CN106517077A - Infrared detector and manufacturing method thereof - Google Patents

Infrared detector and manufacturing method thereof Download PDF

Info

Publication number
CN106517077A
CN106517077A CN201610971868.5A CN201610971868A CN106517077A CN 106517077 A CN106517077 A CN 106517077A CN 201610971868 A CN201610971868 A CN 201610971868A CN 106517077 A CN106517077 A CN 106517077A
Authority
CN
China
Prior art keywords
layer
infrared
substrate
silicon
graphical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610971868.5A
Other languages
Chinese (zh)
Other versions
CN106517077B (en
Inventor
张紫辰
王晓峰
潘岭峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Institute of Microelectronics of CAS
Original Assignee
Institute of Microelectronics of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institute of Microelectronics of CAS filed Critical Institute of Microelectronics of CAS
Priority to CN201610971868.5A priority Critical patent/CN106517077B/en
Publication of CN106517077A publication Critical patent/CN106517077A/en
Application granted granted Critical
Publication of CN106517077B publication Critical patent/CN106517077B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B1/00Devices without movable or flexible elements, e.g. microcapillary devices
    • B81B1/002Holes characterised by their shape, in either longitudinal or sectional plane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00015Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems
    • B81C1/00023Manufacture or treatment of devices or systems in or on a substrate for manufacturing microsystems without movable or flexible elements
    • B81C1/00047Cavities
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J5/10Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors
    • G01J5/20Radiation pyrometry, e.g. infrared or optical thermometry using electric radiation detectors using resistors, thermistors or semiconductors sensitive to radiation, e.g. photoconductive devices
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
    • G01J5/00Radiation pyrometry, e.g. infrared or optical thermometry
    • G01J2005/0077Imaging

Abstract

The invention discloses an infrared detector and a manufacturing method thereof, wherein the infrared detector comprises a substrate, a reflection part, a micro-bridge and a graphical film; the reflection part is arranged on the substrate; the micro-bridge is arranged on the substrate in a suspension manner; a cavity formed by the substrate and the micro-bridge in an encircling manner forms an optical resonant cavity; the micro-bridge is provided with a thermo-sensitive layer; the graphical film is arranged on the thermo-sensitive layer; and infrared light is incident to the substrate from the graphical film. On the basis of a surface plasma enhanced absorption principle, the infrared detector can simultaneously realize detection for medium wave and long wave of infrared light by utilizing the periodic graphical film (such as a metal film); due to the combined action of the thermo-sensitive layer, the optical resonant cavity and the surface plasma enhanced effect, the absorption rate simultaneously for the medium wave and the long wave of the infrared light and device performances of the infrared detector are increased; and thus, relatively comprehensive and accurate detection information is provided for users.

Description

A kind of Infrared Detectorss and preparation method thereof
Technical field
The application is related to microelectronics technology, more particularly, it relates to a kind of Infrared Detectorss and preparation method thereof.
Background technology
Infrared imaging system is the system by target with the radiation generation scene image of background, can 24 hours round-the-clock works Make, and hidden thermal target can be detected through camouflage.Infrared Detectorss are the core components of infrared imaging system, can be according to light Electrical effect and pyroelectric effect are by incident infrared signal transformationization electric signal output.
The Infrared Detectorss of application have polytype at present, wherein the infrared acquisition made using microbolometer thermal technology Device, MEMS (Micro-Electro-Mechanical System, MEMS) technique and device architecture is combined, is had Good development prospect.
As, in atmospheric environment, the infra-red radiation of target object is only capable of at 1~2.5 μm, 3~5 μm and 8~14 μm three Effectively could transmit in window.How to carry out detecting that to become this area urgently to be resolved hurrily for the infrared light in this wavelength band Problem.
Current non refrigerating infrared imaging wave band is concentrated mainly on long wave infrared region (8 μm~14 μm), and imaging band position It is fewer in the product of medium-wave infrared wave band (3 μm~5 μm), therefore the detection target of detector, scope and precision all receive Very big restriction.
As LONG WAVE INFRARED imaging and medium-wave infrared are imaged each advantageous, and different spectral informations are provided, people just open Whether beginning exploration can research and develop one kind can be while realize obtaining target in two wave bands of medium-wave infrared and LONG WAVE INFRARED The Infrared Detectorss of the information of object.
The content of the invention
To solve above-mentioned technical problem, the invention provides a kind of Infrared Detectorss and preparation method thereof, to realize simultaneously The purpose of the Infrared Detectorss of information on target object can be obtained in two wave bands of medium-wave infrared and LONG WAVE INFRARED.
To realize above-mentioned technical purpose, following technical scheme is embodiments provided:
A kind of Infrared Detectorss, including:
Substrate;
Positioned at the reflecting part of the substrate surface;
Deviate from the substrate side, and the hanging microbridge for arranging positioned at the reflecting part, the substrate is enclosed with the microbridge Into cavity formed optical resonator;
The microbridge includes:Along the optical resonator to the support set gradually on the direction of the substrate side Layer, heat-sensitive layer and passivation layer;
Deviate from the graphical thin film of the substrate side positioned at the passivation layer;Wherein,
The graphical thin film strengthens absorption for carrying out surface plasma to incident infrared light;The optical resonance Chamber and the reflecting part are for the infrared light reflection by the substrate surface is incident to the heat-sensitive layer;The heat-sensitive layer is used for The energy of the infrared light of infrared light and reflection to the graphical film absorption is absorbed and is converted into electric signal output.
Optionally, the material of the supporting layer is silicon nitride or silicon oxide or carborundum, and the span of its thickness is 50nm~250nm, including endpoint value;
The material of the heat-sensitive layer is vanadium oxide or titanium oxide or non-crystalline silicon or amorphous germanium or amorphous germanium silicon or the oxidation of germanium silicon Thing, the span of its thickness is 30nm~200nm, including endpoint value;
The material of the passivation layer is silicon nitride or silicon oxide or carborundum, the span of its thickness be 50nm~ 250nm, including endpoint value.
Optionally, the optical resonator be located between the reflecting part and the supporting layer, the reflecting part with it is described The span of the distance between supporting layer is 10nm~1 μm, including endpoint value.
Optionally, the reflecting part and the span of the distance between the supporting layer are 300nm~700nm, including Endpoint value.
Optionally, the material of the graphical thin film is default metal material;
The default metal material is can to produce surface plasma to strengthen the metal or alloy of absorption effect.
Optionally, the default metal material is at least one in gold, silver, aluminum, platinum, nickel, titanium and tungsten.
Optionally, the graphical thin film is the figure in periodic arrangement distribution.
Optionally, the figure in periodic arrangement distribution is the figure of array distribution or interleaves the figure that formula is distributed Shape.
Optionally, the figure in periodic arrangement distribution is included in circle, triangle, rectangle, polygon at least It is a kind of.
Optionally, the span of the circular diameter is 1.5 μm~2.1 μm, including endpoint value.
Optionally, the span in the circular cycle is 1 μm~3 μm, including endpoint value;
The circular cycle refers to the distance between center of circle of adjacent circular.
Optionally, the span of the thickness of the graphical thin film is 50nm~150nm, including endpoint value.
A kind of manufacture method of Infrared Detectorss, including:
Substrate is provided;
Reflecting layer is formed in the substrate surface;
Sacrifice layer is formed away from the substrate side in the reflecting layer;
Supporting layer is formed away from the substrate side in the sacrifice layer;
Heat-sensitive layer is formed away from the substrate side in the supporting layer simultaneously graphical;
Passivation layer is formed away from the substrate side in the heat-sensitive layer;
Graphical thin film is formed away from the substrate side in the microbridge;
Microbridge is etched, and removes the sacrifice layer, to discharge the microbridge.
Optionally, the material of the sacrifice layer includes any one in polyimides, silicon dioxide, polysilicon.
Optionally, the material of the heat-sensitive layer includes vanadium oxide, titanium oxide, non-crystalline silicon, amorphous germanium, amorphous germanium silicon or germanium silicon Oxide.
Optionally, the material of the passivation layer includes any one in silicon nitride, silicon oxide, silicon oxynitride and carborundum;
The material of the supporting layer includes any one in silicon nitride, silicon oxide, silicon oxynitride and carborundum.
From above-mentioned technical proposal as can be seen that embodiments providing a kind of Infrared Detectorss and preparation method thereof, The graphical thin film of the Infrared Detectorss can be realized strengthening infrared light surface plasma and be absorbed, and coordinate the reflecting part With the collective effect of the optical resonator simultaneously, it is possible to increase the Infrared Detectorss are directed to medium-wave infrared and LONG WAVE INFRARED Absorbance and device performance, have provided the user more fully accurately detection information.
And the Infrared Detectorss can be by controlling the optical resonator to the absorption characteristic of long wave infrared region Height interval be modulated, the absorption characteristic of medium wave infrared band can be distributed by the figure to the graphical thin film And size Selection is modulated.
Description of the drawings
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing Accompanying drawing to be used needed for having technology description is briefly described, it should be apparent that, drawings in the following description are only this Inventive embodiment, for those of ordinary skill in the art, on the premise of not paying creative work, can be with basis The accompanying drawing of offer obtains other accompanying drawings.
A kind of one embodiment structural representations of Infrared Detectorss that provide of the Fig. 1 for the application;
A kind of specific embodiment detailed construction schematic diagrams of Infrared Detectorss that provide of the Fig. 2 for the application
One embodiment absorption spectrum schematic diagrams of Infrared Detectorss that provide of the Fig. 3 for the application;
Fig. 4 (a) and Fig. 4 (b) for the application the absorbance spectrum of Infrared Detectorss that provides of one embodiment with incidence Angle change schematic diagram;
Fig. 4 (c) for the application the absorbance of Infrared Detectorss that provides of one embodiment with infrared light wavelength absorption Curve;
Fig. 5 (a) is the structure of the patterned metal film in the Infrared Detectorss that provide of one embodiment of the application Schematic cross-section;
Fig. 5 (b) is the structure of the patterned metal film in the Infrared Detectorss that provide of one embodiment of the application Schematic top plan view;
Fig. 6 (a), (b), (c) and (d) are the patterned metal in the Infrared Detectorss that provide of one embodiment of the application Figure distribution schematic diagram in thin film;
A kind of one embodiment schematic flow sheets of the manufacture method of Infrared Detectorss that provide of the Fig. 7 for the application;
Fig. 8 illustrates for a kind of flow process of the manufacture method of Infrared Detectorss that provides of a specific embodiment of the application Figure;
A kind of one embodiment flow charts of the using method of Infrared Detectorss that provide of the Fig. 9 for the application.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.It is based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made Embodiment, belongs to the scope of protection of the invention.
The embodiment of the present application provides a kind of Infrared Detectorss, as shown in figure 1, including:
Substrate 10;
Positioned at the reflecting part 20 on 10 surface of the substrate;
Deviate from 10 side of the substrate, and the hanging microbridge 30 for arranging, the substrate 10 and institute positioned at the reflecting part 20 State the cavity formation optical resonator 40 that microbridge 30 is surrounded;
The microbridge 30 includes:Along the optical resonator 40 to setting gradually on the 10 side direction of the substrate Supporting layer 31, heat-sensitive layer 32 and passivation layer 33;
Deviate from the graphical thin film 50 of 10 side of the substrate positioned at the passivation layer 33;Wherein,
The formation of the graphical thin film 50 so that the interface between the graphical thin film 50 and the passivation layer 33, Surface plasma excimer effect is produced, the effect promotes the influx and translocation of infrared light;The optical resonator 40 and described anti- Portion 20 is penetrated for the infrared light reflection by 10 surface of the substrate is incident to the heat-sensitive layer 32;It is right that the heat-sensitive layer 32 is used for The infrared light and the energy of the infrared light of reflection that the graphical thin film 50 absorbs is absorbed and is converted into electric signal output.
The embodiment of the present application can be realized to infrared light using the graphical thin film 50 there is provided the Infrared Detectorss Surface plasma strengthen and absorb, and the infrared light to two wave bands of medium-wave infrared and LONG WAVE INFRARED can be realized simultaneously Strengthen and absorb, the surface plasma enhancement effect of the graphical thin film 50 coordinates the reflecting part 20 and the optical resonance The collective effect in chamber 40, can improve absorbance of the Infrared Detectorss to two wave bands of medium-wave infrared and LONG WAVE INFRARED simultaneously And device performance, provide the user more fully accurately detection information.
And the Infrared Detectorss can be by controlling the optical resonator to the absorption characteristic of long wave infrared region 40 height interval is modulated, can be by the figure to the graphical thin film 50 to the absorption characteristic of medium wave infrared band Distribution and size Selection are modulated.
On the basis of above-described embodiment, a specific embodiment of the application provides a kind of the concrete of Infrared Detectorss Structure, as shown in Fig. 2 in fig 2, label 60 represents the Metal contact electrode being connected with peripheral circuit.
The material of the supporting layer 31 is any one in silicon nitride or silicon oxide or carborundum, the value model of its thickness Enclose for 50nm~250nm, including endpoint value;The application is to the concrete material category of the supporting layer 31 and specifically taking for thickness Value is not limited, concrete depending on practical situation.
The material of the heat-sensitive layer 32 is vanadium oxide or titanium oxide or non-crystalline silicon or amorphous germanium or amorphous germanium silicon or germanium silica Compound, the span of its thickness is 30nm~200nm, including endpoint value;But in the other embodiment of the application, the heat As long as the material of photosensitive layer 32 is thermal resistance material.Concrete material category and the tool of thickness of the application to the heat-sensitive layer 32 Body value is not limited, concrete depending on practical situation.
The material of the passivation layer 33 is silicon nitride or silicon oxide or carborundum, the span of its thickness be 50nm~ 250nm, including endpoint value.The application is not limited to the concrete value of the concrete material category and thickness of the passivation layer 33 It is fixed, it is concrete depending on practical situation.
Specifically, in a specific embodiment of the application, the supporting layer 31 uses silicon nitride material, using etc. from Daughter strengthens chemical vapour deposition technique (Plasma Enhanced Chemical Vapor Deposition, PECVD) and makes, Thickness is between 0.1~1 μm.Heat-sensitive layer 32 uses vanadium oxide material, using magnetically controlled sputter method make, thickness be about 30~ 200nm.It is 100~500W that sputtering power is controlled during sputtering, and partial pressure of oxygen is 0.5%~10%, and sputtering time is 5~60min, is splashed Thermosensitive film is annealed after the completion of penetrating to improve its sensitive characteristic, annealing temperature is 200~600 DEG C.Passivation layer 33 is used Silicon nitride material, using plasma strengthen chemical vapour deposition technique (Plasma Enhanced Chemical Vapor Deposition, PECVD) make, thickness is between 0.1~1 μm.Graphical thin film 50 on 30 bridge floor of the microbridge is one layer Metal dish structure, for enhanced highpass filtering.The metal dish structure can be circle, a kind of or many in rectangle, polygon Kind, thickness is 40nm~150nm, including endpoint value.
On the basis of above-described embodiment, in another embodiment of the application, the optical resonator 40 is located at institute State between reflecting part 20 and the supporting layer 31, the reflecting part 20 with the span of the distance between the supporting layer 31 is 10nm~1 μm, including endpoint value.Specifically, the distance between reflecting part 20 and supporting layer 31 correspond to the optical resonance The height in chamber 40, when height is 10nm~1 μm, can realize long wave and medium wave dual band absorption simultaneously;When the optical resonance When the reduced height in chamber 40 is to 300nm~700nm scopes, it is capable of achieving (8~14 μm) of long wave and all absorbs, minimal absorption rate exists More than 70%, medium wave absorbs peak position to be occurred near 5 μm, 4 μm, 3 μm, and absorbance is more than 85%.Specifically can as shown in figure 3, Long wave all absorbs, and minimal absorption rate is more than 70%;There is absworption peak near 4.8 μm and near 3 μm in medium wave, and absorbance exists More than 85%, in fig. 3, label H represents the height of the optical resonator 40, and label D represents that composition is described graphical thin The distance between two neighboring disk of film 50, label L represent the diameter of disk, and the value of D+L is the cycle of the disk.It is described Infrared Detectorss can realize that wide angle is detected, and shown in such as Fig. 4 (a), Fig. 4 (b) and Fig. 4 (c), show when infrared in Fig. 4 (a) When light wave is a length of 4.8 μm, the change curve of the absorbance of the Infrared Detectorss with the angle of incidence of infrared light;Illustrate in Fig. 4 (b) When infrared optical wavelength is 10 μm, the change curve of the absorbance of the Infrared Detectorss with the angle of incidence of infrared light;Fig. 4 Show in (c) when the angle of incidence of infrared light is 45 °, the absorbance of the Infrared Detectorss is bent with the absorption of infrared light wavelength Line.Fig. 4 (a), Fig. 4 (b) and Fig. 4 (c) illustrate that the Infrared Detectorss can be while realize to medium-wave infrared and LONG WAVE INFRARED The absorbing detection of the infrared light of two wave bands, and when the angle of incidence of infrared light is 45 °, the Infrared Detectorss can be realized Multiband INFRARED ABSORPTION.
On the basis of above-described embodiment, in a preferred embodiment of the application, the material of the graphical thin film 50 Expect to preset metal material;
The default metal material is can to produce surface plasma to strengthen the metal or alloy of absorption effect.
Specifically, in one embodiment of the application, the default metal material is gold, silver, aluminum, platinum, nickel, titanium and tungsten In at least one.I.e. described default metal material can for gold silver or aluminum or platinum or nickel or titanium or tungsten, can also be gold, Any alloy of two or more in silver, aluminum, platinum, nickel, titanium and tungsten.The application to the concrete species of the default metal material and Composition is not limited, concrete depending on practical situation.
In the other embodiment of the application, 50 material of graphical thin film can also be other engineers or synthesis Can produce surface plasma strengthen absorption effect material, the application is not limited to this, specifically regarding practical situation Depending on.
In order to strengthen assimilation effect, in a preferred embodiment of the application, the graphical thin film 50 can be in The figure of periodic arrangement distribution.Such as the figure of array distribution or figure etc. of formula distribution is interleave, and the figure can be with For various shapes, such as one or more in circle, triangle, rectangle, polygon.Figure in periodic arrangement distribution can be with Array is formed according to certain rule or irregular arrangement, on the one hand can realizing simultaneously, whole absorptions of far infrared long wave, The absorbance of long wave is improved, on the other hand can also be strengthened the absorption region of medium wave and be improved absorbance.Graphical thin film 50 Concrete structure, shape and distribution can be found in Fig. 5 and Fig. 6.Wherein, Fig. 5 (a) is periodic structure sectional view;Fig. 5 (b) is week Phase property structure top view, wherein L are metal dish diameter, and D is represented between the adjacent metal disk for constituting the graphical thin film 50 Distance, the value of D+L are the cycle of the metal dish, and t is metal disc thickness;Fig. 6 (a) is the one kind in periodic unit CU, can be with Increase the number of metal dish successively and adopt array way, enrich the definition of CU;Periodic unit regular array is flat in top layer Face, it is possible to achieve m n array, Fig. 6 (b) are array arrangement plane of structure figure.Cycle size in each CU is identical or different, week Phase difference can strengthen medium wave band absorption region.As m=0, only longitudinal direction is arranged, shown in such as Fig. 6 (c);As n=0, only Have transversely arranged;When m and n are not zero, the cycle size of the distance between horizontal and vertical CU d and difference CU is defined, Different m n arrays are can be designed that, realizes absorbing the purpose of different-waveband simultaneously, while can also be to the tune of absorption peak position Control is more flexible;Further, some or all of CU in upper figure can be replaced by above-mentioned m n array.Periodic unit is not When specification is arranged, to interleave formula arrangement, such as Fig. 6 (d) is shown for one of which.
Optionally, in one embodiment of the application, in periodic arrangement distribution figure for circle, the circle it is straight The span in footpath is 1 μm~3 μm, including endpoint value;In the preferred embodiment of the application, the circular diameter takes Value scope is 1.5 μm~2.1 μm, including endpoint value.
Optionally, the span in the circular cycle is 1 μm~3 μm, including endpoint value;
The circular cycle refers to the distance between center of circle of adjacent circular.
Optionally, the span of the thickness of the graphical thin film 50 is 50nm~150nm, including endpoint value.
Illustrate, in another specific embodiment of the application, the material of each layer of the Infrared Detectorss is respectively Si (substrate 10), Au (graphical thin film 20), SiN (supporting layer 31), VO2(heat-sensitive layer 32), SiN (passivation layer 33), Au (figures Change thin film 50), in the present embodiment, the thickness of silicon substrate is set to 500nm, the reflector thickness is 100nm, the optics 40 height of resonator cavity is 500nm, and the supporting layer 31 and 33 thickness of passivation layer are 200nm, and golden disc thickness is 50nm, is shaped as circle Shape, a diameter of 1.6 μm, the cycle is set to 2.7 μm.
Accordingly, the embodiment of the present application additionally provides a kind of manufacture method of Infrared Detectorss, as shown in fig. 7, comprises:
S101:Substrate is provided;
S102:Reflecting layer is formed in the substrate surface;
S103:Sacrifice layer is formed away from the substrate side in the reflecting layer;
S104:Supporting layer is formed away from the substrate side in the sacrifice layer;
S105:Heat-sensitive layer is formed away from the substrate side in the supporting layer simultaneously graphical;
S106:Passivation layer is formed away from the substrate side in the heat-sensitive layer;
S107:Graphical thin film is formed away from the substrate side in the passivation layer;
S108:Microbridge is etched, and removes the sacrifice layer, to discharge the microbridge.
It should be noted that in the present embodiment, not to the Infrared Detectorss and peripheral circuit, such as reading circuit The isostructural preparation flow of electrode, via and through hole being connected is illustrated.
On the basis of above-described embodiment, a specific embodiment of the application provides a kind of preparation of Infrared Detectorss Method, as shown in figure 8, including:
S201, is coated with gold thin film on substrate and graphically forms reflecting layer and reading circuit electrode;
S202, forms sacrifice layer on the substrate for forming reflecting layer and reading circuit electrode;
S203, forms through hole on the sacrifice layer;
S204, forms supporting layer on the sacrifice layer;
S205, forms heat-sensitive layer simultaneously graphical on the supporting layer;
S206, forms passivation layer on the heat-sensitive layer;
S207, etching reading circuit electrode contact hole and heat-sensitive layer contact hole;
S208, forms metal contact hole electrode on the passivation layer for etching circuit electrode contact hole and heat-sensitive layer contact hole Layer is simultaneously graphical;
S209, forms patterned metal film on the passivation layer for forming metal contact hole electrode layer;
S210, etches microbridge, and removes the sacrifice layer, discharges microbridge.
Using Infrared Detectorss provided in an embodiment of the present invention, surface etc. can be carried out to infrared light using graphical thin film Gas ions strengthen and absorb, so as under the collective effect of reflecting part, optical resonator and surface plasma enhancement effect, greatly The big device that improves is to infrared medium wave and the absorbance and device performance of long wave, there is provided more fully accurate detection information.
Optionally, the sacrificial layer material includes the nature materials such as polyimides, silicon dioxide, polysilicon and artificial material In any one.
Optionally, the material of the heat-sensitive layer includes vanadium oxide, titanium oxide, non-crystalline silicon, amorphous germanium, amorphous germanium silicon or germanium silicon Oxide.
Optionally, the material of the passivation layer includes any one in silicon nitride, silicon oxide, silicon oxynitride or carborundum; The material of the supporting layer includes any one in silicon nitride, silicon oxide, silicon oxynitride or carborundum.
Optionally, the material of the metal contact hole electrode layer includes any one in titanium, aluminum, titanium nitride, vanadium.
The manufacture method of the Infrared Detectorss provided to the present invention below by specific embodiment is described in detail.
The first step, makes underlying structure:One layer of gold thin film is coated with silicon substrate substrate using electron beam evaporation method, is Increase the adhesiveness of silicon substrate and gold thin film, one layer of chromium thin film of middle addition is completed also with electron beam evaporation method, thick Degree is about 1/10th of gold thin film thickness.Realized graphically by stripping technology, dry etching or wet etching method again, Reflecting layer and two reading circuit electrodes are formed on the same end face of silicon substrate substrate.Used as an example of this example, silicon is thick Degree is set to 500nm, and reflector thickness can be 50nm, and chromium thin film thickness is 5nm;
Second step, makes sacrifice layer:To photosensitive polyimide or non-photosensitivity type polyimides using spin coating method come Make the sacrifice layer;Or, to silicon dioxide or polysilicon using the method for chemical vapor deposition making sacrifice layer;
3rd step, makes sacrifice layer through hole:By photoetching method in the sacrifice layer by made by photosensitive polyimide Upper making sacrifice layer through hole;Or, by dry etching method by non-photosensitivity type polyimides, silicon dioxide or polysilicon Made by sacrifice layer through hole is made on the sacrifice layer;
4th step, makes supporting layer:Using any one of silicon nitride, silicon oxide, silicon oxynitride or carborundum material Material, using plasma strengthen chemical vapour deposition technique and are made;
5th step, makes heat-sensitive layer:Vanadium oxide is coated with to form the heat-sensitive layer using reactive sputtering method;Or, it is right Amorphous silicon using plasma strengthens chemical vapour deposition technique and is coated with to form the heat-sensitive layer, then passes through dry etching reality again It is now graphical;
6th step, makes passivation layer:Using any one of silicon nitride, silicon oxide, silicon oxynitride or carborundum material Material, using plasma strengthen chemical vapour deposition technique and are made;
7th step, makes reading circuit electrode contact hole and heat-sensitive layer contact hole:Using oxygen and fluoroform mixing structure Into etching gas, reading circuit electrode contact hole and heat-sensitive layer contact hole are formed using dry etching method;
8th step, makes metal contact hole electrode layer:A kind of metal in using titanium, aluminum, titanium nitride, vanadium, using electronics Beam evaporation or magnetron sputtering make the Metal contact electrode hole, are then realized by dry etching method again graphical;
9th step, makes golden disk array structure:According to setting the figure of periodic unit, diameter, cycle, spacing and not Realize graphically, realizing array structure with the relevant parameter in array.The preparation of golden disk can use two methods:First is stripping Separating process, i.e., first prepare photoetching offset plate figure, then prepare metallic film, reuse acetone equal solvent remove photoetching offset plate figure so as to Metallic pattern is left on surface.Second is etching technics.Metallic film is first prepared, photoetching offset plate figure is then prepared, recycle etc. The metal etch for not having photoresist to block is removed by gas ions dry etching method, is finally removed photoresist, needed for staying Metallic pattern.
Tenth step, etches microbridge, removes the sacrifice layer, discharges microbridge:First etched using dry etching method micro- Bridge;The sacrifice layer is removed using following method again:Removed by photosensitive polyimide or non-using oxygen plasma dry method The sacrifice layer made by photosensitive polyimide;Or, removed using hydrogen fluoride gas described sacrificial by made by silicon dioxide Domestic animal layer;Or, the sacrifice layer by made by polysilicon is removed using xenon fluoride.
Accordingly, as shown in figure 9, the present invention also provides a kind of making for any one Infrared Detectors that previous embodiment is provided With method, including:
S301, it is special by absorption of the height for the controlling resonator cavity interval modulation Infrared Detectorss to long wave infrared region Property, including long wave peak position, wide-spectrum absorption characteristic and absorbance;Specifically, resonator cavity height is controlled at 300 nanometers to 700 nanometers Between, between 8 microns to 9.3 microns, it is that minimal absorption rate exists between 8 microns to 14 microns to absorb wide range to long wave peak position More than 70%;
S302, modulates the infrared acquisition by the figure distribution to graphical thin film and size Selection and equips red to medium wave The absorption characteristic of wave section, including medium wave peak position, wide-spectrum absorption characteristic and absorbance;Specifically, control the diameter of metallic film It is interval between 1.5 microns to 2.1 microns, medium wave peak position between 4.3 microns to 5 microns, while occurring near 3 microns;
S303, by the selection of figure and size to graphical thin film, realizes double wave crest location, absorbs wide spectral characteristics With the further regulation and control of absorbance.
In sum, the embodiment of the present application provides a kind of Infrared Detectorss and preparation method thereof, the Infrared Detectorss Graphical thin film can realize strengthening the surface plasma of infrared light and absorb such that it is able to realize simultaneously to medium-wave infrared Enhancing with LONG WAVE INFRARED two waveband absorbs, and coordinates the collective effect of the reflecting part and the optical resonator, improves described Absorbance and device performance of the Infrared Detectorss to two wave bands of medium-wave infrared and LONG WAVE INFRARED, have provided the user more fully Accurate detection information.
And it is special by absorption of the height for the controlling resonator cavity interval modulation Infrared Detectorss to long wave infrared region Property, including long wave peak position, wide-spectrum absorption characteristic and absorbance;By figure distribution and size Selection modulation to graphical thin film Absorption characteristic of the Infrared Detectorss to medium wave infrared band, including medium wave peak position, wide-spectrum absorption characteristic and absorbance;Pass through Figure and size Selection to graphical thin film, further regulates and controls double wave crest location, absorbs wide spectral characteristics and absorbance.
In this specification, each embodiment is described by the way of progressive, and what each embodiment was stressed is and other The difference of embodiment, between each embodiment identical similar portion mutually referring to.
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or using the present invention. Various modifications to these embodiments will be apparent for those skilled in the art, as defined herein General Principle can be realized without departing from the spirit or scope of the present invention in other embodiments.Therefore, the present invention The embodiments shown herein is not intended to be limited to, and is to fit to and principles disclosed herein and features of novelty phase one The most wide scope for causing.

Claims (16)

1. a kind of Infrared Detectorss, it is characterised in that include:
Substrate;
Positioned at the reflecting part of the substrate surface;
Deviate from the substrate side, and the hanging microbridge for arranging positioned at the reflecting part, the substrate is surrounded with the microbridge Cavity forms optical resonator;
The microbridge includes:Along the optical resonator to the supporting layer, heat set gradually on the direction of the substrate side Photosensitive layer and passivation layer;
Deviate from the graphical thin film of the substrate side positioned at the passivation layer;Wherein,
The graphical thin film strengthens absorption for carrying out surface plasma to incident infrared light;The optical resonator and The reflecting part is for the infrared light reflection by the substrate surface is incident to the heat-sensitive layer;The heat-sensitive layer is for institute The energy for stating the infrared light of graphical film absorption and the infrared light of reflection is absorbed and is converted into electric signal output.
2. Infrared Detectorss according to claim 1, it is characterised in that the material of the supporting layer is silicon nitride or oxidation Silicon or carborundum, the span of its thickness is 50nm~250nm, including endpoint value;
The material of the heat-sensitive layer is vanadium oxide or titanium oxide or non-crystalline silicon or amorphous germanium or amorphous germanium silicon or germanium Si oxide, its The span of thickness is 30nm~200nm, including endpoint value;
The material of the passivation layer is silicon nitride or silicon oxide or carborundum, and the span of its thickness is 50nm~250nm, is wrapped Include endpoint value.
3. Infrared Detectorss according to claim 1, it is characterised in that the optical resonator be located at the reflecting part with Between the supporting layer, the reflecting part is 10nm~1 μm with the span of the distance between the supporting layer, including end points Value.
4. Infrared Detectorss according to claim 1, it is characterised in that between the reflecting part and the supporting layer away from From span be 300nm~700nm, including endpoint value.
5. Infrared Detectorss according to claim 1, it is characterised in that the material of the graphical thin film is default metal Material;
The default metal material is can to produce surface plasma to strengthen the metal or alloy of absorption effect.
6. Infrared Detectorss according to claim 5, it is characterised in that the default metal material be gold, silver, aluminum, platinum, At least one in nickel, titanium and tungsten.
7. Infrared Detectorss according to claim 1, it is characterised in that the graphical thin film is in periodic arrangement point The figure of cloth.
8. Infrared Detectorss according to claim 7, it is characterised in that the figure in periodic arrangement distribution is battle array The figure of column distribution interleaves the figure that formula is distributed.
9. Infrared Detectorss according to claim 7, it is characterised in that the figure in periodic arrangement distribution includes At least one in circle, triangle, rectangle, polygon.
10. Infrared Detectorss according to claim 9, it is characterised in that the span of the circular diameter is 1.5 μm~2.1 μm, including endpoint value.
11. Infrared Detectorss according to claim 10, it is characterised in that the span in the circular cycle is 1 μ M~3 μm, including endpoint value;
The circular cycle refers to the distance between center of circle of adjacent circular.
12. Infrared Detectorss according to claim 1, it is characterised in that the value model of the thickness of the graphical thin film Enclose for 50nm~150nm, including endpoint value.
13. a kind of manufacture methods of Infrared Detectorss, it is characterised in that include:
Substrate is provided;
Reflecting layer is formed in the substrate surface;
Sacrifice layer is formed away from the substrate side in the reflecting layer;
Supporting layer is formed away from the substrate side in the sacrifice layer;
Heat-sensitive layer is formed away from the substrate side in the supporting layer simultaneously graphical;
Passivation layer is formed away from the substrate side in the heat-sensitive layer;
Graphical thin film is formed away from the substrate side in the microbridge;
Microbridge is etched, and removes the sacrifice layer, to discharge the microbridge.
14. methods according to claim 13, it is characterised in that the material of the sacrifice layer includes polyimides, dioxy Any one in SiClx, polysilicon.
15. methods according to claim 13, it is characterised in that the material of the heat-sensitive layer include vanadium oxide, titanium oxide, Non-crystalline silicon, amorphous germanium, amorphous germanium silicon or germanium Si oxide.
16. methods according to claim 13, it is characterised in that
The material of the passivation layer includes any one in silicon nitride, silicon oxide, silicon oxynitride and carborundum;
The material of the supporting layer includes any one in silicon nitride, silicon oxide, silicon oxynitride and carborundum.
CN201610971868.5A 2016-10-28 2016-10-28 A kind of infrared detector and preparation method thereof Active CN106517077B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610971868.5A CN106517077B (en) 2016-10-28 2016-10-28 A kind of infrared detector and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610971868.5A CN106517077B (en) 2016-10-28 2016-10-28 A kind of infrared detector and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106517077A true CN106517077A (en) 2017-03-22
CN106517077B CN106517077B (en) 2019-02-05

Family

ID=58326104

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610971868.5A Active CN106517077B (en) 2016-10-28 2016-10-28 A kind of infrared detector and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106517077B (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107117579A (en) * 2017-05-11 2017-09-01 烟台睿创微纳技术股份有限公司 A kind of double-deck polarization non-refrigerated infrared detector structure and preparation method thereof
CN108163803A (en) * 2017-12-26 2018-06-15 中国计量大学 A kind of MEMS three-dimensional tunnel structures
CN108565310A (en) * 2017-12-14 2018-09-21 上海集成电路研发中心有限公司 A kind of infrared detector and its manufacturing method
CN111048606A (en) * 2019-12-25 2020-04-21 武汉邮电科学研究院有限公司 Germanium-silicon photoelectric detector with high bandwidth and high responsivity
CN111261733A (en) * 2020-01-21 2020-06-09 苏州众为光电有限公司 Adjustable near-infrared broadband light absorption enhancement structure
CN111261734A (en) * 2020-01-21 2020-06-09 苏州众为光电有限公司 Near-infrared broadband light absorption enhancement structure based on graphene-metal micro-nano array
CN112582495A (en) * 2020-12-03 2021-03-30 无锡中微晶园电子有限公司 Infrared enhanced silicon-based photoelectric detector
CN112645277A (en) * 2020-12-11 2021-04-13 上海集成电路研发中心有限公司 Novel infrared detector and preparation method thereof
CN112730945A (en) * 2020-12-21 2021-04-30 上海交通大学 Flexible MEMS flow velocity sensor based on self-heating amorphous germanium thermal resistor
CN113432726A (en) * 2021-06-25 2021-09-24 北京北方高业科技有限公司 Infrared detector with combined columnar structure
CN113735053A (en) * 2021-08-30 2021-12-03 武汉大学 Micro-electromechanical infrared sensor and preparation method thereof
CN114335202A (en) * 2021-11-30 2022-04-12 北京理工大学 Preparation method of infrared photosensitive element, infrared photosensitive element and infrared spectrometer

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080237467A1 (en) * 2007-03-27 2008-10-02 Nec Corporation Bolometer-type thz-wave detector
CN102175329A (en) * 2010-12-01 2011-09-07 烟台睿创微纳技术有限公司 Infrared detector, manufacturing method thereof and multiband uncooled infrared focal plane
EP2602598A1 (en) * 2011-12-09 2013-06-12 Commissariat A L'energie Atomique Et Aux Energies Alternatives Bolometric detector for electromagnetic radiation in the terahertz spectral band and detector matrix comprising such detectors
CN104535197A (en) * 2014-12-29 2015-04-22 杭州士兰集成电路有限公司 Thermopile infrared detector and manufacturing method thereof
CN104953223A (en) * 2015-07-13 2015-09-30 电子科技大学 Helical antenna coupled micro-bridge structure and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080237467A1 (en) * 2007-03-27 2008-10-02 Nec Corporation Bolometer-type thz-wave detector
CN102175329A (en) * 2010-12-01 2011-09-07 烟台睿创微纳技术有限公司 Infrared detector, manufacturing method thereof and multiband uncooled infrared focal plane
EP2602598A1 (en) * 2011-12-09 2013-06-12 Commissariat A L'energie Atomique Et Aux Energies Alternatives Bolometric detector for electromagnetic radiation in the terahertz spectral band and detector matrix comprising such detectors
CN104535197A (en) * 2014-12-29 2015-04-22 杭州士兰集成电路有限公司 Thermopile infrared detector and manufacturing method thereof
CN104953223A (en) * 2015-07-13 2015-09-30 电子科技大学 Helical antenna coupled micro-bridge structure and preparation method thereof

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107117579A (en) * 2017-05-11 2017-09-01 烟台睿创微纳技术股份有限公司 A kind of double-deck polarization non-refrigerated infrared detector structure and preparation method thereof
CN108565310A (en) * 2017-12-14 2018-09-21 上海集成电路研发中心有限公司 A kind of infrared detector and its manufacturing method
CN108565310B (en) * 2017-12-14 2020-03-31 上海集成电路研发中心有限公司 Infrared detector and manufacturing method thereof
CN108163803A (en) * 2017-12-26 2018-06-15 中国计量大学 A kind of MEMS three-dimensional tunnel structures
CN111048606A (en) * 2019-12-25 2020-04-21 武汉邮电科学研究院有限公司 Germanium-silicon photoelectric detector with high bandwidth and high responsivity
CN111048606B (en) * 2019-12-25 2021-06-29 武汉邮电科学研究院有限公司 Germanium-silicon photoelectric detector with high bandwidth and high responsivity
CN111261733B (en) * 2020-01-21 2021-12-14 苏州众为光电有限公司 Adjustable near-infrared broadband light absorption enhancement structure
CN111261733A (en) * 2020-01-21 2020-06-09 苏州众为光电有限公司 Adjustable near-infrared broadband light absorption enhancement structure
CN111261734A (en) * 2020-01-21 2020-06-09 苏州众为光电有限公司 Near-infrared broadband light absorption enhancement structure based on graphene-metal micro-nano array
CN112582495A (en) * 2020-12-03 2021-03-30 无锡中微晶园电子有限公司 Infrared enhanced silicon-based photoelectric detector
CN112582495B (en) * 2020-12-03 2024-04-09 无锡中微晶园电子有限公司 Infrared reinforced silicon-based photoelectric detector
CN112645277A (en) * 2020-12-11 2021-04-13 上海集成电路研发中心有限公司 Novel infrared detector and preparation method thereof
CN112645277B (en) * 2020-12-11 2023-11-07 上海集成电路研发中心有限公司 Novel infrared detector and preparation method
CN112730945A (en) * 2020-12-21 2021-04-30 上海交通大学 Flexible MEMS flow velocity sensor based on self-heating amorphous germanium thermal resistor
CN113432726A (en) * 2021-06-25 2021-09-24 北京北方高业科技有限公司 Infrared detector with combined columnar structure
CN113432726B (en) * 2021-06-25 2023-03-24 北京北方高业科技有限公司 Infrared detector with combined columnar structure
CN113735053A (en) * 2021-08-30 2021-12-03 武汉大学 Micro-electromechanical infrared sensor and preparation method thereof
CN113735053B (en) * 2021-08-30 2024-01-30 武汉大学 Micro-electromechanical infrared sensor and preparation method thereof
CN114335202A (en) * 2021-11-30 2022-04-12 北京理工大学 Preparation method of infrared photosensitive element, infrared photosensitive element and infrared spectrometer

Also Published As

Publication number Publication date
CN106517077B (en) 2019-02-05

Similar Documents

Publication Publication Date Title
CN106517077B (en) A kind of infrared detector and preparation method thereof
CN106352989B (en) A kind of production method and structure of non-refrigerated infrared focal plane probe microbridge
CN106298827B (en) A kind of non-refrigerated infrared focal plane probe pixel and preparation method thereof
JP5597862B2 (en) Bolometer type THz wave detector
CN110118604B (en) Wide-spectrum microbolometer based on mixed resonance mode and preparation method thereof
US20140291704A1 (en) Plasmonic ir devices
CN102175329A (en) Infrared detector, manufacturing method thereof and multiband uncooled infrared focal plane
CN103940518B (en) A kind of terahertz detection unit micro-bridge structure of low thermal conductance and preparation method thereof
US9488577B2 (en) Miniature gas sensor
CN106082106B (en) A kind of broadband non-refrigerated infrared detector and preparation method thereof
CN107340063B (en) Thermal detector and preparation method thereof
JP2008241439A (en) Bolometer type thz wave detector
CN104953223B (en) A kind of helical antenna coupling micro-bridge structure and preparation method thereof
CN109813449A (en) A kind of integrated polarizing non-refrigerated infrared detector and production method
CN106124066A (en) The microbolometer of a kind of high fill factor and preparation method
CN105129717B (en) A kind of micro-bridge structure of broadband high-selenium corn THz wave and preparation method thereof
CN106340561A (en) Novel uncooled infrared focal plane detector pixel and fabrication method thereof
US10825857B2 (en) Pixel for uncooled infrared focal plane detector and preparation method therefor
CN105811061B (en) A kind of bridge leg separate antenna coupling micro-bridge structure and preparation method thereof
CN109813446A (en) A kind of composite absorption film layer non-refrigerating infrared focal plane and production method
CN104078526A (en) Terahertz wave room temperature detection unit of integrated infrared shielding structure and manufacturing method
CN108358157A (en) A kind of Meta Materials micro-bridge structure and preparation method thereof
CN202066596U (en) Infrared detector and multiband uncooled infrared focal plane
JP2016065786A (en) Infrared radiating element, manufacturing method thereof, and gas analyzer
CN110095185B (en) Terahertz wave detection microbridge structure integrated with sub-wavelength metal ring absorption structure and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant