CN106515145A - 一种防火抗菌消防服面料及其制备方法 - Google Patents

一种防火抗菌消防服面料及其制备方法 Download PDF

Info

Publication number
CN106515145A
CN106515145A CN201610770576.5A CN201610770576A CN106515145A CN 106515145 A CN106515145 A CN 106515145A CN 201610770576 A CN201610770576 A CN 201610770576A CN 106515145 A CN106515145 A CN 106515145A
Authority
CN
China
Prior art keywords
fabric
fire
fiber
fireproof
entry suit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610770576.5A
Other languages
English (en)
Inventor
沈会义
王国新
孙吉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG ZHAOXIN WEAVING Co Ltd
Original Assignee
ZHEJIANG ZHAOXIN WEAVING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG ZHAOXIN WEAVING Co Ltd filed Critical ZHEJIANG ZHAOXIN WEAVING Co Ltd
Priority to CN201610770576.5A priority Critical patent/CN106515145A/zh
Publication of CN106515145A publication Critical patent/CN106515145A/zh
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024—Woven fabric
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/02—Layered materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/02—Layer formed of wires, e.g. mesh
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/14—Macromolecular materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/16—Anti-static materials
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/08—Materials not undergoing a change of physical state when used
    • C09K5/14—Solid materials, e.g. powdery or granular
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/12—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/14—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds a condensation reaction being involved
    • C10M149/18—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M17/00—Producing multi-layer textile fabrics
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00—Layers arrangement
    • B32B2250/20—All layers being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0223—Vinyl resin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0261—Polyamide fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B32B2262/065—Lignocellulosic fibres, e.g. jute, sisal, hemp, flax, bamboo
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/103—Metal fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14—Mixture of at least two fibres made of different materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00—Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10—Inorganic particles
    • B32B2264/102—Oxide or hydroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure

Abstract

本发明提供一种防火抗菌消防服面料及其制备方法，涉及功能面料领域，所述防火抗菌消防服面料由里层和外层组成，其中里层为亲肤面料；外层由复合耐火纤维编织而成，所述复合耐火纤维由以下重量份的物质制成：碳酸亚乙烯酯‑聚甲基丙烯酰亚胺共聚物、聚酰胺、有机硅改性环氧树脂乳液、醋酸丁酯、二氧化钛、硅烷偶联剂、抗老化剂、银纳米线，所述里层和外层通过粘结剂粘结；本发明的防火抗菌消防服面料它不但具有突出的阻燃性能和耐高温性能，还具有杀菌抑菌的作用，为消防员的健康提供保障，而且面料质量轻、穿着舒适、灵活度高，极大地提高了消防员的作战效率。

Description

一种防火抗菌消防服面料及其制备方法
技术领域
本发明涉及功能面料技术领域，具体涉及一种防火抗菌消防服面料及其制备方法。
背景技术
消防服装隔热防护能力的优劣对消防员身处高温环境中救援效率的高低有着至关重要的影响。就目前而言，消防员隔热防护服装主要由外层面料，隔热层，舒适层三部分复合而成。外层面料主要由铝箔与芳纶纤维织物或与玻璃纤维织物层压复合而成，在高温环境中，铝箔可以有效反射高温热辐射热量；隔热层主要是芳纶无纺布或阻燃棉，能够有效阻止外层热量向里传递；舒适层主要是阻燃棉或阻燃粘胶，该层主要与人体皮肤接触，提供人体在高温环境中的舒适感。隔热防护服外层面料是直接与高温接触的一层，当前，外层面料用铝箔与芳纶纤维织物或与玻璃纤维织物复合虽然能够有效反射火焰产生的高温热量，但是，铝箔与芳纶纤维织物复合工艺难度较大，在复合过程中要选择合适的的张力控制才能保证复合后铝箔面不致破损或是不出现褶皱现象，另外，铝箔复合基布外层面料的穿着舒适性较差，这是由于铝箔属非柔性材料，复合在基布上后，整个外层面料手感僵硬，穿在身上时会使得消防员的灭火救援动作变得非常不灵活，致使行动不便，从而导致消防员的安全性能降低而且，铝箔为非透湿性材料，消防员在战斗过程中体表散发的汗液，水汽被阻隔在隔热层及舒适层，会使得消防员产生闷湿感觉，使得面料的舒适度欠佳，穿着不适，从而极大地影响到消防员的作战效率。
中国专利CN200920309275.8提供了一种阻燃织物纤维层、胶粘剂层和抗热辐射的防护外层三层组成结构的抗热辐射耐高温阻燃防护服面料，其中防护外层为聚酯镀铝薄膜。很显然，这种铝膜覆盖的复合面料耐洗涤性能以及穿着舒适性都较差，也未考虑金属膜与有机纤维自身结合困难等问题。综上所述，如何解决现有消防员防护服面料存在的不足已成为该领域亟待解决的技术难题。
发明内容
针对现有技术的不足，本发明提供了一种防火抗菌消防服面料，它不但具有突出的阻燃性能和耐高温性能，还具有杀菌抑菌的作用，而且消防服质量轻、穿着舒适、灵活度高，极大地提高了消防员的作战效率。
为实现以上目的，本发明通过以下技术方案予以实现：
一种防火抗菌消防服面料，其特征在于：所述防火抗菌消防服面料由里层和外层组成，其中里层为亲肤面料；
外层由复合耐火纤维编织而成，所述复合耐火纤维由以下重量份的物质制成：碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺、有机硅改性环氧树脂乳液、醋酸丁酯、二氧化钛、硅烷偶联剂、抗老化剂、银纳米线。
所述里层和外层通过粘结剂粘结。
优选的，所述亲肤面料为竹炭纤维、大麻纤维、亚麻纤维、苎麻纤维、黄麻纤维、剑麻纤维、蕉麻纤维、纯棉纤维、大豆纤维中的一种或多种制成。
优选的，所述二氧化钛为直径为20～50nm的球状结构。
优选的，所述银纳米线的直径为50～100nm，长度为100～200m。
优选的，所述硅烷偶联剂为γ-氨丙基甲基二甲氧基硅烷、γ-氨丙基甲基二乙氧基硅烷、N-β(氨乙基)-γ-氨丙基甲基二甲氧基硅烷，N-β(氨乙基)-γ-氨丙基甲基二乙氧基硅烷中一种或几种。
优选的，所述复合耐火纤维的平均直径为0.5～2m。
一种防火抗菌消防服面料的制备方法，包括以下步骤：
(1)将有机硅改性环氧树脂乳液中加入有机溶剂，加热至80～100℃，再加入碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺，保温10～20min，然后加入醋酸丁酯、二氧化钛、硅烷偶联剂，保温30～90min，再加入抗老化剂，自然冷却至室温，得到纺丝原液，然后通过静电纺丝得到复合耐火纤维；
(2)将1股复合耐火纤维与3～5股银纳米线合股，并捻制成单股线，作为经线，将1～3股复合耐火纤维合股并捻制得纬线，经线和纬线通过织布机捻线编织形成外层面料；
(3)将里层亲肤面料和外层面料通过粘结剂胶粘得到防火抗菌消防服面料，然后将面料在有张力的条件下放入热烘房中进行热定型处理，热烘房温度90～100℃，热定型时间5～8min，经向张力为1000～1200N，纬向张力为600～800N。
优选的，所述步骤(2)中外层面料的经密为78-90根/厘米，纬密为50-60根/厘米。
本发明的有益效果：本发明提供的一种防火抗菌消防服面料具有以下优点：
(1)碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物具有优良的耐热性，聚酰胺具有良好的抗弯强度和抗冲击强度，还有自润滑性和良好的耐磨性，使面料的具有良好的力学性能和很长的使用寿命，还具有良好的阻燃性和自熄性，适用于高温环境；
(2)银纤维具有优异的导热性，在个高温条件下，避免了某一部位热量聚集，从而达到阻燃耐高温的作用，银纤维还可以提高面料的抗静电性、耐沾污性以及织物的柔软舒适性，此外银纤维可帮助皮肤免受细菌的侵袭、抑制细菌的滋生，从而达到抗菌抑菌、美化肌肤的效果；
(3)二氧化钛具有很高的表面能，对聚合物进行改性后，使得聚合物的抗弯曲能力得到显著提升，还能使聚合物表面更加光滑柔软，且它能够对紫外线由很强的反射能力，降低了紫外线对聚合物的伤害；将二氧化钛与高聚物乳液混合后纺丝，使其与聚合物间的结合力增强，延长其使用寿命。
(4)通过静电纺丝得到纤度较大的纤维，将纤维编织成薄且柔软的面料，使面料的质量降低。
综上，本发明的防火抗菌消防服面料它不但具有突出的阻燃性能和耐高温性能，还具有杀菌抑菌的作用，为消防员的健康提供保障，而且面料质量轻、穿着舒适、灵活度高，极大地提高了消防员的作战效率。
具体实施方式
下面将结合本发明实施例对本发明的技术方案进行清楚、完整地说明。
实施例1：
一种防火抗菌消防服面料，其特征在于：所述防火抗菌消防服面料由里层和外层组成，其中里层为由竹炭纤维和纯棉纤维制成的亲肤面料；
外层由复合耐火纤维编织而成，所述复合耐火纤维由以下重量份的物质制成：碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺、有机硅改性环氧树脂乳液、醋酸丁酯、直径为30nm的球状二氧化钛、硅烷偶联剂、抗老化剂、银纳米线；
所述里层和外层通过粘结剂粘结。
所述防火抗菌消防服面料的制备方法，包括以下步骤：
(1)将有机硅改性环氧树脂乳液中加入有机溶剂，加热至80℃，再加入碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺，保温10～20min，然后加入醋酸丁酯、二氧化钛、N-β(氨乙基)-γ-氨丙基甲基二甲氧基硅烷，保温60min，再加入抗老化剂，自然冷却至室温，得到纺丝原液，然后通过静电纺丝得到所述复合耐火纤维的平均直径为1m复合耐火纤维；
(2)将1股复合耐火纤维与5股银纳米线合股，并捻制成单股线，作为经线，将2股复合耐火纤维合股并捻制得纬线，经线和纬线通过织布机捻线编织形成外层面料，所述银纳米线的直径为50nm，长度为200m，所述外层面料的经密78-90根/厘米，纬密为60根/厘米；
(3)将里层亲肤面料和外层面料通过粘结剂胶粘得到防火抗菌消防服面料，然后将面料在有张力的条件下放入热烘房中进行热定型处理，热烘房温度90～100℃，热定型时间5～8min，经向张力为1000～1100N，纬向张力为600～650N。
实施例2：
一种防火抗菌消防服面料，其特征在于：所述防火抗菌消防服面料由里层和外层组成，其中里层为由亚麻纤维和纯棉线制成的亲肤面料；
外层由复合耐火纤维编织而成，所述复合耐火纤维由以下重量份的物质制成：碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺、有机硅改性环氧树脂乳液、醋酸丁酯、直径为50nm的球状二氧化钛、硅烷偶联剂、抗老化剂、银纳米线。
所述里层和外层通过粘结剂粘结。
所述防火抗菌消防服面料的制备方法，包括以下步骤：
(1)将有机硅改性环氧树脂乳液中加入有机溶剂，加热至100℃，再加入碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺，保温10～20min，然后加入醋酸丁酯、二氧化钛、γ-氨丙基甲基二甲氧基硅烷，保温90min，再加入抗老化剂，自然冷却至室温，得到纺丝原液，然后通过静电纺丝得到所述复合耐火纤维的平均直径为1m复合耐火纤维；
(2)将1股复合耐火纤维与3股银纳米线合股，并捻制成单股线，作为经线，将2股复合耐火纤维合股并捻制得纬线，经线和纬线通过织布机捻线编织形成外层面料，所述银纳米线的直径为50nm，长度为100m，所述外层面料的经密为78根/厘米，纬密为50根/厘米；
(3)将里层亲肤面料和外层面料通过粘结剂胶粘得到防火抗菌消防服面料，然后将面料在有张力的条件下放入热烘房中进行热定型处理，热烘房温度90～100℃，热定型时间5～8min，经向张力为1050～1200N，纬向张力为700～800N。
实施例3
一种防火抗菌消防服面料，其特征在于：所述防火抗菌消防服面料由里层和外层组成，其中里层为由大麻纤维、亚麻纤维、制成的亲肤面料；
外层由复合耐火纤维编织而成，所述复合耐火纤维由以下重量份的物质制成：碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺、有机硅改性环氧树脂乳液、醋酸丁酯、直径为20nm的球状二氧化钛、硅烷偶联剂、抗老化剂、银纳米线。
所述里层和外层通过粘结剂粘结。
所述防火抗菌消防服面料的制备方法，包括以下步骤：
(1)将有机硅改性环氧树脂乳液中加入有机溶剂，加热至80℃，再加入碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺，保温10～20min，然后加入醋酸丁酯、二氧化钛、N-β(氨乙基)-γ-氨丙基甲基二乙氧基硅烷，保温60min，再加入抗老化剂，自然冷却至室温，得到纺丝原液，然后通过静电纺丝得到所述复合耐火纤维的平均直径为2m复合耐火纤维；
(2)将1股复合耐火纤维与3股银纳米线合股，并捻制成单股线，作为经线，将3股复合耐火纤维合股并捻制得纬线，经线和纬线通过织布机捻线编织形成外层面料，所述银纳米线的直径为50nm，长度为200m，所述外层面料的经密为90根/厘米，纬密为50根/厘米；
(3)将里层亲肤面料和外层面料通过粘结剂胶粘得到防火抗菌消防服面料，然后将面料在有张力的条件下放入热烘房中进行热定型处理，热烘房温度90～100℃，热定型时间5～8min，经向张力为1000～1200N，纬向张力为600～800N。
实施例4
一种防火抗菌消防服面料，其特征在于：所述防火抗菌消防服面料由里层和外层组成，其中里层为由纯棉线制成的亲肤面料；
外层由复合耐火纤维编织而成，所述复合耐火纤维由以下重量份的物质制成：碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺、有机硅改性环氧树脂乳液、醋酸丁酯、直径为50nm的球状二氧化钛、硅烷偶联剂、抗老化剂、银纳米线。
所述里层和外层通过粘结剂粘结。
所述防火抗菌消防服面料的制备方法，包括以下步骤：
(1)将有机硅改性环氧树脂乳液中加入有机溶剂，加热至100℃，再加入碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺，保温10～20min，然后加入醋酸丁酯、二氧化钛、γ-氨丙基甲基二甲氧基硅烷、γ-氨丙基甲基二乙氧基硅烷，保温30min，再加入抗老化剂，自然冷却至室温，得到纺丝原液，然后通过静电纺丝得到所述复合耐火纤维的平均直径为0.5m复合耐火纤维；
(2)将1股复合耐火纤维与5股银纳米线合股，并捻制成单股线，作为经线，将1股复合耐火纤维合股并捻制得纬线，经线和纬线通过织布机捻线编织形成外层面料，所述银纳米线的直径为100nm，长度为200m，所述外层面料的经密为78根/厘米，纬密为60根/厘米；
(3)将里层亲肤面料和外层面料通过粘结剂胶粘得到防火抗菌消防服面料，然后将面料在有张力的条件下放入热烘房中进行热定型处理，热烘房温度90～100℃，热定型时间5～8min，经向张力为1000～1200N，纬向张力为600～800N。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，可轻易想到的变化或替换，都应涵盖在本发明的保护范围之内。因此，本发明的保护范围应该以权利要求书的保护范围为准。

Claims (8)

1.一种防火抗菌消防服面料，其特征在于：所述防火抗菌消防服面料由里层和外层组成，其中里层为亲肤面料；
外层由复合耐火纤维编织而成，所述复合耐火纤维由以下重量份的物质制成：碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺、有机硅改性环氧树脂乳液、醋酸丁酯、二氧化钛、硅烷偶联剂、抗老化剂、银纳米线；
所述里层和外层通过粘结剂粘结。
2.如权利要求1所述的防火抗菌消防服面料，其特征在于，所述亲肤面料为竹炭纤维、亚麻纤维、大麻纤维、苎麻纤维、黄麻纤维、剑麻纤维、蕉麻纤维、纯棉纤维、大豆纤维中的一种或多种制成。
3.如权利要求1所述的防火抗菌消防服面料，其特征在于，所述二氧化钛为直径为20～50nm的球状结构。
4.如权利要求1所述的防火抗菌消防服面料，其特征在于，所述银纳米线的直径为50～100nm，长度为100～200m。
5.如权利要求1所述的防火抗菌消防服面料，其特征在于，所述硅烷偶联剂为γ-氨丙基甲基二甲氧基硅烷、γ-氨丙基甲基二乙氧基硅烷、N-β(氨乙基)-γ-氨丙基甲基二甲氧基硅烷，N-β(氨乙基)-γ-氨丙基甲基二乙氧基硅烷中一种或几种。
6.如权利要求5所述的防火抗菌消防服面料，其特征在于，所述复合耐火纤维的平均直径为0.5～2m。
7.一种如权利要求1～6任一所述的防火抗菌消防服面料的制备方法，其特征在于，包括以下步骤：
(1)将有机硅改性环氧树脂乳液中加入有机溶剂，加热至80～100℃，再加入碳酸亚乙烯酯-聚甲基丙烯酰亚胺共聚物、聚酰胺，保温10～20min，然后加入醋酸丁酯、二氧化钛、硅烷偶联剂，保温30～90min，再加入抗老化剂，自然冷却至室温，得到纺丝原液，然后通过静电纺丝得到复合耐火纤维；
(2)将1股复合耐火纤维与3～5股银纳米线合股，并捻制成单股线，作为经线，将1～3股复合耐火纤维合股并捻制得纬线，经线和纬线通过织布机捻线编织形成外层面料；
(3)将里层亲肤面料和外层面料通过粘结剂胶粘得到防火抗菌消防服面料，然后将面料在有张力的条件下放入热烘房中进行热定型处理，热烘房温度90～100℃，热定型时间5～8min，经向张力为1000～1200N，纬向张力为600～800N。
8.如权利要求7所述的防火抗菌消防服面料的制备方法，其特征在于，所述步骤(2)中外层面料的经密为78～90根/厘米，纬密为50～60根/厘米。
CN201610770576.5A 2016-08-31 2016-08-31 一种防火抗菌消防服面料及其制备方法 Pending CN106515145A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610770576.5A CN106515145A (zh) 2016-08-31 2016-08-31 一种防火抗菌消防服面料及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610770576.5A CN106515145A (zh) 2016-08-31 2016-08-31 一种防火抗菌消防服面料及其制备方法

Publications (1)

Publication Number Publication Date
CN106515145A true CN106515145A (zh) 2017-03-22

Family

ID=58343704

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610770576.5A Pending CN106515145A (zh) 2016-08-31 2016-08-31 一种防火抗菌消防服面料及其制备方法

Country Status (1)

Country Link
CN (1) CN106515145A (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107637902A (zh) * 2017-09-29 2018-01-30 安徽省创安体育用品有限公司 一种抗疲劳帽子的加工方法
CN107901542A (zh) * 2017-11-14 2018-04-13 东台市黄海耐火材料厂 一种高舒适度的耐火面料
CN109098002A (zh) * 2018-08-17 2018-12-28 深圳市南硕明泰科技有限公司 一种耐火抗菌棉质布料及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1849420A (zh) * 2003-06-27 2006-10-18 罗狄亚化学公司 由阻燃合成材料制成的纱、纤维或长丝
CN103410011A (zh) * 2013-08-16 2013-11-27 苏州东艺技研有限公司 一种放辐射聚丙烯纤维面料
CN103481575A (zh) * 2013-10-23 2014-01-01 王伟民 一种防火抗菌耐腐蚀防静电布料
CN204722311U (zh) * 2015-06-04 2015-10-28 际华三五四三针织服饰有限公司 防辐射阻燃面料
CN105563975A (zh) * 2014-10-13 2016-05-11 顾方钟 防水防火抗菌面料

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1849420A (zh) * 2003-06-27 2006-10-18 罗狄亚化学公司 由阻燃合成材料制成的纱、纤维或长丝
CN103410011A (zh) * 2013-08-16 2013-11-27 苏州东艺技研有限公司 一种放辐射聚丙烯纤维面料
CN103481575A (zh) * 2013-10-23 2014-01-01 王伟民 一种防火抗菌耐腐蚀防静电布料
CN105563975A (zh) * 2014-10-13 2016-05-11 顾方钟 防水防火抗菌面料
CN204722311U (zh) * 2015-06-04 2015-10-28 际华三五四三针织服饰有限公司 防辐射阻燃面料

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107637902A (zh) * 2017-09-29 2018-01-30 安徽省创安体育用品有限公司 一种抗疲劳帽子的加工方法
CN107901542A (zh) * 2017-11-14 2018-04-13 东台市黄海耐火材料厂 一种高舒适度的耐火面料
CN109098002A (zh) * 2018-08-17 2018-12-28 深圳市南硕明泰科技有限公司 一种耐火抗菌棉质布料及其制备方法

Similar Documents

Publication Publication Date Title
CN202286462U (zh) 消防员抢险救援防护服面料
CN104290380B (zh) 多功能汉麻木棉复合救生保暖面料
CN106515145A (zh) 一种防火抗菌消防服面料及其制备方法
CN108081686A (zh) 一种隔热防护面料及其应用
CN103343454A (zh) 阻燃纺织布料及其制造方法
CN205009697U (zh) 一种多功能三层复合阻燃面料
CN210341222U (zh) 阻燃面料及消防服
CN108835742A (zh) 功能型羽绒服面料
CN205871355U (zh) 高强度生物质面料
CN210851615U (zh) 一种防寒服面料及采用该面料制成的防寒服
CN206030683U (zh) 一种防火防水的复合面料
CN206456028U (zh) 一种防水针织植绒布
CN214239865U (zh) 一种防辐射高弹性的人棉弹力针织印花布
CN205234130U (zh) 一种阻燃赛络纺床单布
CN209555477U (zh) 一种高收缩性鞋面针织材料
CN207842210U (zh) 一种弹性防火复合面料
CN209633964U (zh) 一种热防护面料
CN205814904U (zh) 一种用于消防服的舒适面料
CN215590123U (zh) 一种复合阻燃牛津布
CN209307755U (zh) 隔热阻燃消防员防护面料
CN111319327A (zh) 一种消防员灭火防护服透气面料
CN219381870U (zh) 一种防水阻燃复合面料
CN213972886U (zh) 一种高品质环保茄克面料
CN213501202U (zh) 一种耐磨透气面料
CN211334919U (zh) 一种双面阻燃耐高温涂层面料

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170322

RJ01 Rejection of invention patent application after publication