CN106496679B - 改性阻燃顺丁橡胶及其制备方法 - Google Patents
改性阻燃顺丁橡胶及其制备方法 Download PDFInfo
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- CN106496679B CN106496679B CN201610945646.6A CN201610945646A CN106496679B CN 106496679 B CN106496679 B CN 106496679B CN 201610945646 A CN201610945646 A CN 201610945646A CN 106496679 B CN106496679 B CN 106496679B
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- weight
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- butadiene rubber
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229920002857 polybutadiene Polymers 0.000 title claims abstract description 53
- 239000005062 Polybutadiene Substances 0.000 title claims abstract description 51
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 36
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 26
- 238000002156 mixing Methods 0.000 claims abstract description 26
- 239000007822 coupling agent Substances 0.000 claims abstract description 21
- 238000004073 vulcanization Methods 0.000 claims abstract description 19
- 229910052582 BN Inorganic materials 0.000 claims abstract description 15
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 15
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 229920001577 copolymer Polymers 0.000 claims abstract description 12
- 239000013078 crystal Substances 0.000 claims abstract description 12
- 241000609240 Ambelania acida Species 0.000 claims abstract description 9
- 239000010905 bagasse Substances 0.000 claims abstract description 9
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- OLLFKUHHDPMQFR-UHFFFAOYSA-N dihydroxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](O)(O)C1=CC=CC=C1 OLLFKUHHDPMQFR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920005610 lignin Polymers 0.000 claims abstract description 9
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 8
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 7
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 3
- XUBKPYAWPSXPDZ-UHFFFAOYSA-N [Ba].OS(O)(=O)=O Chemical compound [Ba].OS(O)(=O)=O XUBKPYAWPSXPDZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 claims description 3
- 229960002447 thiram Drugs 0.000 claims description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 1
- 235000011613 Pinus brutia Nutrition 0.000 claims 1
- 241000018646 Pinus brutia Species 0.000 claims 1
- 239000012964 benzotriazole Substances 0.000 claims 1
- 239000002304 perfume Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 16
- 239000002994 raw material Substances 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 7
- 239000005060 rubber Substances 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000003063 flame retardant Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 235000019441 ethanol Nutrition 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- -1 ethyl alcohol Amine Chemical class 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IENJMFWWRIWLIW-UHFFFAOYSA-N 3-methyl-1,3-thiazole-2-thione Chemical compound CN1C=CSC1=S IENJMFWWRIWLIW-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (9)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610945646.6A CN106496679B (zh) | 2016-11-02 | 2016-11-02 | 改性阻燃顺丁橡胶及其制备方法 |
CN201910017325.3A CN109810307B (zh) | 2016-11-02 | 2016-11-02 | 一种改性阻燃顺丁橡胶及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610945646.6A CN106496679B (zh) | 2016-11-02 | 2016-11-02 | 改性阻燃顺丁橡胶及其制备方法 |
Related Child Applications (1)
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CN201910017325.3A Division CN109810307B (zh) | 2016-11-02 | 2016-11-02 | 一种改性阻燃顺丁橡胶及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN106496679A CN106496679A (zh) | 2017-03-15 |
CN106496679B true CN106496679B (zh) | 2019-01-22 |
Family
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Family Applications (2)
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CN201610945646.6A Expired - Fee Related CN106496679B (zh) | 2016-11-02 | 2016-11-02 | 改性阻燃顺丁橡胶及其制备方法 |
CN201910017325.3A Active CN109810307B (zh) | 2016-11-02 | 2016-11-02 | 一种改性阻燃顺丁橡胶及其制备方法 |
Family Applications After (1)
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CN201910017325.3A Active CN109810307B (zh) | 2016-11-02 | 2016-11-02 | 一种改性阻燃顺丁橡胶及其制备方法 |
Country Status (1)
Country | Link |
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CN (2) | CN106496679B (zh) |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6291374B1 (en) * | 1994-10-13 | 2001-09-18 | World Properties, Inc. | Polybutadiene and polyisoprene based thermosetting compositions and method of manufacture |
CN101121796A (zh) * | 2006-06-23 | 2008-02-13 | 南京理工大学 | 一种聚合物基阻燃复合材料 |
CN102040779B (zh) * | 2009-10-21 | 2013-05-08 | 比亚迪股份有限公司 | 一种阻燃橡胶及其制备方法 |
CN103819758A (zh) * | 2014-02-26 | 2014-05-28 | 秦荣勤 | 阻燃耐火橡胶组合物、制备方法及耐火阻燃橡胶包带 |
CN103897230B (zh) * | 2014-04-01 | 2015-09-16 | 安徽金科橡塑制品有限公司 | 一种耐寒橡胶密封圈 |
CN104592648B (zh) * | 2015-01-09 | 2017-01-11 | 芜湖航天特种电缆厂股份有限公司 | 电缆用阻燃三元乙丙橡胶及其制备方法 |
CN105367916A (zh) * | 2015-11-24 | 2016-03-02 | 安徽南洋新材料科技股份有限公司 | 一种高强度高耐候阻燃电缆 |
CN106009124A (zh) * | 2016-03-18 | 2016-10-12 | 晶锋集团股份有限公司 | 一种不易氧化变色橡胶电缆料 |
CN106047164A (zh) * | 2016-06-30 | 2016-10-26 | 太仓市金新涂料有限公司 | 一种环保阻燃绝缘涂料及其制备方法 |
-
2016
- 2016-11-02 CN CN201610945646.6A patent/CN106496679B/zh not_active Expired - Fee Related
- 2016-11-02 CN CN201910017325.3A patent/CN109810307B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN106496679A (zh) | 2017-03-15 |
CN109810307A (zh) | 2019-05-28 |
CN109810307B (zh) | 2021-02-26 |
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Effective date of registration: 20191220 Address after: 241000, Anhui 415, Yijiang province Wuhu No. seven business incubator Park No. Patentee after: WUHU QIANKAI MATERIAL TECHNOLOGY Co.,Ltd. Address before: Biguiyuan 241000 Anhui city of Wuhu province Jinghu Sanshan District No. 619 spring Patentee before: WUHU RUIDE MACHINERY TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20201211 Address after: 163000 Naner road beidonghu b14-shangfu 30, Ranghulu District, Daqing City, Heilongjiang Province Patentee after: Daqing shunhexiang Petroleum Machinery Equipment Co.,Ltd. Address before: 241000 Business Incubation Park No. 415, Weiqi Road, Yijiang District, Wuhu City, Anhui Province Patentee before: WUHU QIANKAI MATERIAL TECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20221013 Address after: Commercial Service 01, Comprehensive Building, No. B14, Beidonghu, Naner Road, Ranghu Road District, Daqing City, Heilongjiang Province, 163000 Patentee after: Heilongjiang Xiangyuan Hongye Technology Co.,Ltd. Address before: 163000 Naner road beidonghu b14-shangfu 30, Ranghulu District, Daqing City, Heilongjiang Province Patentee before: Daqing shunhexiang Petroleum Machinery Equipment Co.,Ltd. |
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Granted publication date: 20190122 |