and the Organic substance for removing antibiotic is 1～15:0～20:0～20:0～
55:40～99, mix homogeneously, by pelletize, drying, screening and after the assay was approved, obtain final product fertilizer；
The a great number of elements is carbamide, ammonium sulfate, MAP, APP, PA 800K, potassium sulfate, potassium nitrate, di(2-ethylhexyl)phosphate
One kind or arbitrary proportion in hydrogen potassium, ammonium chloride, ammonium nitrate phosphorus, calcium superphosphate and potassium chloride it is two or more；
The moderate-element be magnesium sulfate, ethylenediamine tetraacetic acid disodium magnesium salt, magnesium acetate, calcium acetate, calcium disodium chelate,
One kind or arbitrary proportion in magnesium nitrate and calcium nitrate it is two or more；
The trace element be copper sulfate, disodiumedetate copper, zinc sulfate, ethylenediamine tetraacetic acid disodium zinc salt, manganese sulfate,
One kind in disodiumedetate manganese, ferrous sulfate, disodiumedetate ferrous iron, boric acid, ammonium molybdate and sodium molybdate
Or arbitrary proportion is two or more；
The adjuvant is bentonite, Pulvis Talci, Kaolin, attapulgite, dimethyl sulfoxide, Polysorbate, potassium humate, Pyrusussuriensiss
Alcohol, potassium fulvate, sodium alginate, fish protein, amine fresh fat, molasses fermented liquid, bacillus cereuss, yeast, trichoderma, sodium glutamate
It is two or more with the one kind in poly-aspartic-acid potassium or arbitrary proportion；
The Organic substance for removing antibiotic is followed the steps below：
By nitrogenous fertilizer, photocatalyst agent and microorganism according to certain mass than being added in Organic substance to be fermented, nitrogenous fertilizer, photocatalyst
The mass ratio of agent, microorganism and Organic substance is 0～150:0～20:0.1～20:1000, keep the moisture of compost to exist during stacking
Between 40%～70%, and it is spaced 2～48h and stirs once, at a temperature of 5～35 DEG C, stacks 5～90 days, it is qualified after testing, obtain final product
Remove the Organic substance of antibiotic；
The nitrogenous fertilizer is the two or more of the one kind in carbamide, ammonium chloride, ammonium sulfate and MAP or arbitrary proportion；
The photocatalyst agent is the one kind in nano titanium oxide, nano zine oxide, nano-sized iron oxide and nano-zinc sulfide or appoints
Meaning ratio it is two or more；
The microorganism is bacillus cereuss, lactic acid bacteria, yeast, nitrogen-fixing bacteria, root nodule bacteria, muscardine, trichoderma and indigenous micro- life
One kind or arbitrary proportion in thing it is two or more；
The Organic substance be crop straw, mushroom residue, humic acidss, furfural dregs, weeds, Testa Tritici, sawdust, bean cake, leaveves, peat and
One kind or arbitrary proportion in people and animals' fecaluria it is two or more.
2. the production method of fertilizer as claimed in claim 1, it is characterised in that the preparation method of the indigenous microorganism is：
Water content is put in gas-permeable container in 40%～65% culture medium, the 30%～60% of fiduciary point gas-permeable container volume is cultivated,
Lid rice paper tighten on gas-permeable container, gas-permeable container be embedded in the fallen leaves of the woods, the temperature during burying is 10 DEG C～35 DEG C,
To white colony is formed, the culture medium with white colony is put in gas impermeable container and adds brown sugar to mix, with white
The mass ratio of the culture medium of bacterium colony and brown sugar is 100:30～60, cover rice paper and tighten, be positioned over 5 in 15～35 DEG C of environment～
35 days, that is, obtain indigenous microorganism stock solution；Indigenous microorganism stock solution after drying, obtains indigenous microorganism original powder；
The culture medium is the one kind in rice, steamed bread, the branch crushed, bark, leaveves, Pericarppium arachidis hypogaeae, wheat straw, Testa oryzae and bean cake
Or arbitrary proportion is two or more.
3. the production method of fertilizer as claimed in claim 2, it is characterised in that：It is 60% that the culture medium is water content
Rice；The 40% of culture fiduciary point gas-permeable container volume；The mass ratio of the culture medium with white colony and brown sugar is 100:45.
4. the production method of fertilizer as claimed in claim 2 or claim 3, it is characterised in that：It is in the preparation of indigenous microorganism, described
Nitrogenous fertilizer is ammonium sulfate；The photocatalyst agent is nano titanium oxide and nano zine oxide according to mass ratio 1:3 compositionss；Micro- life
Thing is yeast and indigenous microorganism according to mass ratio 1:4 compositionss, the yeast are yeast；The Organic substance is chicken manure
With furfural dregs according to 5:1 compositionss；The mass ratio of nitrogenous fertilizer, photocatalyst agent, microorganism and Organic substance is 50:1:2:1000；Often
Stirred once every 8 hours.
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Cited By (16)
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| CN106957206A (en) * | 2017-05-27 | 2017-07-18 | 合肥扬扬农业科技有限公司 | A kind of high nutrition organic agricultural fertilizer and preparation method thereof |
| CN107141150A (en) * | 2017-07-12 | 2017-09-08 | 烟台市昊星晟信息技术有限公司 | A kind of production method of the ecological fertilizer with degraded antibiotic effect |
| CN107162807A (en) * | 2017-07-14 | 2017-09-15 | 烟台市昊星晟信息技术有限公司 | A kind of production method for the ecological organic fertilier for removing antibiotic |
| CN107188723A (en) * | 2017-07-14 | 2017-09-22 | 烟台市昊星晟信息技术有限公司 | A kind of production method of the ecological fertilizer with degraded antibiotic effect |
| CN107266192A (en) * | 2017-07-12 | 2017-10-20 | 烟台市昊星晟信息技术有限公司 | A kind of production method for the ecological organic fertilier for removing antibiotic |
| CN107285842A (en) * | 2017-08-14 | 2017-10-24 | 广西鑫雅皇庭园林工程有限责任公司 | One kind greening sinojackia xylocarpa composite fertilizer and preparation method thereof |
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| CN107324880A (en) * | 2017-07-12 | 2017-11-07 | 烟台市昊星晟信息技术有限公司 | A kind of method that utilization compost removes antibiotic |
| CN107353157A (en) * | 2017-08-18 | 2017-11-17 | 云南茂耕农资有限公司 | A kind of peat organic fertilizer and preparation method thereof |
| CN107915547A (en) * | 2017-10-30 | 2018-04-17 | 融安县飞煌原生草药材专业合作社 | A kind of radix tylophorae plantation special fertilizer and preparation method |
| CN107960253A (en) * | 2017-09-21 | 2018-04-27 | 柳州农投生态农业科技有限公司 | A kind of perfume lemon and the spacing sleeve cropping method of high oleic acid peanut |
| CN108077009A (en) * | 2017-12-08 | 2018-05-29 | 德化县裕民种养殖农民专业合作社 | The method for relying on Dehua ecological environment scale underwood planting polygala arillata |
| CN108440205A (en) * | 2018-05-14 | 2018-08-24 | 王宁 | A kind of bio-feritlizer and preparation method thereof |
| CN108892578A (en) * | 2018-09-13 | 2018-11-27 | 安徽乐农环保科技有限公司 | Nutrition member organic backbone fertilizer main body and preparation method thereof |
| CN109053260A (en) * | 2018-09-13 | 2018-12-21 | 安徽乐农环保科技有限公司 | Balanced nutritious organic carbon source and preparation method thereof |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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Application publication date: 20170322 |