CN106486417A - The method of lifting crystal edge yield - Google Patents

The method of lifting crystal edge yield Download PDF

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Publication number
CN106486417A
CN106486417A CN201510557758.XA CN201510557758A CN106486417A CN 106486417 A CN106486417 A CN 106486417A CN 201510557758 A CN201510557758 A CN 201510557758A CN 106486417 A CN106486417 A CN 106486417A
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China
Prior art keywords
side washing
inter
photoresist layer
level dielectric
wafer substrate
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CN201510557758.XA
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Chinese (zh)
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CN106486417B (en
Inventor
陈亚威
顾费东
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CSMC Technologies Corp
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CSMC Technologies Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76801Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
    • H01L21/76829Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers
    • H01L21/76831Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing characterised by the formation of thin functional dielectric layers, e.g. dielectric etch-stop, barrier, capping or liner layers in via holes or trenches, e.g. non-conductive sidewall liners

Abstract

The present invention relates to a kind of method of lifting crystal edge yield, comprises the following steps:Wafer substrate is provided;In wafer substrate, gluing forms the first photoresist layer, and carries out active area side washing;The position not covered by the first photoresist layer in wafer substrate forms silicon oxide isolation structure;Active area is formed in wafer substrate;Inter-level dielectric is formed on the active area;On inter-level dielectric, gluing forms the second photoresist layer, and carries out contact hole side washing;Under the sheltering of the second photoresist layer, etching inter-level dielectric forms contact hole;Metal is filled to contact in the hole by depositing operation;Inter-level dielectric to being filled with metal carries out planarization process;Side washing region in active area side washing step at least extends to deposition region edge from crystal round fringes.The present invention can lift crystal edge yield by setting suitable side washing region without the need for extra cost.

Description

The method of lifting crystal edge yield
Technical field
The present invention relates to integrated circuit (IC) manufacture field, brilliant in more particularly to a kind of lifting side washing technique The method of side yield.
Background technology
During the gluing of wafer, the effect of centrifugal force can cause photoresist accumulation to be formed at the edge of wafer Residual projection, and then cause the pollution of subsequent technique, reduce crystal edge yield.Wafer is accumulated in order to remove The photoetching glue residua at edge, generally carries out side washing (Edge Bean Removal, EBR) after coating technique, To remove the photoetching glue residua of crystal round fringes.
The lifting of crystal edge yield is most important for 8 cun of factories and below 0.18um technique, and traditional side washing , during follow-up contact metal grinding technics, lapping liquid can be by the contact hole of unfilled metal for technique Corrosion silicon substrate, as shown in figures 1 and 3, causes substrate damage, causes defect exception, affects yield.
Content of the invention
Based on this, it is necessary to for the defect abnormal problem that substrate damage causes is reduced, a kind of lifting is provided brilliant The method of side yield.
A kind of method of lifting crystal edge yield, comprises the following steps:Wafer substrate is provided;It is lithographically formed first Photoresist layer;In the wafer substrate, gluing forms the first photoresist layer, and carries out active area side washing;? The position not covered by the first photoresist layer in the wafer substrate forms silicon oxide isolation structure;In the crystalline substance Active area is formed on circle substrate;Inter-level dielectric is formed on the active area;It is lithographically formed the second photoresist layer; On the inter-level dielectric, gluing forms the second photoresist layer, and carries out contact hole side washing;In second light The inter-level dielectric is etched under the sheltering of photoresist layer forms contact hole;By depositing operation to the contact in the hole Filling metal;Inter-level dielectric to being filled with metal carries out planarization process;In the active area side washing step Side washing region at least extend to from crystal round fringes and described metal filled to the contact in the hole by depositing operation The step of in deposition region edge.
Wherein in one embodiment, described by depositing operation to described contact in the hole fill metal the step of Be using chemical vapor deposition method deposits tungsten.
Wherein in one embodiment, the side washing region in the contact hole side washing step is at least from crystal round fringes Extend to described by depositing operation to the contact in the hole fill metal the step of in deposition region edge 4, According to claim 1 lifting crystal edge yield method, it is characterised in that the active area side washing and The two side washing steps of contact hole side washing are removed unnecessary photoresist by organic solvent.
Wherein in one embodiment, the inter-level dielectric to being filled with metal carries out the step of planarization process Suddenly, including being ground using alkaline slurries.
Wherein in one embodiment, the inter-level dielectric to being filled with metal carries out the step of planarization process After rapid, also include the step of forming metal connecting line.
Wherein in one embodiment, described offer wafer substrate the step of in, wafer substrate be silicon substrate.
The method of above-mentioned lifting crystal edge yield, in unfilled contact hole silicon oxide isolation structure formed below, Never the lapping liquid that the contact hole being filled with metal is penetrated down into stopped because of oxidized silicon seperate structure, therefore not Corrosion damage can be caused to wafer substrate.The method is become without the need for extra by setting suitable side washing region Originally crystal edge yield can be lifted.
Description of the drawings
Fig. 1 is the schematic diagram of traditional handicraft crystal round fringes after contact metal grinding;
Fig. 2 is wafer substrate axle center and edge schematic diagram;
Fig. 3 causes the abnormal Electronic Speculum schematic diagram of defect for traditional handicraft grinding corrosion silicon substrate;
Fig. 4 is the flow chart of the method for present invention lifting crystal edge yield;
Fig. 5 is the schematic diagram of crystal edge after the completion of step S130 in embodiment 1;
Fig. 6 is the schematic diagram of crystal edge after the completion of step S190 in embodiment 1;
Fig. 7 is the schematic diagram of crystal edge after formation metal connecting line in embodiment 2.
Specific embodiment
For the ease of understanding the present invention, the present invention is described more fully below with reference to relevant drawings. The first-selected embodiment of the present invention is given in accompanying drawing.But, the present invention can come real in many different forms Existing, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is made to this Disclosure of the invention content is more thorough comprehensive.
Unless otherwise defined, all of technology used herein and scientific terminology and the technology for belonging to the present invention The implication that the technical staff in field is generally understood that is identical.The art for being used in the description of the invention herein Language is intended merely to describe the purpose of specific embodiment, it is not intended that in the restriction present invention.Used herein Term " and/or " include the arbitrary and all of combination of one or more related Listed Items.
As described in the background art, as the filling of contact hole 10 is formed in 20 metal deposition process of tungsten plug, Metal deposit regions 300 will not cover full wafer wafer substrate 100, as shown in figure 1, traditional side washing technique exists In follow-up 20 process of lapping of tungsten plug, lapping liquid (such as alkaline solution) can be by unfilled metal (figure Oval circle 500 in 1) the corrosion active area of contact hole 10, substrate damage 510 is formed, as Fig. 3 electron microscope institute Show, cause defect exception, affect yield.
Fig. 2 is the schematic diagram at wafer substrate axle center 110 and edge 120, in this specification side washing technique with And the reference direction of depositing operation is the direction that wafer substrate edge 120 points to wafer substrate axle center 110, i.e., The direction of arrow in Fig. 2.
Fig. 4 is the flow chart of the method for present invention lifting crystal edge yield, enters below by way of two embodiments respectively Row explanation.
Embodiment 1:
S110, provides wafer substrate 100.
Specifically chosen what kind of substrate can be decided in its sole discretion according to product demand, material including substrate, Crystal orientation, doping type etc., are not limited herein.Silicon substrate commonly employed in the art.
S120, is lithographically formed the first photoresist layer.
Please also refer to Fig. 5, in wafer substrate 100, gluing forms the first photoresist layer 210, and is had Source region side washing (removing the photoetching glue residua of crystal round fringes using organic solvent) and photoetching.In the present embodiment, Side washing size a1 that points to from wafer substrate edge 120 on 110 direction of wafer substrate axle center is sufficiently large, makes light Photoresist is washed off the deposition region 300 that region at least extends to follow-up metal deposition process from crystal round fringes.
S130, the position not covered by the first photoresist layer in wafer substrate form silicon oxide isolation structure.
Refer to Fig. 5, in wafer substrate 100 not by the first photoresist layer cover position formed silica every From structure 200.It should be understood that the first photoresist layer 210 is not necessarily directly as silicon oxide isolation structure 200 mask layer, for example, first deposit can form silicon nitride layer in wafer substrate 100, then pass through the first light 210 photoetching of photoresist layer and etch the silicon nitride layer and form suitable pattern, then using the silicon nitride layer as covering firmly Film layer, forms silicon oxide isolation structure 200.
S140, forms active area in wafer substrate.
After forming silicon oxide isolation structure 200, the structure of active area next can be formed.Can adopt herein Conventional process, therefore do not repeat.
S150, forms inter-level dielectric on the active area.
Equally inter-level dielectric (ILD) 220 can be formed using conventional process.
S160, is lithographically formed the second photoresist layer.
On inter-level dielectric 220, gluing forms the second photoresist layer, and carries out contact hole side washing and photoetching.
S170, under the sheltering of the second photoresist layer, etching inter-level dielectric forms contact hole.
The photoresist at wafer substrate edge 120 is removed because of side washing, therefore the ILD of lower section exposes, so as to Be etched in this step removal.
S180, fills metal by depositing operation to contact in the hole.
In the present embodiment, it is to be in filling tungsten, i.e. this step into contact hole (contact) 10 with chemistry Vapour deposition (CVD) process deposits tungsten, forms tungsten plug 20.Due to the scope (i.e. deposition region 300) for depositing Wafer substrate edge 120 will not be covered, therefore the contact hole 10 outside deposition region 300 will not be filled by tungsten, So as to form cavity, as shown in Figure 6.
S190, the inter-level dielectric to being filled with metal carry out planarization process.
It is ground by abrasive disk.In the present embodiment, lapping liquid is alkaline solution.
The method of above-mentioned lifting crystal edge yield, unfilled 10 lower section of contact hole is silicon oxide isolation structure 200, The contact hole that lapping liquid is never filled with metal in step S190 is penetrated down into, but because of oxidized silicon seperate structure 200 are stopped, therefore will not cause corrosion damage to wafer substrate 100.
It should be understood that metal connecting line 310 is formed by photoetching and etching in crystal column surface after step S190, Metal connecting line is electrically connected to tungsten plug 20 active area of lower section.
Embodiment 2:
Embodiment 1 be by protecting substrate, embodiment in the oxide layer formed below of unfilled contact hole 10 2 pass through to remove unnecessary ILD so that will not form contact hole outside deposition region 300, prevent grinding Liquid corrodes the hidden danger of substrate by contact hole 10.
Therefore the differring primarily in that of embodiment 2 and embodiment 1, by rationally arranging from wafer in step S160 Edges of substrate 120 points to side washing size a2 on 110 direction of wafer substrate axle center so that photoresist is washed off Region at least extends to deposition region 300 from crystal round fringes.Consequently, it is possible in step S170, unnecessary Inter-level dielectric 220 will be etched away, and directly avoid the generation of the contact hole 10 for being not filled by metal.As schemed Shown in 7.
Same as Example 1, also include to form metal connecting line 310 by photoetching and etching after step S190 The step of.
Embodiment described above only have expressed the several embodiments of the present invention, and its description is more concrete and detailed, But therefore can not be construed as limiting the scope of the patent.It should be pointed out that for this area For those of ordinary skill, without departing from the inventive concept of the premise, some deformation can also be made and is changed Enter, these belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be with appended power Profit requires to be defined.

Claims (7)

1. a kind of method of lifting crystal edge yield, comprises the following steps:
Wafer substrate is provided;
It is lithographically formed the first photoresist layer;In the wafer substrate, gluing forms the first photoresist layer, goes forward side by side Row active area side washing;
The position not covered by the first photoresist layer in the wafer substrate forms silicon oxide isolation structure;
Active area is formed in the wafer substrate;
Inter-level dielectric is formed on the active area;
It is lithographically formed the second photoresist layer;On the inter-level dielectric, gluing forms the second photoresist layer, goes forward side by side Row contact hole side washing;
The inter-level dielectric is etched under the sheltering of second photoresist layer forms contact hole;
Metal is filled to the contact in the hole by depositing operation;
Inter-level dielectric to being filled with metal carries out planarization process;
Side washing region in the active area side washing step at least extends to described by depositing work from crystal round fringes Deposition region edge of the skill in the step of the contact in the hole filling metal.
2. the method for lifting crystal edge yield according to claim 1, it is characterised in that described by heavy Product technique to described contact in the hole fill metal the step of be using chemical vapor deposition method deposits tungsten.
3. according to claim 1 lifting crystal edge yield method, it is characterised in that the contact hole Side washing region in side washing step at least extends to described by depositing operation to the contact hole from crystal round fringes Deposition region edge in the step of interior filling metal.
4. according to claim 1 lifting crystal edge yield method, it is characterised in that the active area Side washing and the two side washing steps of contact hole side washing are removed unnecessary photoresist by organic solvent.
5. according to claim 1 lifting crystal edge yield method, it is characterised in that described to filling The step of inter-level dielectric of metal carries out planarization process, including being ground using alkaline slurries.
6. according to claim 1 lifting crystal edge yield method, it is characterised in that described to filling After the step of inter-level dielectric of metal carries out planarization process, also include the step of forming metal connecting line.
7. the method for lifting crystal edge yield according to claim 1, it is characterised in that the offer is brilliant In the step of circle substrate, wafer substrate is silicon substrate.
CN201510557758.XA 2015-09-02 2015-09-02 The method for promoting crystal edge yield Active CN106486417B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112086352A (en) * 2020-08-06 2020-12-15 北京烁科精微电子装备有限公司 Process for growing oxidation isolation layer by using Locos and preparing IGBT chip

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040035450A1 (en) * 2000-12-15 2004-02-26 Ko Se-Jong Apparatus for cleaning the edges of wafers
CN1505111A (en) * 2002-11-28 2004-06-16 华邦电子股份有限公司 Process for removing ditch and protrusion
CN101206181A (en) * 2006-12-22 2008-06-25 中芯国际集成电路制造(上海)有限公司 Device and method for testing edge-washing effect of crystal round fringes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040035450A1 (en) * 2000-12-15 2004-02-26 Ko Se-Jong Apparatus for cleaning the edges of wafers
CN1505111A (en) * 2002-11-28 2004-06-16 华邦电子股份有限公司 Process for removing ditch and protrusion
CN101206181A (en) * 2006-12-22 2008-06-25 中芯国际集成电路制造(上海)有限公司 Device and method for testing edge-washing effect of crystal round fringes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112086352A (en) * 2020-08-06 2020-12-15 北京烁科精微电子装备有限公司 Process for growing oxidation isolation layer by using Locos and preparing IGBT chip
CN112086352B (en) * 2020-08-06 2024-02-20 北京晶亦精微科技股份有限公司 Technology for growing oxidation isolation layer and preparing IGBT chip by using Locos

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