CN106449999A - Novel environment-friendly wide-spectrum solar cell material - Google Patents
Novel environment-friendly wide-spectrum solar cell material Download PDFInfo
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- CN106449999A CN106449999A CN201610837275.XA CN201610837275A CN106449999A CN 106449999 A CN106449999 A CN 106449999A CN 201610837275 A CN201610837275 A CN 201610837275A CN 106449999 A CN106449999 A CN 106449999A
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Abstract
The invention discloses a novel environment-friendly wide-spectrum solar cell material, which comprises the following raw materials: beta-methylthiophene, 2-amino-5-sulfydryl-1,3,4-thiadiazole, trimethylolpropane, an epoxy silane coupling agent, a maleic anhydride-grafted compatilizer, an acrylic acid-type bridging agent, a platinum catalyst, graphite, carbon black, silicon carbide, aluminum nitride, silicon nitride, aluminum oxide, silicon dioxide, diatomite, a carbon fiber, a quartz glass layer, hydroxyethylcellulose, dibasic lead phosphite, an acrylate regulator, glycidoxypropyl trimethoxysilane, 701 powder, polymeric aluminum, ethylene propylene rubber, sebacic acid bis-(2,2,6,6-tetramethyl-4-piperidine ester), dibasic lead stearate, 2-hydroxy-4-methoxybenzophenone and ammonium polyphosphate. According to the solar cell material disclosed by the invention, energy including an ultraviolet band and an infrared band in the sunlight can be effectively utilized; and the photoelectric conversion efficiency, the carrier transmission efficiency and the carrier mobility are improved.
Description
Technical field
The invention belongs to battery material preparing technical field is and in particular to a kind of novel environment friendly wide spectrum solaode material
Material.
Background technology
The energy of shortage has had a strong impact on the life of people and the development of restriction society.Abundant solar energy is important clear
The clean energy, is the energy that inexhaustible, nexhaustible, pollution-free, the cheap, mankind can freely utilize.The first oil crisis
Afterwards, various countries competitively carry out the applied research of the cleanings such as solar energy, water energy, wind energy and regenerative resource, especially solar energy
Applied research is the most extensive.
Solar energy does not have any nonstaining property as a kind of green energy resource to environment, and its source simple it may be said that
It is that it is inexhaustible in the existence time limit of the mankind.Solar energy is not only the disposable energy, or cleaning energy
Source, its aboundresources, generally existing, need not transport, also can freely using, above all there is no any pollution to environment.Too
Sun energy battery is also because the particularity of solar energy has the advantages that not available for other generation modes many：Without geographical restrictions, no
Consume fuel, scale is changeable, motility is big, pollution-free, noiselessness, safe and reliable, the construction period is short, maintenance is simple,
There is the probability of large-scale application.So a lot of experts go solar energy to exploitation as the alternative energy it is desirable to too
Sun can be brought benefit to the mankind.Nowadays the solar energy being used have greatly by solar cell conversion get.Because
Solaode has sensing to light, the luminous energy being radiated at its surface can be converted to electric energy.At present, exerting in relevant expert
Under power, solaode oneself through having moved towards commercialization and industrialization.
The most crucial part of solaode is the p-n junction being made up of quasiconductor.Solar irradiation on semiconductor p-n junctions,
Form hole-electron pair, in the presence of p-n junction internal electric field, hole flows to n area by p area, and electronics flows to p area by n area, connect
It is formed for electric current after circuit.Because quasiconductor has certain bandwidth, solaode can only be by close to quasiconductor bandwidth, energy
Photon for hv is effectively converted into electric energy.The photon that energy is less than bandwidth cannot be absorbed by battery, and energy is more than bandwidth
Photon then only has part energy to be utilized by battery, and the part beyond bandwidth is converted into heat by the interaction such as electronics-phonon
Can be thus leading to energy loss.More than the 99% of solar radiation spectrum is in wavelength 150-4000nm, wherein about 50% sunlight
For visible ray, remaining is ultraviolet light or infrared light.By the semi-conducting material difference being used, outside different solaodes
Portion's quantum efficiency is substantially different.But for fixing semi-conducting material, solaode all only sun to specific band
Light carries out effectively utilizes.Even the current wider unijunction silica-based solar cell of spectral response range also can only utilize visible ray
The energy in area, therefore how effectively utilizes sunlight includes ultraviolet and infrared band in interior wide spectrum energy is the current sun
An important problem in energy battery research.
Content of the invention
The present invention provides a kind of novel environment friendly wide spectrum solar cell material, only to solve existing solar cell material
Effectively utilizes are carried out to the sunlight of specific band, and ultraviolet and infrared band cannot be included interior by effectively utilizes sunlight
Wide spectrum energy, leads to photoelectric transformation efficiency, carrier transmission efficiency and the low problem of carrier mobility.The present invention's is new
Environmental protection wide spectrum solar cell material has a good electronics bulk property, higher carrier mobility, in 150-
All there is absworption peak in the range of 4000nm, ultraviolet and infrared band can be included in interior wide spectrum energy by effectively utilizes sunlight,
The photoelectric transformation efficiency of solaode can be effectively improved, have broad application prospects.
For solving above technical problem, the present invention employs the following technical solutions：
A kind of novel environment friendly wide spectrum solar cell material, in units of weight, including following raw material：Beta-methyl thiophene 36-
49 parts, 2- amino -5- sulfydryl -1,3,4- thiadiazoles 19-24 parts, trimethylolpropane 4-8 part, epoxy silane class coupling agent 1-2
Part, maleic anhydride grafting compatilizer 1-2 part, acrylic type bridging agent 0.6-1.2 part, platinum catalyst 0.1-0.2 part, graphite 15-
24 parts, white carbon black 18-28 part, carborundum 3-7 part, aluminium nitride 5-10 part, silicon nitride 6-12 part, aluminium sesquioxide 7-9 part, titanium dioxide
Silicon 4-8 part, kieselguhr 3-6 part, carbon fiber 4-7 part, quartz glass fibre 3-5 part, hydroxyethyl cellulose 5-9 part, two alkali formulas are sub-
Lead phosphate 0.6-1.2 part, esters of acrylic acid regulator 0.5-0.9 part, glycidoxy-propyltrimethoxy silane 2-4 part, 701 powder
0.8-1.6 part, aluminium polychlorid 0.7-1.4 part, EP rubbers 1.2-1.6 part, decanedioic acid are double（2,2,6,6- tetramethyl -4- piperazines
Pyridine ester）3-10 part, dibasic lead stearate 2-6 part, ESCALOL 567 3-5 part, APP 2-4 part；
The preparation method of described novel environment friendly wide spectrum solar cell material, comprises the following steps：
S1：By Beta-methyl thiophene, 2- amino -5- sulfydryl -1,3,4- thiadiazoles, trimethylolpropane, epoxy silane class coupling agent,
Maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, are 200-300W in microwave power, temperature
For 240-280 DEG C, rotating speed is to stir 2-4h, prepared mixture A under 400-600r/min；
S2：By graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, kieselguhr, carbon fiber, stone
English glass fibre, hydroxyethyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy
Silane, 701 powder, aluminium polychlorid, EP rubbers mixing, are 250-360W in microwave power, temperature is 82-90 DEG C, rotating speed is
1-2h, prepared mixture B is stirred under 500-700r/min；
S3：The mixture B that step S2 is obtained is added in the mixture A that step S1 is obtained, in adition process, with 90-120r/
The rotating speed stirring of min, control charging rate is 12-14g/min, after charging terminates, is heated up with the heating rate of 12-16 DEG C/min
To 720-750 DEG C, mixing speed improves to 700-800r/min, and stirs 1.5-2.5h under microwave power is for 150-240W,
Prepared mixture C；
S4：Add decanedioic acid double in the mixture C being obtained to step S3（2,2,6,6- tetramethyl -4- piperidine esters）, dibasic hard
Fat acid lead, ESCALOL 567, APP, are 216-285 DEG C in temperature, and rotating speed is 300-400r/min
Lower stirring 1-1.5h, is cooled to room temperature, prepared novel environment friendly wide spectrum solar cell material.
Preferably, microwave power described in step S1 is 250-300W, and temperature is 260-280 DEG C, and rotating speed is 500-600r/
2-3h is stirred under min.
It is highly preferred that described microwave power is 300W, temperature is 280 DEG C, and rotating speed is to stir 2h under 600r/min.
Preferably, microwave power described in step S2 is 300-360W, and temperature is 85-90 DEG C, and rotating speed is 600-700r/
1-1.5h is stirred under min.
It is highly preferred that described microwave power is 360W, temperature is 90 DEG C, and rotating speed is to stir 1h under 700r/min.
Preferably, microwave power described in step S3 is to stir 1.5-2h under 200-240W.
It is highly preferred that described microwave power is to stir 1.5h under 240W.
Preferably, temperature described in step S4 is 250-285 DEG C, and rotating speed is to stir 1-1.2h under 350-400r/min.
It is highly preferred that described temperature is 285 DEG C, rotating speed is to stir 1h under 400r/min.
The invention has the advantages that：
（1）The novel environment friendly wide spectrum solar cell material of the present invention has a good electronics bulk property, higher current-carrying
Transport factor, all has absworption peak, energy effectively utilizes sunlight includes ultraviolet and infrared band exists in the range of 150-4000nm
Interior wide spectrum energy, can effectively improve the photoelectric transformation efficiency of solaode, have broad application prospects；
（2）The novel environment friendly wide spectrum solar cell material environmental protection that the present invention is obtained, preparation cost are low.
Specific embodiment
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the present invention's
Protection domain, but do not limit the scope of the invention.
In an embodiment, described novel environment friendly wide spectrum solar cell material, in units of weight, including following former
Material：Beta-methyl thiophene 36-49 part, 2- amino -5- sulfydryl -1,3,4- thiadiazoles 19-24 parts, trimethylolpropane 4-8 part, epoxy
Silane coupling agent 1-2 part, maleic anhydride grafting compatilizer 1-2 part, acrylic type bridging agent 0.6-1.2 part, platinum catalyst
0.1-0.2 part, graphite 15-24 part, white carbon black 18-28 part, carborundum 3-7 part, aluminium nitride 5-10 part, silicon nitride 6-12 part, three oxygen
Change two aluminum 7-9 parts, silicon dioxide 4-8 part, kieselguhr 3-6 part, carbon fiber 4-7 part, quartz glass fibre 3-5 part, ethoxy fibre
The plain 5-9 part of dimension, dibasic lead phosphite 0.6-1.2 part, esters of acrylic acid regulator 0.5-0.9 part, epoxypropoxy front three
TMOS 2-4 part, 701 powder 0.8-1.6 parts, aluminium polychlorid 0.7-1.4 part, EP rubbers 1.2-1.6 part, decanedioic acid are double
（2,2,6,6- tetramethyl -4- piperidine esters）3-10 part, dibasic lead stearate 2-6 part, ESCALOL 567 3-
5 parts, APP 2-4 part；
The preparation method of described novel environment friendly wide spectrum solar cell material, comprises the following steps：
S1：By Beta-methyl thiophene, 2- amino -5- sulfydryl -1,3,4- thiadiazoles, trimethylolpropane, epoxy silane class coupling agent,
Maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, are 200-300W in microwave power, temperature
For 240-280 DEG C, rotating speed is to stir 2-4h, prepared mixture A under 400-600r/min；
S2：By graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, kieselguhr, carbon fiber, stone
English glass fibre, hydroxyethyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy
Silane, 701 powder, aluminium polychlorid, EP rubbers mixing, are 250-360W in microwave power, temperature is 82-90 DEG C, rotating speed is
1-2h, prepared mixture B is stirred under 500-700r/min；
S3：The mixture B that step S2 is obtained is added in the mixture A that step S1 is obtained, in adition process, with 90-120r/
The rotating speed stirring of min, control charging rate is 12-14g/min, after charging terminates, is heated up with the heating rate of 12-16 DEG C/min
To 720-750 DEG C, mixing speed improves to 700-800r/min, and stirs 1.5-2.5h under microwave power is for 150-240W,
Prepared mixture C；
S4：Add decanedioic acid double in the mixture C being obtained to step S3（2,2,6,6- tetramethyl -4- piperidine esters）, dibasic hard
Fat acid lead, ESCALOL 567, APP, are 216-285 DEG C in temperature, and rotating speed is 300-400r/min
Lower stirring 1-1.5h, is cooled to room temperature, prepared novel environment friendly wide spectrum solar cell material.
Embodiment 1
A kind of novel environment friendly wide spectrum solar cell material, in units of weight, including following raw material：Beta-methyl thiophene 42
Part, 2- amino -5- sulfydryl -1,3,4- 22 parts of thiadiazoles, 6 parts of trimethylolpropane, 1.5 parts of epoxy silane class coupling agent, Malaysia
Anhydride 1.5 parts of compatilizer of grafting, 0.9 part of acrylic type bridging agent, 0.1 part of platinum catalyst, 20 parts of graphite, 24 parts of white carbon black, carbonization
5 parts of silicon, 8 parts of aluminium nitride, 9 parts of silicon nitride, 8 parts of aluminium sesquioxide, 6 parts of silicon dioxide, 5 parts of kieselguhr, 6 parts of carbon fiber, quartz
4 parts of glass fibre, 7 parts of hydroxyethyl cellulose, 0.9 part of dibasic lead phosphite, 0.7 part of esters of acrylic acid regulator, epoxy third
3 parts of oxygen propyl trimethoxy silicane, 1.2 parts of 701 powder, 1 part of aluminium polychlorid, 1.4 parts of EP rubbers, decanedioic acid are double（2,2,6,
6- tetramethyl -4- piperidine ester）7 parts, 4 parts of dibasic lead stearate, 4 parts of ESCALOL 567, APP 3
Part；
The preparation method of described novel environment friendly wide spectrum solar cell material, comprises the following steps：
S1：By Beta-methyl thiophene, 2- amino -5- sulfydryl -1,3,4- thiadiazoles, trimethylolpropane, epoxy silane class coupling agent,
Maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, are 250W in microwave power, and temperature is 260
DEG C, rotating speed is to stir 3h, prepared mixture A under 500r/min；
S2：By graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, kieselguhr, carbon fiber, stone
English glass fibre, hydroxyethyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy
Silane, 701 powder, aluminium polychlorid, EP rubbers mixing, are 300W in microwave power, temperature is 85 DEG C, and rotating speed is 600r/min
Lower stirring 1.5h, prepared mixture B；
S3：The mixture B that step S2 is obtained is added in the mixture A that step S1 is obtained, in adition process, with 100r/min
Rotating speed stirring, controls charging rate be 13g/min, feed terminate after, be warming up to 740 DEG C with the heating rate of 14 DEG C/min,
Mixing speed improves to 750r/min, and stirs 2h, prepared mixture C under microwave power is for 200W；
S4：Add decanedioic acid double in the mixture C being obtained to step S3（2,2,6,6- tetramethyl -4- piperidine esters）, dibasic hard
Fat acid lead, ESCALOL 567, APP, are 250 DEG C in temperature, and rotating speed is to stir under 350r/min
1.2h, is cooled to room temperature, prepared novel environment friendly wide spectrum solar cell material.
Embodiment 2
A kind of novel environment friendly wide spectrum solar cell material, in units of weight, including following raw material：Beta-methyl thiophene 36
Part, 2- amino -5- sulfydryl -1,3,4- 19 parts of thiadiazoles, 4 parts of trimethylolpropane, 1 part of epoxy silane class coupling agent, maleic acid
Acid anhydride 1 part of compatilizer of grafting, 0.6 part of acrylic type bridging agent, 0.1 part of platinum catalyst, 15 parts of graphite, 18 parts of white carbon black, carborundum 3
Part, 5 parts of aluminium nitride, 6 parts of silicon nitride, 7 parts of aluminium sesquioxide, 4 parts of silicon dioxide, 3 parts of kieselguhr, 4 parts of carbon fiber, quartz glass
3 parts of fiber, 5 parts of hydroxyethyl cellulose, 0.6 part of dibasic lead phosphite, 0.5 part of esters of acrylic acid regulator, epoxy the third oxygen third
2 parts of base trimethoxy silane, 0.8 part of 701 powder, 0.7 part of aluminium polychlorid, 1.2 parts of EP rubbers, decanedioic acid are double（2,2,6,6-
Tetramethyl -4- piperidine ester）3 parts, 2 parts of dibasic lead stearate, 3 parts of ESCALOL 567,2 parts of APP；
The preparation method of described novel environment friendly wide spectrum solar cell material, comprises the following steps：
S1：By Beta-methyl thiophene, 2- amino -5- sulfydryl -1,3,4- thiadiazoles, trimethylolpropane, epoxy silane class coupling agent,
Maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, are 200W in microwave power, and temperature is 240
DEG C, rotating speed is to stir 4h, prepared mixture A under 400r/min；
S2：By graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, kieselguhr, carbon fiber, stone
English glass fibre, hydroxyethyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy
Silane, 701 powder, aluminium polychlorid, EP rubbers mixing, are 250W in microwave power, temperature is 82 DEG C, and rotating speed is 500r/min
Lower stirring 2h, prepared mixture B；
S3：The mixture B that step S2 is obtained is added in the mixture A that step S1 is obtained, in adition process, with 90r/min
Rotating speed stirring, controls charging rate be 12g/min, feed terminate after, be warming up to 720 DEG C with the heating rate of 12 DEG C/min,
Mixing speed improves to 700r/min, and stirs 2.5h, prepared mixture C under microwave power is for 150W；
S4：Add decanedioic acid double in the mixture C being obtained to step S3（2,2,6,6- tetramethyl -4- piperidine esters）, dibasic hard
Fat acid lead, ESCALOL 567, APP, are 216 DEG C in temperature, and rotating speed is to stir under 300r/min
1.5h, is cooled to room temperature, prepared novel environment friendly wide spectrum solar cell material.
Embodiment 3
A kind of novel environment friendly wide spectrum solar cell material, in units of weight, including following raw material：Beta-methyl thiophene 49
Part, 2- amino -5- sulfydryl -1,3,4- 24 parts of thiadiazoles, 8 parts of trimethylolpropane, 2 parts of epoxy silane class coupling agent, maleic acid
Acid anhydride 2 parts of compatilizer of grafting, 1.2 parts of acrylic type bridging agent, 0.2 part of platinum catalyst, 24 parts of graphite, 28 parts of white carbon black, carborundum 7
Part, 10 parts of aluminium nitride, 12 parts of silicon nitride, 9 parts of aluminium sesquioxide, 8 parts of silicon dioxide, 6 parts of kieselguhr, 7 parts of carbon fiber, quartzy glass
5 parts of glass fiber, 9 parts of hydroxyethyl cellulose, 1.2 parts of dibasic lead phosphite, 0.9 part of esters of acrylic acid regulator, epoxy third oxygen
4 parts of propyl trimethoxy silicane, 1.6 parts of 701 powder, 1.4 parts of aluminium polychlorid, 1.6 parts of EP rubbers, decanedioic acid are double（2,2,6,
6- tetramethyl -4- piperidine ester）10 parts, 6 parts of dibasic lead stearate, 5 parts of ESCALOL 567, APP 4
Part；
The preparation method of described novel environment friendly wide spectrum solar cell material, comprises the following steps：
S1：By Beta-methyl thiophene, 2- amino -5- sulfydryl -1,3,4- thiadiazoles, trimethylolpropane, epoxy silane class coupling agent,
Maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, are 300W in microwave power, and temperature is 280
DEG C, rotating speed is to stir 2h, prepared mixture A under 600r/min；
S2：By graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, kieselguhr, carbon fiber, stone
English glass fibre, hydroxyethyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy
Silane, 701 powder, aluminium polychlorid, EP rubbers mixing, are 360W in microwave power, temperature is 90 DEG C, and rotating speed is 700r/min
Lower stirring 1h, prepared mixture B；
S3：The mixture B that step S2 is obtained is added in the mixture A that step S1 is obtained, in adition process, with 120r/min
Rotating speed stirring, controls charging rate be 14g/min, feed terminate after, be warming up to 750 DEG C with the heating rate of 16 DEG C/min,
Mixing speed improves to 800r/min, and stirs 1.5h, prepared mixture C under microwave power is for 240W；
S4：Add decanedioic acid double in the mixture C being obtained to step S3（2,2,6,6- tetramethyl -4- piperidine esters）, dibasic hard
Fat acid lead, ESCALOL 567, APP, are 285 DEG C in temperature, and rotating speed is to stir 1h under 400r/min,
It is cooled to room temperature, prepared novel environment friendly wide spectrum solar cell material.
The novel environment friendly wide spectrum solar cell material that embodiment 1-3 is obtained is applied to organic photovoltaic solar-electricity
Chi Shang, investigates its device photoelectric conversion efficiency, carrier transmission efficiency and carrier mobility, and result is as shown in the table.
As seen from the above table, the novel environment friendly wide spectrum solar cell material of the present invention has good electronics accumulation property
Can, higher carrier mobility, the photoelectric transformation efficiency of solaode can be effectively improved, have broad application prospects.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanations, the affiliated technology neck for the present invention
For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made,
The scope of patent protection that the present invention is determined all should be considered as belonging to by the claims submitted to.
Claims (9)
1. a kind of novel environment friendly wide spectrum solar cell material is it is characterised in that in units of weight, including following raw material：
Beta-methyl thiophene 36-49 part, 2- amino -5- sulfydryl -1,3,4- thiadiazoles 19-24 parts, trimethylolpropane 4-8 part, epoxy silicon
Alkanes coupling agent 1-2 part, maleic anhydride grafting compatilizer 1-2 part, acrylic type bridging agent 0.6-1.2 part, platinum catalyst 0.1-
0.2 part, graphite 15-24 part, white carbon black 18-28 part, carborundum 3-7 part, aluminium nitride 5-10 part, silicon nitride 6-12 part, three oxidation two
Aluminum 7-9 part, silicon dioxide 4-8 part, kieselguhr 3-6 part, carbon fiber 4-7 part, quartz glass fibre 3-5 part, hydroxyethyl cellulose
5-9 part, dibasic lead phosphite 0.6-1.2 part, esters of acrylic acid regulator 0.5-0.9 part, glycidoxypropyl trimethoxy
Silane 2-4 part, 701 powder 0.8-1.6 parts, aluminium polychlorid 0.7-1.4 part, EP rubbers 1.2-1.6 part, decanedioic acid are double（2,2,
6,6- tetramethyl -4- piperidine esters）3-10 part, dibasic lead stearate 2-6 part, ESCALOL 567 3-5 part,
APP 2-4 part；
The preparation method of described novel environment friendly wide spectrum solar cell material, comprises the following steps：
S1：By Beta-methyl thiophene, 2- amino -5- sulfydryl -1,3,4- thiadiazoles, trimethylolpropane, epoxy silane class coupling agent,
Maleic anhydride grafting compatilizer, acrylic type bridging agent, platinum catalyst mix homogeneously, are 200-300W in microwave power, temperature
For 240-280 DEG C, rotating speed is to stir 2-4h, prepared mixture A under 400-600r/min；
S2：By graphite, white carbon black, carborundum, aluminium nitride, silicon nitride, aluminium sesquioxide, silicon dioxide, kieselguhr, carbon fiber, stone
English glass fibre, hydroxyethyl cellulose, dibasic lead phosphite, esters of acrylic acid regulator, glycidoxypropyl trimethoxy
Silane, 701 powder, aluminium polychlorid, EP rubbers mixing, are 250-360W in microwave power, temperature is 82-90 DEG C, rotating speed is
1-2h, prepared mixture B is stirred under 500-700r/min；
S3：The mixture B that step S2 is obtained is added in the mixture A that step S1 is obtained, in adition process, with 90-120r/
The rotating speed stirring of min, control charging rate is 12-14g/min, after charging terminates, is heated up with the heating rate of 12-16 DEG C/min
To 720-750 DEG C, mixing speed improves to 700-800r/min, and stirs 1.5-2.5h under microwave power is for 150-240W,
Prepared mixture C；
S4：Add decanedioic acid double in the mixture C being obtained to step S3（2,2,6,6- tetramethyl -4- piperidine esters）, dibasic hard
Fat acid lead, ESCALOL 567, APP, are 216-285 DEG C in temperature, and rotating speed is 300-400r/min
Lower stirring 1-1.5h, is cooled to room temperature, prepared novel environment friendly wide spectrum solar cell material.
2. novel environment friendly wide spectrum solar cell material according to claim 1 is it is characterised in that described in step S1
Microwave power is 250-300W, and temperature is 260-280 DEG C, and rotating speed is to stir 2-3h under 500-600r/min.
3. novel environment friendly wide spectrum solar cell material according to claim 2 is it is characterised in that described microwave power
For 300W, temperature is 280 DEG C, and rotating speed is to stir 2h under 600r/min.
4. novel environment friendly wide spectrum solar cell material according to claim 1 is it is characterised in that described in step S2
Microwave power is 300-360W, and temperature is 85-90 DEG C, and rotating speed is to stir 1-1.5h under 600-700r/min.
5. novel environment friendly wide spectrum solar cell material according to claim 4 is it is characterised in that described microwave power
For 360W, temperature is 90 DEG C, and rotating speed is to stir 1h under 700r/min.
6. novel environment friendly wide spectrum solar cell material according to claim 1 is it is characterised in that described in step S3
Microwave power is to stir 1.5-2h under 200-240W.
7. novel environment friendly wide spectrum solar cell material according to claim 6 is it is characterised in that described microwave power
For stirring 1.5h under 240W.
8. novel environment friendly wide spectrum solar cell material according to claim 1 is it is characterised in that described in step S4
Temperature is 250-285 DEG C, and rotating speed is to stir 1-1.2h under 350-400r/min.
9. novel environment friendly wide spectrum solar cell material according to claim 8 is it is characterised in that described temperature is
285 DEG C, rotating speed is to stir 1h under 400r/min.
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