CN106477910A - 一种超疏水太阳能电池盖板玻璃的制备方法 - Google Patents
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Abstract
本发明提供一种超疏水太阳能电池盖板玻璃的制备方法，其特征在于它包括以下步骤：将聚二甲基硅氧烷胶状物和固化剂混合，固化一段时间后得到聚二甲基硅氧烷固体，将此固体和太阳能电池盖板玻璃放在密闭的器皿中蒸发镀膜后，即得超疏水太阳能电池盖板玻璃。本发明利用聚二甲基硅氧烷表面的憎水官能团，使得镀膜后的太阳能电池盖板玻璃具有极强的疏水性，保护和增强了盖板玻璃的稳定性，提升了太阳能电池在雨天等恶劣环境下的应用。
Description
技术领域：
本发明涉及一种太阳能电池盖板的制备方法，具体地说就是一种超疏水太阳能电池盖板玻璃的制备方法。
背景技术：
如何提高太阳能电池的盖板玻璃的稳定性，延长其使用寿命，已得到越来越多的关注。具有超高疏水性、高透光率的无机非金属材料，在光伏行业和玻璃行业有着巨大的应用前景。现在使用的太阳能盖板玻璃疏水性较低，水容易在玻璃表面铺张而不易汇聚成滴，影响了透光率和玻璃的稳定性，特别在灰尘较多的环境中，雨后太阳能电池盖板玻璃表面布满尘土，这些都继而影响了太阳能电池的光电转换效率。
现有技术公开了多种超疏水材料在吸附剂、表面活性剂等领域的应用，例如：还原性石墨烯包裹海绵吸附剂，碳纳米管吸附剂，然而在半导体领域，利用超疏水材料聚二甲基硅氧烷镀膜制成的超疏水太阳能电池盖板玻璃尚未发明。聚二甲基硅氧烷无毒亲肤无刺激性，常用于护肤品、皮革制品、电器品，因而其超高疏水性的研究和在半导体领域的拓展应用，有着巨大的潜力和价值。
发明内容：
本发明就是为了克服现有技术中的不足，提供一种超疏水太阳能电池盖板玻璃的制备方法。
本发明提供以下技术方案：
一种超疏水太阳能电池盖板玻璃的制备方法，其特征在于它按如下步骤进行：
a、将聚二甲基硅氧烷固化，
b、将固化后的聚二甲基硅氧烷和盖板玻璃放在蒸发腔体中共蒸发镀膜，
c、缓慢降温冷却后取出盖板玻璃，即得超疏水太阳能电池盖板玻璃。
在上述技术方案的基础上，还可以有以下进一步的技术方案：
在所述步骤a中所述固化的条件为：使用聚二甲基硅氧烷胶状物和固化剂的质量比为10:1-2:1，固化温度为300C-1000C，固化时间为10-20小时。
所述步骤b中所述聚二甲基硅氧烷材料质量为5-10g。
在所述步骤b中所述共蒸发腔体温度为200-3000C，共蒸发时间为2-8小时。
在所述步骤c中所述冷却为程序降温，降温时间为1-3小时。
发明优点：
1、本发明利用聚二甲基硅氧烷富含疏水性官能团的特性，使得镀膜后的太阳能电池盖板玻璃具有极强的疏水性，合成方法简单，制备快捷，可大面积工业化制备；所获得的太阳能电池盖板玻璃稳定性强，具有超疏水的特性。
2、本发明所使用的聚二甲基硅氧烷膜层厚度可通过镀膜时间直接调控，膜层本身是一层透明薄膜，透光率高，并不会影响太阳能电池光电转换效率。
具体实施方式：
实施例1：
一种超疏水太阳能电池盖板玻璃的制备方法，其特点在于按如下步骤进行：
a、调节聚二甲基硅氧烷和固化剂的比例为3:1，在烧杯中混合后，置于烘箱中固化，所述的聚二甲基硅氧烷为美国道康宁SYLGARD DC184，固化温度为500C，固化时间为15小时。
b、待烘箱冷却1小时，固化后的聚二甲基硅氧烷温度冷却至250C后，取出固化后的聚二甲基硅氧烷8g。
c、用去离子水清洗3次将太阳能电池盖板玻璃清洗3次后，在500C环境下烘干4小时后，再将其和固化后的聚二甲基硅氧烷一起放入蒸发腔体中，在腔体温度2400C下，非真空的环境中共蒸发时间为6小时镀膜。
d、蒸发腔体缓慢程序降温冷却2小时降至250C后取出盖板玻璃，即得超疏水太阳能电池盖板玻璃。
使用接触角测量仪，对采用实施例1的方法制备所得超疏水太阳能电池盖板玻璃上镀膜层进行检测，检测数据如下：
实施例2：
一种超疏水太阳能电池盖板玻璃的制备方法，其特点在于按如下步骤进行：
a、调节聚二甲基硅氧烷和固化剂的比例为6:1，在烧杯中混合后，置于烘箱中固化，固化温度为800C，固化时间为12小时。
b、待烘箱冷却1.5小时，固化后的聚二甲基硅氧烷温度冷却至250C后，取出固化后的聚二甲基硅氧烷6g。
c、用去离子水清洗2次将太阳能电池盖板玻璃清洗2次后，在300C环境下烘干2小时后，再将其和固化后的聚二甲基硅氧烷一起放入蒸发腔体中，在腔体温度2400C下，非真空的环境中共蒸发时间为8小时镀膜。
d、蒸发腔体缓慢程序降温冷却3小时降至200C后取出盖板玻璃，即得超疏水太阳能电池盖板玻璃。
使用接触角测量仪，对采用实施例2的方法制备所得超疏水太阳能电池盖板玻璃上镀膜层进行检测，检测数据如下：
实施例3：
一种超疏水太阳能电池盖板玻璃的制备方法，其特点在于按如下步骤进行：
a、调节聚二甲基硅氧烷和固化剂的比例为4:1，在烧杯中混合后，置于烘箱中固化，固化温度为600C，固化时间为18小时。
b、待烘箱冷却1小时，固化后的聚二甲基硅氧烷温度冷却至300C后，取出固化后的聚二甲基硅氧烷5g。
c、用去离子水清洗2次将太阳能电池盖板玻璃清洗2次后，在600C环境下烘干2小时后，再将其和固化后的聚二甲基硅氧烷一起放入蒸发腔体中，在腔体温度2000C下，真空的环境中共蒸发时间为3小时镀膜。
d、蒸发腔体缓慢程序降温冷却3小时降至300C后取出盖板玻璃，即得超疏水太阳能电池盖板玻璃。
使用接触角测量仪，对采用实施例3的方法制备所得超疏水太阳能电池盖板玻璃上镀膜层进行检测，检测数据如下：
Claims (5)
1.一种超疏水太阳能电池盖板玻璃的制备方法，其特征在于它按如下步骤进行：
a、将聚二甲基硅氧烷固化，
b、待将固化后的聚二甲基硅氧烷和盖板玻璃放在蒸发腔体中共蒸发镀膜，
c、缓慢降温冷却后取出盖板玻璃，即得超疏水太阳能电池盖板玻璃。
2.根据权利要求1所述的一种超疏水太阳能电池盖板玻璃的制备方法，其特征在于：在所述步骤a中所述固化的条件为：使用聚二甲基硅氧烷胶状物和固化剂的质量比为10:1-2:1，固化温度为300C-1000C，固化时间为10-20小时。
3.根据权利要求1所述的一种超疏水太阳能电池盖板玻璃的制备方法，其特征在于：所述步骤b中所述聚二甲基硅氧烷材料质量为5-10g。
4.根据权利要求1所述的一种超疏水太阳能电池盖板玻璃的制备方法，其特征在于：在所述步骤b中所述共蒸发腔体温度为200-3000C，共蒸发时间为2-8小时。
5.根据权利要求1所述的一种超疏水太阳能电池盖板玻璃的制备方法，其特征在于：在所述步骤c中所述冷却为程序降温，降温时间为1-3小时。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107402459A (zh) * | 2017-05-31 | 2017-11-28 | 中国电子科技集团公司第五十五研究所 | 一种消除液晶显示模块凝露/凝霜的方法及结构 |
| CN107812678A (zh) * | 2017-09-25 | 2018-03-20 | 吉林大学 | 一种在金属上制备无氟超疏水性表面的方法 |
| CN111318053A (zh) * | 2020-02-28 | 2020-06-23 | 广州大学 | 一种超疏水性铝合金滤网及其制备方法与应用 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101955225A (zh) * | 2010-08-13 | 2011-01-26 | 东华大学 | 一种超疏水性nh4v4o14纳米带薄膜的制备方法 |
| CN103302842A (zh) * | 2013-05-27 | 2013-09-18 | 苏州扬清芯片科技有限公司 | 一种聚二甲基硅氧烷薄膜的制作方法 |
| KR20180012386A (ko) * | 2016-07-26 | 2018-02-06 | (재)한국나노기술원 | 진공증착에 의한 나노구조체 패턴 형성방법 및 이를 이용한 센서 소자 |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101955225A (zh) * | 2010-08-13 | 2011-01-26 | 东华大学 | 一种超疏水性nh4v4o14纳米带薄膜的制备方法 |
| CN103302842A (zh) * | 2013-05-27 | 2013-09-18 | 苏州扬清芯片科技有限公司 | 一种聚二甲基硅氧烷薄膜的制作方法 |
| KR20180012386A (ko) * | 2016-07-26 | 2018-02-06 | (재)한국나노기술원 | 진공증착에 의한 나노구조체 패턴 형성방법 및 이를 이용한 센서 소자 |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107402459A (zh) * | 2017-05-31 | 2017-11-28 | 中国电子科技集团公司第五十五研究所 | 一种消除液晶显示模块凝露/凝霜的方法及结构 |
| CN107812678A (zh) * | 2017-09-25 | 2018-03-20 | 吉林大学 | 一种在金属上制备无氟超疏水性表面的方法 |
| CN111318053A (zh) * | 2020-02-28 | 2020-06-23 | 广州大学 | 一种超疏水性铝合金滤网及其制备方法与应用 |
| CN111318053B (zh) * | 2020-02-28 | 2022-02-11 | 广州大学 | 一种超疏水性铝合金滤网及其制备方法与应用 |
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